Review: Q in a CSTR
CSTR with a heat exchanger, perfectly mixed inside and outside of reactor
FA0
& UA(T T)
Q Ta
a Ta
T, X
T, X
The heat flow to the reactor is in terms of:
Overall heat-transfer coefficient, U
Heat-exchange area, A
Difference between the ambient temperature in the heat jacket, Ta, and
rxn temperature, T
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-5
&
dQ Heat transfer to a perfectly mixed PFR in a jacket
Ua(Ta - T)
dV For a tubular reactor of diameter D, a = 4 / D
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
Relating HRX(T) to HRX(TR) and
L12-7
n T
& W
0Q & F C dT Ho ( T ) T C dT F X
s A0 i p,i RX R TR P A0 A
i1Ti0
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-9
Rearrange:
n
FA0 iCp,i T Ti0 Q s RX R
T T F X
& Ho (T ) C
& W
P R A0 A
i1
Which term in this equation is zero because were solving for an adiabatic
reaction?
a) dEsys/dt
b) Q&
c)
d) FA0 is adiabatic (Q=0):
When the reaction
n e) None of the above
FA0 iCp,i T Ti0 Q s RX R
T T F X
& Ho (T ) C
& W
P R A0 A
i1
n
FA0 iCp,i T Ti0 0 W RX R
T T F X
& Ho (T ) C
s P R A0 A
i1
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-10
Rearrange:
n
FA0 iCp,i T Ti0 Q s RX R
T T F X
& Ho (T ) C
& W
P R A0 A
i1
When shaft work can be neglected (=0) and the reaction is adiabatic (Q=0):
n
FA0 iCp,i T Ti0 0 0 HoRX (TR ) C
T T F X
i1
P R A0 A
n
Solve for XA: FA0 iCp,i T Ti0
i1 XA
HoRX (TR ) C
P T TR FA0
n Solve this eq simultaneously
iCp,i T Ti0 with design equation
i1 XA Design eqs do not change,
HoRX (TR ) C
P T TR except k will be a function of T
T = reaction temp Ti0 = initial (feed) temperature TR= reference temp
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-11
n
& W
Q & F C%( T T ) F X Ho ( T ) C ( T T ) 0
s A0 i pi i0 A0 RX R p R
i1
n
% (T T )
iCpi i0
Q 0
X i1
W 0
o
HRX (T T )
(TR ) C Xenergy balance s
p R
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-12
Nonisothermal CSTR
FA0 X
Design equation (From mass balance) : V
rA
Energy balance: Coupled
n
& & % (T T ) F X Ho (T ) C
Q Ws FA0 iC (T T ) 0
pi i0 A0 RX R p R
i1
With the exception of processes involving highly viscous materials,
the work done by the stirrer can be neglected (i.e. W s 0 )
With heat exchanger: Q & UA(T T)
a
n
% (T T ) F X Ho (T ) C
UA(Ta T) 0 FA0 iC (T T ) 0
pi i0 A0 RX R p R
i1
n
% (T T ) F X Ho (T ) C (T T )
UA(Ta T) FA0 iCpi i0 A0 RX R p R
i1
UA(Ta T) n %
iCpi (T Ti0 ) X HRX
o (T T )
(TR ) C
FA0 i1
p R
UA(Ta T) o
n
% (T T )
X HRX (TR ) Cp ( T TR ) iC
FA0 i1 pi i0
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-13
Application to CSTR
Case 1: Given FA0, CA0, A, E, Cpi, HI, and XA, calculate T & V
T Texit
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-14
XA
T
distance
Negligible shaft work (S=0) and adiabatic (Q=0)
Given A, E, T0, 0, CA0, and FA0, find the reactor volume that produces a
conversion XA. The heat capacities of A & B are approximately equal, & S=0.
a) Solve TEB for T: n
0Q & F C T T Ho (T ) C T T F X
& W
s A0
i1
i p,i i0 RX R P R A0 A
n 0 0
FA0 iCp,i T Ti0 HoRX (TR ) CP T TR FA0 X A
i1
n
iCp,i T Ti0 HoRX (TR ) CP T TR X A Multiply out
i1
n
iCp,iT iCp,iTi0 HoRX (TR )X A CP TX A CPTR X A Isolate T
i1
n n
iCp,iT CP TX A HoRX (TR )X A CPTR X A iCp,iTi0
i1 i1
n
Factor out T T iCp,i CP X A HoRX (TR )X A CPTR X A Cp,A TA0
i1
Temp when n Plug in values (Cp,
o
specified H RX (TR )X A CPTR X A iCp,iTi0 H (T ), C ) given
XA is T i1 RX R p,i
n in problem statement
reached
iCp,i CP X A (look them up if
i1
necessary) & solve
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
A first order reaction A(l) B(l) is to be carried out adiabatically in a CSTR.
