Bagian Calvin

Calvin Fernando (1606905235)

Desya Pramadhanti (1506729600)
Ridhan Fauzan Prasetyo (1606883575)
Comparison of Techniques
Procedure Diagram (MPD)
Procedure Diagram (SGD)
Procedure Diagram (CVD)
Procedure Diagram (PLD)
 Electrospraying
• Ditemukan pada akhir tahun 1980-an
• Biasa digunakan untuk menganalisis sampel liquid
• Dapat digunakan untuk mengeluarkan liquid dalam bentuk yang seragam
• Ukuran liquid dipengaruhi besaran tegangan yang diberikan
 Electrophoretic Deposition (EPD)
• EPD dikenal sebagai teknik yang efektif
untuk bioactive coatings dan
biomedical nanostructures
• Bisa diterapkan untuk berbagai macam
bentuk material, bubuk (30 µm) dan
larutan koloid.
• Menggunakan dua elektroda dengan
memanfaatkan elektroforesis dan
koagulasi partikel (Heavens 1990;
Sarkar & Nicholson 1996)
 Electrophoretic Deposition (EPD)
• EPD dikenal sebagai teknik yang efektif
untuk bioactive coatings dan
biomedical nanostructures
• Bisa diterapkan untuk berbagai macam
bentuk material, bubuk (30 µm) dan
larutan koloid.
• Menggunakan dua elektroda dengan
memanfaatkan elektroforesis dan
koagulasi partikel (Heavens 1990;
Sarkar & Nicholson 1996)
Field Emission Scanning Electron Microscopy
(FESEM)
 Field Emission Scanning Electron Microscopy
(FESEM)
Dibandingkan SEM:
• Menghasilkan hasil foto yang lebih jelas dengan sedikit distorsi
pada elektrostatisnya dengan resolusi spasial hingga 1,5
nanometer (3 – 6 kali lebih baik)
• Ketebalan coating dan keseragaman struktur lebih baik
• Kontaminasi yang sedikit
X-Ray Diffraction (XRD)

• Dapat mengidentifikasi:
a. Struktur kristal
b. Tekstur
c. Amorphous material
d. Cacat
e. Karakterisasi polymorphs
X-Ray Diffraction
(XRD)

Bragg’s Law
𝑛𝜆 = 2𝑑𝑠𝑖𝑛𝜃
N : indeks bias
𝜆 : Panjang
gelombang
d : jarak antar
planar
X-Ray Diffraction (XRD)
 Stylus
Profilometry

(XP-1, Ambios Tech.,

USA)
 XP-1,
AMBIOS
Tech.,
USA

Source:
https://www.iitk.ac.in/dord/data/care_funding/2008-
09/Monica_Katiyar.pdf
 Surface Profilometer
Definition:
A profilometer is a measuring instrument used to measure a surface's
profile, in order to quantify its roughness computed from the surface
topography.

Critical dimensions as
• step,
• curvature,
• flatness
 Surface Profilometer

• The thickness of the bioceramic coating layers was measured

using a surface profilometer (XP-1, Ambios Tech., USA),
Source :
https://doi.org/10.1016/j.ceramint.2018.12.159 (Pg.6704)
 Surface Profilometer
0.386 J/m2
27 μm/min

22 μm/min In the AD process,

0.025 – 0.0076 J/m2
Factor that affects
deposition rate
• surface energy,
• density, shape,
• size,
• etc. of raw powder
5.02 J/m2 1.01 J/m2
0.38 μm/min 0.75 μm/min [43,44].
 Optical
Profilometry
Optical
Profilometry
 Optical
Profilometry
 Optical
Profilometry
 (AFM, N8
NEOS, Brucker,
Germany)
Cutaway
AFM
 AFM Principles :Imaging
(Surface Sensing + PPSD Monitoring)
 AFM Principles :Imaging
(Surface Sensing + PPSD Monitoring)
 AFM Principles :Imaging
(Surface Sensing + PPSD Monitoring)
 AFM Principles :Imaging
(Surface Sensing + PPSD Monitoring)
 AFM Principles :Imaging
(Surface Sensing + PPSD Monitoring)
Since the structure of
brushite powders
generally shows a
tendency toward
flatness according to
010 face and mainly
consists of fairly thin
and fragile plates
 Daftar Pustaka
• Boccaccini, A. R., Keim, S., Ma, R., Li, Y., & Zhitomirsky, I. (2010). Electrophoretic Deposition of Biomaterials.
Journal of The Royal Society Interface, 7(5), S581-S613. doi:10.1098/rsif.2010.0156.focus
• Dutrow, B. L., & Clark, C. M. (n.d.). X-Ray Powder Diffraction (XRD). Retrieved March 2019, from Geochemical
Instrumentation and Analysis:
https://serc.carleton.edu/research_education/geochemsheets/techniques/XRD.html
• Field Emission Scanning Electron Microscopy. (n.d.). Retrieved March 2019, from Universiitat Politecnica De
Valencia: http://www.upv.es/entidades/SME/info/859071normali.html
• Muthutantri, A. I., Huang, J., Edirisinghe, M. J., Bretcanu, O., & Boccaccini, A. R. (2008). Dipping and
Electrospraying for the Preparation of Hydrocyapatite Foams for Bone Tissue Engineering. Biomedical Materials,
3, 1-14. doi:10.1088/1748-6041/3/2/025009
• Cho, M.-Y. et al. (2019) “Evaluation of structural and mechanical properties of aerosol-deposited bioceramic
films for orthodontic brackets,” Ceramics International, 45(6), pp. 6702–6711. doi:
10.1016/j.ceramint.2018.12.159.
• Atomic Force Microscope Principle | AFM Scanning | How AFM Works (2015) Parksystems.com. Available at:
https://www.parksystems.com/index.php/medias/nano-academy/how-afm-works (Accessed: March 17, 2019).
 References
• Monika Furkó et.al, Comparative Study On Preparation and
Characterization of BioActive Coatings for Biomedical Applications -
A Review of Recent Patents and Literature, 2016
• http://news.mit.edu/2015/explained-chemical-vapor-deposition-
0619
• https://www.osapublishing.org/ome/abstract.cfm?uri=ome-6-1-91
• https://en.wikipedia.org/wiki/Sol%E2%80%93gel_process#/media/
File:SolGelTechnologyStages.svg
• https://iopscience.iop.org/article/10.1088/0268-
1242/16/3/308/fulltext/