Quantities
In Reactions
Homework
• Assigned Problems (odd numbers only)
• “Problems” 17 to 73
• “Cumulative Problems” 75-95
• “Highlight Problems” 97-99
Calculations Using Balanced Equations:
Stoichiometry
• Stoichiometry is the study of the quantitative
relationships among reactants and products in a
chemical reaction
• These chemical calculations can be used to
determine the amount of one reactant needed to
completely react with another
• Or, to determine the amount of reactant needed
to produce a desired amount of product
• To calculate chemical quantities in reactions
involves knowing how to interpret a balanced
chemical equation
Calculations Using Balanced Equations:
Law of Conservation of Mass
moles A moles B
Mole-mole
moles B
factorA
moles
Using Mole-Mole Factors in Calculations:
Calculating Moles of a Product
• Calculate the moles of CO2 formed when 4.30
moles of C3H8 reacts with (the required) 21.5
moles of O2
C 3 H 8 (g) 5 O 2 (g) 3 CO 2 (g) 4 H 2 O(g)
• Balance the equation
• Plan to convert the given amount of moles to the
needed amount of moles
• Use coefficients to state the relationships and
mole-mole factors
• Set up the problem using the mole-mole factor
and canceling units
Using Mole-Mole Factors in Calculations:
Calculating Moles of a Product
MM
MWofofA
A Stoichiometry MMofof
MW B B
moles A moles B
moles A
Mole-mole
Given: 4.30 mol C 3 H 8 moles
factorB Find: mol CO 2
3 mol CO 2
Mole-mole factor
1 mol C3 H 8
grams A grams B
MW of
MM ofAA Stoichiometry MMofofBB
MW
moles A moles B
moles BA
moles
Mole-mole
factor
moles
moles AB
Mass-to-Mass Conversions
• Mass-to-mass conversions begin with a given
mass of substance A
• By use of the balanced equation, find the mass of
another (substance B)
1. Convert grams of A to moles of A
2. Convert the moles of A to moles of B by use of mole-mole
ratio
3. Convert moles of B to mass of B
grams A grams B
MM of A Stoichiometry MM of B
moles A moles B
moles B
moles A
Mass-to-Mass Conversions
(Mass of Product from Mass of Reactant)
• Calculate the mass of carbon dioxide produced when 96.1
g of propane react with sufficient oxygen.
C3 H8 (g) 5 O 2 (g) 3 CO 2 (g) 4 H 2 O(g)
• Balance the equation
• Plan to convert the given mass to given moles
• Convert the given moles to sought-after moles by the use of mole-
mole factor
• Convert the needed moles to needed mass
MM of Stoichiometry MM of CO2
C3H8
moles C3H8 moles CO2
moles CO2
Mole-mole
factor
moles C3H8
Mass-to-mass Conversions: Example 1
• Write the equalities
• 1 mol C3H8 = 44.09 g C3H8
• 1 mol CO2 = 44.01 g CO2
• 1 mol C3H8 = 3 mol CO2 to create mole-mole factor
grams N
Li2 Solution Map: grams Li3N
Li2
MM of N Stoichiometry MM of Li3N
Li2
moles N moles Li3N
moles Li3N
moles
moles Li
N2
Limiting Reactant Problem
6 Li (s) N 2 (g) 2Li 3 N(s)
Limiting reactant 56.0 g Li 56.0 g N 2 (x) g Li 3 N
56.0 g Li 1 mol Li
8.07 mol Li
6.941 g Li
2 mol Li3 N 34.82 g Li3 N
8.07 mol Li 93.67 g Li3N
6 mol Li 1 mol Li3 N
56.0 g N 2 1 mol N 2
2.00 mol N2
28.02 g N 2
2 mol Li3 N 34.82 g Li3 N
2.00 mol N 2 139.3 g Li3N
1 mol N 2 1 mol Li3 N
Limiting Reactant Problem
34.83 g Li3 N
2.69 mol Li3 N 93.7 g Li N
1 mol Li3 N 3
Theoretical yield
Percent Yield
• The calculated amount of product that
should be obtained is called the theoretical
yield
• Assumes all reactants are converted to
product based on the mole-mole ratios of
reactant to product
• Rarely do you get the maximum amount of
product
– Side reactions
– Loss during transfer
– Accidental spills
Percent Yield
• Theoretical Yield
– The calculated amount of product
• Actual Yield
– The actual amount of product
– Something less than the theoretical
• Percent Yield
– The fraction of the theoretical yield actually
obtained is expressed as a percent
Actual Yield
% Yield 100%
Theoretical Yield
Percent Yield Example
• Suppose, in the previous limiting
reactant problem, you actually
produced 90.8 g of Li3N. What is the
percent yield of this reaction?
actual 90.8 g
100 % 100 % 96.9 % yield
theoretical 93.7 g
Enthalpy
• Chemical reactions are associated with an
absorption or evolution of heat
– A change in energy occurs as bonds are
broken (reactants) and new ones form
(products)
– Nearly all chemical reactions absorb or
produce heat
– Measured by the heat of reaction or enthalpy
• Enthalpy change is the amount of heat
produced or consumed in a process (∆H )
Sign of ∆Hrxn
• Endothermic reactions absorb heat as they
occur
– If (∆H ) is positive, then heat is added to the
reaction
– If heat supply is removed, the reaction stops
Sign of ∆Hrxn
• Exothermic reactions produce heat as they
occur
– If (∆H ) is negative, then heat is evolved by
the reaction
Sign of ∆Hrxn
Enthalpy of Reaction
• Photosynthesis reaction
– Carbon dioxide reacts with water to produce glucose
and oxygen
6 CO2 (g) 6 H2 O () C6H12 O 6 (s) 6 O 2 (g)
∆H = +2801 kJ
• Cell metabolism
– Glucose reacts with oxygen to produce carbon dioxide
and water
C6H12 O 6 (s) 6 O 2 (g) 6 CO2 (g) 6 H2 O ()
∆H = -2801 kJ
Stoichiometry of ∆Hrxn
• The coefficients in a given chemical reaction
represent the number of moles of reactants and
products that produce the given heat of reaction
(enthalpy change)
• The combustion of methane gas:
CH4 (g) 2 O2 (g) CO2 (g) 2 H2O(g) ∆Hrxn = -890 kJ
1 mol CH 4 890 kJ
Solution: 4.50 g CH4 -2.50 × 102 kJ
16.00 g CH 4 1 mol CH 4
Stoichiometry Involving ∆H