Nama : Fixalis Oktafia

NRP

: 2310 030 085

Menghitung Panas Reaksi pada Suhu T

Reaksi berikut berlangsung pada fase gas, dan konversi reaksinya 90%.
Hitung panas reaksi per gmol gas CO2 pada 3000C dan gas H2 4000C,
sedangkan gas keluar pada reactor dengan suhu 5000C.
CO2(g) + 4H2(g)

2H2O(g) + CH4(g)

Basis 1 gmol gas CO2

Tabulasi :
CO2(g) +

4H2(g)

H0f Reaksi konversi 90%

H0f CO2(g) = 0,9 (-354,15) = -318,735
H0f H2O(g) = 0,9 (-217,64)=-195,876
H0f CH4(g) = 0,9 (-67,35)= -60,615
H0f H2(g) = 0
H0produk = 2(H0f 2H2O(g)) + (H0f CH4(g))
= 2(-195,876) + (-60,615)
= -452,367 J
= -108,118 cal
H0reaktan = (H0f CO2(g)) + 4(H0f H2(g))
= -318,735 J
= -76,179 Cal
Hreaksi = H0produk - H0reaktan
= [-108,118 -(-76,179)]
= [-108,118 + 76,179]
= -31,939 Cal
Satuan Cp = Cal/gmol k
Cp CO2= 6,339 + 10,14010-3 T - 3,41510-6 T2
Cp H2 = 6,946 0,19610-3 T + 0,475710-6 T2
Cp H2O

= 7,136+ 2,64010-3 T + 0,045910-6 T2

Cp CH4 = 3,204 + 18,4110-3 T 4,4810-6 T2

2H2O(g)

CH4(g)

 = [0,9(13,204) + 0,9(27,136)] + [0,1(16,339) +

0,1(46,946)] - [0,9(16,339) + 0,9(46,946)]
= [2,8836 + 12,8448] + [0,6339 + 2,7784] [5,7051 + 25,0056]
= [15,7284 + 3,4123 - 30,7107]
= -11,57
= [(0,9(118,41) + 0,9(2 2,640)) x 10-3] + [(0,1(1 10,140) 0,1(4 x 0,196)) 10-3] - [(0,9(1 10,140) + 0,9(4 -0,196)) x 103

= [(16,569 + 4,752) x 10-3] + [(1,014 0,0784) 10-3] [(9,126

0,7056) 10-3]
= (21,321 + 0,9356 8,4204) x 10-3
= 13,8362 10-3
= [(0,9(1 (-4,48) + 0,9(2 0,0459)) x 10-6] + [(0,1(1 (-3,415))
+ 0,1(4 0,4757)) 10-6] - [(0,9(1 (-3,415)) + 0,9(4
0,4757)) 10-6]
= [((-4,032) + 0,08262) x 10-6] + [((-0,3415) + 0,19028) x 10-6]
[((-3,0735) + 1,71252) x 10-6]
= ((-3,94938) + (-0,15122) + 1,36098) x 10-6
= -2,73962 10-6
Hreaksi

= [-31,939] + [-

11,57(773-273)] + [ (13,8362 10-3) (7732 - 2732)]

[ (-2,73962 10-6) (7733 - 2733)]
= [(-31,939) + (-5785) + (1729,525) (-114,151)]
= -3973,263 Cal