UJIAN BAB TERMOKIMIA

WAKTU 90 MENIT
NAMA :
KELAS :

1. Tuliskan Bunyi Hukum Kekekalan Energi/Azaz kekekalan Energi! (Bobot soal 10)
2. Jelaskan perbedaan sistem dan lingkungan. Berdasarkan pertukaran energi dan materi ada berapa jenis sistem?
sebutkan!
o
3. Ke dalam 50 ml larutan HCl 1M dengan suhu 26 C ditambahkan 50 ml larutan NaOH 1M, suhu tertinggi
o o
campuran 35 C. Jika massa cairan dianggap sama dengan massa air dan kalor jenis air = 5,2 Joule/ C.gram,
Hitunglah besarnya perubahan entalpi untuk reaksi tersebut! (Bobot soal 20)
4. Perhatikan diagram tingkat energi berikut :
2 S(s) + O2 (g)

∆H2 = -278 kJ

∆H1=-571kJ

SO2 (g) + O2 (g)

∆H3 =....?

SO3(g)

Hitunglah besarnya perubahan entalpi (∆H3)! (Bobot soal 20)

5. Reaksi :
C2H6 (g) + O2 (g) CO2 (g) + H2O (g)

Jika diketahui :

H H = 436 kJ

C H = 413 kJ

O H = 463 kJ

C O = 799 kJ

O O = 495 kJ

C C = 343 kJ
Hitung besarnya perubahan entalpi berdasarkan data energi ikatan rata-rata! (Bobot soal 20)
6. Diketahui entalpi pembentukan standar H 2O = -925 kJ/mol, entalpi pembentukan standar CO 2 = -393,2
kJ/mol dan entalpi pembentukan standar CH4 = -55,6 kJ/mol. Hitunglah perubahan entalpi pada reaksi :

CO2 + 2 H2O CH4 + 2 O2 (Bobot soal 20)

“Selamat Bekerja”

“Emosi positif meningkatkan kekuatan otak, keberhasilan dan kehormatan diri maka percayalah bahwa kamu
bisa!”
Kunci jawaban tugas 1

1. Massa = 50 + 50 = 100 gr

∆T = 33 – 26 = 7K

C = 4,2 J/g.K

Q = m c ∆T

= 100 4,2 x 7

= 2940 j

∆H = –Q

= -2940 J

2. ∆H1 = ∆H2 + ∆H3

∆H2 = ∆H1 – ∆H3
∆H2 = -571 – (-298)

∆H2 = -273 kJ

3. ∆H = Hhasil – Hperaksi

∆H = (2x∆HH O +∆HCO )– ∆HCH )

2 2 4

∆H = (2x(-926) +(-393,5)) – (-55,6 )

∆H = (–1852 – 393,5) + 55,6

∆H = (–2245.5) + 55,6

∆H = –2189.9 kJ
Kunci jawaban tugas 1

1. Energi tidak dapat diciptakan dan dimusnahkan tetapi hanya dapat diubah dari bentuk satu ke bentuk lain,
pernyataan ini merupakan hukum.
2. Sistem adalah segala sesuatu yang diisolasi dari lingkungan, lingkungan segala sesuatu di luar sistem.

Sistem dibedakan menjadi :

a. Sistem terbuka adalah sistem yang dapat terjadi pertukaran materi dan energi dari sistem ke lingkungannya atau
sebaliknya.
b.Sistem tertutup adalah sistem yang hanya dapat terjadi pertukaran energi dari sistem ke lingkungannya atau sebaliknya
c. Sistem terisolasi sistem yang tidak dapat terjadi pertukaran baik materi maupun energi dari sistem ke lingkungannya atau
sebaliknya
3. Massa = 50 + 50 = 100 gr

∆T = 35 – 26 = 9K

C = 5,2 J/g.K

Q = m c ∆T

= 100 5,2 x 9

= 4.680 j

∆H = –Q

= -4.680 J

1. ∆H1 = ∆H2 + ∆H3

∆H3 = ∆H1 – ∆H2

∆H2 = -571 – (-278)

∆H2 = -293 kJ
Rumus
H struktur
H
H C C H + 3½ O O
H H
3 C O +3H O H

O
Pemutusan ikatan
C C = 343 kJ x 1
C H = 413 kJ x 6
O O = 495 kJ x 3,5
Pembentuukan ikatan
O H = 413 kJ x 2 x 3
C O = 495 kJ x 2 x 3
ΔH = E(pereaksi) – E(hasil reaksi)
 2. ∆H = Hhasil – Hperaksi

∆H = (∆HCH - 2x∆HH O +∆HCO ))

