Table 3.

1 Biegler
Components u01
Methane
Ethylene
Propylene
Diethyl Ether
Ethanol
Isopropanol
Water
Total

u02
1
96
3

100

771.797
771.797

u1

u2
u31
u32
u04
200.000 200.0000 199.2000
0.8000
1289.000 1198.7700 1180.7885 17.9816
268.600 266.7198 248.5829 18.1369
2.4252
1.2126
1.2126
0.560
90.7900
10.9856 79.8044
1.8802
0.1561
1.7241
771.870 679.7598
36.7070 643.0528

u41
199.2000
1155.9919
223.9732
0.2910
0.1099
0.0011
0.0697

u42
24.7966
24.6097
0.9216
10.8757
0.1550
36.6336

u51
1150.2119
222.8533
0.2896
0.1093
0.0011

u52
u6
u71
u72
u81
u82
u91
0.9960
5.7800 42.7781 42.7781
42.7781
1.1199 42.7466 42.7466
42.7466
0.0015
2.1342
2.1342
2.1342
0.0005 90.6801 86.1461
0.4534
0.4307 85.7154 85.2868
0.0000
1.8791
1.8039
0.0752
0.0003 679.6864 67.9686
611.7178
0.0000 67.9686
0.0000

u92

0.4286
0.0000

Algoritma:
Perhitungan aliran massa masing-masing komponen menggunakan persamaan seperti yang terlihat
pada tabel 1.
U52

5. SPL

U03
U41

Loop 1

4. SPL

U51

U31
U01

U1

1. MIX

U2

2. RXN

U42

3. FLASH

U02

6. MIX
U32

Loop 2
U81

8. DIST

U6
U71

U91

7. DIST

9. DIST
U82
U92

U72

Table 1 : Persamaan pada masing masing stream

Basis 100 mol fresh feed ( F )
Komponen
01
02
1
Methane
0.1F
0
(1-005)1(M) +1
Ethylene
0.96F
0
01(EL)+(0.995)(0.979)(0.985)(0.93)1(El)+(1)(1)(0.021(0.985)+ 0.015)(0.93)1(EL)
Prppylene
0.3F
0
01(PL)+(0.995)(0.901)(0.932)(0.993)1(PL)+(1)(1)(0.099(0.932)+ 0.068)(0.993)1(PL)
Diethyl ether
0
0
0.2(2(EA)^2/2(W)
Ehanol
0
0
(0.995)(0.001)(0.121)(1(EA)+90.2) + (0.005)(0.995)(0.879+ 0.121)(0.99))(1(EA)+90.2)
Isopropanol
0
0
0
water
0
1w-51w
0.61(EL)

41
31(M)
0.97931(EL)
0.90131(PL)
0.2431(DEE)
0.0131(EA)
0.006531(IPA)
0.001931(W) + 0.0009231(W)

Komponen
Methane
Ethylene
Prppylene
Diethyl ether
Ehanol
Isopropanol
water

81
71(M)
71(EL)
71(PL)
0.99571(DEE)
0.00571(EA)
0
0

Komponen
Methane
Ethylene
Prppylene
Diethyl ether
Ehanol
Isopropanol
water

42
0
0.02131(EL)
0.09931(PL)
0.7631(DEE)
0.9931(EA)
0.99331(IPA)
0.99831(W) + 0.99931(W)

82
0
0
0
0.00571(DEE)
0.99571(EA)
71(IPA)
71(W)

91
0
0
0
82(DEE)
0.99582(EA)
0.001(91(EA) + 91(W))
(14.5/85.5)91(EA)

Table 2 : Hasil perhitungan ulang tabel 3.1 Biegler ( menggunakan excel ).

Components
01
02
1
2
31
Methane
1.00
0.00
200.00
200.00
199.20
Ethylene
96.00
0.00
1289.00
1198.77
1180.79
Propylene
3.00
0.00
268.60
266.72
248.58
Diethyl Ether
0.00
0.00
2.42
2.42
1.21
Ethanol
0.00
0.00
0.56
90.76
10.98
Isopropanol
0.00
0.00
0.00
1.88
0.16
Water
0.00
773.30
773.40
681.29
36.79
Total
100.00
773.30
2533.98
2441.84
1677.71
Temperatur, K
300.00
300.00
590
590
393
Pressure, bar
1.00
1.00
69.00
69.00
68.50
Vap Frac
1.00
0.00
1.00
1.00
1.00

Perhitungan distilasi
P Feed
17.00
Temp Feed
560.00
Pressure
17.00
Temp Top
529.98 Trial
Temp Bot
604.35 Trial
Temp avg
567.16

51
0.99541(M)
0.99541(EL)
0.99541(PL)
0.99541(DEE)
0.99541(EA)
0.99541(IPA)
0.99541(W)

