Desulfurizer ZnO h2s ZnS

Konversi H2S 1 -1 -1 1
r 0.069

Gas alam masuk (kmol/h) 2300 Gas keluaran (Ali 2300

Senyawa %MOL Komposisi Komposisi
CH4 0.83805 1927.515 1927.515
CO2 0.12472 286.856 286.856
H20 0.00265 6.095 6.164
C2H6 0.01746 40.158 40.158 2300
N2 0.00915 21.045 21.045
C5H12 0.0006 1.38 1.38
C3H8 0.00374 8.602 8.602
C4H10 0.0013 2.99 2.99
C6H14 0.0023 5.29 5.29
H2S 0.00003 0.069 0

Mixer
Steam to carbon molar ratio 1.6 Mr 12
Carbon molar 1571.08742
Aliran 4 (steam) 2513.73988
Aliran 3 2300 Aliran 5
Senyawa Komposisi %mol Mr Mol C Komposisi
CH4 1927.515 0.83805 16 1445.63625 1927.515
CO2 286.856 0.12472 44 78.2334545455 286.856
H20 6.164 0.00268 18 2519.903879
C2H6 40.158 0.01746 30 32.1264 40.158
N2 21.045 0.00915 28 21.045
C5H12 1.38 0.0006 72 1.15 1.38
C3H8 8.602 0.00374 44 7.038 8.602
C4H10 2.99 0.0013 58 2.4744827586 2.99
C6H14 5.29 0.0023 86 4.4288372093 5.29
H2S 0 0 34 0

Pre-Reformer
Aliran 5 4813.73988
Senyawa Komposisi %mol C2H6 1
CH4 1927.515 0.40041943 r 40.158
CO2 286.856 0.05959109 OutC2H6 0
H20 2519.90388 0.52348152 OutH2O 2439.58787922
C2H6 40.158 0.00834237 OutCO 80.316
N2 21.045 0.00437186 OutH2 200.79
C5H12 1.38 0.00028668
C3H8 8.602 0.00178697 CO Total reaksi cracking 156.722
C4H10 2.99 0.00062114 H2 Total reaksi cracking 371.864
C6H14 5.29 0.00109894 H2O Sisa reaksi 2363.181879
H2S 0 0
Reaksi Methanasi X H2
r 123.954666667
OutH2 0
OutCO 32.7673333333
OutCH4 2051.46966667
OutH2O 2487.13654589

Steam Reformer
Konversi CH4\ 0.85
r 1743.74922

Aliran 6 4879.27455 Aliran 7 8366.77297922

Senyawa Komposisi %mol Senyawa Komposisi %mol
CH4 2051.46967 0.42044563 CH4 307.72045 0.036778869
CO2 286.856 0.05879071 CO2 286.856 0.034285142
H20 2487.13655 0.5097349 H20 743.387329221 0.088849946
C2H6 0 0 C2H6 0 0
N2 21.045 0.00431314 N2 21.045 0.002515307
C5H12 0 0 C5H12 0 0
C3H8 0 0 C3H8 0 0
C4H10 0 0 C4H10 0 0
C6H14 0 0 C6H14 0 0
H2S 0 0 H2S 0 0
CO 32.7673333 0.00671562 CO 1776.51655 0.212329957
H2 5231.24765 0.625240778

Separating Tank 1
Aliran 7 8366.77298
Senyawa Komposisi %mol Antoine Coefficient
CH4 307.72045 0.03677887 Senyawa A B
CO2 286.856 0.03428514 CH4 3.7687 395.744
H20 743.387329 0.08884995 CO2 3.8191 291.743
C2H6 0 0 N2 3.6195 255.68
N2 21.045 0.00251531 CO 6.9356 1347.786
C5H12 0 0 H2 2.9493 67.5078
C3H8 0 0 H20 8.0557 1723.6425
C4H10 0 0
C6H14 0 0 P BUBL 852.896517255
H2S 0 0 yi/Psat 0.0901388815
CO 1776.51655 0.21232996 PDEW 11.0939916616
H2 5231.24765 0.62524078
V 0.9560082864
yi 1.0002279583

