TIPE 9

1. Perhatikan slide!

Konsentrasi Awal Waktu

Percobaan
[H2O] [O2] (sekon)
1 2,4 x 10-1 6 x 10-2 91,2
-1
2 4,8 x 10 6 x 10-2 45,6
-1 -2
3 7,2 x 10 6 x 10 30,4
4 2,4 x 10-1 12 x 10-2 X
-1 -2
5 2,4 x 10 16 x 10 91,2
Berdasarkan data yang tertera pada slide, berapakah nilai X ?

Jawaban : X = 91,2 s
Pembahasan :
a. Orde terhadap H2O :
v3 [ H 2 O]3
v2 = [ [ H 2 O]2 ]X

1
30,4 7,2 x 101
1 = [ 4,8 x 101 ]X
45,6

1,5 = [1,5]X
X = 1

b. Orde terhadap O2 :
v5 [O 2]5
= [ Y
v1 [O 2]1

1
91,2 16 x 102
1 = [ 6 x 102 Y

91,2

1 = [2,66667]Y
Y = 0
 v H2O
1 = k[ ]
1 1
91.2 = k [2,4 x 10 M]
1
91,2 = k [2,4 x 10-1 M]

1 1
s
91,2
k=
2,4 x 101 M
1 1
s
91,2
k= 1
2,4 x 10 M
0,01096 s
k= 1
2,4 x 10 M
1 1
k = 0,045687134 M s

v5 H2O
= k[ ]
1 1
s1 [2,4 x 101 M]
x = 0,045687134 M
1 1
x = 0,010964912 s

X = 91,2 s

2. Perhatikan slide!

Konsentrasi Awal (M) Waktu

Percobaan
[H2] [I2] (Sekon)
1 2 x 10-2 4 x 10-2 7,2
2 4 x 10-2 4 x 10-2 3,6
-2 -2
3 8 x 10 4 x 10 X
4 8 x 10-2 2 x 10-2 3,6
5 8 x 10-2 1 x 10-2 7,2
Berdasarkan data yang tertera pada slide, berapakah nilai X ?

Jawaban : X = 1,8 s

Pembahasan :
a. Orde terhadap H2 :
v2 [ H 2]2
= [ X
v1 [ H 2]1

1
3,6 4 x 102
1 = [ 2 x 102 X

7,2

2 = [2]X
X = 1
b. Orde terhadap I2 :
v5 [ I 2]5
v4 = [ [I 2 ]4 ]Y

1
2
7,2 1 x 10
1 = [ 2 x 103 ]Y
3,6
1 1
2 = [ 2 ]Y

Y =1

v = k [H2] [I2]
1

1 2 2
10 M] [ 4 x 10 M]
7,2 = k [2 x
1 4
7,2 = k [8 x 10 M2]

1 1
s
7,2
k=
8 x 104 M 2
1 1
s
7,2
k= 4 2
8 x 10 M

0.1388 s1
k= 8 x 104 M 2
 2 1
k = 173,6111111 M s
v3
= k [H2] [I2]
1
M 2 s1 [8 x 102 M] [ 4 x 102 M]
x = 173,6111111
1 2 1 4 2
= 173,6111111 M s [32 x 10 ] M
x
1
x = 0,555555555 s

X = 1,8 s

3. Perhatikan slide!

Konsentrasi Awal (M) Waktu

Percobaan
[NO2] [CO] (sekon)
1 1,2 x 10-2 2,4 x10-2 11,7
-2
2 1,2 x 10 1,2 x 10-2 23,4
3 3 x 10-3 2,4 x 10-2 46,8
-3 -3
4 6 x 10 6 x 10 X
Berdasarkan data yang tertera pada slide, berapakah nilai X?

