LEMBAR PERHITUNGAN REAGEN

 NaOH
𝑔𝑟 1000
N = 𝐵𝑀 × ×%
𝑉
𝑔𝑟 1000
0,35 = 40 × 250 𝑚𝑙 × 98%

gr = 3,571gr

 Kalibrasi Picnometer
𝑚
𝜌 = = (𝑚2 − 𝑚1)
𝑉
𝑔𝑟 (47,564−22,576)
=
𝑚𝑙 𝑣

V = 24,988 ml

 Katalis HCL
𝑔𝑟 1000
N = 𝐵𝑀 × × % × 𝑉𝑎𝑙𝑒𝑛𝑠𝑖
𝑉
𝑔𝑟 1000
0,15 = 36,5 × 250 𝑚𝑙 × 25% × 1
250𝑔𝑟
0,15 = 36,5×250𝑚𝑙
250𝑔𝑟
0,15 = 9125

1368,75 = 250gr
3,475 = gr

 Katalis H2SO4
𝑔𝑟 1000
N = 𝐵𝑀 × × % × 𝑉𝑎𝑙𝑒𝑛𝑠𝑖
𝑉
𝑔𝑟 1000
0,15 = 98 × 250 𝑚𝑙 × 95% × 2
950𝑔𝑟
0,15 = 24500 × 2

3675 = 1900gr
gr = 1,934 gr

 Densitas HCl
𝑚 (𝐻𝐶𝑙)
𝜌HCl = 𝑉 (𝐻𝐶𝑙)

(51,433−22,576)
𝜌 HCl = 24,988𝑚𝑙
28,857
𝜌 HCl = 24,988𝑚𝑙

𝜌 HCl = 1,1548
 Densitas H2SO4
𝑚 (𝐻𝐶𝑙)
𝜌H2SO4 = 𝑉 (𝐻𝐶𝑙)

(68,232−22,576)
𝜌H2SO4 = 24,988𝑚𝑙

𝜌 H2SO4 = 1,8271

 Densitas Metanol
𝑚 𝑚𝑒𝑡𝑎𝑛𝑜𝑙
𝜌𝑚𝑒𝑡𝑎𝑛𝑜𝑙= 𝑉 𝑚𝑒𝑡𝑎𝑛𝑜𝑙
42,791−22,576
= 24,988

= 0,8344

 Densitas Asam Asetat

𝑚 𝑎𝑠𝑒𝑡𝑎𝑡
𝜌𝑎𝑠𝑒𝑡𝑎𝑡 = 𝑉 𝑎𝑠𝑒𝑡𝑎𝑡
48,695−22,576
= 24,988

= 1,04526

 Volume katalis HCl

𝑚 (𝐻𝐶𝑙)
𝜌HCl basis = 𝑉 (𝐻𝐶𝑙)

5,475
1,1548 = 𝑉
5,475
V = 1,1548

V = 4,741ml

 Volume katalis H2SO4

𝑚 (𝐻2𝑆𝑂4)
𝜌H2SO4 basis = 𝑉 (𝐻2𝑆𝑂4)

1,934
1,8271 = 𝑉
1,934
V = 1,8271

V = 1,0585

 Volume Larutan dengan katalis HCl

Vtotal = Vmetanol + Vasetat + Vkatalis HCl
250 = Vmetanol + Vasetat + 4,741
245,259 = Vmetanol + Vasetat (1)
 𝑉× 𝜌 × %
𝐵𝑀 1
𝑉× 𝜌 × % =
4
𝐵𝑀
𝑉𝐴× 1,04526 × 98%
60 1
𝑉𝑀× 0,8344 ×98 % =
4
32
0,0171 ×𝑉𝐴 1
=
0,02555 ×𝑉𝑀 4
0,02555 VM = 0,0684 VA
VM = 2,6771 VA (2)

Subtitusi persamaan (2) ke persamaan (1)

VA + 2,6771 VA = 245,259
3,6771 VA = 245,259
VA = 66,699 ml

VM = 245,259 – 66,699
VM = 178,56 ml

 Volume Larutan dengan katalis H2SO4

Vtotal = Vmetanol + Vasetat + Vkatalis
250 = Vmetanol + Vasetat + 1,0585
Vmetanol + Vasetat = 248,9415 (1)
𝑉× 𝜌 × %
𝐵𝑀 1
𝑉× 𝜌 × % =
4
𝐵𝑀
𝑉𝐴× 1,04526 × 98%
60 1
𝑉𝑀× 0,8344 ×98 % =
4
32
0,0171 ×𝑉𝐴 1
=
0,02555 ×𝑉𝑀 4
0,02555 VM = 0,0684 VA
VM = 2,6771 VA (2)
Subtitusi persamaan (2) ke persamaan (1)
VA + 2,6771 VA = 248,9415
3,6771 VA = 248,9415
VA = 67,7 ml

VM = 248,9415 – 67,7
VM = 181,2415 ml