Reaktor Metanol
Konversi CO 0.8
Konversi CO2 0.8
r1 1420.57793
r2 229.282152

Aliran Top 8000.52767 Aliran Keluaran reaktor

Senyawa yi Laju alir molar yi Laju alir molar
CH4 0.038 307.130798 0.065 307.1307975
CO2 0.036 286.602689 0.012 57.32053789
N2 0.003 21.0213716 0.004 21.02137155
CO 0.222 1775.72241 0.076 355.1444826
H2 0.653 5222.91024 0.360 1693.907926
H20 0.048 387.140157 0.131 616.4223083
CH3OH 0.351 1649.860082

Separation tank 2
Keluaran reaktor 4700.80751
Senyawa yi Laju alir molar Antoine Coefficien
CH4 0.065 307.130798 Senyawa A
CO2 0.012 57.3205379 CH4 3.7687
N2 0.004 21.0213716 CO2 3.8191
CO 0.076 355.144483 N2 3.6195
H2 0.360 1693.90793 CO 6.9356
H20 0.131 616.422308 H2 2.9493
CH3OH 0.351 1649.86008 H20 8.0557
CH3OH 5.1504

V 0.4575
yi 0.999506416

Splitter 1%
Aliran Top 2 2149.437 Aliran Purge 21.49436921
Senyawa yi Laju alir molakg/h yi Laju Alir
CH4 0.11708773 251.80 3525.158 0.11709 2.517
CO2 0.02443012 52.54 2311.625 0.02443 0.525
N2 0.00879057 18.90 529.3152 0.00879 0.189
CO 0.14674983 315.59 8836.387 0.14675 3.154
H2 0.69613124 1497.03 2994.058 0.69613 14.963
H20 0.00049025 1.05 18.97713 0.00049 0.011
CH3OH 0.00582667 12.53 400.9677 0.00583 0.125

18616.49

Distilasi
Aliran Bot 2 2551.37059
Senyawa yi Laju alir molar Recovery HK D 99%
CH4 0.02169691 55.3338277 Recovery LK B 97%
CO2 0.00187569 4.78359596
N2 0.0008302 2.1172559
CO 0.01551154 39.5592161
H2 0.07719802 196.878824
H20 0.24129154 615.368023
CH3OH 0.6420123 1637.32984

Feed Distilat Bottom

Comp
XF F xd D XB B
H2 0.07719802 196.960766 0.625206 196.960765819 0 0
N2 0.0008302 2.11813711 0.006724 2.1181371111 0 0
CO 0.01551154 39.5756808 0.125624 39.5756808044 0 0
CH4 0.02169691 55.3568579 0.175717 55.3568579144 0 0
CO2 (LK) 0.00187569 4.78558692 0.014735 4.6420193077 6.4167193E-05 0.143567607
CH3OH (HK) 0.6420123 1638.01131 0.051995 16.3801130711 0.7247841193 1621.631194
H20 0.24129154 615.624142 0 0 0.2751517136 615.6241423
2551.37059 315.033574027 2237.398904
H2o
1

CH4 16 30840.24
CO2 44 12621.66
H20 18 110.952
C2H6 30 1204.74
N2 28 589.26
C5H12 72 99.36
C3H8 44 378.488
C4H10 58 173.42
C6H14 86 454.94
H2S 34 0
CO 28 46473.06

91720.38

4813.74
5 4
30840 45247.32
12622
45358
1205
589
99
378
173
455
0
91720

C3H8 1 C4H10 1 C5H12 1

r 8.602 r 2.99 r 1.38
OutC3H8 0 OutC4H10 0 OutC5H12 0
OutH2O 2413.7818792 OutH2O 2401.82187922 OutH2O 2394.922
OutCO 25.806 OutCO 11.96 OutCO 6.9
OutH2 60.214 OutH2 26.91 OutH2 15.18
 1

