Data kapasitas panas sebagai fungsi suhu

Komponena b c d e
CH4 38.387 -0.073664 0.000291 -2.64E-07 8.007E-11
C2H6 33.8339 -0.015518 0.0003769 -4.12E-07 1.389E-10
C3H8 47.2659 -0.131469 0.00117 -1.7E-06 8.189E-10
i-C4H10 52.9035 -0.107178 0.0013804 -2.07E-06 1.009E-09
n-C4H10 66.7088 -0.185523 0.0015284 -2.19E-06 1.046E-09
i-C5H12 41.9952 0.0744763 0.0010258 -1.61E-06 7.794E-10
n-C5H12 83.1454 -0.241925 0.0019465 -2.81E-06 1.353E-09
C6H14 42.7147 0.199102 0.0007895 -1.28E-06 5.915E-10
CO2 19.0223 0.079629 -7.37E-05 3.746E-08 -8.13E-12
N2 29.4119 -0.003007 5.451E-05 5.132E-09 -4.25E-12
H2S 34.5234 -0.017648 6.767E-05 -5.32E-08 1.407E-11
H2O 34.0471 -0.009651 3.3E-05 -2.04E-08 4.302E-12
H2 17.6386 0.0670055 -0.000131 1.059E-07 -2.92E-11
CO 29.0063 0.0024924 -1.85E-05 4.799E-08 -2.87E-11
O2 29.8832 -0.011384 4.338E-05 -3.7E-08 1.01E-11
Data Panas Reaksi Pembentukan
KomponenHf (kJ/moHf (kJ/kmol)
CH4 -74.8884 -74888.4
C2H6 -84.7206 -84720.6
C3H8 -103.892 -103892
i-C4H10 -13.4573 -13457.3
n-C4H10 -126.202 -126202
i-C5H12 -154.54 -154540
n-C5H12 -146.503 -146503
C6H14 -167.265 -167265
CO2 -393.674 -393674
N2 0 0
H2S -20.1756 -20175.6
H2O -241.939 -241939
H2 0 0
CO -110.589 -110589
ZnO -348 -348000
ZnS -202.9 -202900
 Tref 25 298.15
T2 30 303.15
T3 415 688.15
T9 450 723.15
T10 299 572.15

Perhitungan Cp Pada T = 30 Perhitungan Cp Pada T = 415 Perhitungan Cp Pada T = 450

KomponenCp dt KomponenCp dt Komponen Cp dt
CH4 180.1295 CH4 18002.922694 CH4 20048.25
C2H6 265.9037 C2H6 29770.625455 C2H6 33281.08
C3H8 370.3572 C3H8 43008.487398 C3H8 48044.04
i-C4H10 487.6926 i-C4H10 56655.409706 i-C4H10 63257.49
n-C4H10 490.8682 n-C4H10 56303.553163 n-C4H10 62862.21
i-C5H12 598.312 i-C5H12 69554.459581 i-C5H12 77677.84
n-C5H12 605.5762 n-C5H12 69406.801436 n-C5H12 77478.88
C6H14 720.1026 C6H14 82552.554103 C6H14 92131.6
CO2 186.2588 CO2 17157.193057 CO2 18895.08
N2 167.698 N2 16479.847968 N2 18411.33
H2S 170.0096 H2S 14370.048254 H2S 15789.06
H2O 15054.32
H2 12514.93
CO 12758.32

Umpan Masuk HE 1 Umpan Keluar HE 1

Stream 2 Stream 3
Komponenmassa (kg)kmol Cp dt Q3 Komponenmassa (kg) kmol
CH4 15901.74 993.8589 180.1295 179023.3 CH4 15901.742 993.8589
C2H6 1231.917 41.0639 265.9037 10919.04 C2H6 1231.917 41.0639
C3H8 971.0634 22.06962 370.3572 8173.645 C3H8 971.06343 22.06962
i-C4H10 246.7166 4.253734 487.6926 2074.515 i-C4H10 246.71657 4.253734
n-C4H10 310.7295 5.357405 490.8682 2629.78 n-C4H10 310.72952 5.357405
i-C5H12 112.1127 1.55712 598.312 931.6439 i-C5H12 112.11267 1.55712
n-C5H12 77.56223 1.077253 605.5762 652.3589 n-C5H12 77.562226 1.077253
C6H14 131.7977 1.532531 720.1026 1103.579 C6H14 131.79765 1.532531
CO2 1152.747 26.19881 186.2588 4879.759 CO2 1152.7474 26.19881
N2 604.8552 21.60197 167.698 3622.606 N2 604.85517 21.60197
H2S 10.7567 0.316373 170.0096 53.7865 H2S 10.756696 0.316373
214064

