E.

CH2OH O H OH H O H OH H H H OH

CH2OH O HO H H OH H H OH

Hasil
+ CH3COO2Cu + CH3COOH

Pengamatan
1. Tabel Pengamatan
Sampel Glukosa Molisch (+) Cincin Ungu Fruktosa (+) Cincin Ungu Laktosa (+) Cincin Ungu Amilum (+) Cincin Ungu Singkong (+) Cincin Ungu Apel (+) Cincin Ungu Susu (+) Cincin Ungu Roti (+) (++) (+++) (+) Merah Coklat (-) (+) (-) (++++) (+++++) (+) Merah Coklat (+) kuning (+) Merah Coklat (+) Merah Bata (+) Hijau (-) (+) (-) (+) (++) (++) (+) (-) Larutan Biru (-) Larutan Biru (+) Biru kehijauan (+) Merah (++++) (+) (+) (+) Merah Seliwanoff (+++) Fehling (+++) Benedict (+) Barfoed (+) Merah Iodium (+) Biru Kehitaman (-) Larutan Kuning (-) Larutan Kuning (+) Biru Kehitaman (+) Biru Kehitaman (+) Merah Coklat (-) Larutan Kuning (+)

Hijau Cincin Ungu Air beras (+) Cincin Ungu Tepung Terigu (+) Cincin Ungu (-) (+) Larutan Kuning (+) Merah Coklat (+) Merah Hijau Kuning (+) Hijau

Larutan Biru Biru Kehitaman (+) Hijau (+) Biru Kehitaman (+) Hijau (+) Biru Kehitaman

