1.

Konsetrasi logam berat Cr

Data :
Adsorbansi sample Cr = 0,11109
C blanko

=0

V1

= 30,2 L/menit = 1,1185 m3/menit

V2

= 30,5 L/menit = 1,1296 m3/menit

P1

= 756 mmHg

P2

= 759 mmHg

T1

= 29,3 C

T2

= 32,4 C

Volume Udara =

Volume 1+Volume 2
2
1,12+1,13
2

x T x Pa/Ta x 298/760

x 150 menit x 759/305,4 x 298/760

= 164,44 m3
Kurva
Kalibrasi Cr
0.5
0.4

f(x) = 0.03x + 0
R = 1

0.3
0.2
0.1
0
0

Konsentrasi
(ppm)
0
1
2
4
8
12

Y absorbansi
0
0.04349
0.0724
0.12023
0.27802
0.40201

Persamaan kurva kalibrasi :

10

12

14

y = 0,0334 x + 0,0022
0,11109 = 0,0334 x + 0,0022
x = 3,31
Kadar Cr di udara (g/m3) :

( Ct Cb ) Vt
Ccr

S
St

( 3,310 ) 50 ml
=

6358,5
1589,6

164 , 44

= 4,026 g/m3
Konsentrasi Cr di Udara ambien :
C = b/v x 10/25 x 1000
C = 4,026 / 164,44 x 10/25 x 1000
C = 9,79 g/Nm3

2. Konsetrasi logam berat Cd

Data :
Adsorbansi sample Cd = 0,00342
C blanko

=0

V1

= 30,2 L/menit = 1,1185 m3/menit

V2

= 30,5 L/menit = 1,1296 m3/menit

P1

= 756 mmHg

P2

= 759 mmHg

T1

= 29,3 C

T2

= 32,4 C

Volume Udara =

Volume 1+Volume 2
2

x T x Pa/Ta x 298/760

1,12+1,13
2

x 150 menit x 759/305,4 x 298/760

0.06
0.04

f(x) = 0.02x + 0
R = 1

0.02
0
0

0.5

1.5

2.5

= 164,44 m3
Kurva Kalibrasi
Cd
Konsentrasi
(ppm)
0
0.03
0.05
2

Y absorbansi
0
0.00224
0.00409
0.044

Persamaan kurva kalibrasi :

y = 0.0213x + 0.00150
0,00342 = 0.0213x + 0.00150
x

= 0,112

Kadar Cd di udara (g/m3) :

( Ct Cb ) Vt
Ccd

S
St

( 0,1120 ) 50 ml
=

6358,5
1589,6

164,44

= 0,14 g/m3
Konsentrasi Cd di Udara ambien :
C = b/v x 10/25 x 1000
C = 0,14/ 164,44 x 10/25 x 1000

C = 0,34 g/Nm3

3. Konsetrasi logam berat Pb

Data :
Adsorbansi sample Pb = 0,00055
C blanko

=0

V1

= 30,2 L/menit = 1,1185 m3/menit

V2

= 30,5 L/menit = 1,1296 m3/menit

P1

= 756 mmHg

P2

= 759 mmHg

T1

= 29,3 C

T2

= 32,4 C

Volume Udara =

Volume 1+Volume 2
2
1,12+1,13
2

x T x Pa/Ta x 298/760

x 150 menit x 759/305,4 x 298/760

= 164,44 m3
Kurva Kalibrasi
Pb
0.1
0.08

f(x) = 0.01x - 0
R = 1

0.06
0.04
0.02
0
0

Konsentrasi
(ppm)
0
1
2
4
12

Y absorbansi
0
0.00266
0.01468
0.02382
0.07998

10

12

14

Persamaan kurva kalibrasi :

y = 0.0068x - 0.0014
0,00055 = 0.0068x - 0.0014
x

= 0,259

Kadar Pb di udara (g/m3) :

( Ct Cb ) Vt
CPb

S
St

( 0,2590 ) 50 ml
=

6358,5
1589,6

164,44

= 0,32 g/m3
Konsentrasi Pb di Udara ambien :
C = b/v x 10/25 x 1000
C = 0,32/ 164,44 x 10/25 x 1000
C = 0,78 g/Nm3