dq/dt -8179779 Masuk 72992885 21512246

Keluar 72992885 -29692026
Selisih 0
n Cp Pada T = 450 Perhitungan Cp pada T = 299
KomponenCp dt
CH4 11727.62
C2H6 19040.5
C3H8 27531.27
i-C4H10 36316.73
n-C4H10 36116.84
i-C5H12 44549.93
n-C5H12 44549.48
C6H14 53002.18
CO2 11589.46
N2 10698.97
H2S 9826.587
H2O 9490.227
H2 8058.233
CO 8103.112

Gas Converter Masuk HE 1 Gas Converter Keluar HE 1

Stream 9 Stream 10
Cp dt Q4 Komponenmassa (kg)kmol Cp dt Q9 Komponen
18002.92 17892364 CH4 1590.174 99.38589 20048.25 1992513 CH4
29770.63 1222498 C2H6 6.159585 0.20532 33281.08 6833.255 C2H6
43008.49 949181.1 C3H8 97.10634 2.206962 48044.04 106031.4 C3H8
56655.41 240997 i-C4H10 49.34331 0.850747 63257.49 53816.1 i-C4H10
56303.55 301641 n-C4H10 62.1459 1.071481 62862.21 67355.67 n-C4H10
69554.46 108304.7 i-C5H12 22.42253 0.311424 77677.84 24190.75 i-C5H12
69406.8 74768.69 n-C5H12 15.51245 0.215451 77478.88 16692.87 n-C5H12
82552.55 126514.3 C6H14 19.76965 0.22988 92131.6 21179.18 C6H14
17157.19 449498 CO2 48410.43 1100.237 18895.08 20789064 CO2
16479.85 355997.2 N2 604.8552 21.60197 18411.33 397721 N2
14370.05 4546.301 H2O 5566.596 309.2553 15054.32 4655627 H2O
21726310 H2 8420.212 4210.106 12514.93 52689161 H2
CO 303.7684 10.84887 12758.32 138413.4 CO2
80958600
Gas Converter Keluar HE 1
Stream 10
massa (kg)kmol Cp dt Q10
1590.174 99.38589 11727.62 1165560
6.159585 0.20532 19040.5 3909.387
97.10634 2.206962 27531.27 60760.47
49.34331 0.850747 36316.73 30896.34
62.1459 1.071481 36116.84 38698.51
22.42253 0.311424 44549.93 13873.92
15.51245 0.215451 44549.48 9598.213
19.76965 0.22988 53002.18 12184.12
48410.43 1100.237 11589.46 12751149
604.8552 21.60197 10698.97 231118.8
5566.596 309.2553 9490.227 2934903
8420.212 4210.106 8058.233 33926013
303.7684 10.84887 8103.112 87909.63
51266574
Tref 25 298.15
T3 415 688.15
T4 425 698.15

Umpan Masuk Desulfur

Perhitungan Cp pada T=415 Perhitungan Cp pada T=425 Stream 3
KomponenCp dt komponenCp dt Komponen
CH4 18002.92 CH4 18580.36 CH4
C2H6 29770.63 C2H6 30761.5 C2H6
C3H8 43008.49 C3H8 44430.25 C3H8
i-C4H10 56655.41 i-C4H10 58520.24 i-C4H10
n-C4H10 56303.55 n-C4H10 58155.83 n-C4H10
i-C5H12 69554.46 i-C5H12 71849.21 i-C5H12
n-C5H12 69406.8 n-C5H12 71686.54 n-C5H12
C6H14 82552.55 C6H14 85260 C6H14
CO2 17157.19 CO2 17651.2 CO2
N2 16479.85 N2 17022.28 N2
H2S 14370.05 H2O 14113.99 H2S

