LOGO

HUKUM FARADAY
NAMA KELOMPOK

1. KEVIN ABANI

2. ELSA MEIFANI

3. Cristi Giovani

4. Thessalonika

5. DIAN SYAHPUTRA

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PEMBAHASAN

Penemu

Dalil Hukum Faraday

HUKUM
FARADAY
Perhitungan Hukum Faraday

Contoh Soal

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 HUKUM FARADAY I

“Massa zat yang dihasilkan (G) pada elektrolisis sebanding

dengan jumlah muatan listrik yang digunakan (Q). “
m = e . i . t / 96.500
q=i.t
Dimana:
m = massa zat yang dihasilkan (gram)
e = berat ekivalen = Ar/ Valensi = Mr/Valensi
i = kuat arus listrik (amper)
t = waktu (detik)
q = muatan listrik (coulomb

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HUKUM FARADAY II

“Massa zat yang dihasilkan (G) pada elektrolisis sebanding

dengan massa ekuivalen zat (ME ) tersebut.”
m1 : m2 = e1 : e2
Dimana:
m = massa zat (gram)
e = beret ekivalen = Ar/Valensi = Mr/Valensi

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KESIMPULAN FARADAY

Faraday menyimpulkan bahwa Satu Faraday adalah jumlah listrik yang

diperlukan untuk menghasilkan satu ekivalen zat pada elektroda.

Muatan 1 elektron = 1,6 x 10-19 Coulomb

1 mol elektron = 6,023 x 1023 eletron

Muatan untuk 1 mol eletron = 6,023 . 1023 x 1,6 . 10 -19 = 96.500

Coulomb = 1 faraday.

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 CONTOH SOAL HUKUM
FARADAY
1. Pada elektrolisis larutan CuSO4 dengan elektroda inert, dialirkan listrik 10
ampere selama 965 detik.
Hitunglah massa tembaga yang diendapkan pada katoda dan volume gas
oksigen yang terbentuk di anoda pada (O°C, 1 atm), (Ar: Cu = 63.5 ; O =
16).

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 JAWABAN SOAL

 CuSO4 (aq) ® Cu2+(aq) + SO42-(aq)

Katoda [elektroda - : reduksi] : Cu2+(aq) + 2e- ® Cu(s)
Anoda [elektroda + : oksidasi]: 2 H2O(l) ® O2(g) + 4 H+(aq) + 4 e-
 a.massa tembaga:
m = e . i . t/96.500 = (Ar/Valensi) x (10.965/96.500) = 63.5/2 x
9.650/96.500 = 31.25 x 0,1 = 3,125 gram
 b.m1 : m2 = e1 : e2
mCu : mO2 = eCu : eO2
3,125 : mO2 = 6.32/2 : 32/4
3,125 : mO2 = 31,25 : 8
mO2 = (3.125 x 8)/31.25 = 0.8 gram
mol O2 = 0.8/32 = 8/320 = 1/4 mol
volume O2 (0°C, 1 atm) = 1/40 x 22.4 = 0.56 liter

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CONTOH SOAL KE-2

 2. Pada elektrolisis larutan CuSO4 dengan elektroda inert, dialirkan listrik

10 amper selama 965 detik.
Hitunglah massa tembaga yang diendapkan pada katoda dan volume gas
oksigen yang terbentuk di anoda pada (O°C, 1 atm), (Ar: Cu = 63.5 ; O =
16).

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 JAWABAN SOAL

CuSO4 (aq) ® Cu2+(aq) + SO42-(aq)

Katoda [elektroda - : reduksi] : Cu2+(aq) + 2e- ® Cu(s)
Anoda [elektroda + : oksidasi]: 2 H2O(l) ® O2(g) + 4 H+(aq) + 4 e-

a.massa tembaga:
m = e . i . t/96.500 = (Ar/Valensi) x (10.965/96.500) = 63.5/2 x
9.650/96.500 = 31.25 x 0,1 = 3,125 gram

b.m1 : m2 = e1 : e2
mCu : mO2 = eCu : eO2
3,125 : mO2 = 6.32/2 : 32/4
3,125 : mO2 = 31,25 : 8
mO2 = (3.125 x 8)/31.25 = 0.8 gram
mol O2 = 0.8/32 = 8/320 = 1/4 mol
volume O2 (0°C, 1 atm) = 1/40 x 22.4 = 0.56 liter
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