2016 NEET Chemistry Solved Paper

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Chemistry - 2016
Chemistry Exam
NEET Year
2016 2016
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Multiple Choice Questions
1. The addition of a catalyst during a chemical reaction alters which of the following quantities ?
Internal energy
Enthalpy
Activation energy
Entropy
Answer
2. Predict the correct order among the following.
long pair-lone pair> bond pair-bond pair> lone pair>bond pair
bond pair-bond pair> lone pair-bond pair > lone pair -lone pair
lone pair -bond pair > bond pair- bond pair> lone pair -lone pair
lone pair - lone pair > lone pair-bond pair > bond pair -bond pair
Answer
3. Two electrons occupying the same orbital are distinguished by
Magnetic quantum number
Azimuthal quantum number
Spin quantum number
Principal quantum number
Answer
4. The electronic configuration of Eu (Atomic no.63), Gd (Atomic no. 64) and Tb (Atomic no. 65) are
[Xe]4f 6 5d 1 6s 2 , [Xe] 4f 7 5d 1 6s 2 and [Xe] 4f 9 6s 2
[Xe] 4f 6 5d 1 6s 2 , [Xe] 4f 7 5d 1 6s 2 and [Xe] 4f 8 5d 1 6s 2
[Xe] 4f 7 6s 2 , [Xe] 4f 7 5d 1 6s 2 and [Xe] 4f 9 6s 2
[Xe] 4f 7 6s 2 ,[Xe] 4f 8 6s 2 and [Xe] 4f 8 5d 1 6s 2

Answer
5. Which one of the following characteristics is associated with adsorption?
ΔG, ΔH and ΔS all are negative
ΔG and ΔH are negative but ΔS is positive
ΔG and ΔS are negative but ΔH is positive
ΔG is negative but ΔH and ΔS are positive
Answer
6. Consider the molecules CH 4 , NH 3 and H 2 O. Which of the given statement is false?
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Chemistry Exam
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The H-O-H bond angle in H 2 O is larger than the H-C-H bond angle in CH 4 .
The H-O-H bond angle in H 2 O is smaller than the H-N-H bond angle in NH 3 .
The H-C-H bond angle in CH 4 is larger than the H-N-H bond angle in NH 3
The H-C-H bond angle in CH4, the H-N-H bond angle in H 2 O are all greater than 90.
Answer
7. The correct thermodynamic conditions for the spontaneous reaction at all temperatures is
Δ H > 0 and Δ S < 0
Δ H < 0 and ΔS > 0

ΔH ΔS > 0
ΔH < 0 and Δ S = 0
Answer
8. In which of the following options the order of arrangement does not agree with the variation of the property
indicated against it?
B < C < N < O (increasing first ionisation enthalpy)
I<Br<Cl<F(increasing electron gain enthalpy)
L i < N a < K < R b (increasing metallic radius)
Al 3 + < Mg 2 + <Na + <F - (increasi ng ionic size)

Answer
9. Equal moles of hydrogen and oxygen gases are placed in a container with a pin-hole through which both
can escape. What fraction of the oxygen escapes in the time required for one-half of the hydrogen to
escape?
1/4
3/8
1/2
1/8
Answer
10. MY and NY , two nearly insoluble salts. have the same K values of 6.2 x 10 - 1 3 at room temperature. Which
3 sp
statement would be true in regard to MY and NY 3 ?
The molar solubility of MY in water is less than that of NY 3
The salts MY and NY 3 are more soluble in 0.5 M KY than in pure water
The addition of the Salt of KY to the solution of MY and NY 3 will have no effect on their solubilities.
The molar solubilities of MY and NY 3 in water identical.
Answer
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Chemistry Exam
NEET Year
2016 2016
11. Consider the following liquid-vapour equilibrium
Which of the following relations is correct?
Answer
12. The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is
The eclipsed conformation of ethane is more stable than staggered conformation because eclipsed
conformation has no torsional strain
The eclipsed conformation of ethane is more stable than staggered conformation even though the
eclipsed conformation has torsional strain
The staggered conformation of ethane is more stable than eclipsed conformation because staggered
conformation has no torsional strain
The staggered conformation of ethane is less stable than eclipsed conformation, because staggered
conformation has torsional strain.
Answer
13. Which of the following statement about hydrogen is incorrect?
Hydrogen never acts as cation in ionic salts
Hydronium ion, H O + exist freely in solution

3
Dihydrogen does not act as a reducing agent

Hydrogen has three isotopes of which tritium is the most common
Answer
14. The pair of an electron in the given carbanion, is present in which orbital?
sp 3
sp 2
sp
2p
Answer
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Chemistry Exam
NEET Year
2016 2016
15. When copper is heated with conc. HNO3 it produces

