I.

DATA PERCOBAAN & ANALISIS

a.

Data Pembakuan Larutan Baku Sekunder NaOH 0,1 N

Berat KHP

No.

Volume NaOH

Normalitas NaOH

(mg)
(ml)
1.
50,3
0,00 2,70
2.
50,6
0,00 2,40
3.
50,6
0,00 2,40
N NaOH rata rata
Perhitungan Normalitas NaOH

(N)
0,0910
0,1032
0,1032
0,0991

Normalitas NaOH = ____ mg KHP______

BM KHP x Vol. NaOH
N1 =

50,3

= 0,0910 N

204,2 x 2,70
N2 =

50,6

= 0,1032 N

204,2 x 2,40
N3 = _

50,6

= 0,1032 N

204,2 x 2,40
Normalitas (rata-rata) =

0,0910 + 0,1032 + 0,1032

= 0,0991 N

3
Karena BE NaOH = BM NaOH maka normalitas NaOH sama dengan
molaritasnya.
b.

Data Titrasi Asetosal dengan NaOH

Volume
No
.

1.

Volume
Sampel
(ml)

5,0

NaOH
Suhu

Waktu

(C)

(menit)

Volume NaOH (ml)

ratarata
(ml)

40

10

II

III

00,00-8,45

00,00-8,60

00,00-8,55

8,53

5,0

c.

50

5,0

60

40

00,00-8,70

00,00-8,75

00,00-8,90

8,78

70

00,00-8,55

00,00-8,50

00,00-8,60

8,55

100

00,00-8,80

00,00-8,90

00,00-8,90

8,86

10

00,00-8,75

00,00-8,55

00,00-8,60

8,63

40

00,00-9,20

00,00-9,10

00,00-9,15

9,15

70

00,00-9,30

00,00-9,45

00,00-9,20

9,32

100

00,00-10,20

00,00-10,25

00,00-10,40

10,28

10

00,00-8,90

00,00-9,00

00,00-8,90

8,93

40

00,00-9,80

00,00-10,00

00,00-9,90

9.90

70

00,00-10,45

00,00-10,55

00,00-10,50

10,50

100

00,00-11,20

00,00-11,25

00,00-11,30

11,25

Penetapan Kadar Awal Asetosal (C0)

Massa Asetosal

= 13 gram

Massa Na Sitrat

= 26 gram

BE = BM asetosal

= 180,16

Volume

= 500 ml

M Asetosal

13 x 1000

= 0,1443 M

180,16 x 500
Di titrasi 5 ml, sehingga mol asetosal awal

=VxM
= 5 ml x 0,1443 M
= 0,7215 mmol

d.

Perhitungan Konsentrasi Asetosal yang Tersisa (Ct)

Reaksi asetosal :
Asetosal
asam asetat
mula-mula :
bereaksi :
a
sisa
a
Rumus:

0,7215
a

: (0,7215-a)
mek reaksi asetosal

asam salisilat
-

+
-

a
a
= mek NaOH

(0,7215 a) + a + a

= (Vol. NaOH x N NaOH)

0,7215 + a
= (Vol. NaOH x

N NaOH)

a = mek asetosal yang terurai = (Vol. NaOH x N NaOH) 0,7215

mek asetosal yang tersisa = 0,7215 a
1. Suhu 40C
- t = 10 menit
a = Vol. NaOH rata-rata = 8,45 + 8,60 + 8,55 = 8,53 ml
3
b = mek asetosal yang terurai = (8,53 x 0,0991) 0,7215 = 0,1238 mmol
c = mek asetosal yang tersisa = 0,7215 0,1238 = 0,5977 mmol
d = Ct = 0,5977mmol / 5ml = 0,1195M
e = log Ct = -0,9226
-

t = 40 menit
a = Vol. NaOH rata-rata = 8,70 + 8,75 + 8,90 = 8,78 ml
3
b = mek asetosal yang terurai = (8,78 x 0,0991) - 0,7215 = 0,1486 mmol
c = mek asetosal yang tersisa = 0,7215 0,1486 = 0,5729 mmol
d = Ct = 0,5729 mmol / 5 ml= 0,1146 M
e = log Ct = -0,9408

t = 70 menit
a = Vol. NaOH rata-rata = 8,55 + 8,50 + 8,60 = 8,55 ml
3
b = mek asetosal yang terurai = (8,55 x 0,0991) - 0,7215 = 0,1258 mmol
c = mek asetosal yang tersisa = 0,7215 0,1258 = 0,5957 mmol
d = Ct = 0,5957 mmol/ 5ml = 0,1191 M
e = log Ct = -0,9241
-

t = 100 menit

a = Vol. NaOH rata-rata = 8,80 + 8,90 +8,90 = 8,86 ml

3
b = mek asetosal yang terurai = (8,86 x 0,0991) - 0,7215 = 0,1565 mmol
c = mek asetosal yang tersisa = 0,7215 0,1565 = 0,5650 mmol
d = Ct = 0,5650 mmol / 5ml = 0,1130 M
e = log Ct = -0,9469