Perhitungan entalpi reaksi

KomponenReaktan (kProduk (k Hf 250C (kJ/kmol)
Hf 250C (kJ/jam) dq/dt (kJ/ 674079.2
H2S 0.316373 0 -20175.6 -6383.01
ZnO 0.318854 0 -348000 -110961 Total enta 22400390
ZnS 0 0.318854 -202900 -64695.5 Total ental 22400390
H2O 0 0.318854 -241939 -77143.3
-24494.6
Umpan Masuk Desulfur Umpan Keluar Desulfur
Stream 4
massa (kg)kmol Cp dt Q3 komponenmassa (kg)kmol Cp dt Q4
15901.74 993.8589 18002.92 17892364 CH4 15901.74 993.8589 18580.36 18466258
1231.917 41.0639 29770.63 1222498 C2H6 1231.917 41.0639 30761.5 1263187
971.0634 22.06962 43008.49 949181.1 C3H8 971.0634 22.06962 44430.25 980558.8
246.7166 4.253734 56655.41 240997 i-C4H10 246.7166 4.253734 58520.24 248929.5
310.7295 5.357405 56303.55 301641 n-C4H10 310.7295 5.357405 58155.83 311564.3
112.1127 1.55712 69554.46 108304.7 i-C5H12 112.1127 1.55712 71849.21 111877.9
77.56223 1.077253 69406.8 74768.69 n-C5H12 77.56223 1.077253 71686.54 77224.55
131.7977 1.532531 82552.55 126514.3 C6H14 131.7977 1.532531 85260 130663.6
1152.747 26.19881 17157.19 449498 CO2 1152.747 26.19881 17651.2 462440.4
604.8552 21.60197 16479.85 355997.2 N2 604.8552 21.60197 17022.28 367714.8
10.7567 0.316373 14370.05 4546.301 H2O 5.694721 0.316373 14113.99 4465.292
21726310 22424884
T4 425 698.15
T5 350 623.15
T25 300 573.15
Tref 25 298.15

Perhitungan Cp pada T=425 Perhitungan Cp pada T=350 Perhitungan Cp Pada T=300

stream 4 stream 5 Stream 25
komponenCp dt komponenCp dt KomponenCp dt
CH4 18580.36 CH4 14389.03 H2O 9526.191
C2H6 30761.5 C2H6 23578.73
C3H8 44430.25 C3H8 34100.15
i-C4H10 58520.24 i-C4H10 44957.4
n-C4H10 58155.83 n-C4H10 44689.73
i-C5H12 71849.21 i-C5H12 55165.05
n-C5H12 71686.54 n-C5H12 55109.41
C6H14 85260 C6H14 65556.12
CO2 17651.2 CO2 13998.64
N2 17022.28 N2 13129.04
H2O 14113.99 H2O 11339.04
Stream 4 Stream 5
komponenmassa (kg)kmol Cp dt Q4 komponenmassa (kg)kmol
CH4 15901.74 993.8589 18580.36 18466258 CH4 15901.74 993.85885
C2H6 1231.917 41.0639 30761.5 1263187 C2H6 1231.917 41.063902
C3H8 971.0634 22.06962 44430.25 980558.8 C3H8 971.0634 22.069623
i-C4H10 246.7166 4.253734 58520.24 248929.5 i-C4H10 246.7166 4.2537339
n-C4H10 310.7295 5.357405 58155.83 311564.3 n-C4H10 310.7295 5.3574055
i-C5H12 112.1127 1.55712 71849.21 111877.9 i-C5H12 112.1127 1.5571205
n-C5H12 77.56223 1.077253 71686.54 77224.55 n-C5H12 77.56223 1.0772531
C6H14 131.7977 1.532531 85260 130663.6 C6H14 131.7977 1.5325308
CO2 1152.747 26.19881 17651.2 462440.4 CO2 1152.747 26.198805
N2 604.8552 21.60197 17022.28 367714.8 N2 604.8552 21.60197
H2O 5.694721 0.316373 14113.99 4465.292 H2O 44427.25 2468.1808
22424884

Total enta 45335028

Total ental 45335028
selisih 0
 Stream 25
Cp dt Q5 Komponenmassa (kg)kmol Cp dt Q25
14389.03 14300669 H2O 44421.56 2467.864 9526.191 23509348
23578.73 968234.7
34100.15 752577.5
44957.4 191236.8
44689.73 239421
55165.05 85898.63
55109.41 59366.78
65556.12 100466.8
13998.64 366747.6
13129.04 283613.2
11339.04 27986796 22910144
45335028

dq/dt -599204.75
T5 350 623.15 Fluida dingin
T6 500 773.15 Fluida dingin
T29 27 300.15 Fluida Panas
T30 100 373.15 Fluida Panas
Tref 25 298.15

Perhitungan Cp Pada T=350 Perhitungan Cp Pada T=500 Perhitungan Cp Pada T=27

Stream 5 Stream 6 Stream 29
komponenCp dt komponenCp dt komponenCp dt
CH4 14389.03 CH4 23084.97 N2 66.98715
C2H6 23578.73 C2H6 38493.35 O2 58.89936
C3H8 34100.15 C3H8 55531.94
i-C4H10 44957.4 i-C4H10 73060.21
n-C4H10 44689.73 n-C4H10 72605.64
i-C5H12 55165.05 i-C5H12 89725.07
n-C5H12 55109.41 n-C5H12 89472.08
C6H14 65556.12 C6H14 106302.2
CO2 13998.64 CO2 21418.83
N2 13129.04 N2 21336.25
H2O 11339.04 H2O 16958.47