4 2 2

∆H = ( -55,6 – (2x(-925) +(-393,2))

∆H = -55,6 –(-1,850-393,2)

∆H =-55,6 –(-2.243,2)

∆H = 2187.6 kJ
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 TUGAS TERMOKIMIA

o
1. Ke dalam 50 ml larutan HCl 1M dengan suhu 26 C ditambahkan 50 ml larutan NaOH 1M, suhu tertinggi
o o
campuran 33 C. Jika massa cairan dianggap sama dengan massa air dan kalor jenis air = 4,2 Joule/ C.gram,
Hitunglah besarnya perubahan entalpi untuk reaksi tersebut
2. Perhatikan diagram tingkat energi berikut :
2 S(s) + O2 (g)

∆H2 = ? kJ

∆H1=-571kJ

SO2 (g) + O2 (g)

∆H3 =- 298 kJ

SO3(g)

Hitunglah besarnya perubahan entalpi (∆H2)

3. Diketahui entalpi pembentukan standar CH 4 = -55,6 kJ/mol, entalpi pembentukan standar H 2O = -926 kJ/mol
dan entalpi pembentukan standar CO2 = -393,5 kJ/mol. Hitunglah perubahan entalpi pada reaksi :
CH4 + 2 O2 CO2 + 2 H2O

“Fighting....!!”

Catatan :

 Soal diatas merupakan gambaran soal ujian pada materi TERMOKIMIA

 Soal diselesaikan dirumah dan dikumpulkan sebelum mengerjakan Ujian pada hari selasa,17 oktober 2017
 Bagi yang tidak mengerjakan dan tidak mengumpulkan tugas ,hasil ujian dikurangi 50%
 TUGAS TERMOKIMIA

o
4. Ke dalam 50 ml larutan HCl 1M dengan suhu 26 C ditambahkan 50 ml larutan NaOH 1M, suhu tertinggi
o o
campuran 33 C. Jika massa cairan dianggap sama dengan massa air dan kalor jenis air = 4,2 Joule/ C.gram,
Hitunglah besarnya perubahan entalpi untuk reaksi tersebut
5. Perhatikan diagram tingkat energi berikut :
2 S(s) + O2 (g)

∆H2 = ? kJ

∆H1=-571kJ

SO2 (g) + O2 (g)

∆H3 =- 298 kJ

SO3(g)

Hitunglah besarnya perubahan entalpi (∆H2)

6. Diketahui entalpi pembentukan standar CH 4 = -55,6 kJ/mol, entalpi pembentukan standar H 2O = -926 kJ/mol
dan entalpi pembentukan standar CO2 = -393,5 kJ/mol. Hitunglah perubahan entalpi pada reaksi :
CH4 + 2 O2 CO2 + 2 H2O

“Fighting....!!”

Catatan :

 Soal diatas merupakan gambaran soal ujian pada materi TERMOKIMIA

 Soal diselesaikan dirumah dan dikumpulkan sebelum mengerjakan Ujian pada hari selasa,17 oktober 2017
 Bagi yang tidak mengerjakan dan tidak mengumpulkan tugas ,hasil ujian dikurangi 50%

TUGAS TERMOKIMIA

o
7. Ke dalam 50 ml larutan HCl 1M dengan suhu 26 C ditambahkan 50 ml larutan NaOH 1M, suhu tertinggi
o o
campuran 33 C. Jika massa cairan dianggap sama dengan massa air dan kalor jenis air = 4,2 Joule/ C.gram,
Hitunglah besarnya perubahan entalpi untuk reaksi tersebut
8. Perhatikan diagram tingkat energi berikut :
2 S(s) + O2 (g)
 ∆H2 = ? kJ

∆H1=-571kJ

SO2 (g) + O2 (g)

∆H3 =- 298 kJ

SO3(g)

Hitunglah besarnya perubahan entalpi (∆H2)

9. Diketahui entalpi pembentukan standar CH 4 = -55,6 kJ/mol, entalpi pembentukan standar H 2O = -926 kJ/mol
dan entalpi pembentukan standar CO2 = -393,5 kJ/mol. Hitunglah perubahan entalpi pada reaksi :
CH4 + 2 O2 CO2 + 2 H2O

“Fighting....!!”

Catatan :

 Soal diatas merupakan gambaran soal ujian pada materi TERMOKIMIA

 Soal diselesaikan dirumah dan dikumpulkan sebelum mengerjakan Ujian pada hari selasa,17 oktober 2017
 Bagi yang tidak mengerjakan dan tidak mengumpulkan tugas ,hasil ujian dikurangi 50%