Kolom Destilasi 27 EG dan DEG

21 Konversi 99%

25.000kg\jam

402,787 Kmol

31

EG, EC dan DEG

Data (Backer,1985) Data (Kawabe,1998)

KomposisiX1EG = 0,99 KomposisiX3EG=0,2482 KomposisiX2EG=0,99

Kompisoso X1DEG =0,009 KomposisiX3DEG=0,6263 KomposisiX2DEG=0.01

Komposisi X1EC= 0.001 KomposisiX3EC=0,1255

Neraca Massa Total N1= N2 + N3

EG= X1EGN1 = X3EGN3 + X2EGN2

0,99 N1 = 0,2483 N3 + 0,99.25252,5253 kg/jam

0,99 N1 = 0,2483 N3 + 25000 kg/jam

0,99 N1 = 0,2483 N3 + 402,784 kmol/jam .................. (1)

DEC= X1DEC N1 = X1DEC N3 + X2DEC N2

0,009 N1 = 0,6263 N3 + 0,01 (25252,5253 kg/jam)

0,009 N1 = 0,6263 N3 + 252,525253 kg/jam

0,009 N1 = 0,6263 N3 + 2,3823 Kmol/jam ................ (2)

Eliminasi persamaan (1) dan (2)

0,99 N1 - 0,2483 N3 = 402,784 x 0.009 0,00891 N1 - 0,0022 N3 =3,625056

0,99 N1 - 0,6263 N3 = 2,3823 x 0,99 0,00891 N1 0,6200 N3 =2,358477 -

0,6222 N3 =1,266579

N3 = 2,03564

0,0089 N1 0,0022 N3 = 3,625056

0,0089 N1 0,0022.2,3564 = 3,625056

0,0089 N1 0,00518408 = 3,625056

0,0089 N1 = 3,63024

N1 = 407,8921

N2 = 407,8921 Kmol/jam

N3 = 2,03564 Kmol/jam

Alur 21

Total = N21 = 407,8921 Kmol/jam

EG = N21 . X21EG = 407,8921 x 0,99 = 403,81318 Kmol/jam

DEG = N21 . X21DEG = 407,8921 x 0,009 = 3,67103 Kmol/jam

EC = N21 . X31EC = 407,8921 x 0,001 = 0,4078 Kmol/jam

Alur 31

Total = N31 = 2,03564 Kmol/jam

EG = N31 . X31EG = 2,03564 x 0,2482 = 0,50524 Kmol/jam

DEG = N31 . X31DEG = 2,03564 x 0,6263 = 1,27492 Kmol/jam

EC = N31 .X31EC = 2,03564 x 0,1255 = 0,25547 Kmol/ja

 Alur27

N27 = 407,8921 - 2,03564 = 405,85647 Kmol/jam

EG = N27 . X27EG = 405,85647 x 0,99 = 401,7979053 Kmol/jam

DEG = N27 . X27DEG = 405,85647 x 0,01 = 4,017979 Kmol/jam

Kompon BM AlurMasuk (21) (27) Alurkeluar (31)

en Kmol/jam Kg/jam Kmol/ja Kg/jam Kmol/ja Kg/jam
m m
C2H6O2 62,068 403,81318 25063,8765 401,7979 24938,792 0,50524 31,35923
C4H10O 106 3,67103 389,12918 4,017979 425,9057 1,27492 135,14152
3
C3H4O3 88,06 0,4078 35,910868 - - 0,25547 22,4966882
Total 407,89201 25488,9165 405,8158 25364,6977 2,03653 188,997438
5 2
 KONDENSOR

Table LA.2 Konstanta persamaan tekanan uap Antoine:

In Psat = A-B/T+C ( P dalam Kpa T dalam Celcius )

Konstanta persamaan, tekanan uap Antoine (P dalam Kpa dan T dalam Kelvin )

Komponen A B C
C2H6O2 16,1847 4493,79 -82,1026
C4H10O3 17,6738 6034,08 -53,2122
C3H4O3 13,1897 3985,44 -68,9974
(sumber :Reklatis 1983)