P 20
Coefficient T 100
C Log P P (bar) P (atm) zi Ki Ki-1
266.681 2.6894 489.148100141 479.365 0.036779 23.9683 22.96826
268 3.0263 1062.52732765 1041.277 0.034285 52.0638 51.06384
266.55 2.9219 835.485596886 818.776 0.002515 40.9388 39.93879
273 3.3222 2099.87144459 2057.874 0.21233 102.8937 101.8937
275.7 2.7696 588.294262351 576.528 0.625241 28.8264 27.82642
233.08 2.8809 760.098028527 1.000 0.08885 0.0500 -0.94999
 L 0.0439917136 Vtrp 7998.70429852
Ltrp 368.068680701

4700.808
ju alir molar
2434.52511557

P 60
Antoine Coefficient T 50
B C Log P Psat (bar) Psat (atm) Ki Ki-1
395.744 266.681 2.5190386689 330.399 323.79097876 5.396516 4.396516
291.743 268 2.9016891824 797.4238 781.47530397 13.02459 12.02459
255.68 266.55 2.811761897 648.2789 635.313337326 10.58856 9.588556
1347.786 273 2.7628479257 579.2258 567.641320125 9.460689 8.460689
67.5078 275.7 2.7420101197 552.0903 541.048497626 9.017475 8.017475
1723.643 233.08 1.9668416999 92.64921 0.1219068495 0.002032 -0.99797
1549.48 236.642 -0.2551979261 0.555651 0.5445379469 0.009076 -0.99092

L 0.5425
n

Aliran Recycle 2127.94255

yi Laju Alir kg/h purge kg/h recycle Mr
0.11709 249.156 35.23 3488.183 14
0.02443 51.986 23.10 2287.38 44
0.00879 18.706 5.29 523.7634 28
0.14675 312.275 88.32 8743.706 28
0.69613 1481.327 29.93 2962.655 2
0.00049 1.043 0.19 18.77809 18
0.00583 12.399 4.01 396.7621 32

186.07 18421.23 18607.30

 Aliran 6 4879.275 91720.38
C6H14 1 Senyawa Komposisi %mol
r 5.29 CH4 2051.47 0.420446 32823.51
OutC6H14 0 CO2 286.856 0.058791 12621.66
OutH2O 2363.182 H20 2487.137 0.509735 44768.46
OutCO 31.74 C2H6 0 0 0
OutH2 68.77 N2 21.045 0.004313 589.26
C5H12 0 0 0
 C3H8 0 0 0
C4H10 0 0 0
C6H14 0 0 0
H2S 0 0 0
CO 32.76733 0.006716 917.4853

Aliran Top 0.956226 Aliran Bot 0.043774 Aliran Top 8000.528

yi Laju alir molar xi Laju alir Molar Laju alir molar
0.03840 0.036708 0.001602 7.05E-05 307.1308
0.03583 0.034255 0.000688 3.03E-05 286.6027
0.00263 0.002512 6.42E-05 2.82E-06 21.02137
0.22200 0.212235 0.002158 9.49E-05 1775.722
0.65297 0.624244 0.022652 0.000996 5222.91
0.04840 0.046271 0.967882 0.042579 387.1402
1.000228
 1

Aliran top 0.457248 Aliran bot 0.542752 Aliran Top 2149.437 Aliran bot
yi Laju alir xi Laju alir
0.1170877 0.053565 0.021697 0.011771 251.797 55.33383
0.0244301 0.011176 0.001876 0.001018 52.53694 4.783596
0.0087906 0.004021 0.00083 0.00045 18.90412 2.117256
0.1467498 0.067134 0.015512 0.008415 315.5853 39.55922
0.6961312 0.318462 0.077198 0.041882 1497.029 196.8788
0.0004903 0.000224 0.241292 0.130907 1.054285 615.368
0.0058267 0.002666 0.642012 0.348308 12.53024 1637.33
Aliran Bottom 366.2453
xi Laju alir Molar
0.589652
0.253311
0.023628
0.794137
8.337409
356.2472
2551.371