32
0.80
17.98
18.14
1.21
79.78
1.72
644.50
764.13
393
68.50
1.00

52
0.00541(M)
0.00541(EL)
0.00541(PL)
0.00541(DEE)
0.00541(EA)
0.00541(IPA)
0.00541(W)

2
1(M)
(1-0.07)1(EL)
(1-0.007)1(PL)
0.2(2(EA)^2/2(W)
(0.07)1(EL) + 1(EA)
(0.007)1(PL) + 1(IPA)
1(W) - 0.07 1(EL)-0.0071(PL)

6
32(M) + 42(M)
32(EL) + 42(EL)
32(PL) + 42(PL)
32(DEE)+ 42(DEE)
32(EA) + 42(EA)
32(IPA) + 42(IPA)
32(W) + 42(W)

41
199.20
1155.99
223.97
0.29
0.11
0.00
0.10
1579.65
381
68.00
1.00

42
0.00
24.80
24.61
0.92
10.87
0.15
36.72
98.07
338.00
68.00
1.00

51
198.20
1150.21
222.85
0.29
0.11
0.00
0.10
1571.75
381
67.50
1.00

52
1.00
5.78
1.12
0.00
0.00
0.00
0.00
7.90
381
67.50
1.00

6
0.80
42.78
42.75
2.13
90.65
1.88
681.22
862.20
372
68.00
0.00

256.98 C
331.35 C

2.11

kN/ hk hk
m

1 ( kN/mhk 1) hk

Komp
6
Methane
Ethylene
Propylene
Diethyl Ether
Ethanol(lk)
Isopropanol
Water(hk)
Total

0.80
42.78
42.75
2.13
90.65
1.88
681.22
862.20

Komp
72
Methane
Ethylene
Propylene
Diethyl Ether
Ethanol(lk)
Isopropanol
Water(hk)
Total

0.00
0.00
0.00
0.00
0.45
0.04
613.09
613.59

3.7687
3.91382
3.95606
4.44136
5.333675
5.24268
4.4087

Xk
0
0
0
0
0.000739
7.32E-05
0.999188
1

C
395.744
596.526
789.624
1025.56
1648.22
1580.92
1692.77

266.681
256.37
247.58
256.05
230.918
219.61
200.44

po
K
1030.31
564.66
246.08
276.90
90.25
84.24
5.10

Temperatur Bottom
po
k
yk
1279.2588 75.25051
0
792.21291 46.60076
0
390.95811 22.99754
0
495.94989 29.17352
0
252.52995
14.8547 0.010973
236.21322
13.8949 0.001017
16.809824 0.988813
0.98801
1.000001

k
60.61
33.22
14.48
16.29
5.31
4.96
0.30

1.00
1.00
1.00
1.00
0.9950
0.98
0.10

Nm

log x LK / x Hk D x Hk / x LK B
log( LK / HK ) avg

Nm

1.659639986

Perhitungan Refluks minimum

1 Perhitungan q line
q line merupakan perbandingan fase cair terhadap feed pada temperatur feed perhitungan dilakukan
dengan cara flash pada temperatur feed masuk distilasi 7
6
0.80
42.78
42.75
2.13
90.65
1.88
681.22
862.20

Komp
Methane
Ethylene
Propylene
Diethyl Ether
Ethanol(lk)
Isopropanol
Water(hk)
Total

B/D
F
D
B
B/F

Zf
po(T feed) k
Xk
0.000928 1132.2676 66.60398 3.78E-05
0.049615 654.62634 38.50743 0.003434
0.049579
301.2782 17.72225 0.007086
0.002468 357.14243 21.00838 0.000302
0.105138 141.67047 8.333557 0.028965
0.002179 132.46287 7.791933 0.000634
0.790092 8.6282727 0.507545 0.959541
1
1

1.79
100.00
35.84229391
64.16
0.641577061

2 Perhitungan
x1 f ir
x2 f 2r
1 q

..............
ir 2 r
Trial
1-q
komp
Methane
Ethylene
Propylene
Diethyl Ether
Ethanol(lk)
Isopropanol
Water(hk)

-1.9827488
0.358422939

3.72143E-05
0.003338753
0.006679036
0.000287307
0.025800048
0.000560804
0.321696838
0.358400001

3. Perhitungan Rm

Rm

5.22E-05
0.005038
0.011196
0.0005
0.060874
0.001316
0.305936
0.384913

71
201.83
110.61
48.21
54.24
17.68
16.50
1.00

po(Tavg) K( Tavg)
ir(Tavg)
1156.324 68.019065 119.3581
676.5193 39.795251 69.83167
315.1388 18.537578 32.52926
377.9481 22.232243 39.01256
156.5674 9.2098456
16.1612
146.4232 8.6131288 15.11409
9.687857 0.5698739
1