L12-16
Given A, E, T0, 0, CA0, and FA0, find the reactor volume that produces a
conversion XA. The heat capacities of A & B are approximately equal, & S=0.
a) Solve TEB for T of reaction when the specified XA is reached:
n
HoRX (TR )X A CPTR X A iCp,iTi0
T i1
n
iCp,i CP X A
i1
b) Calculate k = Ae-E/RT where T was calculated in step (a)
Look up E in a thermo book
c) Plug the k calculated for the reactions temperature when the specified X A
is reached (in step b) into the design equation to calculate V CSTR
FA0 X A FA0 X A FA0 X A C A00 X A
V V V V
rA kC A kC A0 1 X A kC A0 1 X A
0 X A
V
k 1 XA
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-17
Now, the first order reaction A(l) B(l) is carried out adiabatically with and
inlet temp of 300 K, CPA = 50 cal/molK, and the heat of reaction = -20,000
cal/mol. Assume S=0. The energy balance is:
n 0 0
FA0 iCp,i T Ti0 W
& Q
s
&
XA i 1 HRX T Ho
RX (TR ) C TT
P R
HoRX (TR ) C T T F
P R A0
n
% TT
iC n
i1
pi 0 iCpi 1 Cp A CP T T0
XEB i1 XEB A
HRX T HRX T
From thermodynamics
XEB 50 T 300
XEB
20000
T
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-18 in
The irreversible, elementary liquid-phase reaction 2A B is carried out adiabatically
a flow reactor with S=0 and without a pressure drop. The feed contains equal molar
amounts of A and an inert liquid (I). The feed enters the reactor at 294 K with 0 = 5
dm3/s and CA0= 1 mol/dm3. What would be the temperature inside of a steady-state
CSTR that achieved XA= 0.8? Extra info:
E = 10,000 cal/mol CpA= 15 cal/molK CpB= 30 cal/molK CpI = 15 cal/molK
HA(TR) = -20 kcal/mol HB(TR) = -50 kcal/mol HI(TR) = -15 kcal/mol
n
Start with SS EB & solve for T: 0 Q Ws FA0 iCp,i T Ti0 HRX (T)FA0 X A
k = 0.02 dm3/mols at 350 K & &
i1
n
0 0 0 FA0 iCp,i T Ti0 HRX (T)FA0 XA
i1
n
FA0 iCp,i T Ti0 HoRX TR CP T TR FA0 X A
i1
n
iCp,i T Ti0 HoRX (TR ) CP T TR X A Multiply out brackets & bring
i1
terms containing T to 1 side
n n
iCp,i T CP TX A HoRX (TR )X A CP TR X A iCp,iTi0
i1 i1
n
HoRX (TR )X A CP TR X A iCp,iTi0
T i1
n
iCp,i CP X A
i1
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-19 in
The irreversible, elementary liquid-phase reaction 2A B is carried out adiabatically
a flow reactor with S=0 and without a pressure drop. The feed contains equal molar
amounts of A and an inert liquid (I). The feed enters the reactor at 294 K with 0 = 5
dm3/s and CA0= 1 mol/dm3. What would be the temperature inside of a steady-state
CSTR that achieved XA= 0.8? Extra info:
E = 10,000 cal/mol CpA= 15 cal/molK CpB= 30 cal/molK CpI = 15 cal/molK
HA(TR) = -20 kcal/mol HB(TR) = -50 kcal/mol HI(TR) = -15 kcal/mol
n
k = 0.02 dm3/mols at 350 K o
H (T )X C T X C T
RX R A P R A i p,i i0
T i1
Start with SS EB & solve for T: n
iCp,i CP X A
i1
b 1 cal cal C 0
Cp Cp Cp Cp 30 15 p
a B A 2 molgK molgK
n cal cal cal
A 1 B 0 I 1 iCp,i = 1 15 + 1 15 30
i1 mo l gK mo lgK molgK
d c b
HoRX TR HoD TR HoC TR HoB TR HoA TR
a a a
cal
1
HoRX TR 50,000
2
cal
mol
cal o
20,000 H RX TR 5000
m ol mol
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-20 in
The irreversible, elementary liquid-phase reaction 2A B is carried out adiabatically
a flow reactor with S=0 and without a pressure drop. The feed contains equal molar
amounts of A and an inert liquid (I). The feed enters the reactor at 294 K with 0 = 5
dm3/s and CA0= 1 mol/dm3. What would be the temperature inside of a steady-state
CSTR that achieved XA= 0.8? Extra info:
E = 10,000 cal/mol CpA= 15 cal/molK CpB= 30 cal/molK CpI = 15 cal/molK
HA(TR) = -20 kcal/mol HB(TR) = -50 kcal/mol HI(TR) = -15 kcal/mol n
o
k = 0.02 dm3/mols at 350 K H RX (TR )X A CP TR X A iCp,iTi0
i1
Start with SS EB & solve for T: T n
iCp,i CP X A
i1
n cal cal
Cp 0 iCp,i 30
i1 molgK
HoRX TR 5000
mol
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-21 in
The irreversible, elementary liquid-phase reaction 2A B is carried out adiabatically
