) or
organlc nlLrogen (eg urea (nP
2
)
2
CC)
W 1he lnerL naLure of n
2
means LhaL blologlcally
avallable nlLrogen ls ofLen ln shorL supply ln
naLural ecosysLems llmlLlng planL growLh and
blomass accumulaLlon
W nlLrogen ls an lncredlbly versaLlle elemenL
exlsLlng ln boLh lnorganlc and organlc forms as
well as many dlfferenL oxldaLlon sLaLes
W 1he movemenL of nlLrogen beLween Lhe
aLmosphere blosphere and geosphere ln
dlfferenL forms ls descrlbed by Lhe nlLrogen cycle
one of Lhe ma[or blogeochemlcalcycles
W Slmllar Lo Lhe carbon cycle Lhe nlLrogen cycle
conslsLs of varlous sLorage pools of nlLrogen and
processes by whlch Lhe pools exchange nlLrogen
1he nlLrogen cycle ?ellow arrows lndlcaLe human sources of nlLrogen Lo Lhe
envlronmenL 8ed arrows lndlcaLe mlcroblal LransformaLlons of nlLrogen 8lue arrows
lndlcaLe physlcal forces acLlng on nlLrogen And green arrows lndlcaLe naLural non
mlcroblal processes affecLlng Lhe form and faLe of nlLrogen Lcology LcosysLem
nlLrogen cycle
W lve maln processes cycle nlLrogen Lhrough
Lhe blosphere aLmosphere and geosphere
nlLrogen flxaLlon nlLrogen upLake (organlsm
growLh) nlLrogen mlnerallzaLlon(decay)
nlLrlflcaLlon and denlLrlflcaLlon
Mlcroorganlsms parLlcularly bacLerla play
ma[or roles ln all of Lhe prlnclpal nlLrogen
LransformaLlons
W As mlcroblal medlaLed processes Lhese
nlLrogen LransformaLlons Lend Lo occur fasLer
Lhan geologlcal processes llke plaLe moLlon a
very slow purely physlcal process LhaL ls a parL
of Lhe carbon cycle
W lnsLead raLes are affecLed by envlronmenLal
facLors LhaL lnfluence mlcroblal acLlvlLy such
as LemperaLure molsLure and resource
avallablllLy
-trogen faton
W n
2
nP
4
+
nlLrogen flxaLlon bacLerla ls Lhe process
whereln n
2
ls converLed Lo ammonlum essenLlal
because lL ls Lhe only way LhaL organlsms can
aLLaln nlLrogen dlrecLly from Lhe aLmosphere
W CerLaln bacLerla for example Lhose among Lhe
genus kblzoblom are Lhe only organlsms LhaL flx
nlLrogen Lhrough meLabollc processes
W nlLrogen flxlng bacLerla ofLen form symbloLlc
relaLlonshlps wlLh hosL planLs 1hls symbosls ls
wellknown Lo occur ln Lhe legume famlly of
planLs (eg beans peas and clover)
W ln Lhls relaLlonshlp nlLrogen flxlng bacLerla
lnhablL legume rooL nodules and recelve
carbohydraLes and a favorable envlronmenL from
Lhelr hosL planL ln exchange for some of Lhe
nlLrogen Lhey flx
W 1here are also nlLrogen flxlng bacLerla LhaL exlsL
wlLhouL planL hosLs known as freellvlng nlLrogen
flxers ln aquaLlc envlronmenLs bluegreen algae
(really a bacLerla called cyanobacLerla) ls an
lmporLanL freellvlng nlLrogen flxer
W ln addlLlon Lo nlLrogen flxlng bacLerla hlgh
energy naLural evenLs such as llghLnlng foresL
flres and even hoL lava flows can cause Lhe
flxaLlon of smaller buL slgnlflcanL amounLs of
nlLrogen (lgure 3)
W 1he hlgh energy of Lhese naLural phenomena can
break Lhe Lrlple bonds of n
2
molecules Lhereby
maklng lndlvldual n aLoms avallable for chemlcal
LransformaLlon
W
W JlLhln Lhe lasL cenLury humans have become as
lmporLanL a source of flxed nlLrogen as all naLural
sources comblned
W 8urnlng fossll fuels uslng synLheLlc nlLrogen
ferLlllzers and culLlvaLlon of legumes all flx
nlLrogen
W 1hrough Lhese acLlvlLles humans have more Lhan
doubled Lhe amounL of flxed nlLrogen LhaL ls
pumped lnLo Lhe blosphere every year Lhe
consequences of whlch are dlscussed below
-trogen faton
W uurlng Lhls process a slgnlflcanL amounL of
Lhe nlLrogen conLalned wlLhln Lhe dead
organlsm ls converLed Lo ammonlum
W Cnce ln Lhe form of ammonlum nlLrogen ls
avallable for use by planLs or for furLher
LransformaLlon lnLo nlLraLe (nC
3
) Lhrough Lhe
process called nlLrlflcaLlon
W -trfcaton
W nP
4
+
nC
3
n
2
+ n
2
C 1hrough denLlrflcaLlon oxldlzed
forms of nlLrogen such as nlLraLe and nlLrlLe (nC
2
nC
2
nC n
2
C n
2
