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  • UV Curing Presentation

    Diunggah oleh

    Si Sam Jo
    643 tayangan26 halaman
    The document summarizes the basic mechanisms of UV curing systems. It describes the composition of UV ink which includes pigments, monomers, oligomers, and photoinitiators. Polymerization occurs through either radical or cationic curing systems initiated by photoinitiators and results in the formation of a 3D network. Different UV curing systems such as radical, cationic, and electron beam have varying properties in terms of reactivity, flexibility, resistances and sensitivity to factors like oxygen and moisture.

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    The document summarizes the basic mechanisms of UV curing systems. It describes the composition of UV ink which includes pigments, monomers, oligomers, and photoinitiators. Polymerization occurs through either radical or cationic curing systems initiated by photoinitiators and results in the formation of a 3D network. Different UV curing systems such as radical, cationic, and electron beam have varying properties in terms of reactivity, flexibility, resistances and sensitivity to factors like oxygen and moisture.

    Hak Cipta:

    Attribution Non-Commercial (BY-NC)
    Unduh sebagai PPT, PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    643 tayangan26 halaman

    UV Curing Presentation

    Diunggah oleh

    Si Sam Jo
    The document summarizes the basic mechanisms of UV curing systems. It describes the composition of UV ink which includes pigments, monomers, oligomers, and photoinitiators. Polymerization occurs through either radical or cationic curing systems initiated by photoinitiators and results in the formation of a 3D network. Different UV curing systems such as radical, cationic, and electron beam have varying properties in terms of reactivity, flexibility, resistances and sensitivity to factors like oxygen and moisture.

    Hak Cipta:

    Attribution Non-Commercial (BY-NC)
    Unduh sebagai PPT, PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    dari 26

    Basic mechanisms of UV curing systems

    Content

    The composition of UV ink

    Polymerisation
    Different UV curing systems

    The composition of UV ink

    The composition of UV ink


    PIGMENTS

    ADDITIVES
    Slip; Stability; Foam

    MONOMERES
    Viscosity; Reactivity

    UV ink

    PHOTOINITIATORES
    Activation of the system; Reactivity

    OLIGOMERES
    Viscosity; Reactivity; Flexibility; Adhesion; Resistances

    The composition of UV ink

    UV ink
    Pigments 12 16 %

    Offset ink
    Pigments 18 22 %

    Solvent based ink


    Pigments 10 12 %

    Monomeres & Oligomeres ~75 %

    Solvents ~70 % Resins & oils 65-80 % Binders ~15 %

    Photoinitiatores 6-10 % Additives 2-4 %

    Additives 2-10 %

    Additives 35 %

    The composition of UV ink

    -Ray
    <10pm

    X-Ray
    10pm-1nm

    UV
    1-380nm

    VIS
    380-700nm

    IR
    700-10000nm

    UV-C

    UV-B

    UV-A

    100-280nm 280-315nm 315-380nm

    Surface curing Complete curing

    Complete curing

    How does the polymerisation happen?

    Radical curing

    P-P
    P-P

    P-P
    Pigment Oligomer Monomer Photoinitiator

    P-P

    P-P

    P-P

    Radical curing
    PP

    . . .P. P

    .P. P

    .P. P

    .P. P
    PP

    . .

    Radical curing
    PP PP

    PP

    PP

    PP

    PP

    Radical curing
    PP PP

    PP

    PP

    PP

    PP

    Radical curing
    PP PP

    PP

    PP

    PP

    PP

    Radical curing
    PP PP

    PP

    PP

    PP

    PP

    Radical curing
    PP PP

    PP

    PP

    PP

    PP

    Radical curing
    PP PP

    PP

    PP

    PP
    PP PP

    PP

    PP

    PP

    A three-dimensional network is formed

    Cationic curing

    P-H
    P-H P-H
    Monomer Photoinitiator Pigment Oligomer

    P-H P-H

    Cationic curing

    P H+ P

    H+

    H+ P

    P H+

    Cationic Curing

    P P H+

    H+

    Cationic Curing

    P P H+

    H+

    Cationic Curing
    H+ P P H+ P H+

    H
    P

    How does the polymerisation happen?

    P P P P

    A three-dimensional network is formed

    Different UV curing systems

    Radical curing RAD H+ Cationic curing

    Polymeric ink layer


    e-

    Electron ray curing

    How does the polymerisation happen?

    On a substrate (0.09 m2) printed with 4 g/m2 UV ink, there are about

    41020
    (400000000000000000000)

    Monomeres/Oligomeres

    Different UV curing systems

    Different UV curing systems


    RADICAL
    Reactivity After drying Adhesion foils Adhesion paper high limited good good

    CATIONIC
    medium complete good very good good very good

    Flexibility
    Resistances Shrinkage Moisture sensitivity Inhibition by O2

    high
    high up to 10% No Yes

    very high
    high < 3% Yes No

    Summary statement:

    The curing of UV ink is initiated by a chemical reaction (polymerisation)

    Different UV systems show different properties Optimal properties of UV inks are achieved by targeting the composition of monomeres, oligomeres, photoinitiators and additives

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