Cu(NO 3 ) 2 and NO
Cu(NO 3 ) 2 , NO and NO 2
Cu(NO 3 ) 2 and N 2 O
Cu(NO 3 ) 2 and NO 2
Answer
16. A 100C the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If Kb = 0.52, the
boiling point of this solution will be
100C
102C
103C
101C
Answer
17. Match the compounds given in column I with the hybridization and shape given in column II and mark the
correct option.
Column I Column II
A.XeF6 1.Distorted octahedral
B.XeO3 2.Square planar
C.XeOF4 3.Pyramidal
D.XeF4 4.Square pyramidal
A B C D
1 2 4 3
A B C D
4 3 1 2
A B C D
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Chemistry Exam
NEET Year
2016 2016
4 1 2 3
A B C D
1 3 4 2
Answer
18. Match items of Columns I with the items of Columns II and assign the correct code.
Column I Column II
A.Cyanide process 1.Ultrapure Ge
B. Froth floatation process 2.Dressing of ZnS
C.Electrolytic reduction 3.Extraction of Al
D.Zone refining 4.Extraction of Au
5.Purification of Ni
A B C D
2 3 1 5
A B C D
1 2 3 4
A B C D
3 4 5 1
A B C D
4 2 3 1
Answer
19. Which is the correct statement for the given acids?
Phosphinic acid is a monoprotic acid while phosphonic acid is a diprotic acid.
phosphinic acid is a diprotic acid while phosphonic acid is a monoprotic acid
Page 6 of 13
Chemistry Exam
NEET Year
2016 2016
Both are triprotic acids

Both are diprotic acids
Answer
20. Which one of the following statements is correct when SO 2 is passed through acidified K 2 Cr 2 O 7 solution?
The solution is decolourized
SO 2 is reduced
Green Cr 2 (SO 4 ) 3 is formed
The solution turns blue
Answer
21. The product obtained as a result of a reaction of nitrogen with CaC 2 is
CaCN
CaCN 3
Ca 2 CN
Ca(CN) 2
Answer
22. Fog is a colloidal solution of
Gas in liquid
Solid in gas
Gas in gas
Liquid in gas
Answer
23. Which one of the following orders is correct for the bond dissociation enthalpy of halogen molecules?
Cl 2 >B r 2 >F 2 >I 2
B r 2 >I 2 >F 2 >Cl 2
F 2 >Cl 2 >B r 2 >I 2
I2 > B r 2 > C l 2 > F 2
Answer
24. Lithium has a bcc structure. Its density is 530 kg m -3 and its atomic mass is 6.94 g mol-1. Calculate the edge
length of a unit cell of lithium metal. (N = 6.02 x 10 2 3 mol -1).

A
352pm
527pm
264pm
154pm
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Chemistry Exam
NEET Year
2016 2016
Answer
25. Which of the following statements about the composition of the vapour over an ideal 1:1 molar mixture of
benzene and toluene is correct? Assume that the temperature is constant at 25C.
(Given, vapour pressure data at 25C benzene = 12.8 kPa, toluene = 3.85 kPa)
The vapour will contain a higher percentage of toluene
The vapour will contain equal amounts of benzene and toluene
Not enough information is given to make a prediction
The vapour will contain a higher percentage of benzene
Answer
26. The rate of a first-order reaction is 0.04 mol L -1 s -1 at 10 sec and 0.03 mol -1 L -1 s - 1 at 20 sec after initiation of
the reaction. the half-life period of the reaction is
34.1 s
44.1 s
54.1 s
24.1 s
Answer
27. The ionic radii of A + and B - ions are 0.98 x 10 - 1 0 m and 1.81 x10 - 1 0 m. The coordination number of each ions in
AB is
4
8
2
6
Answer
28. Which of the following has longest C-O bond length? (free C-O bond length in CO is 1.128 A)
[Co(CO) ]-
4
[Fe(CO) ] -2
4
[Mn(CO) ] +
6
Ni(CO) 4
Answer
29. Among the following, the correct order of acidity is
HClO<HClO 2 <HClO 3 <HClO 4
HClO 2 <HClO<HClO 3 <HClO 4
HClO 4 <HClO<HClO <HClO 3
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Chemistry Exam
NEET Year
2016 2016
HClO 3 <HClO 4 <HClO 2 <HClO
Answer
30. The pressure of H 2 required to make the potential of H 2 -electrode zero in pure water at 298 K is
10 - 1 2 atm
10 - 1 0 atm
10 - 4 atm
10 - 1 4 atm
Answer
31. Which of the following biphenyls is optically active?
Answer
32. The correct statement regarding the basicity of arylamines is
Arylamines are generally more basic than alkylamines because the nitrogen lone pair electrons are
not delocalized by interaction with the aromatic ring pi-electron system
Arylamines are generally more basic than alkylamines, because of aryl group
Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is
sp-hydridized.
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Chemistry Exam
NEET Year
2016 2016
Arylamines are generally less basic than alkylamines because the nitrogen lone pair electrons are
delocalized by interaction with aromatic ring pi-electron system.
Answer
33. For the following reactions,
i) CH 3 CH 2 CH 2 Br + KOH --> CH 3 CH=CH 2 +KB r + H 2 O
ii)
iii)
(i) is elimination reaction, (ii) is substitution reaction, and (iii) is addition reaction.
(i) is elimination reaction, (ii) is addition reaction, (iii) is substitution reactions.
(i) is substitution, (ii) addition reaction (iii) is addition reactions
(i) and (ii) are elimination reactions and (iii) is addition reaction.
Answer
34. The reaction
Can be classified as
Alcohol formation reaction
Dehydration reaction
Williamson alcohol synthesis reaction
Williamson ether synthesis reaction
Answer
35. The correct statement regarding a carbonyl compound with a hydrogen atom on its alpha -carbon, is a
carbonyl compound with a hydrogen atom on its alpha -carbon rapidly equilibrates with its
corresponding enol and this process is known as aldehyde-ketone equilibration.
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Chemistry Exam
NEET Year
2016 2016
a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its
corresponding enol and this process is known as carbonylation
a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its
corresponding enol and this process is known as keto-enol tautomerism
a carbonyl compound with a hydrogen atom on its alpha carbon never equilibrates with its
corresponding enol
Answer
36. In a protein molecule various amino acids are linked together by
β-glycosidic bond
peptide bond
dative bond
α - glycosidic bond
Answer
37. Which of the following is an analgesic?
Penicillin
Streptomycin
Chloromycetin
Novalgin
Answer
38. Natural rubber has
All trans-configuration
Alternate cis and trans configuration
Random cis and trans configuration
All cis configuration
Answer
39. Which of the following reagents would distinguish cis-cyclopenta-1-,2-diol from the trans isomer?
Ozone
MnO 2
Aluminium isopropoxide
Acetone
Answer
40. Which of the following statement is false?
Ca 2 + ions are important in blood clotting
Ca 2 + ions are not important in maintaining the regular beating of the heart.
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Chemistry Exam
NEET Year
2016 2016
M g 2 + ions are important in the green parts of plants
M g 2 + ions form a complex ATP