Keterangan :
2. Reaksi a. Uji Fehling 1) Glukosa
CH2OH H

: Endapan

CH2OH O H H O H OH OH H
CH2OH O H C OH OH H OH OH H OH H O C OH

H OH H O H OH

+ Cu2+ + 4OHH

H O OH H

OH

CH2OH H

H OH H

+ H+

+ Cu2O

OH H OH

2) Fruktosa

H CH2OH CH2OH H H OH H O OH OH CH2OH C HO H H C C C O H OH OH HO H H H C C C C C O O H OH OH H

+ Cu2+ + 4OH-

CH2OH

CH2OH

H C C HO H H C C C O OH OH OH + H+ HO H H H

H C C C C C O H

H C C HO H H C C C O O H H OH OH + H+

O H H OH OH

CH2OH

CH2OH

CH2OH

H C O O H OH OH H H HO H H

H C C C C C O OH H OH OH H

O C C C C C H OH OH H

:C

OH + Cu2O

H + HO
H H

C C C

+ Cu2+

HO H H

CH2OH

CH2OH

CH2OH

3) Laktosa
CH2OH OH H OH H H OH O H H H OH O H H OH CH2OH O H OH H + 4 Cu2+ + 8OH-

CH2OH OH H OH H H OH O H H O H H C
H

CH2OH O H OH H O H OH H + 4 Cu2+ + 8OHH

CH2OH OH O H OH H H H OH O +H H + C

CH2OH O H OH H O H OH H + H + 4 Cu2+ + 8OH-

CH2OH OH H OH H H OH OH H O C H
+

CH2OH H H OH OH H OH OH H H C O
+ 4 Cu2+ + 8 OH-

CH2OH OH OH H OH H OH C O H OH
+

CH2OH H H OH OH H OH OH H O C OH
+ 2 Cu2O + 4H2O

4) Amilum

CH2OH H O H OH O H OH H O H H

CH2OH O H H O H
n

H
+ Cu2+ + OH-

b. Uji Molisch 1) Glukosa

CH2OH H OH H
O C H HO H H C C C C H OH H OH OH

CH2OH O H OH OH OH H
O C C H OH H

CH2OH OH H OH OH OH H OH H H H OH OH H O C H

H OH

H OH

- H2SO4
H

C C C

OH

CH2OH

CH2OH

H H C OH C H

H C O -H2O

H H C OH C C H O

H C O

OH

CH2 CH2 C H OH OH

C C H +

H H C OH C H C O

H C C

OH

H H C

H C C O O C

O
C

H +

OH

C H

+ H+

OH

OH

H H C OH C C H O

H C OH
+

OH H H C OH C C H
OH OH

H C O

H OH

C C H

C C H

OH H -H2O H C OH C C H O H C C C OH

Cincin Ungu

2) Fruktosa
H CH2OH CH2OH H OH OH H O OH CH2OH H HO H H C C C C H OH OH O H C C HO H H C C C H OH OH O H O

CH2OH

CH2OH

H C C HO H H C C C OOH OH OH H+ - H+ H HO H H

H C C C C C O OH H OH OH H HO H H

O C H C C C C OH H OH OH H OH H H

O C H C C C C OH H OH OH

CH2OH

CH2OH

CH2OH

CH2OH

O C C C H H C C H OH H OH OH

O C C C C C H OH H OH OH

H C C O -H2O C H

-H

H C OH C C

H OH OH

CH2OH

CH2OH

H H C OH C C H O

H C O

OH

H H C OH C C H O

H C O C C+ H +

OH

C C H +

OH H H C OH C C H O H C O
+ H+

C C H

H H C OH C C H O

H C

OH
-

O C C H

-H2O

OH OH

OH H H C OH C C H O

H C C C OH

Cincin Ungu

3) Laktosa
CH2OH OH H H OH O H OH H H H OH O H CH2OH O H OH H OH H H OH H OH CH2OH O H OH H OH H +

Galaktosa - glukosa
CH2OH O H OH H OH OH H OH H H H OH OH H OH OH H OH
O H OH H OH OH C C C C C H OH H OH OH