4. Konsetrasi logam berat Ni

Data :
Adsorbansi sample Ni = 0,0318
C blanko

=0

V1

= 30,2 L/menit = 1,1185 m3/menit

V2

= 30,5 L/menit = 1,1296 m3/menit

P1

= 756 mmHg

P2

= 759 mmHg

T1

= 29,3 C

T2

= 32,4 C

Volume Udara =

Volume 1+Volume 2
2
1,12+1,13
2

x T x Pa/Ta x 298/760

x 150 menit x 759/305,4 x 298/760

= 164,44 m3

0.25
0.2

f(x) = 0.02x + 0
R = 1

0.15
0.1
0.05
0

Kurva Kalibrasi
Ni
Konsentrasi
(ppm)
0
1
2
4
12

Y absorbansi
0
0.02448
0.03825
0.06523
0.20406

Persamaan kurva kalibrasi :

y

= 0.0167x + 0.003

0,0318 = 0.0167x + 0.003

x

= 1,8

Kadar Ni di udara (g/m3) :

( Ct Cb ) Vt
CNi

S
St

( 1,80 ) 50 ml
=

164,44

6358,5
1589,6

10

12

14

= 2,2 g/m3
Konsentrasi Ni di Udara ambien :
C = b/v x 10/25 x 1000
C = 2,2 / 164,44 x 10/25 x 1000
C = 5,35 g/Nm3

5. Konsetrasi logam berat Zn

Data :
Adsorbansi sample Zn = 0,16159
C blanko

=0

V1

= 30,2 L/menit = 1,1185 m3/menit

V2

= 30,5 L/menit = 1,1296 m3/menit

P1

= 756 mmHg

P2

= 759 mmHg

T1

= 29,3 C

T2

= 32,4 C

Volume Udara =

Volume 1+Volume 2
2
1,12+1,13
2

x T x Pa/Ta x 298/760

x 150 menit x 759/305,4 x 298/760

= 164,44 m3

0.2
f(x) = 0.09x + 0
R = 1

0.15
0.1
0.05
0

Kurva Kalibrasi
Zn
Konsentrasi

0.5

Y absorbansi

1.5

2.5

(ppm)
0
0.03
0.05
0.07
1
2

0
0.00188
0.00585
0.00945
0.0932
0.17117

Persamaan kurva kalibrasi :

y

= 0.0861x + 0.0017

0,16159 = 0.0861x + 0.0017

x

= 1,87

Kadar Zn di udara (g/m3) :

( Ct Cb ) Vt
CZn

S
St

( 1,870 ) 50 ml
=

6358,5
1589,6

164,44

= 2,27 g/m3
Konsentrasi Zn di Udara ambien :
C = b/v x 10/25 x 1000
C = 2,27 / 164,44 x 10/25 x 1000
C = 5,52 g/Nm3

TSP (Total Suspended Partikulat)

Data :
W awal = 0,44 gr
W akhir = 0,45 gr
Koreksi laju alir pada kondisi standar :

Qs1 = 1,12 x

298 x 756
)
302,3 x 760

1/2

Qs1 = 1,109 m3/ menit

Qs2 = 1,13 x

298 x 759
)
305,4 x 760

1/2

Qs2 = 1,115 m3/ menit

Volum Udara yang diambil

( Qs 1+Qs 2 )
x 150
2

( 1,109+1,115 )
x 150
2
3

= 166,8 m

Konsentrasi partikel tersuspensi total dalam udara ambien:

0,450,44
x 10

C=(
( 6 166,8)

C = 59,95 g/N m

Faktor konversi Canter (p) :

C1 = C2 (t1/t2) p
230 = 59,95 ( 1/365) p
3,84 = ( 1/365) p
3,84 = 0,0027 p
diperoleh nilai p =
Konsentrasi TSP :
C1

= C2 ( t1/t2)p
= 59,95g/N m3 ( 24jam/2,5jam)
=

g/N m3

Kesimpulan:
No.

Parameter

1.
2.
3.
4.
5.
6.

Cr
Cd
Pb
Ni
Zn
TSP

Konsentarsi
(g/Nm3)
9,79
0,34
0,78
5,35
5,52

Baku Mutu
(g/Nm3)

Keterangan

Memenuhi Baku Mutu