Menentukan kondisi umpan

Umpan masuk pada kondisi uap jenuh (trial umpan sampai syarat)

P = 1 bar = 100 Kpa

TBP = 197c =470,15 K

Table LA.3 titik didih umpan masuk destilasi

Komponen Yif Pi Ki Xif=Yif\Ki Aif=Ki\khk

C2H6O2 0,9900 99,9012 0.9990 0.9910 4,0664
C4H10O3 0,0090 24,5675 0,2457 0,0366 1
C3H4O3 0,0010 1469,2572 14,6926 0,0001 59,8049
Total 1 1,0276
(sumber: Reklaitis 1983)

Menentukan kondisi operasi atas (kondensor total)

Untuk mengetahui suhu pada destilat, maka perlu perhitungan trial dew point
sampai syarat yid/ki = 1 terpenuhi

P = 0,1 mPa =100 Kpa

TDP = 195c = 468,15 K

Table LA.4 Dew Point Destilat

Komponen Yid Pi Ki Yid\K Aid

C2H6O2 0,9941 94,0839 0,9408 1,0566 4,1063
C4H10O3 0,0059 22,9122 0,2291 0,0257 1
C3H4O3 0 1407,3073 14,0731 0 61,4218
Total 1 1,0823

Menentukan Kondisi Operasi Bottom (reboiler)

Untuk mengetahui suhu Vb, maka perlu perhitungan train bubble point
sampai syarat xy,ki = 1 terpenuhi

P = 0,141 Mpa = 141 Kpa

TBP = 252c = 525,15 K

Table LA.5 Boiling point produk bawah

Komponen Xib Pi Ki Xib.Ki aib

C2H6O2 0,2482 401,7360 3,9776 0,7073 3,1968
C4H10O3 0,6263 125,6666 1,2442 0,5582 1
C3H4O3 0,1255 82,6114 0,8178 0,0735 0,6574
Total 1,3390
Table LA.6 Omega point Destilat

= 0,0001 dan =1,1

Komponen Xif Alfa1 (alfa*Xif)(alfa I-

teta)
C2H6O2 0,9910 4,0664 1,3585
C4H10O3 0,0366 1,0000 -0,3663
C3H4O3 0,0001 59,8049 0,0001
Total 1,0276 6,1211 0,9921

Komponen Xi.d Alfai (alfa I*Xid)(alfa I-

teta)
C2H6O2 0,9941 4,1063 1,3579
C4H10O3 0,0059 1,0000 -0,0588
C3H4O3 0 0 0
Total 1,0000 1,2991

Mencari Refluks Minimum

Umpan masuk 468,15 k, sehingga q = 0

1 q = 1 XF1

Rm + 1 = 1,2991

Rm = 0,2991

Rd = 1,5 Rm ........ (Geankopplis)

Rd = 1,5 . 0,2991

= 0,4486

Rd = Ld/D

Ld = Rd x D

= 0,4486 x 405,85647
 = 182,0672 Kmol/jam

Alur LD (alur 26)

Total = Ld = 182,0672 kmol/jam

EG = LdEG = X19EG x Ld = 0,99 x 182,0672 = 180,24653

DEC = Lddec = X19DEC x Ld = 0,01 x 182,0672 = 1,820672

Alur 27 = 21

Total = F21 = F27 = 405,85647 Kmol/jam

EG = F21EG = F27EG = 401,7979053 Kmol/jam

DEG = F21DEG = F27DEG = 4,017979 Kmol/jam

Alur Vd (alur 25)