2. Suhu 50C

t = 10 menit
a = Vol. NaOH rata-rata = 8,75 + 8,55 + 8,60 = 8,63 ml
3
b = mek asetosal yang terurai = (8,63 x 0,0991) - 0,7215 = 0,1337 mmol
c = mek asetosal yang tersisa = 0,7215 0,1337 = 0,5878 mmol
d = Ct = 0,5878 mmol / 5ml = 0,1175 M
e = log Ct = -0,9299

t = 40 menit
a = Vol. NaOH rata-rata = 9,20 + 9,10+ 9,15 = 9,15ml
3
b = mek asetosal yang terurai = (9,15ml x 0,0991) - 0,7215 = 0,1853 mmol
c = mek asetosal yang tersisa = 0,7215 0,1853 = 0,5362 mmol
d = Ct = 0,5362 mmol / 5ml = 0,1072 M
e = log Ct = -0,9698

t = 70 menit
a = Vol. NaOH rata-rata = 9,30 + 9,45 + 9,20 = 9,32 ml
3
b = mek asetosal yang terurai = (9,32 x 0,0991) - 0,7215 = 0,2021 mmol
c = mek asetosal yang tersisa = 0,7215 0,2021 = 0,5194 mmol
d = Ct = 0,5194 mmol / 5ml = 0,1038M
e = log Ct = -0,9838

t = 100 menit

a = Vol. NaOH rata-rata = 10,20 + 10,25 + 10,40 = 10,28 ml

3
b = mek asetosal yang terurai = (10,28 x 0,0991) - 0,7215 = 0,2972 mmol
c = mek asetosal yang tersisa = 0,7215 0,2972 = 0,4243 mmol
d = Ct = 0,4243 mmol / 5ml = 0,0848 M
e = log Ct = -1,0716
3. Suhu 60C
- t = 10 menit
a = Vol. NaOH rata-rata = 8,90 + 9,00 + 8,90 = 8,93 ml
3
b = mek asetosal yang terurai = (8,93 x 0,0991) - 0,7215 = 0,1634 mmol
c = mek asetosal yang tersisa = 0,7215 0,1634 = 0,5581mmol
d = Ct = 0,5581 mmol / 5ml = 0,1116 M
e = log Ct = -0,9523
-

t = 40 menit
a = Vol. NaOH rata-rata = 9,80 + 10,00+9,90 = 9.90 ml
3
b = mek asetosal yang terurai = (9.90 x 0,0991) - 0,7215 = 0,2595 mmol
c = mek asetosal yang tersisa =0,7215 0,2595 = 0,4620 mmol
d = Ct = 0,4620 mmol / 5ml = 0,0924 M
e = log Ct = -1,0343

t = 70 menit
a = Vol. NaOH rata-rata = 10,45 + 10,55 + 10,50 = 10,50 ml
3
b = mek asetosal yang terurai = (10,50 x 0,0991) - 0,7215 = 0,3190 mmol
c = mek asetosal yang tersisa = 0,7215 0,3190 = 0,4025 mmol
d = Ct = 0,4025 mmol / 5ml = 0,0805 M
e = log Ct = -1,0942

t = 100 menit
a = Vol. NaOH rata-rata = 11,20 + 11,25 + 11,30 = 11,25 ml
3

b = mek asetosal yang terurai = (11,25 x 0,0991) - 0,7215 = 0,3933 mmol

c = mek asetosal yang tersisa = 0,7215 0,3933 = 0,3282 mmol
d = Ct = 0,3282 mmol / 5ml = 0,0656 M
e = log Ct = -1,1830

e.

Grafik log Ct terhadap T

1. Suhu 40C

a
b
r
r2

Waktu (x)

Ct(M)

Log Ct (y)

10

0,1195

-0,9336

40

0,1146

-0,9408

70

0,1191

-0,9241

100

0,1130

-0,9469

Ct(M)

Log Ct (y)

= -0,9233
= -1,87 x 10-4
= -0,5991
= 0,0932

2. Suhu 50C
Waktu (x)

10

0.1175

-0.9299

40

0.1072

-0.9698

70

0.1038

-0.9838

100

0.0848

-1.0716

Waktu (x)

Ct(M)

Log Ct (y)

10

0.1116

-0.9523

40

0.0924

-1.0343

70

0.0805

-1.0942

100

0.0656

-1.1830

= -0,879

= -0,0439

= -0,9486

r2

= 0,9

3. Suhu 60C

= -0,8779

= -0,0752

= -0,9974

r2

= 0,995

a. Perhitungan Nilai K pada Masing-masing Suhu

k = 2,303 . log C0
t
Ct
= log C0 - log Ct

k.t
2,303
log Ct

-K

t + Log C0

2,303
Y

b = -k / 2,303
k = -2,303 x b
40C

50C

60C

-0,9233

-1,87 x 10

-4

4,30661

-0,879

-0,8779

-0,0439

-0,0752

0,1011017

x10-4

0,1731856

b. Grafik log k terhadap 1/T

T (C)

T (K)

1/T (x)

Log k (y)

40

313

0,0032

-3,3659

50

323

0,0031

-0,9952

60

333

0,0030

-0,7615

a = 38,66
b = -13022
r = -0,903

Grafik log k terhadap 1/T

-2
-2.2
0.0032
-2.4
-2.6
-2.8
-3
-3.2
-3.4
-3.6

Log k

0.0031

1/T (Kelvin)

c. Penentuan Ea, k27, t1/2, dan t90

K = A -Ea/RT
log K = log A

Ea .

2,303.R T
Y

+
b=

-Ea
2,303 R
Ea = -2,303 x 8,314 x (-3093,5) = 59231, 684Joule

0.003

Log k27

k27

= a + b/(27+273)
= a + b/300
= 38,66+(-13022)/300
= -4,7467
= 1,7919x10-5

t1/2

= 0,693 / k27
= 0,693 / 1,7919x10-5
= 38672,29 menit
= 644 jam 32 menit

t90

= 0,105 / k27
= 0,105 / 1,7919x10-5
= 5859,70 menit
= 97 jam 39 menit