Bab 4

Neraca Massa dan Neraca Panas

BAB 4
NERACA MASSA DAN NERACA PANAS

Kapasitas Produksi : 85.000 ton/ tahun

Operasi : 300 hari/ tahun
Basis Perhitungan : 1 jam operasi

4.1. Neraca Massa

4.1.1. Tangki Pelarut (TP-01)
a. Pada saat Start Up
Neraca Massa di Tangki Pelarut (TP-01)
Input (kg)
Komponen Output (kg)
Feed Pelarut
NaClO3 19795,127 - 19795,127
H2O 75,599 79081,035 79156,634
Cl2 19,895 - 19,895
K 1,989 - 1,989
Ca 0,995 - 0,995
Fe 0,995 - 0,995
19894,600 79081,035
Total 98975,635
98975,635

b. Pada kondisi Steady State

Neraca Massa di Tangki Pelarut (TP-01)

Komponen Input (kg) Output (kg)
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Neraca Massa dan Neraca Panas

Feed Recycle
NaClO3 18980,244 814,883 19795,127
H2O2 - 2742,868 2742,868
H2SO4 - 22391,571 22391,571
H2O 72,416 79084,214 79156,634
Cl2 3,581 16,314 19,895
K 0,398 1,591 1,989
Ca 0,199 0,796 0,995
Fe 0,199 0,796 0,995
19057,037 105053,037
Total 124110,074
124110,074

4.1.2. Mixing Point (MP-01)

a. Pada saat Start Up
Neraca Massa di Mixing Point-01 (MP-01)
Input (kg)
Komponen Output (kg)
TP-01 T-02
NaClO3 19795,127 - 19795,127
H2O2 - 6324,493 6324,493
H2O 79156,634 - 79156,634
Cl2 19,895 - 19,895
K 1,989 - 1,989
Ca 0,995 - 0,995
Fe 0,995 - 0,995
98975,635 6324,493
Total 105300,128
105300,128

b. Pada Kondisi Steady State

Neraca Massa di Mixing Point-01 (MP-01
Input (kg)
Komponen Output (kg)
TP-01 T-02
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Neraca Massa dan Neraca Panas

NaClO3 19795,127 - 19795,127

H2O2 2742,868 3581,625 6324,493
H2SO4 22391,571 - 22391,571
H2O 79156,634 - 79156,634
Cl2 19,895 - 19,895
K 1,989 - 1,989
Ca 0,995 - 0,995
Fe 0,995 - 0,995
124110,074 3581,625
Total 127691,699
127691,699

4.1.3. Reaktor-01 (R-01)

a. Pada saat Start Up
Neraca Massa di Reaktor-01 (R-01)
Input (kg) Output (kg)
Komponen
MP-01 T-03 AB-01 FP-01
NaClO3 19795,127 - - 986,573
H2O2 6324,493 - - 3321,204
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Neraca Massa dan Neraca Panas

H2SO4 - 35774,469 - 27111,764

H2O 79156,634 729,933 - 83066,520
Cl2 19,895 - - 19,895
K 1,989 - - 1,989
Ca 0,995 - - 0,995
Fe 0,995 - - 0,995
ClO2 - - 11924,823 -
Na2SO4 - - - 12543,147
O2 - - 2826,625 -
105300,128 36504,402 14751,448 127053,082
Total
141804,530 141804,530

b. Pada kondisi Steady State

Neraca Massa di Reaktor-01 (R-01
Input (kg) Output (kg)
Komponen
MP-01 T-03 AB-01 FP-01
NaClO3 19795,127 - - 986,573
H2O2 6324,493 - - 3321,204
H2SO4 22391,571 13382,898 - 27111,764
H2O 79156,634 729,933 - 83066,520
Cl2 19,895 - - 19,895
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Neraca Massa dan Neraca Panas

K 1,989 - - 1,989
Ca 0,995 - - 0,995
Fe 0,995 - - 0,995
ClO2 - - 11924,823 -
Na2SO4 - - - 12543,147
O2 - - 2826,625 -
127691,699 14112,831 14751,448 127053,082
Total
141804,530 141804,530

4.1.4. Filter Press (FP-01)

Neraca Massa di Filter Press-01 (FP-01)
Input (kg) Output (kg)
Komponen
R - 01 Air Pencuci RD-01 T-01
NaClO3 986,573 - 4,748 981,825
H2SO4 3321,204 - 16,313 3304,891
H2O2 27111,764 - 133,891 26977,873
H2O 83066,520 12705,288 409,829 95361,979
Cl2 19,895 - 0,099 19,796
K 1,989 - 0,010 1,979
Ca 0,995 - 0,004 0,991
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Neraca Massa dan Neraca Panas