Answer
41. In the reaction,
X and Y are
X=2-butyne; Y = 3-hexyne
X=2-butyne;Y=2-hexyne
X=1-butyne ;Y = 2-hexyne
X=1-butyne; Y =3-hexyne
Answer
42. Consider the nitration of benzene using mixed conc. H 2 SO 4 and HNO 3 . If a large amount of KHSO 4 is added
to the mixture, the rate of nitration will be
slower
uncharge
doubled
faster
Answer
43. The correct statement regarding RNA and DNA, respectively is
The sugar component in RNA is ribose and sugar component in DNA is 2' deoxyribose
The sugar component in RNA is arabinose and the sugar component in DNA is ribose
The sugar component in RNA is 2'-deoxyribose and the sugar component in DNA is arabinose
The sugar component in RNA is arabinose and the sugar component in DNA is 2' deoxyribose.
Answer
44. Which one given below is a non - reducing sugar?
Lactose
Glucose
Sucrose
Maltose
Answer
45. The product formed by the reaction of an aldehyde with a primary amine is
Page 12 of 13
Chemistry Exam
NEET Year
2016 2016
Ketone
Carboxylic acid
Aromatic acid
Schiff base
Answer
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Multiple Choice Questions

[Xe]4f 6 5d 1 6s 2 , [Xe] 4f 7 5d 1 6s 2 and [Xe] 4f 9 6s 2

[Xe] 4f 6 5d 1 6s 2 , [Xe] 4f 7 5d 1 6s 2 and [Xe] 4f 8 5d 1 6s 2

[Xe] 4f 7 6s 2 , [Xe] 4f 7 5d 1 6s 2 and [Xe] 4f 9 6s 2

[Xe] 4f 7 6s 2 ,[Xe] 4f 8 6s 2 and [Xe] 4f 8 5d 1 6s 2

Δ H < 0 and ΔS > 0

Al 3 + < Mg 2 + <Na + <F - (increasi ng ionic size)

statement would be true in regard to MY and NY 3 ?

The molar solubility of MY in water is less than that of NY 3

The molar solubilities of MY and NY 3 in water identical.

11. Consider the following liquid-vapour equilibrium

Which of the following relations is correct?

Hydronium ion, H O + exist freely in solution

Dihydrogen does not act as a reducing agent

15. When copper is heated with conc. HNO3 it produces

A.XeF6 1.Distorted octahedral

B.XeO3 2.Square planar

D.XeF4 4.Square pyramidal

A.Cyanide process 1.Ultrapure Ge

B. Froth ﬂoatation process 2.Dressing of ZnS

C.Electrolytic reduction 3.Extraction of Al

D.Zone reﬁning 4.Extraction of Au

Both are triprotic acids

The solution is decolourized

The solution turns blue

B r 2 >I 2 >F 2 >Cl 2

F 2 >Cl 2 >B r 2 >I 2

I2 > B r 2 > C l 2 > F 2

length of a unit cell of lithium metal. (N = 6.02 x 10 2 3 mol -1).

HClO 2 <HClO<HClO 3 <HClO 4

HClO 4 <HClO<HClO <HClO 3

HClO 3 <HClO 4 <HClO 2 <HClO

31. Which of the following biphenyls is optically active?

i) CH 3 CH 2 CH 2 Br + KOH --> CH 3 CH=CH 2 +KB r + H 2 O

34. The reaction

Ca 2 + ions are important in blood clotting

M g 2 + ions are important in the green parts of plants

M g 2 + ions form a complex ATP

41. In the reaction,

to the mixture, the rate of nitration will be

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