Lecture 03
Crystal Structure of Ceramics Part-2
1. AX - type Structures
Rocksalt, CsCl, and ZnS
Filling of 2/3 of the octahedral sites in the basal plane of corundum. Only
one close- packed anion plane is shown.
Rutile Structures
The smaller B (Ti) cation occupies the octahedral sites and has
only oxygen as its nearest neighbours.