•For pH =7 , Neutral.
•For pH >7, Basic.
•For pH< 7 ,Acidic.
Conductivity
Conductivity is the current carrying
capacity of any solution.It is the direct
measure of total ionisable solids in the
water
It depends upon:
•Concentration of the electrolyte. (Cions)
•the type of ions present
• the temperature of the electrolyte.
Unit of conductivity is micromho/cm
Alkalinity
pH 8.5 –9.5
pH 8.5 – 9.5
Conductivity < 10
Co-ordinated Phosphate-pH
&
Congruent Phosphate
Co-ordinated Phosphate
• Control of pH comes from hydrolysis of
trisodium phosphate in water
10.8
10.6 “Free” Caustic
MOLAR RATIO
Region 2.8 : 1
10.4 4 Na/PO 4
10.2
CONTROL BOUNDARY 3.0:1 Na/PO
10.0
2.7 : 1
9.8
Na/PO 4
9.6
9.4
2.6 : 1 cau TSP
9.2 Na/PO 4 CONTROL BOUNDARY 2.2:1 Na/PO4 MOLAR RATIOstic
9.0
DSP
8.8
Captive
8.6 Alkalinity
8.4 Region
MSP
blow down
8.2
1 2 3 4 5 6 7 8 10 15 20 30 40 50 60
ppm Orthophosphates, as PO 4
Phosphate treatment
Trisodium phosphate and disodium phosphate
reactions :
Na 3PO4 + 2 H2 O = 2 NaOH + NaH2 PO4
Na 2HPO4 + H2 O = NaOH + NaH2 PO4
In both the reactions considerable amount of
caustic alkalinity is produced .Caustic can not
concentrate beyond a certain level in the
presence of acid phosphate ions because as
the pH value rises the above reactions reverse
from right to left thereby removing caustic.
Phosphate treatment
Phosphate dosing to work it is essential
to have disodium hydrogen phosphate
available to combine with free caustic
to form trisodium phosphate.Thus the
dosing rate should be such that pH
value and phosphate concentration are
at a point should be below the curve in
which area only trisodium phosphate
and disodium hydrogen phosphate
coexist.
Phosphate vs pH curve
pH Boosters
•Ammonia ( NH3 )
•Caustic ( NaOH)
• Derivatives of Amines
•Cyclohexylamine
•Morpholine
Film Forming Amines
PROTECTIVE FILM BARRIER
AMINE FILM
N R
N R
N R
WATER
SURFACE
METAL
LEGEND
N R = AMINE MOLECULE
N+ = AMINO GROUP
R- = ALKYL GROUP
PROTECTION AGAINST OXYGEN
PITTING
Molecular Configuration
of Amine Film Size of Molecule
Oxygen
1A0
12A0
Triangular
Carbon Dioxide
14A0
5A0
Square
FILM FORMING AMINE
Agglomeration
Dispersion
Neutralizing Amine
Neurtalising amines
Neutralizing amines are used to neutralize
carbon dioxide.
•The most commonly used neutralizing
amines are morpholine , diethylamino-
ethanol, cyclohexylamine and ammonia.
•The distribution ratio ( D.R)
of a particular amine plays an important role
in the selection of an amine.
Neurtalising amines
Amine DR
Morpholine 0.4
diethylamino-ethanol 1.7
Cyclohexylamine 4.0
Ammonia 10.0
Neurtalising amines
In order to neutralize CO2 the amine must be
present in the water phase.Ammonia has a
high DR and a significant amount will be lost
during the deaeration step. Morpholine ,
preferring the water phase is often applied
for systems where the major part of the
steam is used for turbine supply.Two or more
amines may be applied simultaneously .
Neutralizing amines are normally fed to the
feed water header.
Priming, Foaming and Carry over
Foaming
Foaming is the formation of stable foam on
the evaporating surface in the boiler drum.
Bubbles are formed continuously and
possess high surface tension .They retain
their shape even after their disengagement
from the water surface.
Foaming
Factors responsible for foam generation
are:
•High salt content in boiler water
•Presence of oils and grease in boiler water
•Presence of suspended sludge in a finely
dispersed state in boiler water
•High alkali concentration in boiler water
Priming
Priming is the infiltration of boiler feed
water into steam lines of the boiler drum
Boiler drum
Steam vent
Regulating
valve
Flash tank
drain