TUGAS KELOMPOK

AZAS TEKNIK KIMIA

Disusun oleh :

1. Mayrani Ainun Charisama P. (21030116060067)

2. Nissa Ayu Maulinda (21030116060072)
3. Kartika Mi’raj Novelgi (21030116060077)
4. Fajrin Nur Amirullah (21030116060088)

PSD III TEKNIK KIMIA

UNIVERSITAS DIPONEGORO
SEMARANG
𝐻𝑎𝑠𝑖𝑙 𝑝𝑒𝑚𝑏𝑎𝑘𝑎𝑟𝑎𝑛 𝐶𝐻4 𝑑𝑒𝑛𝑎𝑔𝑎𝑛 𝑂2 𝑑𝑎𝑟𝑖 𝑢𝑑𝑎𝑟𝑎 𝑚𝑒𝑛𝑔ℎ𝑎𝑠𝑖𝑙𝑘𝑎𝑛 𝑟𝑒𝑎𝑘𝑠𝑖 𝑠𝑒𝑏𝑎𝑔𝑎𝑖 𝑏𝑒𝑟𝑖𝑘𝑢𝑡:

𝐶𝐻4 + 𝑂2 → 𝐻𝐶𝑂𝐻 + 𝐻2𝑂

𝐶𝐻4 + 2𝑂2 → 𝐶𝑂2 + 2𝐻2𝑂

𝑅𝑒𝑎𝑘𝑠𝑖 𝐼 𝑎𝑑𝑎𝑙𝑎ℎ 𝑟𝑒𝑎𝑘𝑠𝑖 𝑢𝑡𝑎𝑚𝑎

𝐵𝑖𝑙𝑎 𝑑𝑖𝑘𝑒𝑡𝑎ℎ𝑢𝑖 𝑑𝑒𝑟𝑎𝑗𝑎𝑡 𝑘𝑒𝑠𝑒𝑚𝑝𝑢𝑟𝑛𝑎𝑎𝑛 𝑟𝑒𝑎𝑘𝑠𝑖

= 95% 𝑑𝑎𝑛 𝑑𝑎𝑟𝑖 𝐶𝐻4 𝑦𝑎𝑛𝑔 𝑏𝑒𝑟𝑒𝑎𝑘𝑠𝑖 95% 𝑏𝑒𝑟𝑒𝑎𝑘𝑠𝑖 𝑠𝑒𝑠𝑢𝑎𝑖 𝑝𝑒𝑟𝑠𝑎𝑚𝑎𝑎𝑛 𝑟𝑒𝑎𝑘𝑠𝑖 𝐼

𝑑𝑎𝑛 𝑠𝑖𝑠𝑎𝑛𝑦𝑎 𝑏𝑒𝑟𝑒𝑎𝑘𝑠𝑠𝑖 𝑠𝑒𝑠𝑢𝑎𝑖 𝑝𝑒𝑟𝑠𝑎𝑚𝑎𝑎𝑛 𝑟𝑒𝑎𝑘𝑠𝑖 𝐼𝐼.

