14.

EVAPORATOR 01 (EV-01)
Fungsi : Untuk menguapkan gliserol
Gambar:

Keterangan :
Aliran 2 = Aliran masuk dari tanki
Aliran 3 = Aliran output ke H-01

Feed masuk pada kondisi :

T = 284 oC
P = 2,5 atm

Komponen masuk pada evaporator-01:

Komponen Kmol Kg Xi
Gliserol 304,989 28059,000 0,975
Air 7,833 141,000 0,025
Total 312,822 28200,000 1,000

Hasil Perhitungan :
Persamaan Antoine Ln Pi = A-B/(T+C)

Komponen A B C Pi (atm) ki yi = xi*ki

Gliserol 17,239 4487,040 -140,200 650,422 0,342 0,334
Air 18,303 3816,440 -46,130 50783,200 26,728 0,669

Total 1,000

Ditetapkan : Light Key (LK) komponen = Air

Heavy Key (HK) komponen = Gliserol
Penentuan distribusi masing-masing komponen didalam destilate dan bottom produk dengan
komponen referensi Air (H2O).

Komponen Pi (atm) Ki Xi yi = ki/k ref log

Gliserol 650,4220 0,3420 0,9750 0,0130 -1,8930

0,3340

Air 50783,2000 26,7280 0,0250 0,6690 1,0000 0,0000

Total 1,0000 1,0000

Distribusi komponen kunci :

Destilat = 99%

Bottom = 1%

Light Key (LK) komponen:

Top Product

Light Key : (H2O)D = 0,99 x mol H2O

= 0,99 x 7,83 Kmol = 7,755 Kmol

(H2O)B = 0,01 x mol H2O

= 0,01 x 7,83 Kmol = 0,078 Kmol

Heavy Key : (C3H8O3)D = 0,99 x mol C3H8O3

= 0,99 x 304,989 Kmol = 301,939 Kmol

(C3H8O3)B = 0,01 x mol C3H8O3

= 0,01 x 304,989 Kmol = 3,050 Kmol

7,755
log (LK T/LK B) = 0,078 = 2

301,939
log (HK T/HK B) = =2
3,050

Komponen X = log Y = log iT/iB XY X2

Gliserol -1,893 2,00 -3,777 3,582

Air 0,000 2,00 0,000 0,000

 TOTAL -1,893 3,991 -3,777 3,582

. .
Slope = 2 ()2

2 (3,777)(1,893 2)
= 2 3,582 (3,777)^2

= 0,000

2 .
Intercept = 2 ()2

(3,582 3,991) (3,777) (1,893)

= = 1,996
2 3,582 (1,893)^2

Persamaan garis lurus Y = AX + B

Y = 0 X + 1,996

X = log TOP BOTTOM TOTAL INPUT

Komponen Y = log iT/iB iD/iB=10Y
kmol kmol kmol kmol

Gliserol -2,138 1,690 49,000 368,003 7,5103 375,513 375,513

Air 0,000 1,690 49,000 9,451 0,1929 9,644 9,644

TOTAL 377,454 7,703 385,157 385,157

Kondisi Top EV-

01

Komponen kmol Kg
Gliserol 368,003 33856,288

Air 9,451 170,120

TOTAL 377,454 34026,408

Kondisi Bottom
EV-01

Komponen kmol Kg

Gliserol 7,5103 690,944656

Air 0,1929 3,471840

TOTAL 7,7031 694,416

Tabel Material Balance Kolom Destilasi-01 (KD-01)

Komponen

Input Output

Bottom Top

kmol Kg kmol kg kmol kg

gliserol 375,513 34547,233 7,510 690,945 368,003 33856,288

Air 9,644 173,592 0,193 3,472 9,451 170,120

Jumlah 385,157 34720,825 7,703 694,416 377,454 34026,408

34720,825 34720,825