STUDI KASUS II

REAKTOR CSTR
ISOTERMAL
Annisa Hasna A (1606839025)
Anton Prayoga (1606905292)
Didit Ardi Maulana (1606822213)
Huriya (1606905336)
Miranda Meidistira (1606889585)
CASE
Two configuration of CSTRs are
contemplated for performing reversible
hydrolysis of compound A to produce
compound B and C. The forward reaction is
pseudo-first-order with respect to A, with rate
constant 𝒌𝟏 = 𝟏. 𝟖𝟐 × 𝟏𝟎−𝟒 𝒔−𝟏 . The reverse
reaction is second-order with rate constant
𝒌−𝟏 = 𝟒. 𝟒𝟗 × 𝟏𝟎−𝟒 𝑴−𝟏 𝒔−𝟏 .
𝑨 → 𝑩 + 𝑪; 𝒓𝟏 = 𝒌𝟏 [𝑨]
𝑩 + 𝑪 → 𝑨; 𝒓𝟐 = 𝒌−𝟏 𝑩 [𝑪]
The feed is dilute aqueous solution of A
(concentration 0.25 mol/L at a rate of 0.25
L/h)
2
CASE
Consider the following configurations:
◦ A single 15 L CSTR
◦ Three 5 L CSTR in series, with 75% of
product species B & C selectively removed
between stages 1 and 2 and between
stages 2 and 3, with appropriate
adjustment in flow rate; the volumetric
flow rates in the two streams leaving a
separator are proportional to the total
number of moles of A, B, and C in each
stream.

3
 Net Rate Stoichiometry

−𝑟1 = 𝑘1 𝐴 𝐶𝐴 = 𝐶𝐴0 (1 − 𝑋)
−𝑟2 = 𝑘−1 [𝐵][𝐶] 𝐶𝐵 = 𝐶𝐵0 + 𝐶𝐴0 𝑋
−𝑟𝐴 = 𝑘1 𝐴 − 𝑘−1 [𝐵][𝐶] 𝐶𝐶 = 𝐶𝐶0 + 𝐶𝐴0 𝑋
𝑟𝐵 = −𝑟𝐴
𝑟𝐶 = −𝑟𝐴

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 Mass Balance

𝑑𝑁𝐴
𝐹𝐴0 − 𝐹𝐴 + 𝑟𝐴 𝑉 = =0
𝑑𝑡

𝐹𝐴0 𝑋
𝑉=
−𝑟𝐴

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 Case 1

Data:
𝑘1 = 0.000182 𝑠 −1
𝑘−1 = 0.000449 𝑀−1 𝑠 −1
𝐹𝐴0 = 𝐶𝐴0 . 𝑞0
𝐶𝐴0 = 0.25 𝑚𝑜𝑙/𝐿
𝐹𝐴0 = 1.7361 × 10−5 𝑚𝑜𝑙/𝑠
𝐶𝐵0 = 0 𝑚𝑜𝑙/𝐿
𝐶𝐶0 = 0 𝑚𝑜𝑙/𝐿
𝑞0 = 0.25𝐿/ℎ = 6.944 × 10−5 𝐿/𝑠
 𝐹𝐴0 𝑋 𝐹𝐴0 𝑋
V= =
−𝑟𝐴 𝑘1 𝐶𝐴 − 𝑘−1 𝐶𝐵 𝐶𝐶

Subtituting the stoichiometric equation

𝐹𝐴0 𝑋 𝐹𝐴0 𝑋
𝑉= =
−𝑟𝐴 𝑘1 𝐶𝐴0 1 − 𝑋 − 𝑘−1 𝐶𝐵0 + 𝐶𝐴0 𝑋 𝐶𝐶0 + 𝐶𝐴0 𝑋

As 𝐶𝐵0 and 𝐶𝐶0 are both 0, then

𝐹𝐴0 𝑋 𝐹𝐴0 𝑋
𝑉= = 2 2
−𝑟𝐴 𝑘1 𝐶𝐴0 1 − 𝑋 − 𝑘−1 𝐶𝐴0 𝑋

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 GRAFIK PERBANDINGAN KONVERSI VS
VOLUME
0.8

0.7

0.6
X (konversi)

0.5

0.4

0.3

0.2

0.1

0
0 2 4 6 8 10 12 14 16
Volume

For a reactor volume of 15L, the conversion is found to be 𝑋 = 0.68936

At this conversion,
𝐹𝐴 = 5.39296 × 10−6 𝑚𝑜𝑙/𝑠
𝐹𝐵 = 𝐹𝐵0 + 𝐹𝐴0 𝑋
𝐹𝐵 = 𝐹𝐶 = 1.19682 × 10−5 𝑚𝑜𝑙/𝑠
8
 GRAFIK PERBANDINGAN FA0/-RA VS
KONVERSI
50

0
0 0.2 0.4 0.6 0.8 1 1.2

-50
Fa0/-ra

-100

-150

-200
X (konversi)

9
 GRAFIK PERBANDINGAN KONVERSI VS
VOLUME
0.8

0.7

0.6

0.5
X (konversi)

0.4

0.3

0.2

0.1

0
0 2 4 6 8 10 12 14 16
Volume

10