F25 = F26 + F27 = 587,92368 Kmol/jam

EG = F26EG + F27EG = 180,24653 + 401,7979053 = 582,0444

DEG = F26DEG + F26DEG = 1,820672 + 4,017979 = 5,838651

Kompone BM Alur masuk (25/Vd) (26) alur keluar (27)

n Kmol/jam Kg/jam Kmol/jam Kg/jam Kmol/jam Kg/jam
C2H6O2 62,068 582,0444 36126,332 180,24653 11187,5416 401,79790 24938,79206
C4H10O3 106 5,838651 618,897006 1,820672 192,991232 4,017979 425,905774
C3H4O3 18 - - - - - -
Total 587,88305 36745,2290 182,06720 11380,5328 405,81587 25364,69783
1 1 2 3 9
 REBOILER
Berdasarkan geankoplis (1997) untuk kondisi umpan dalam keadaan tidak jenuh q = 0

Lb = Vb + B atau Lb = Ld + (q+f) q = 0

Lb = Ld + (0 x f)

Lb = Ld

Lb = 182,0672 Kmol/jam

Maka :

Lb = VB + B

VB = LB - B

=182.0672 - 2,03564

= 180,03156 kmol/jam

Komposisi : X31EG = XvbEG = XLDEG = 0,2482

X31DEG = XVBDEG = XLDDEG = 0,6263

X31EC = XVBEC = XLDEC = 0,1255

Alur Lb

Total Lb = B + Vb = 182,0672 kmol/jam

Etilen glikol = LBEG = 182,0672 x XLDEG

= 182,0672 x 0,2482 = 45,18907904 kmol/jam

Dietilen glikol = LBDEG = 182,0672 x XLDDEG

=182,0672 x 0,6263 = 114,0286874 Kmol/jam

Etilen karbonat = LBEC = 182,0672 x XLDEC

= 182,0672 x 0,1255 = 22,8494336 Kmol/jam

 Alur Vb

Total Vb = Lb B = 180,03156 Kmol/jam

Etilen glikol = VbEG = 180,03156 x XVBEG = 44,68383319 Kmol/jam

Dietilen glikol = VbDEG = 180,03156 x XVBDEG = 112,753766 Kmol/jam

Etilen Karbonat = VbEC = 180,03156 x XVBEC = 22,59396078 Kmol/jam

Kompone BM Alur masuk (LB) (31) alur keluar (VB)

n Kmol/jam Kg/jam Kmol/jam Kg/jam Kmol/jam Kg/jam
C2H6O2 62,068 45,1890790 0,50524 44,6838331
4 9
C4H10O3 106 114,028687 1,27492 112,753766
4
C3H4O3 8 22,8494336 0,25547 22,5939607
8
Total 182,0672 2,03564 180,03156
 FLASH DRUM

32 EG dan DEG

31

35 EC

Dimana dari perhitungan reboiler diperoleh perhitungan sebagai berikut:

Alur 31 (Bottom = B)

N31 = 2,03564 Kmol/jam

N31eg = 0,50524 Kmol/jam

N31deg = 1,27492 Kmol/jam

N32ec = 0,25547 Kmol/jam

Menentukan Pi saturated

Konstanta Persamaan tekanan uap Antoine lnP = A - (B-\T+c) P dalam Kpa, T dalam
K

Komponen A B C
C2H6O2 16,1847 4493,79 -82,1026
C4H10O3 17,6738 6034,08 -53,2122
C3H4O3 13,1897 3985,44 -68,9974

Tekanan uap jenuh komponen T = 250c = 523,15 K

Komponen Pvp
C2H6O2 401,735991
C4H10O3 125,6666344
C3H4O3 82,61138182
Menentukan Pbuble dengan Zi = Xi

Pb = Xi . Pivp .... (Smith,2001)

Pb = 185,5116329

Menentukan Pdew Dengan Zi = Xi

Pdew = 1\yi\PIsat

P = 141 Kpa Pd < P < Pb

Karena P yang dihitung terletak antara Pb dan Pdew

Ki = Pisat / P

K1 = 2,849191425

K2 = 0,891252726

K3 = 0,585896325

Data trial temperatur dan komposisi Flash Drum

Kompone Xi Pi Ki(Pi/P) XiPi KiXi 1/(Yi/Pi)

n
C2H6O2 0,2353 401,7360 8,1179 94,5406 0,6705 0,0006
C4H10O3 0,6457 125,6666 0,7943 81,1424 0,5755 0,0051
C3H4O3 0,1190 82,6114 16,7944 9,8286 0,0697 0,0014
185,512 139,5847