and nP
4
+
) presenL ln
surface waLers and solls can also enLer Lhe
aLmosphere as Lhe smogcomponenL nlLrlc oxlde
(nC) and Lhe greenhouse gas nlLrous oxlde (n
2
C)
LvenLually Lhls aLmospherlc nlLrogen can be
blown lnLo nlLrogensenslLlve LerresLrlal
envlronmenLs causlng longLerm changes
or example nlLrogen oxldes comprlse a
slgnlflcanL porLlon of Lhe acldlLy ln acld raln
whlch has been blamed for foresL deaLh and
decllne ln parLs of Lurope and Lhe norLheasL
unlLed SLaLes
lncreases ln aLmospherlc nlLrogen deposlLlon
have also been blamed for more subLle shlfLs
ln domlnanL specles and ecosysLem funcLlon
ln some foresL and grassland ecosysLems
W CurrenLly much research ls devoLed Lo
undersLandlng Lhe effecLs of nlLrogen enrlchmenL
ln Lhe alr groundwaLer and surface waLer
SclenLlsLs are also explorlng alLernaLlve
agrlculLural pracLlces LhaL wlll susLaln hlgh
producLlvlLy whlle decreaslng Lhe negaLlve
lmpacLs caused by ferLlllzer use 1hese sLudles
noL only help us quanLlfy how humans have
alLered Lhe naLural world buL lncrease our
undersLandlng of Lhe processes lnvolved ln Lhe
nlLrogen cycle as a whole
W hLLp//wwwvlslonlearnlngcom/llbrary/module_v
lewerphp?mld98mcldl 13/10/10
W ln 1938 aLmospherlc carbon dloxlde aL Mauna
Loa was abouL 320 parLs per mllllon (ppm)
and ln 2010 lL ls abouL 383ppm
3
W uLure CC
2
emlsslon can be calculaLed by Lhe
kaya ldenLlLy
W 1he envlronmenLal sulphur cycle lnvolves many physlcal chemlcal
and blologlcal agenLs
W As such Lhe flgure lndlcaLes Lhe relaLlonshlps beLween sulphur S
hydrogen sulphlde P
2
S sulphur dloxlde SC
2
and Lhe sulphaLe lon
SC
4
W 1ypes of LcosysLem
W 1erresLrlal AquaLlc ArLlflclal
oresL Crassland ueserL resh waLer Marlne JaLer
W oresL LcosysLem are four Lypes 1hey are
Conlferous ueclduous
W Lvergreen 1roplcal 8alnforesL
W resh waLer LcosysLem are Lwo Lypes
W SLandlng waLer ls called as Len Llc (Lakes ponds
reservolrs)
W 8unnlng JaLer ls called as LoLlc (rlvers sLreams)
W Malnly based on depLh and peneLraLlon of
llghL ln ponds and lakes Lhere are Lhree zones
W LlLLoral shallow waLer zone
W LlmneLlc LlghL peneLraLe open waLer up
W rofound pauclLy of llghL boLLom or deep
waLer zone (no llghL)
W 1he planLs aLLach aL boLLom sedlmenLs or free
1hey geL nuLrlenLs from Lhe sedlmenLs
W LoLlc LcosysLem JaLer currenL ls Lhe ma[or
llmlLlng facLor 1he veloclLy of currenL varles
greaLly dlfferenL parLs of sLreams or rlver As a
resulL of flowlng naLure of Lhe sLreams or rlvers
oxygen Lenslon ls unlform and Lhere ls llLLle or no
Lhermal sLraLlflcaLlon MosL of Lhe planLs are
aLLached flrmly Lo subsLraLes ln order Lo avold
geLLlng carrled away
W 1he anlmals are elLher powerful swlmmers or
Lhey aLLached Lo Lhe subsLraLes by means of
speclal sLrucLures such as suckers or hooks
W Marlne LcosysLem 1he LarLh area 73 ls
covered wlLh oceans 1he ocean waLer ls salLy
1oLal dlssolved solld ln ocean are 73 mg/L
W 1he ocean or sea conslsLs of number of zones
W 1he shallow waLer zone ls called nerlLlc or
conLlnenLal shelf
W 1he zone beLween Lwo Lldes ls called lnLerLldal
zone
W LsLuary LcosysLem 1he esLuary ls parLlally
enclosed coasLal area aL Lhe mouLh of a rlver
where fresh waLer and salLy sea waLer meeL
W LsLuary ls lnfluenced by Lldal acLlon and ln whlch
sea waLer ls consLanLly ln lnLeracLlon wlLh fresh
waLer 1he esLuarles also exporL energy and
nuLrlenLs Lo deeper parLs of Lhe sea 1he
plankLons and nekLons ofLen move beLween boLh
shallow waLer and Lhe deeper parL of esLuarles
nekLon means free swlmmlng organlsms
neusLon means anlmals llvlng are llvlng aL
surface
W ArLlflclal LcosysLem ManlpulaLlon of Lhe
envlronmenLal aLLrlbuLes by man has broughL
ma[or changes ln Lhe ecosysLems whlch have a
resulLed ln arLlflclal ecosysLems le wasLe
LreaLmenL planLs soclal foresLry mechanlzed
agrlculLural farms