Fe 0,995 - 0,004 0,991

Na2SO4 12543,147 - 12543,147 -

127053,082 12705,288 13108,045 126650,325

Total
139758,370 139758,370

4.1.5. Rotary Dryer (RD-01)

Neraca Massa di Rotary Dryer-01 (RD-01)
Input (kg) Output (kg)
Komponen
FP - 01 Udara SC-01 Udara + Debu
NaClO3 4,748 - 4,655 0,093
H2SO4 16,313 - 15,916 0,397
H2O2 133,891 - 130,508 3,383
H2O 409,829 - 12,335 397,494
Cl2 0,099 - 0,097 0,002
K 0,010 - 0,0097 0,0003
Ca 0,004 - 0,0039 0,0001
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Neraca Massa dan Neraca Panas

Fe 0,004 - 0,0039 0,0001

Na2SO4 12543,147 - 12229,608 313,539
Udara - -

Total 13108,045 12393,136

4.1.6. Absorber (AB-01)

Neraca Massa di Absorber-01 (AB-01)
Input (kg) Output (kg)
Komponen
R-01 Absorbent Vapor Liquid
ClO2 11924,823 - 119,248 11805,575
H2O - 123924,657 34,019 123890,638
O2 2826,625 - 2826,625 -
14751,448 123924,657 2979,892 135696,213
Total
138676,105 138676,105

4.2. Neraca Panas

4.2.1. Neraca Panas Tangki Pelarut (TP-01)

Q masuk (kkal) Q keluar (kkal)

Q1 = 21.140,640
Q2 = 223.813,270 Q3 = 243.996,471
Qs = -957,439
ΣQ= 243. 996 , 471 ΣQ= 243. 996 , 471

4.2.2. Neraca Panas Mixing Point (MP-01)

Q masuk (kkal) Q keluar (kkal)

Q3 = 243.996,471
Q5 = 255.215,394
Q4 = 11.218,923
ΣQ=255. 215 , 394 ΣQ=255. 215 , 394
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Neraca Massa dan Neraca Panas

4.2.3. Neraca Panas Heater – 01 (H-01)

Q masuk (kkal) Q keluar (kkal)
Q5 = 255.215,394 Q6 = 2.853.836,933
Qin = 4.244.151,638 Qout = 1.645.530,099
∑ Q=4 . 499 . 367 , 032 ∑ Q=4 . 499 . 367 , 032

4.2.4. Neraca Panas Heater -02 (H-02)

Q masuk (kkal) Q keluar (kkal)

Q7 = 31.954,802 Q8 = 358.634,765
Qin = 533.544,142 Qout= 206.864,169
∑ Q=565. 498 , 944 ∑ Q=565. 498 , 944

4.2.5. Neraca Panas Reaktor (R-01)

Q masuk (kkal) Q keluar (kkal)

Q6 = 2.853.836,933 Q9 = 137.902,213
Q8 = 358.634,765 Q10 = 2.879.515,229
Qin = 687.123,039 Qout = 5.267.943,299
Qr = -4.385.766
∑Q = 3 . 899 .594 ,737 ∑ Q = 3 . 899 .594 ,737

4.2.6. Neraca Panas Cooler -01 (C-01)

Qmasuk (kkal/jam) Qkeluar(kkal/jam)

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Neraca Massa dan Neraca Panas

Q10 = 2.879.515,229 Q11 = 259.260,867

Qin = 393.038,154 Qout = 3.013.292,516
∑Q = 3.272.553,383 ∑Q = 3.272.553,383

4.2.7. Neraca Panas Cooler – 02 (C-02)

Qmasuk (kkal/jam) Qkeluar(kkal/jam)

Q9 = 137.902,213 Q12 = 12.810,128
Qin = 18.763,813 Qout = 143.855,898
∑Q = 156.666,026 ∑Q = 156.666,026

4.2.8. Neraca Panas Absorber (AB -01)

Qmasuk (kkal/jam) Qkeluar(kkal/jam)

Q12 = 12.810,128 Q13 = 3.774,039
Q14 = 255.994,911 Q15 = 265.029,972
∑Q = 268.804,040 ∑Q = 268.804,040

4.2.9. Neraca Panas Filter Press (FP-01)

Qmasuk (kkal/jam) Qkeluar (kkal/jam)

Q11 = 259.260,867 Q16 = 15.685,801
Q17 = 26.245,596 Q18 = 269.820,662
∑Q = 285.506,463 ∑Q = 285.506,463

4.2.10. Neraca Panas Rotary Dryer (RD – 01)

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Neraca Massa dan Neraca Panas

Q masuk(kkal/jam) Q keluar(kkal/jam)
Q16 = 15.685,801 Q19 = 72.481,403
Q20 = 1.357.801,956 Q21 = 1.301.006,354
Q=¿ Q=¿
1.373.487,757 1.373.487,757
∑¿ ∑¿

4.2.11. Neraca Panas Heater – 03 (H - 03)

Q masuk(kkal/jam) Q keluar(kkal/jam)
Q22 = 23.324,053 Q20 = 1.357.801,956
Qin = 2.179.511,904 Qout = 845.034,001
∑Q = 2.202.835,957 ∑Q = 2.202.835,957