Penentuan komposisi umpan dan bottom flash drum I mol umpan total (alur
31
31) N = 2,05364 kmol/jam

Vj+1 = Vj f (Vj)

F1 (Vj)

J = 0,1,2,3 .............................. dst dilakukan iterasi Vj+1 = Vj (Smith, 2001)

Iterasi
 Vo = 0,7240

F (Vo) = 0,0001

F1 (Vo) = 1,1265

V1 = 0,7240 ( 0,0001 ) = 0,7241

-1,1265

Zi . F = Xi . L + Yi . V . L Yi = Ki . Xi

Zi F = Xi . L + Ki . Xi V

Zi . F = Xi ( L + Ki . V )

Xi = Zif

L + Ki . V

Basis F = 1 mol maka Xi = Zi

L + Ki . V

Maka V = 0,8

Table LA.12 Nilai V flash drum

Komponen Zi.Ki Ki-I Sum(zi.ki\(1+v(ki-

1))
EG 0,6705 1,8492 0,2704
DEG 0,5755 -0,1087 0,6303
EC 0,0697 -0,4141 0,1042
1,005

Dimana L = I V = 0,2

Y1 = 0,27043 = 0

Y2 = 0,63031

Y4 = 0.10424 = 0

Y1 = 1.00499
 Dari hasil diatas diperoleh, pada produk atas terdapat semua dietilen glikol
dan etilen glikol ( temperature Flash drum 250c (523,15 k ) jauh melebihi titik didih
senyawa tersebut pada 1,41 atm (141 Kpa) sedangkan semua etilen karbonant
terdepat pada bagian bottom, karena tidak menguap kebagian destilat neraca massa
komponen :

Etilen Glikol = F31EG = F32EG + O x F35EG

= 0,505241 Kmol/jam

Dietilen Glikol = F31DEG = F32DEG + O x F35DEG

= 1,27492 Kmol/jam

Etilen Karbonat = F31EC = F32EC + O x F35EC

= 0,25547 Kmol/jam

Tabel LA.13 Tabel Neracamassa Flash Drum

Komponen BM Alur masuk

N(Kmol/jam) F(kg/jam)
C2H6O2 62,068 0,50524 31,359
C4H10O3 106 1,27492 135,14152
C3H4O3 88,06 0,25547 22,496

Alur Keluar
Komponen Alur Atas Alur Bawah
N (kmol/jam) F (kg/jam) N (kmol/jam) F (kg/jam)
C2H6O2 0,50524 31,359 0 0
C4H10O3 1,27492 135,14152 0 0
C3H4O3 0 0 0,25547 22,496
Total 1,78016 166,50052 0,25547 22,496
Evaporator 19 EO

EG

DEG 18 20

EC

EO

H2O

CO2

Asumsi efisiensi penguapan air pada evaporator = 100% alur keluar F20 =
407,89201 km01/jam = 25488,91655

Data (bhise : 1983)

Komposisi X18FG = 0,739 Komposisi X19H20 = 0,9485

Komposisi X18H20 = 0,243 Komposisi X 19C20 = 0,0484

Komposisi X19EO = 0,0031

Neraca massa total

F18 = F19 + F20

Neraca massa komponen

Etilen glikol = N18 = 0 x N19 = N20

0,739 x N18 = N20 407,89201 kmol/jam .................... (3)

Air = F18air = F19air + F20air

0,243 F18 = 0,9485. F19air .............................. (4)

Eleminasi pers (3) & (4)

EG = 0,739 N18 + 0 N19 = 407,89201 x 0,243 0,179577 N18 + 0 N19 =99,117

Air = 0,243 N18 0,9485 N19 = 0 x 0,739 0,179577 N18 0,70094 N19 = 0 -
 0,7009 N19 = 99,1177