Jawaban : X = 93,6 s
Pembahasan :
a. Orde terhadap NO2 :

v3 [ NO 2 ] 3
v1 = [ [ NO2 ] 1 X

1
46,8 3 x 103
1 = [ 1,2 x 102 X

11,7

0,25 = [0,25]X
X = 1
b. Orde terhadap CO :
v4 [CO]4
v3 = [ [CO ]3 ]Y
 1
23,4 1,2 x 102
1 = [ 2,4 x 10
2 ]Y
11,7

0,5 = [ 0,5 Y

Y = 1

v = k [NO2] [CO]
1

1 2 2
= k [ 1,2 x 10 M] [ 2,4 x 10 M]
11,7
1 4
11,7 = k [2,88 x 10 M2]

1 1
s
11,7
k=
2,88 x 104 M 2
1 1
s
11,7
k= 4 2
2,88 x 10 M

0,085470085 s1
k= 2,88 X 104 M 2

k = 296,7711301 M 2 s1

t5
= k [NO] [Br2]
1 2 1 3 3
M s [6x 10 M] [ 6 x 10
x = 296,7711301 M]

1
= 296,7711301 M 2 s1 [ 36 x 106 ] M2
x
1 1
x = 0,01068376 s

X = 93,6 s

4. Perhatikan slide!

Percobaan Konsentrasi Awal (M) Waktu

 [SO2] [Cl2] (detik)
-1 -2
1 1,2 x 10 3 x 10 45,6
-1 -2
2 2,4 x 10 3 x 10 22,8
3 3,6 x 10-1 3 x 10-2 x
-1 -2
4 1,2 x 10 6 x 10 45,6
5 1,2 x 10-1 8 x 10-2 45,6
Berdasarkan data yang tertera pada slide, berapakah nilai X?
Jawab : X = 15,2 s
Pembahasan :
a. Orde terhadap SO2 :

v2 [ SO2 ]2
v1 = [ [ SO2 ]1 X

1
22,8 2,4 x 101
1 = [ 1, 2 x 101 X

45,6

2 = [2]X
X = 1

b. Orde terhadap Cl2 :

v5 [Cl 2]5
v4 = [ [Cl2 ]4 ]Y

1
45,6 6 x 102
1 = [ 8 x 10
3 ]Y
45,6

1 = [0,75]Y
Y = 0

v1 SO 2
= k[ ]
1
101 M]
45,6 = k [1,2 x
1
45,6 = k [1,2 X 10-1M]
 1
s
45,6
k=
1,2 x 104 M
1
s
45,6
k= 1
1,2 x 10 M
0.0219 s
k= 1.2 x 101 M
1
k = 0,1827 48538 M s

v3 SO 2
= k[ ]
1 1 1
x = 0,1827 48538 M s [3,6 x 10 M]
1 1 1
= 0,182748538 M s [3,6 x 10 M ]
x
1
x = 0,06578947368 s

X = 15,2 s

5. Perhatikan slide!

Konsentrasi Awal (M) Waktu

Percobaan
[H2] [SO2] (sekon)
1 2 x 10-2 8 x 10-2 7,2
2 4 x 10-2 8 x 10-2 3,6
-2 -2
3 8 x 10 8 x 10 1,8
4 8 x 10-2 4 x 10-2 3,6
-2 -2
5 8 x 10 2 x 10 X
Berdasarkan data yang tertera pada slide, berapakah nilai X ?
Jawaban : X = 7,2 s
Pembahasan :
a. Orde terhadap H2 :

v2 [ H 2]2
v1 = [ [ H 2]1 X
 1
3,6 4 x 102
1 = [ 2 x 102 X

7,2

2 = [2]X
X = 1
b. Orde terhadap SO2 :
v4 [SO 2 ]4
v3 = [ [ SO 2]3 ]Y

1
2
3,6 4 x 10
1 = [ 8 x 10
2 ]Y
1,8
1 1
2 = [ 2 ]Y

Y = 1

v1
= k [H2] [SO2]
1 2 2
7,2 = k [2 x 10 M] [ 8 x 10 M]
1 4
7,2 = k [16 x 10 M2]

1 1
S
7,2
k= 4 2
16 x 10 M
1 1
S
7,2
k= 4 2
16 x 10 M

0.1388 S1
k= 16 x 104 M 2

k = 86,80555556 M 2 s1

v5
= k [H2] [SO2]
 1
M 2 s [8 x 102 M] [ 2 x 102 M]
x = 86,80555556 x
1
= 86,80555556 M 2 s [16 x 104 ] M2
x
1 1
x = 0,13888888889 s

X = 7,2 s

6. Perhatikan slide!

Konsentrasi Awal (M) Waktu

Percobaan
[CO] [H2] (sekon)
1 4 x 10-2 8 x 10-2 39
-2
2 4 x 10 4 x 10-2 78
-2 -2
3 1 x 10 8 x10 156
-2 -2
4 2 x 10 2 x10 X
Berdasarkan data yang tertera pada slide, berapakah nilai X ?