Perhitungan Q5 Perhitungan Q6
Stream 5 Stream 6
komponenmassa (kg)kmol Cp dt Q5 komponenmassa (kg)kmol
CH4 15901.74 993.8589 14389.03 14300669 CH4 15901.74 993.8589
C2H6 1231.917 41.0639 23578.73 968234.7 C2H6 1231.917 41.0639
C3H8 971.0634 22.06962 34100.15 752577.5 C3H8 971.0634 22.06962
i-C4H10 246.7166 4.253734 44957.4 191236.8 i-C4H10 246.7166 4.253734
n-C4H10 310.7295 5.357405 44689.73 239421 n-C4H10 310.7295 5.357405
i-C5H12 112.1127 1.55712 55165.05 85898.63 i-C5H12 112.1127 1.55712
n-C5H12 77.56223 1.077253 55109.41 59366.78 n-C5H12 77.56223 1.077253
C6H14 131.7977 1.532531 65556.12 100466.8 C6H14 131.7977 1.532531
CO2 1152.747 26.19881 13998.64 366747.6 CO2 1152.747 26.19881
N2 604.8552 21.60197 13129.04 283613.2 N2 604.8552 21.60197
H2O 44427.25 2468.181 11339.04 27986796 H2O 44427.25 2468.181
45335028

Q furnace 24391805
Perhitungan Cp pada T=100
Stream
komponenCp dt
N2 2603.258
O2 2226.293

Perhitungan Massa udara pembakar

Stream 29
Cp dt Q6 komponenKomposisi Cp dt ko Cp dt ko Cp dt UdaCp dt uda
23084.97 22943199 N2 0.79 66.98715 2603.258
65.28871 2068.943
38493.35 1580687 O2 0.21 58.89936 2226.293
55531.94 1225569
73060.21 310778.7
72605.64 388977.8
89725.07 139712.7
89472.08 96384.08
106302.2 162911.4
21418.83 561147.7
21336.25 460905.1
16958.47 41856561
69726833
Mr kompoQ Furnace mol (kmol)Mr Udara Massa TotalMassa Komponen (kg)
28 277359.8
24391805 12173.66 28.84 351088.4
32 73728.57
T6 500 773.15 Umpan
T7 820 1093.15 Produk
T20 30 303.15 Reformer Fuel
T28 100 373.15 Udara dari Furnace
T29 55 328.15 Power Generator
T32 55 328.15 Purge
Tref 25 298.15

Perhitungan Cp Pada T=500 Perhitungan Cp pada T=820 Perhitungan Cp pada T=30

Stream 6 Stream 7 Stream 20
komponenCp dt komponenCp dt KomponenCp dt
CH4 23084.97 CH4 45197.9 CH4 180.1295
C2H6 38493.35 C2H6 76206.7 C2H6 265.9037
C3H8 55531.94 C3H8 116814.3 C3H8 370.3572
i-C4H10 73060.21 i-C4H10 152464.5 i-C4H10 487.6926
n-C4H10 72605.64 n-C4H10 151701.5 n-C4H10 490.8682
i-C5H12 89725.07 i-C5H12 182776.9 i-C5H12 598.312
n-C5H12 89472.08 n-C5H12 187669.9 n-C5H12 605.5762
C6H14 106302.2 C6H14 211300.5 C6H14 720.1026
CO2 21418.83 CO2 38480.63 CO2 186.2588
N2 21336.25 N2 45467.84 N2 167.698
H2O 16958.47 H2O 29889.36 H2 142.6888
H2 23482.67 CO 145.7445
CO 24610.07

Perhitungan Q6
Perhitungan Cp pada T=100 Perhitungan Cp pada T=55 Perhitungan Cp pada T=55
Stream 28 Stream 32 Stream 29
komponenCp dt KomponenCp dt KomponenCp dt
N2 2603.258 CH4 1095.838 N2 1018.09
O2 2226.293 C2H6 1638.898 O2 886.0128
C3H8 2297.959
i-C4H10 3028.522
n-C4H10 3041.134
i-C5H12 3716.798
n-C5H12 3752.159
C6H14 4467.008
CO2 1133.971
N2 1018.09
H2 860.8431
CO 874.9938
O2 886.0128