Korosi 1
Korosi 1
High pH (> 9)
Calculating the cell potential, Eocell,
at standard conditions
H2O with O2
Consider a drop of oxygenated
Fe water on an iron object
Prinsip : Logam yang lebih reaktif (Eo kecil) akan lebih dahulu
berkarat.
Syarat : Logam yang akan digunakan untuk melindungi harus lebih
reaktif
Anoda dikorbankan untuk
melindungi Katoda
Anoda dikorbankan untuk
melindungi Katoda
Preventing the Corrosion of Iron
(cathodic protection/sacrificial anode)
Sacrificial anode
Applications of Cathodic Protection
• Galvanized Steel
Zinc coating
• Sacrificial Anodes
Ship Hulls
Subs (free flooding areas)
Arleigh-Burke Destroyer
KEGUNAAN ELEKTROLISIS
Commercial Electrolytic Processes
• Elektroplatting
• Purification of metals
• Production of aluminum
• Metal plating
• Production of chlorine and sodium
• Production of chlorine and sodium
hydroxide
(a) A silver-plated teapot. (b) Schematic
of the electroplating of a spoon.
Electrolyt :
lart. AgNO3
Purification of Metals
Electrolysis
Zone refining
Prinsp :
logam yang akan dimurnikan harus
dipasang sebagai ANODA
Sebagai katoda harus logam murni.
20.2
Elektrolisis Larutan CuSO4 dengan anoda Cu
dankatoda Cu
CuSO4(aq) Cu2+ (aq) + SO42- (aq)
Reaksi yang terjadi dalam sel tersebut adalah:
anoda : Cu(s) Cu2+ + 2e
katoda : Cu2+ + 2e Cu(s)
Cu(s) + Cu2+ (aq) Cu(s) + Cu2+(aq)
Cu(s)(A) + Cu(s)(K)
Tembaga tidak murni dipasang sebagi anoda
Tembaga muri diperoleh di katoda
The Hall Process for Aluminum
• Electrolysis of molten Al2O3 mixed with
cryolite – lowers melting point
• Cell operates at high temperature – 1000 oC
http://academic.pgcc.edu/~ssinex/E_ 29
cells.ppt.
graphite anodes From: http://academic.pgcc.edu/~ssinex/E_cells.ppt. e-
+
from
power
CO2 source
bubbles Al+3
Al+3 -
O-2 e-
O-2 O-2
Al2O3 (l)
Al (l)
Draw
carbon-lined steel vessel off
acts as cathode Al (l)
Cathode: Al+3 + 3e- Al (l)
Anode: 2 O-2 + C (s) CO2 (g) + 4e- 30
The Hall Process
Cathode: Al+3 + 3e- Al (l) x4
31
The Hall-Heroult Process for Al Production
17_378
Electrodes of
graphite rods
To external
power source
Carbon
dioxide Molten Al 2O3/Na3AlF6
formed at mixture
the anodes
Molten
aluminum
Carbon-lined iron tank
Plug