N19 = 141,414

N18 = N19 = N20

= 141,414 + 407,8921

= 549,3061Kmol/jam

Alur 19
Total = N19 = 141,414 kmol/jam

Air = N19 x X19air = 141,414 x 0,9485 =134,131179 kmol/jam

CO2 = N19 x X19CO2 = 141,414 x 0,0484 = 6,8444376 kmol/jam

EO = N19 x X19EO = 141,414 x 0,0031 = 0,43838341 kmol/jam

Alur 18
Total N18 = N19 + N20 = 549,3061kmol/jam

EG = N18EG = 403,81318kmol/jam

DEG = N10DEG = 3,67103kmol/jam

EC = N18DEG = 0,4078kmol/jam

Air = N18H2O = 134,131179 kmol/jam

CO2 = N18CO2 = 6,8444376kmol/jam

EO = N18EO = 0,4383834kmol/jam
 Neraca Massa Evaporator
Kompone BM AlurMasuk 19 AlurKeluar 20
n
N F (kg/jam) N F N F (kg/jam)
(kmol/jam) (kmol/jam) (kg/jam) (kmol/jam
)
C2H6O2 62,06 403,81318 25063,8764 - - 403,81318 25063,87646
8 6
C4H10O3 106 3,67103 389,12918 - - 3,67103 389,12918
H2O 18 134,131179 2414,36122 134,131179 2414,36122 - -
2 2
C3H4O3 88,06 0,4078 35,910868 - - 0,4078 35,910868
CO2 44 6,8444376 301,155254 6,8444376 301,155254 - -
1 4
C2H4O 44,05 0,4383834 19,3121039 0,4383834 19,3121039 - -
3 2 2
Total 549,3001 28223,7450 141,414 2734,82858 407,8921 25488,91655
9
Separator 11
Diasum

- Alur masuk F17 = 549,3061

kmol/jam
- Separatur dapat memisahkan CO2
sebanyak 90%
Data (Bhise, 1983)

Komposisi X15EO = 0,018

Komposisi X15CO2 = 0,3921

Menentukan Pisaturated
Tabel LA.15 Konstanta persamaan tekanan uap antoine In P = A (B/(T-C)) (P dalam
Kpa, T dalam K)

Komponen A B C
C2H4O2 16,1847 4493,79 -82,1026
C4H10O3 17,6738 6034,08 -53,2122
H2O 16,5362 3985,44 -38,9974
C3H4O3 13,1897 3985,44 -68,9974
CO2 15,3768 1956,25 -2,1117
C2H4O 14,5116 2478,12 -33,1582
Sumber:Reklaitis, 1983
Tabel LA.16 tekanan uap jenuh komponen pada T = 148C = 421,15 K

Komponen PVP
C2H6O2 2,105678324
C4H10O3 0,305328832
H2O 100,4032116
C3H4O3 1,090108871
CO2 24451,16737
C2H4O 1370,369892

Menentukan Pbuble dengan Zi = Xi

Pb = Xi ,PiVp ............ (Smith 2001)

Pb = 9598,110797 Kpa

Menentukan P dew denganZi = Yi

P dew = 1 ............ (Smith, 2001)

Yi / Pisat

P dew = 3,683940099 kPa

P = 250 kPaPd< P <Pb

Karena P yang dihitung terletak antara Pbuble dan Pdew

Ki = Pisat / P

K1 = 0,008422713

K2 = 0,001221315

K3 = 0,401612846

K4 = 0,004360435

K5 = 97,80466948

K6 = 5,48147957
Substitusi nilai K ke pers (10,16)

[(Zi, Ki)/(1+V(Ki-1))] = 1 ....................... (Smith, 2001)

V = 0,39

Tabel LA.17 nilai V separator 1

Komponen Zi . Ki Ki 1 Sum(Zi,Ki/(1+V(Ki-1))
H2O 0,0257 -0,5984 0,0335
CO2 38,3524 96,8047 0,9629
C2H4O 0,0099 4,4815 0,0036
1
Dimana L = 1-V = 0,61

Denganpers (10,16) ............... (Smith, 2001)

