Lewis diagrams
Lewis suggested a means of keeping track of outer (or valence) electrons
He
Li Be B C N
O
S
F Cl
Ne
Na
Mg
Si
Ar
group number. For example, hydrogen is in group IA (group 1) and it has one valence electron. Neon is in 0 (group 8) and it has 8 valence electrons. The only exception is He which is in group 8 but has 2 valence electrons. Q1 Write Lewis diagrams for a) Ne, b) Sb (Z=51), c) Rb, d) a neutral atom with 9 total electrons Q2 Write all possible variations of the Lewis diagram for phosphorus.
Q1
Ne Sb Rb F
Q2
P P P P
Most Noble gasses have 8 electrons in their outer shell as shown in the above stable conformation
The Octet Rule When atoms form ions or combine in compounds they obtain electron configurations of the nearest noble gas (usually this means that there will be 8 outer electrons).
The Octet rule and ion formation As stated, when atoms form ions they seek an electron configuration like that of the nearest noble gas. Nearest refers to the number of representative elements between an element and a noble gas. For example Br is 1 space removed from Kr, but 7 spaces removed from Ar (see your periodic table). So, Br would gain 1 electron to form Br. Similarly, Mg would lose 2 electrons to become Mg2+.
Ne
Al
Ca
Resulting ion Br
Group IVA elements are equal distances from two noble gasses. These elements tend not to form ions
Br P Ne Al Ca Noble gas Kr Ar Ne Ne Ar (3) (0) (3) (2) (spaces) (1) Br P 3 none Al 3+ Ca 2+ Ion
In covalent bonding the attraction for electrons is similar for two atoms. They share their electrons to obtain an octet.
Ionic bonding
Ionic bonding involves 3 steps 1) loss of an electron(s) by one element 2) gain of electron(s) by a second element 3) attraction between positive and negative 1)
Na
2)
Cl
3)
Na+ Na+ Cl
2.
3.
Li
Cl
[Li]+ [ Cl ]
Ionic bonding: Mg + O
1.
Mg + O [Mg]2+[O]2
1e8p+ 8n0 12p+ 2e- 8e- 8e- 2e- 8p+ 8n0 12n0
6e- 2e-
1e-
3.
Mg
[Mg]2+ [
]2
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Ionic bonding: Li + O
1. 2Li 2.
1e6e- 2e8p+
3p+ 2e4n0
8e- 2e-
8p+ 8n0
3p+ 2e-1e4n0
1e-
3.
Li Li
[Li]2+ [
]2
Ionic bonding: Al + Cl
1e7e- 8e- 2e17p+ 18n0 8e- 8e- 2e17p+ 18n0
1e-
Ionic bonding: Al + Cl
Al + 3Cl [Al]3+[Cl]3
Cl Al Cl Cl [Al]3+ [ Cl ]3
Covalent bonding
Thus far we have looked at when atoms bond due to the transfer of electrons An ionic bond forms when an atom has a greater attraction for es than a second atom However, if two atoms have approximately the same pull on electrons, they share the electrons (forming a covalent bond) Read Covalent bonding and Covalent bonding continued. Do Q7.
Covalent bonding
Q7 CCl4 - Covalent HCl - Covalent MgF2 - Ionic H Cl NH3 - Covalent H N H H2O - Covalent H O H H OH - Covalent O H
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Cl
Cl C Cl Cl
[Mg]2+[
]2
H2 - Covalent
H H
Multiple bonds
Do Q. 8. Build models of molecules, O3 as challenge (cant build it or ionic) HCl - Covalent CO2 - Covalent Na O - Ionic
2
O O
H C H H C H
O O O