Chemical Formulas
and Equations
3.1 Molecular/Formula Weights
3.2 The Mole Concept
3.3 Mass Percentages
3.4 Elemental Analysis
3.5 Determining Formulas
1-octanol
Sulfur
Mercury(II)
Iodide
Methanol
100.0 g Fe
moles Fe
55.8 g/mol
1.79 moles of Fe
140 grams of Mg
Or 1.40 x 102 grams of Mg
100.0 g H 2O
moles H 2O
18.0 g/mol
5.56 moles of H 2O
36.5g HCl
1 mole HCl
Moles
Convert to
Atoms
23
6.02
x
10
atoms = 6.0 x 1022 U atoms
0.10 moles U ----------------------1 mole
Moles
Convert to
Grams
238.029 g U
0.10 moles U ----------------------= 24 grams U
1 mole U
Moles
Convert to
Molecules
23
6.02
x
10
molecules = 6.02 x 1023 C H
1.00 mole C3H8 ----------------------------3 8
1 mole
molecules
Moles
Convert to
Grams
44.096 g C3H8
1.00 mole C3H8 ----------------------= 44.1 grams C3H8
1 mole C3H8
Moles Propane
Convert to
atoms of H atoms
23
8
moles
of
H
6.02
x
10
atoms = 4.82 x 1024
1.00 mole C3H8 ------------------- -----------------------1 mole C3H8
1 mole H
H atoms
Grams
Convert to
Grams
Percent Composition
What is the % composition of C6H12O6?
12.011g C
72.066 x100%=40.0% C
6 moles C -------------- = 72.066 g C
180.155
1 mole C
1.0079g H
12 moles H -------------- = 12.0948 g H 12.0948 x100%=6.7% H
180.155
1 mole H
15.999g O
6 moles O -------------- = 95.994g O 95.994 x100%=53.3% O
180.155
1 mole O
180.155
% composition is 40.0% C, 6.7% H, and 53.3% O
Cx HyOz
C HO
1 mol C
68.8 g C
5.73( 3) mol C
12.0 g
1 mol H
5. 0 g C
5.0 mol H
H
1.0 g
1 mol O
26.2 g O
1.63(7 )mol O
16.0 g
C2H4O2
Percent Composition
What is the Empirical Formula if the % composition is 40.0% C,
6.7% H, and 53.3% O?
1 mole C
40.0 g C -------------- = 3.33 moles C 3.33 =1.0 mole C
3.33
12.011g C
1 mole H = 6.64 moles H
6.7 g H -------------1.0079g H
1 mole O
53.3 g O ------------- = 3.33 moles O
15.999g O
= 1.0 mole O
CH2O x 6 = C6H12O6
Calculations with
Chemical Formulas
and Equations
3.6 Molar Interpretation of a
Chemical Equation
3.7 Amounts of Substances in a
Chemical Reaction
3.8 Limiting Reactant, % Yields
Molar Interpretation of a
Chemical Equation
The balanced chemical equation can be interpreted
in numbers of molecules, but generally chemists
interpret equations as mole-to-mole relationships.
For example, the Haber process for producing
ammonia involves the reaction of hydrogen and
nitrogen.
N 2 (g ) 3 H 2 (g ) 2 NH 3 (g )
Molar Interpretation of a
Chemical Equation
This balanced chemical equation shows that
one mole of N2 reacts with 3 moles of H2 to
produce 2 moles of NH3.
N 2 (g)
1 molecule N2
1 mol N 2
3H 2 (g)
3 molecules H2
3 mol H 2
2 NH 3 (g )
2 molecules NH3
2 mol NH 3
N 2 (g) 3H 2 (g) 2 NH 3 (g )
Because the coefficients in the balanced equation
represent mole-to-mole ratios, the calculation is
simple.
2 mol NH 3
4.8 mol H 2
3.2 mol NH 3
3 mol H 2
36.5 g HCl
1 mol MnO 2 4 mol HCl
5.00 g MnO 2
8.40 g HCl
Limiting Reagent
The limiting reactant (or
limiting reagent) is the
reactant that is entirely
consumed when the
reaction goes to
completion. The limiting
reagent ultimately
determines how much
product can be obtained.
For example, bicycles
require one frame and
two wheels. If you have
20 wheels but only 5
frames, it is clear that the
number of frames will
determine how many
bicycles can be made.
Limiting Reagent
Zinc metal reacts with hydrochloric acid by
the following reaction.
Limiting Reagent
Take each reactant in turn and ask how much
product would be obtained if each were totally
consumed. The reactant that gives the
smaller amount is the limiting reagent.
1 mol H 2
0.30 mol Zn
0.30 mol H 2
1 mol Zn
1 mol H 2
0.52 mol HCl
0.26 mol H 2
2 mol HCl
Since HCl is the limiting reagent, the amount of H2
produced must be 0.26 mol.
actual yield
%Yield
100%
theoretical yield
0.22 g H 2
%Yield
100% 42%
0.52 g H 2
H2 + I 2
2HI
2.00 g
254 g HI
C3 H8
2.19 g
CO2