a flow reactor with S=0 and without a pressure drop. The feed contains equal molar
amounts of A and an inert liquid (I). The feed enters the reactor at 294 K with 0 = 5
dm3/s and CA0= 1 mol/dm3. What would be volume of the steady-state CSTR that
achieves XA= 0.8? Extra info:
E = 10,000 cal/mol CpA= 15 cal/molK CpB= 30 cal/molK CpI = 15 cal/molK
HA(TR) = -20 kcal/mol HB(TR) = -50 kcal/mol HI(TR) = -15 kcal/mol
k = 0.02 dm3/mols at 350 K
FA 0 X A
Solve the CSTR design eq for V at XA = 0.8 & T = 427.3K: VCSTR
-rA
CA0 0 X A
rA kCA Stoichiometry : C A C A 0 1 X A Combine : VCSTR
2
k C A0 2 1 X A
2
dm3 dm3
k 0.02 exp 2.60124 k 0.2696
mol s mol s
dm3
5 0.8
VCSTR s V 370.9dm 3
CSTR
dm3 mol
2
0.2696 1 1 0.8
mol s dm3
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-22 in
The irreversible, elementary liquid-phase reaction 2A B is carried out adiabatically
a flow reactor with S=0 and without a pressure drop. The feed contains equal molar
amounts of A and an inert liquid (I). The feed enters the reactor at 294 K with 0 = 5
dm3/s and CA0= 1 mol/dm3. Use the 2-point rule to numerically calculate the PFR
volume required to achieve XA=0.8? Extra info:
E = 10,000 cal/mol CpA= 15 cal/molK CpB= 30 cal/molK CpI = 15 cal/molK
HA(TR) = -20 kcal/mol HB(TR) = -50 kcal/mol HI(TR) = -15 kcal/mol
k= 0.02
Usedmthe /mols
3
energyatbalance
350 K to construct table of T as a function of X
A
For each XA , calculate k, -rA and FA0/-rA
Use numeric evaluation to calculate VPFR
XA T(K) k(dm3/mols) -rA(mol/dm3s) FA0/-rA(dm3)
0 294* 0.00129 0.00129
0.8 427.3* 0.2696* 0.010784
*Calculated in CSTR portion of this problem
dm3 1 1 dm3
k 0.02 exp 5032.7126K k 0.00129
mol s 350K 294 mol s
dm3 mol2 mol
rA k CA 0 1 X A rA XA 0 0.00129
2 2
2
1 1 0 rA X A 0 0.00129
mol s dm6 dm3 gs
dm3 mol2 mol
2
rA X 0.8 0.2696 1 1 0.8 r A XA 0.8 0.010784
A
mol s dm6 dm3 gs
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-23 in
The irreversible, elementary liquid-phase reaction 2A B is carried out adiabatically
a flow reactor with S=0 and without a pressure drop. The feed contains equal molar
amounts of A and an inert liquid (I). The feed enters the reactor at 294 K with 0 = 5
dm3/s and CA0= 1 mol/dm3. Use the 2-point rule to numerically calculate the PFR
volume required to achieve XA=0.8? Extra info:
E = 10,000 cal/mol CpA= 15 cal/molK CpB= 30 cal/molK CpI = 15 cal/molK
HA(TR) = -20 kcal/mol HB(TR) = -50 kcal/mol HI(TR) = -15 kcal/mol
k= 0.02
Usedmthe /mols
3
energyatbalance
350 K to construct table of T as a function of X
A
For each XA , calculate k, -rA and FA0/-rA
Use numeric evaluation to calculate VPFR
XA T(K) k(dm3/mols) -rA(mol/dm3s) FA0/-rA(dm3)
0 294 0.00129 0.00129 3876
0.8 427.3 0.2696 0.010784 463.6
mol mol
FA0 5 FA0 5
s 3876 dm3 s 463.6 dm3
mol mol
r
A X 0 0.00129 r
A X 0.8 0.010784
A A
dm3 gs dm3 gs
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.
L12-24 in
The irreversible, elementary liquid-phase reaction 2A B is carried out adiabatically
a flow reactor with S=0 and without a pressure drop. The feed contains equal molar
amounts of A and an inert liquid (I). The feed enters the reactor at 294 K with 0 = 5
dm3/s and CA0= 1 mol/dm3. Use the 2-point rule to numerically calculate the PFR
volume required to achieve XA=0.8? Extra info:
E = 10,000 cal/mol CpA= 15 cal/molK CpB= 30 cal/molK CpI = 15 cal/molK
HA(TR) = -20 kcal/mol HB(TR) = -50 kcal/mol HI(TR) = -15 kcal/mol
k= 0.02
Usedmthe /mols
3
energyatbalance
350 K to construct table of T as a function of X
A
For each XA , calculate k, -rA and FA0/-rA
Use numeric evaluation to calculate VPFR
XA T(K) k(dm3/mols) -rA(mol/dm3s) FA0/-rA(dm3)
0 294 0.00129 0.00129 3876
0.8 427.3 0.2696 0.010784 463.6
X1
h
2
2-point rule: f x dx f X0 f X1 where h X1 X0 h 0.8 0 h 0.8
X0
0.8
VPFR 3876dm3 463.6dm3
2
Slides courtesy of Prof M L Kraft, Chemical & Biomolecular Engr Dept, University of Illinois, Urbana-Champaign.