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Lecture No.

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Semiconductor Physics
• At the end of this lecture, student will be able to :
• Define a semiconductor
• Classify semiconductor, insulator and conductor
• Define intrinsic and extrinsic semiconductor
• Explain P-type and N-type semiconductor
• Illustrate conduction in semiconductor

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Topics

• Insulators, Semiconductors, and Conductors comparison


• Semiconductors
• Intrinsic and extrinsic semiconductor
• P type and N type semiconductor
• Conduction in Semiconductors

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Introduction

Insulators, Semiconductors, and Conductors

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Insulators, Semiconductors, and Conductors

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Insulators, Semiconductors, and Conductors
Continued..

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Insulators, Semiconductors, and Conductors Continued..

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Periodic Table
Column 3 Column 4 Elements
Elements have 3 have 4 electrons in
electrons in the the Valence Shell
Valence Shell

Column 5
Elements have 5
electrons in the
Valence Shell

Position of semiconductors in Periodic Table 7


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Semiconductor
Electron
Energy

r3

r2 r1
r2 14P
r3
r1

Center of core Valence orbit


has four electrons
Energy levels in a single atom Isolated silicon atom

Electrons in the same orbit has same energy


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Covalent Bond

Electron

14P
An electron
shared by two
neighboring atoms
14P 14P 14P to form a covalent
bond.
This way an atom
14P can have a stable
structure with
eight valence band
electrons.
Silicon Crystal

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Energy Bands
Electron (in conduction band)
Higher band higher energy

Conduction band
Hole (in valence band)

Valence band

14P
2nd band

1st band

Energy bands in silicon Crystal


silicon ion
In a crystal, electrons in the same orbit do not
have the same energy and thus form energy bands
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Thermal Energy Produces Free Electron and Hole
Pair
Electron (in conduction band)

14P Hole (in valence band)

14P 14P 14P

14P

Electron hole pair creation 11


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Recombination of Free Electron and Hole

Electron (in conduction band)

14P Hole (in valence band)

14P 14P 14P

14P

Recombination of Free Electron & Hole


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Hole / Electron Flow Through a Semiconductor
+ -
Free Electron (in conduction band)
+ -
+ -
+ -
+ 14 14P 14P -
+ P A C D F -
+ -
B E
+ Hole 14P 14P 14P -
+ -
+ (in valence band) -
Hole / Electron Flow

The electron moves F-E-D-C-B-A


The hole moves A-B-C-D-E-F (pseudo movement)
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Types of Semiconductors

Semiconductors can be classified as:


1. Intrinsic Semiconductor
2. Extrinsic Semiconductor

Extrinsic Semiconductors are further classified as:


a. n-type Semiconductors
b. p-type Semiconductors

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Intrinsic Semiconductor

Si Si Si
FREE ELECTRON

Si Si Si
HOLE

Si Si Si

n  p  ni
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Intrinsic Semiconductor Energy Band Diagram

Energy in ev Conduction Band

FERMI
LEVEL

Valence Band

• Fermi level lies in the middle


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Doping

• Doping means mixing a pure semiconductor with


impurities to
– increase its electrical conductivity

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Doping Ways

• Doping Can be done in two ways

– By mixing pentavalent elements such as phosphorous, arsenic,


antimony

– By mixing Trivalent elements such as aluminum, boron, gallium

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Extrinsic Semiconductor

Extrinsic Semiconductors

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Extrinsic Semiconductor Energy Band Diagram

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n-type semiconductor
Has many free electrons in conduction band and few holes
In valence band
Free Electron

Phosphorous atom
14P

14P 15P 14P

14P

n-type semiconductor
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n-type Semiconductor

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p-type Semiconductor
Has few free electrons in conduction band and many holes
In valence band

Hole
Aluminum atom
14P

14P 13P 14P

14P

p-type semiconductor
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p-type Semiconductor

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Comparison of Semiconductors

Intrinsic Semiconductor Extrinsic Semiconductor

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Comparison Between n-type and p-type
Semiconductors

n-type p-type

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Comparison Between n-type and p-type
Semiconductors continued..

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Summary

• Silicon and Germanium are the most commonly used


semiconductors.
• Semiconductor in the extreme pure form is known as intrinsic
semiconductors.
• In intrinsic semiconductors Fermi level lies in middle of band gap
• Doping with pentavalent impurity will result in n-type and with
trivalent impurity will result in p- type.
• P-type and n-type semiconductors are electrically neutral.
• Fermi level lies near conduction band in n-type and it lies near
valance band in p-type
• Conduction in semiconductors is through Drift and Diffusion
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