𝐻𝑖𝑡𝑢𝑛𝑔𝑙𝑎ℎ 𝑘𝑜𝑚𝑝𝑖𝑠𝑖𝑠𝑖 𝑔𝑎𝑠 ℎ𝑎𝑠𝑖𝑙 𝑝𝑒𝑚𝑏𝑎𝑘𝑎𝑟𝑎𝑛 (𝑔ℎ𝑝) 𝑦𝑎𝑛𝑔 𝑑𝑖𝑛𝑦𝑎𝑡𝑎𝑘𝑎𝑛 𝑑𝑎𝑙𝑎𝑚,

a. 𝐷𝑟𝑦 𝑏𝑎𝑠𝑖𝑠
b. 𝑊𝑒𝑡 𝑏𝑎𝑠𝑖𝑠

𝐽𝑎𝑤𝑎𝑏 ∶

𝐵𝑎𝑠𝑖𝑠 = 10,000 𝑙𝑏

𝐵𝑀 𝑢𝑑𝑎𝑟𝑎 = (0.79 𝑥 28) + (0.21 𝑥 32) = 28.84 𝑙𝑏/𝑚𝑜𝑙

𝑀𝑜𝑙 𝑢𝑑𝑎𝑟𝑎 = 10,000 / 28.84 = 346.740 𝑙𝑏/𝑚𝑜𝑙

𝑂2 = 0.21 𝑥 346.740 = 72.815 𝑙𝑏/𝑚𝑜𝑙

𝑁2 = 0.79 𝑥 346.740 = 273.924 𝑙𝑏/𝑚𝑜𝑙

100
𝑂2 𝑡ℎ𝑒𝑜𝑟𝑖𝑡𝑖𝑠 = 𝑥 72.815 = 36. 407 𝑙𝑏/𝑚𝑜𝑙
100 + 100

𝐶𝐻4 + 𝑂2 → 𝐻𝐶𝑂𝐻 + 𝐻2𝑂

100
𝐶𝐻4 𝑦𝑎𝑛𝑔 𝑑𝑖𝑔𝑢𝑛𝑎𝑘𝑎𝑛 𝑙𝑏/𝑚𝑜𝑙 = 𝑥 36.407 = 38.323 𝑙𝑏/𝑚𝑜𝑙
95

5
𝐼𝑛𝑒𝑟𝑡 𝑑𝑎𝑙𝑎𝑚 𝑙𝑏/𝑚𝑜𝑙 = 𝑥 38.323 = 1.916 𝑙𝑏/𝑚𝑜𝑙
100
𝐶𝐻4 100% 𝑑𝑎𝑙𝑎𝑚 𝑙𝑏 = 36.407 𝑥 16 = 585,512 𝑙𝑏

100
𝐶 𝑦𝑎𝑛𝑔 𝑑𝑖𝑔𝑢𝑛𝑎𝑘𝑎𝑛 = 𝑥 582.512 = 613.170 𝑙𝑏
95

5
𝐼𝑛𝑒𝑟𝑡 = 𝑥 582.512 = 29.125 𝑙𝑏
100

CH4 95% 𝑥 34.586 =

32.856 𝑙𝑏/𝑚𝑜𝑙
CH4 95% 𝑥 36.407 =
34.586 𝑙𝑏/𝑚𝑜𝑙
CH4 CH4 5% 𝑥 34.586 =
100% 1.729 𝑙𝑏/𝑚𝑜𝑙
CH4 5% 𝑥 36.407 =
1.820 𝑙𝑏/𝑚𝑜𝑙

(I) 𝐶𝐻4 + 𝑂2 → 𝐻𝐶𝑂𝐻 + 𝐻2𝑂

(II) 𝐶𝐻4 + 2𝑂2 → 𝐶𝑂2 + 2𝐻2𝑂

𝑂2 𝑠𝑖𝑠𝑎 = 𝑂2 𝑑𝑎𝑙𝑎𝑚 𝑢𝑑𝑎𝑟𝑎 – 𝑡𝑜𝑡𝑎𝑙 𝑢𝑑𝑎𝑟𝑎 𝑑𝑎𝑙𝑎𝑚 𝑟𝑒𝑎𝑘𝑠𝑖

= 72.815 − (32.856 + 3.458)

= 36.501 𝑙𝑏/𝑚𝑜𝑙

𝐶𝐻4 𝑠𝑖𝑠𝑎 = 1.820 𝑙𝑏/𝑚𝑜𝑙

𝑂𝑢𝑡𝑝𝑢𝑡

𝐶𝐻4 𝑡𝑜𝑡𝑎𝑙 = 32.856 + 1.729 = 34.585 𝑙𝑏/𝑚𝑜𝑙

𝑂2 𝑡𝑜𝑡𝑎𝑙 = 72.815 𝑙𝑏/𝑚𝑜𝑙

𝑁2 = 273.924 𝑙𝑏/𝑚𝑜𝑙

𝐶𝑂2 = 1.729 𝑙𝑏/𝑚𝑜𝑙

𝐻𝐶𝑂𝐻 = 32.856 𝑙𝑏/𝑚𝑜𝑙

𝐻2𝑂 = 32.856 + 3.458 = 36.314 𝑙𝑏/𝑚𝑜𝑙

a. Wet basis
Komposisi Jumlah mol % Komposisi
CH4 total 34.585 𝑙𝑏𝑚𝑜𝑙 7.64 %
O2 total 72.815 𝑙𝑏𝑚𝑜𝑙 16.101 %
N2 273.924 𝑙𝑏𝑚𝑜𝑙 60.572%
CO2 1.729 𝑙𝑏𝑚𝑜𝑙 0.382%
H2O 36.314 𝑙𝑏𝑚𝑜𝑙 8.303 %
HCOH 32.856 𝑙𝑏𝑚𝑜𝑙 7.265%
Jumlah 452.223 𝑙𝑏𝑚𝑜𝑙 99.987%

b. Dry basis
Komposisi Jumlah mol % Komposisi
CH4 total 34.585 𝑙𝑏𝑚𝑜𝑙 8.315 %
O2 total 72.815 𝑙𝑏𝑚𝑜𝑙 18.228 %
N2 273.924 𝑙𝑏𝑚𝑜𝑙 65.861%
CO2 1.729 𝑙𝑏𝑚𝑜𝑙 0.415%
HCOH 32.856 𝑙𝑏𝑚𝑜𝑙 7.899%
Jumlah 415.909 𝑙𝑏𝑚𝑜𝑙 100.718%