Yi ((Zi , Ki)/(1+V(Ki-1))) Y3 = 0,0335

Y5 = 0,9629

Y6 = 0,0036Yi = 1

Dengan pers (10,10) ............... (Smith, 2001)

Xi = Yi/Ki

X3 = 0,0834

X5 = 0,0101

X6 = 0,0007

Xi = 0,0941

Neraca Massa total: N15 = N16 + N17

CO2 F16CO2 = F16CO2 + F17CO2

0,3921 = 0,9896 N16 + 6,8444376 ................ (5)

EO F15EO = F16EO + F17EO

0,0018 = 0,0036 N16 + 0,4383834 .................(6)

Eliminasi persamaan 5 dan 6

CO2 0,3921 N15=0,9896 N16+6,8444376 x0,0018 7,0578x10-4N15=0,0017812

EO 0,0018 N15=0,0036 N16+0,4383834 x0,3921 70578x10-4N15

N16 = 431,6906828kmol/jam N15 = N16 + N17

N15 = 980,9967828kmol/jam = 431,6906828 + 549,3061

= 980,9967828

Alur 16
Total = N16 = 431,6906828kmol/jam

Air = 431,6906828 x 0,0335 = 14,46163787

CO2 = 431,6906828 x 0,9629 = 415,6749585

EO = 431,6906828 x 0,0036 = 1,554086458

Alur 15
Total N15 = 980,9967828kmol/jam

EO: N15 = 0 + 403,81318 = 403,81318 kmol/jam

DEC: N15DEC = 0 + 3,67103 = 3,67103 kmol/jam

EC: N15EC = 0 + 0,4078 = 0,4078 kmol/jam

H2O:N15H20 = 14,46163787 + 134,131179 = 148,5928169 kmol/jam

CO2: N15CO2 = 415,6749585 + 6,8444376 = 4235193961 kmol/jam

 EO: N15EO = 1,554086458 + 0,4383834 = 1,992469858 kmol/jam

Kompone BM AlurMasuk 15 16 AlurKeluar 17

n
N F (kg/jam) N F N F (kg/jam)
(kmol/jam) (kmol/jam) (kg/jam) (kmol/jam)
C2H6O2 62,06 403,81318 25063,87646 - - 403,81318 25063,87646
8
C4H10O3 106 3,67103 389,12918 - - 3,67103 389,12918
H2O 18 148,5928169 2674,670704 14,4616378 260,3094817 134,131179 2414,361222
7
C3H4O3 88,06 0,4078 35,910868 - - 0,4078 35,910868
CO2 44 422,5193961 18590,85343 415,674958 18289,69817 6,8444376 301,1552544
5
C2H4O 44,05 1,992469858 87,77427465 1,55408645 68,46217073 0,4383834 19,31210392
3 8
Total 980,9967828 46842,21492 431,690682 18618,46982 549,3061 28223,74509
8
Reaktor Hidrolis
6 Air

EC

EO 12

CO2

13 DEG

Air

EC

EO

CO2

EG
Data:

Dari ekspunder diperoleh data laju alir sebagai berikut:

N13 = 980,9967828 N13EC = 0,4078

N13EG = 403,81318 N13CO2 = 422,5193961

N13DEG = 3,67103 N13EO = 1,992469858

N13H20 = 148,5928169

Neraca massa total:

F13 = F6 + F12

Reaksi 1

C3H4O3(l) + H2O(g) C2H6O2(l) + CO2(g)

M=x

B = 0,95 x

S = 0,5 x

Neraca komponen

EG = N13 = N6EG + N12EG + r1

r1 = 403,81318 kmol/jam

Air = N13air = N6air r1 r2

148,5928169 = N6air 403,81318 r2 .................. (7)

EC = N13EC = N12EC r1 2 r1
 0,4078 = N12EC 403,81318 2 r2 .................... (8)

CO2 = N13CO2 = N12CO2 + r1 + 2 r2

422,5193961 = N12CO2 + 403,81318 2 r2 .............. (9)