CH2OH H OH H OH

CH2OH H H H OH OH H O C H

O C H HO H H C C C C H OH H OH OH OH H H H

O C C C C C H OH H OH OH H H

O C C C C C

-H

CH2OH

CH2OH

CH2OH

CH2OH

H H C OH C H C

H C C O C H -H2O

H H C OH C H C O

H C C O C H +

OH

OH OH

H H C OH C C H O

H C O

OH

H H C OH C C O

H C O - H+

C C+ H + -

C C H

OH

OH

H H C OH C C H O

H C OH
+

OH H H C OH C C H
OH OH

H C O

H OH

C C H

C C H

OH H -H2O H C OH C C H O H C C C OH

Cincin Ungu

4) Amilum

CH2OH H O H OH O H OH H O H H

CH2OH O H H O H
n

H2O

CH2OH H OH H OH H OH O H OH OH H H

CH2OH H OH H OH H OH OH OH H H

CH2OH H OH H OH H OH
O H OH H OH OH C C C C C H OH H OH OH

O C H

O C H HO H H C C C C H OH H OH OH OH H H H

O C C C C C H OH H OH OH H H

O C C C C C

-H

CH2OH

CH2OH

CH2OH

CH2OH

H H C OH C H C

H C C O C H -H2O

H H C OH C H C O

H C C O C H +

OH

OH OH

H H C OH C C H O

H C O

OH

H H C OH C C O

H C O - H+

C C+ H + -

C C H

OH

OH

H H C OH C C H O

H C OH
+

OH H H C OH C C H
OH OH

H C O

H OH

C C H

C C H

OH H -H2O H C OH C C H O H C C C OH

Cincin Ungu

c. Uji Barfoed 1) Glukosa

CH2OH H OH H OH H OH O H H + OH CH3COO2Cu + CH3COOH OH H OH H CH2OH H OH O H H

H+
O-

CH2OH H O H OH OH H OH H C OH H

CH2OH OH H OH OH H OH H O C OH

+ H+

Cu

2) Fruktosa

CH2OH H OH OH

O OH H

+
CH2OH

CH3COO2Cu + CH3COOH

H CH2OH C HO H H C C C O H OH OH HO H H H C C C C C O O H OH OH H

CH2OH

CH2OH

H C C HO H H C C C O OH OH OH + H+ HO H H H

H C C C C C O H

H C C HO H H C C C O O H H OH OH + H+

O H H OH OH

CH2OH

CH2OH

CH2OH

H C O O H OH OH H H HO H H

H C C C C C O OH H OH OH

:C

H+ + HO
H H

C C C

+ Cu2+

CH2OH

CH2OH

O C H HO H H C C C C H OH OH H

OH
H

CH2OH

CH3COO2Cu + CH3COOH

H OH H

OH O H OH C + Cu O 2 H

OH

CH2OH

3) Laktosa

4) Amilum

CH2OH H O H OH H OH O H O H H

CH2OH H O H O H
n

CH3COO2Cu + CH3COOH

d. Uji Iodium 1) Glukosa

CH2OH H OH H OH H OH O H OH H + I2

2) Fruktosa

CH2OH H OH OH

H OH H CH2OH + I2

3) Laktosa

H OH

CH2OH O H H OH H OH

H O H

CH2OH O H H OH H OH

H + I2 OH

4) Amilum
OH H H OH H CH2OH
OH
H

OH

OH CH
H

2 OH

OH

H
OH

OH

OH H H

OH CH 2

H
CH
CH2OH

OH
H

2 OH

OH

CH2OH

CH 2

CH O 2 H OH

OH

HO
CH

OH

H
OH CH 2OH
CH2OH
CH O 2 H
CH

H CH 2O

OH
H

H
2 OH

H O 2

H
OH

H H
OH OH
CH 2OH

H
OH

H
OH

H
OH

H
OH

OH

OH

OH H

H
OH

H
OH

H
CH

H
OH

2 OH

CH

OH

CH2OH

H H
OH OH

H
OH

H
OH

+ I2

H
OH

OH H

H OH H CH2OH
OH
H

OH

OH
H CH 2 OH
OH
H

OH

H
OH

OH H H

OH CH 2

H
CH
CH2OH

OH
H

2 OH

I-

H OH

CH 2OH

CH 2

CH O 2 H OH

OH

HO
CH

OH

H
OH CH2OH CH O
2

H CH 2O

OH
H

H
2 OH

H
H O 2

H
OH

CH

CH2OH

H H
OH OH
CH 2OH

H
OH

H
OH

H
OH

H
OH

OH

OH

OH H

H
OH

H
OH

H
CH

H
OH

2 OH

CH

OH

CH2OH

H H
OH OH

H
OH

H
OH

H
OH

e. Uji Seliwanoff 1) Glukosa

CH2OH H OH H OH H OH O H OH OH H OH

2) Fruktosa
CH2OH H OH OH O H OH H CH2OH + OH OH

CH2OH C O HO C H + H C OH H C OH CH2OH

OH

OH

H H C OH C O HO C H + H C OH H C OH CH2OH
OH

H
C O

OH + OH

OH

C OHO C H H C OH H C OH CH2OH
O

H C H C O OH
+ OH OH

C H C OH H OH OH
+ OH OH

HO C H H C OH H C OH CH2OH

H2SO4
H

C C C

CH2OH

H H C OH C C

H C O C H C +

OH -H2O OH

H H C

H O C

H OH OH

OH C C C C H O H

OH

H H C OH C C H O

H C OC C H +

H H C
+

H C OC C H +

O-

OH C C
OH

OH

3) Laktosa

CH2OH OH OH H H OH H H OH O H O H OH H CH2OH O H OH H OH

+
OH

4)

Amilu m
OH

+
OH

f.

Uji Benedict
1) Glukosa
CH2OH H OH H OH H OH O H O H H

+ Cu2+ + 2 OH-

2) Fruktosa
H CH2OH CH2OH H H OH H O OH OH CH2OH C HO H H C C C O H OH OH HO H H H C C C C C O O H OH OH H

+ Cu2+ + 2OH-

CH2OH

CH2OH

H C C HO H H C C C O OH OH OH + H+ HO H H H

H C C C C C O O H H OH OH HO H H H

H C C C C C O O H OH OH H

+ H+

CH2OH

CH2OH

CH2OH

H C O O H OH OH H H HO H H

H C C C C C O OH H OH OH

:C

H + HO
H H

C C C

+ Cu2+ + 2OH-

CH2OH

CH2OH

CH2OH H OH H OH H OH OH O H C OH

+ Cu2O (Merah Bata)

3) Laktosa
CH2OH OH H OH H H OH H H O O H H OH H OH H
CH2OH OH OH H H OH H O C H H O H H C O H OH

CH2OH O H

+ 4 Cu2+ + 8 OH-

OH

CH2OH OH

+ H+

+
OH

OH

+ H+ + 4 Cu2+ + 8 OH-

CH2OH OH H OH H H OH H H O OH H

CH2OH O H C OH H OH H OH H

+ 4 Cu2+ + 8 OH-

CH2OH OH H OH H H OH H H OH O O H H

CH2OH O H OH H O H
CH2OH OH O C H H H H OH H C O H OH

+ 4 Cu2+ + 8 OHH

OH

CH2OH OH H OH H H OH

+
OH

OH

+ 4 Cu2+ + 8 OH-

CH2OH OH H OH H H OH H C O OH OH H

CH2OH OH H O C OH H OH

+
OH

OH

+ 2 Cu2O + 4H2O

4) Amilum
CH2OH H O H OH O H OH H O H
n

CH2OH H H O H H O H

CH2OH H OH H OH H OH OH O H C H

+ n Cu2+ + n OH-

CH2OH H OH H OH H OH OH H OH C O

+ n Cu2O

+ n H2O