Menghitung Try minimum

ir
yk
0.00252 131.22761
0.132217 75.869917
0.125582 34.917556
0.006343 41.392112
0.241384 16.419331
0.004943 15.352188
0.487011
1
1

71
6(M)
6(EL)
6(PL)
6(DEE)
0.9956(EA)
0.966(IPA)
0.16(W)

32
0.0042(M)
0.0152(EL)
0.0682(PL)
0.52(DEE)
0.8792(EA)
0.9172(IPA)
0.9462(W)

72
0
0
0
0
(1-0.995)6(EA)
(1-0.96)6(IPA)
(1-0.1)6(W)

92
0
0
0
0
82(EA) - 91(EA)
(82(IPA) - 91(IPA))
82(W) - 91(W)

Nm = Ln [ { lk ( 1 hk ) } / {hk (1- lk) }] / lnlk/hk

Nm

31
0.9962(M)
0.9852(EL)
0.9322(PL)
0.52(DEE)
0.1212(EA)
0.0832(IPA)
0.0542(W)

0.80
42.78
42.75
2.13
90.20
1.83
68.12
248.61

Temperatur Top
yk
Xk
0.00322 5.31E-05
0.17207 0.005181
0.17195 0.011879
0.00856 0.000526
0.36281 0.068342
0.00738 0.001489
0.27401 0.912531
1
1

71
0.80
42.78
42.75
2.12
90.20
1.80
68.12
248.56
310.00
17.00
0.00

72
0.00
0.00
0.00
0.00
0.45
0.08
613.09
613.62
480
18.00
0.00

81
0.80
42.78
42.75
2.11
0.45
0.00
0.00
88.89
310
10.00
1.00

82
0.00
0.00
0.00
0.01
89.75
1.80
68.12
159.67
418
11.00
0.00

91
0.00
0.00
0.00
0.01
89.30
0.10
15.16
104.74
350
1.00
0.00

92
0.00
0.00
0.00
0.00
0.45
1.70
52.80
54.94
383.00
1.50
0.00

u2=
90.8
u31=
10.99
u32=
79.81
u41=
0.11
u42=
10.88
u51=
0.1093
u52=
0.0005
Table 3.1 Biegler
Components u01
Methane
Ethylene
Propylene
Diethyl Ether
Ethanol
Isopropanol
Water
Total

u6=
u71=
u72=
u81=
u82=
u91=
u92=

u02
1
96
3
0
0
0
0
100

0
0
0
0
0
0
771.797
771.797

u1

90.8
90.23
0.45
0.45
89.77
89.33
0.45

u2
u31
u32
200.000 200.0000 199.2000
0.8000
1289.000 1198.7700 1180.7885 17.9816
268.600 266.7198 248.5829 18.1369
2.418
2.4182
1.2091
1.2091
0.560
90.7600
10.9820 79.7780
0.000
1.8802
0.1561
1.7241
773.400 681.2898
36.7896 644.5002
2533.978 2441.8380 1677.7081 764.1299

u41
199.2000
1155.9919
223.9732
0.2902
0.1098
0.0011
0.0800
1579.6461

u42
u51
u52
u6
u71
u72
u81
u82
u91
0.0000
198.2040
0.9960
0.8000
0.8000
0.0000
0.8000
0.0000
0.0000
24.7966
1150.2119
5.7800 42.7781 42.7781
0.0000 42.7781
0.0000
0.0000
24.6097
222.8533
1.1199 42.7466 42.7466
0.0000 42.7466
0.0000
0.0000
0.9189
0.2887
0.0015
2.1280
2.1174
0.0000
2.1174
0.0106
0.0106
10.8721
0.1093
0.0005 90.6502 90.1969
0.4533
0.4510 89.7459 89.2972
0.1550
0.0011
0.0000
1.8791
1.8039
0.0752
0.0000
1.7949
0.1046
36.7161
0.0796
0.0004 681.2162 68.1216
613.0946
0.0000 68.1216 15.3232
98.0683
1571.7479
7.8982 862.1983 248.5646
613.6230 88.8931 159.6731 104.7356

u92
0.0000
0.0000
0.0000
0.0000
0.4487
1.6903
52.7984
54.9375

1. Diambil inlet reaktor sebagai tear stream sehingga dapat dihitung u1(EL), u1(PL) dan u1(ET)
2. Dihitung u2 berdasarkan konversi EL thd ET
3. Dihitung u31 dan u32 berdasarkan perhitungan flash
4. Dihitung u41 dan u42 berdasarkan perhitungan absorbsi
5. Dihitung u51 dan u52 berdasarkan ratio purging
6. Dihitung u6 berdasarkan hasil mixing u41 dan u42
7. Dihitung u71 dan u72 berdasarkan data dewatering kolom
8. Dihitung u81 dan u82 berdasarkan data deetering kolom
9. Dihitung u91 dan 92 berdasarkan data destilasi pemisahan azeotrop