Reaksi 2

2 C3H4O3(l) + H2O(g) C4H10O3(l) + 2 CO2(g)

Neraca komponen

DEG = N13DEG = N6DEG + N12DEG + r2

T2 = N13DEG + (N6DEG N12DEG) = 3,67103 + (0-0) = 3,67103 kmol/jam

EO = N13EO = N12EO = 1,992469858 kmol/jam

Air = 148,5928169 = N6air 403,81318 3,67103

N6air = 148,5928169 + 403,81318 + 3,67103 = 556,0770269 kmol/jam

EC = 0,4078 = N12EC 403,81318 2 (r2)

N12EC = 0,4078 + 403,81318 + 2 (3,67103) = 411,56304 kmol/jam

CO2 = 422,5193961 = N12CO2 + 403,81318 2 (r2)

N12CO2 = 422,5193961 403,81318 + 2 (3,67103) = 26,0482761 kmol/jam

Neraca Massa Reaktor Hidrolisis

Kompone BM AlurMasuk 15 6 AlurKeluar 12
n
N F (kg/jam) N F N F (kg/jam)
(kmol/jam) (kmol/jam) (kg/jam) (kmol/jam)
C2H6O2 62,06 403,81318 25063,87646 - - - -
8
C4H10O3 106 3,67103 389,12918 - - - -
H2O 18 148,5928169 2674,670704 556,077026 10009,38648 - -
9
C3H4O3 88,06 0,4078 35,910868 - - 411,56304 36242,2413
CO2 44 422,5193961 18590,85343 - - 26,0482761 1146,124148
C2H4O 44,05 1,992469858 87,77427465 - - 1,99246985 87,7742746
3 8 5
Total 980,9967828 46842,21492 556,077026 - 439,603786 37476,1397
9 2

Separator 1
9

EC CO2

EO 8 EC

CO2EO

10

EC

EO
 CO2

Dari data perhitungan di R Hidrolisis diperoleh laju alir 10 yaitu: 439,603786

kmol/jam
Data (bhise, 1983):
Komposisi x8co2 = 0,004
Komposisi x8EO = 0,018

Menentukan Pi Saturated
Tabel konstanta persamaan tekanan uap antoine In P = A (B/(T+C)) P dalam kPa T
dalam K

Komponen A B C
CO2 15,3768 1956,25 -2,1117
C2H4O 14,5116 2478,18 -33,1582
C3H4O3 13,1897 3985,44 -68,9974
(Sumber: Reklaitis: 1983)

Tabel tekanan uap jenuh komponen pada T = 100C = 373,15K

Komponen PVP
CO2 24451,17
C2H4O 1370,37
C3H4O3 1,090109

Menentukan P Buble denganZi = Xi

Pb = Xi .PNP ........ (Smith, 2001)

Pb = 1116,851 kPa

Menentukan Pdew dengan Zi = Yi

P dew = 1 ................... (Smith, 2001)

Yi/Pisat

Pdew = 1,337 kPa

P = 250 kPaPd< P <Pb

Konsep P yang dihitung terletak antara P buble dan Pdew

Ki = Pisat / P

K1 = 97,80467

K2 = 5,48148

K3 = 0,00436

Substitusi kepersamaan (10.16)

[(Zi.Ki)/(1+V(ki-1))] = 1 ............. (Smith, 2001)

Tabel nilai V separator 1

Komponen Zi, Ki Ki-1 Sum [(Zi,ki/(1+V(ki-1))]
CO2 17,65525 96,8047 0,9581
C2H4O 0,0226 4,4815 0,0125
C3H4O3 0,0036 -0,9956 0,0043
0,9749

Dalam L = 1 V

= 1 0,18

= 0,82

Dengan persamaan (10,16) ................. (Smith, 2001)

Yi = ((Zi, Ki)//1+V(Ki-1))

Y1 = 0,9581

Y2 = 0,0125

Y3 = 0,0043

Yi = 0,9749

Dengan pers (10,10) ..................... (Smith, 2001)