Jawaban : X = 312 s-
Pembahasan :
a. Orde terhadap CO :

v3 [ CO]3
v1 = [ [ CO]1 X

1
156 1 x 102
1 = [ 4 x 102 X

39

0,25 = [0,25]X
X = 1
b. Orde terhadap H2 :
v2 [H 2]2
v1 = [ [ H 2]1 ]Y
 1
78 4 x 102
1 = [ 8 x 10
2 ]Y
39

0,5 = [ 0,5 Y

Y = 1

v1
= k [CO] [H2 ]
1 2 2
39 = k [4 x 10 M] [ 8 x 10 M]
1 3
39 = k [ 3,2 x 10 M2]

1 1
s
39
k =
3,2 x 103 M 2
1 1
s
39
k = 3 2
3,2 x 10 M

0.025641025 s1
k= 3,2 X 103 M 2

k = 8,012820513 M 2 s1

v5
= k [CO] [H2]
1
M 2 s1 [ 2 x 102 M] [ 2 x 102 M]
x = 8,012820513
1
= 8,012820513 M 2 s1 [ 4 x 104 ] M2
x
1 1
x = 0,003205128 s

X = 312 s
7. Perhatikan slide!

Konsentrasi Awal (M) Waktu

Percobaan
[NO] [Br2] (sekon)
1 8 x 10-1 2 x 10-1 304
-1
2 16 x 10 2 x 10-1 152
-1 -1
3 24 x 10 2 x 10 X
4 8 x 10-1 4 x 10-1 304
5 8 x 10-1 8 x 10-1 304
Berdasarkan data yang tertera pada slide, berapakah nilai X ?

Jawaban : X = 101,3333339 s
Pembahasan :

Orde terhadap NO :

v2 [ NO ]2
v1 = [ [ NO ]1 X

1
152 16 x 101
1 = [ 8 x 101 X

304

2 = [2]X
X = 1

a. Orde terhadap Br2 :

v5 [ Br2 ]5
v4 = [ [Br 2 ]4 ]Y

1
304 8 x 101
1 = [ 4 x 101 ]Y
304

1 = [ 2 Y

Y = 0
 v1
= k [NO]
1 1
304 = k [8 x 10 M]
1 1
304 = k [8 x 10 M]

1 1
s
304
k=
8 x 101 M

0.003289473 s1
k= 8 x 101 M
1
0.003289473 s
k= 1
8 X 10 M

k = 0,0041118421 M s1

v5
= k [NO]
1 3 1 1
M s [24 x 10
x = 0,0041118421 M]

1 1
= 0,0041118421 Ms [24 x 10-1] M
x
1
x = 0,009868421 s

X = 101,3333339 s

8. Perhatikan slide!

Konsentrasi Awal (M) Waktu

Percobaan
[S2O82-] [I-] (sekon)
1 2 x 10-2 4 x 10-2 19,5
2 2 x 10-2 2 x 10-2 39
3 5 x 10-3 4 x 10-2 78
4 1 x 10-2 1 x 10-2 X

Berdasarkan data yang tertera pada slide, berapakah nilai X ?

Jawaban : X = 156 s
Pembahasan :
a. Orde terhadap S2O82- :

v3 [S 2 O8 ]3
X
v1 = [ [S 2O ]1
8

1
78 5 x 103
1 = [ 2 x 102 X

19,5

0,25 = [0,25]X
X = 1
b. Orde terhadap I- :

I 2

v2
v1 = [ I 1 ]Y



1
2
39 2 x 10
1 = [ 4 x 102 ]Y
19,5

0,5 = [ 0,5 Y

Y = 1

v = k [S2O82-] [I-]
3

1 3 2
78 = k [ 5 x 10 M] [ 4 x 10 M]
1
78 = k [0,0002 M2]

1 1
s
78
k= 2
0,0002 M
1 1
s
78
k= 2
0,0002 M
 0,012820512 s1
k= 0,0002 M 2

k = 64,1025641 M 2 s1

v4
= k [S2O82-] [I-]
1
M 2 s1 [1 x 102 M] [ 1 x 102 M]
x = 64,1025641
1
= 64,1025641 M 2 s1 [ 0.0001 ] M2
x
1 1
x = 0,006410256 s

X = 156 s