Xi = Yi/Ki

X1 = 0,0098
X2 = 0,0023

X3 = 0,9934

Xi = 1,0855

Neraca total Massa

N8 = N9 + N10

Neraca Massa Komponen

EC = N9EC + N10EC ......................... (10)

CO2 = 0,004 N8 = 0,9581 N9CO2 + 26,0482761 ............. (11)

EO = 0,018 N8 = 0,0125 N9EO + 1,992469858 ............. (12)

Reaktor karbonasi
Co2

4 7

EO EO,DEG dan EG

Data (bhisem,1983)

Konversi reaksi = 99%

Dari data perhitunga di ekspender I diperoleh data:

N7= 466,4067896 kmol/jam

N7ec = 411,6812602 kmol/jam

N7co2 = 52,38939594 kmol/jam

N7EO = 2,336133348 kmol/jam

Reaksi :

C2H4O+CO2 C C3H4O3

M= X

B= 0,99X

S=0,1 X

Neraca massa total:

Alur7

EC=N7ec=N2ec+N4ec-r

r=N7EC-(N2ec+N4ec)= 411,6812602-0=411,6812602 kmol/jam

EO=N7eo=N2eo + N4eo r

N4eo= 2,33361333348+411,6812602=414,6812602 kmol/jam

CO2= N7co2= N2co2+N4co2 r

N2co2= 52,38939594-0 + 411,6812602=464,0706561

Kompo BM Alur keluar 7 2 Alur masuk 4

nen N(Kmol/j F(Kg/ja N(Kmol/ F(Kg/ja N(Kmol/ F(Kg/ja
am m) jam) m) jam) m)
C3H4 88,06 411,6812 36252,6 - - - -
O3 602 5177
CO2 44 52,38939 2305,13 464,0706 20419,1 - -
594 3421 561 6887
C2H4o 44,05 2,334613 102,913 - - 414,0173 18238,7
30 3348 6824 935 0824
TOTA 466,4067 3860,69 464,0706 20419,1 414,0173 18238,7
L 896 887 561 0887 935 0824

Eliminasi Nominasi Persamaan pers 11 & 12

0,004N8=0,9581 N9+26,0482761 x0,018 7,2x10-5N8=0,0172458N9+0,468868969

0,018 N8=0,0125N9+1,992469858 x0,004 7,2x10-5N =0,00005N9+0,007969879432

0,0171958N9 =0,460899089

N9 =26,80300358

N9 = 26,80300358 kmol/jam

N8 = 466,4067896 kmol/jam

N10 = 439,603786 kmol/jam

Alur 9
Total N9 = 26,80300358 kmol/jam

EC = N9 x Y9ec = 27,49307989 x 0,0043 = 0,118220243

CO2= N9 x Y9Co2= 27,49307989 x 0,9581 = 26,341111984

EO=N9 x Y9eo = 27,49307989 x o,0125 = 0,34366349

Alur 8
Total N8= 466,4067896 kmol/jam

EC= N8ec = N9ec + N10 = 0,118220243 + 411,56304 = 411,6812602

CO2= N8co2= N9co2 + N10co2= 26,34111984+26,0482761 = 52,38939594

EO=N8eo= N9eo + N10eo = 0,3436634951,992469858 = 2,336133348

NERACA MASSA
Kompon BM Alur masuk 8 9 Alur masuk 10
en N(Kmol/ja F(Kg/jam) N(Kmol/ja F(Kg/jam) N(Kmol/ja F(Kg/jam)
m m) m)
C3H4O 88,06 411,68126 36252,65 0,1182202 10,41047 411,56304 36242,24
3 02 177 43 46 13
CO2 44 52,389395 2305,133 26,341119 1159,0092 26,048276 1146,1241
94 421 84 73 1 48
C2H4o 44,05 2,3346133 102,9136 0,3436634 15,13940 1,9924698 87,77427
30 348 824 9 772 58 465
TOTAL 466,40678 3860,698 26,803003 1184,5591 439,60378 37476,13
96 87 58 55 6 972