KOLOM DESTILASI (KD-02)

Fungsi : Fungsi untuk memisahkan light product berupa etilen dan heavy
produk.

Gambar :

Keterangan:

Aliran 25 = Aliran masuk (feed) KD-02

Aliran 29 = Aliran Top Product KD-02

Aliran 26 = Aliran bottom product KD-02

Aliran 31 = Aliran refluks KD-02

Aliran 28 = Aliran Boilup dari RB-02

Aliran 27 = Aliran Out RB-02

Kondisi operasi:

Kondisi operasi feed :

T = 87,6 oC
P = 3,0500 bar
 Tabel 8.2. Komponen Feed
Komponen Input (KD-02) XF

kmol/jam kg/jam
CH3SCH3 163.8407 10,179.4222 0.5192

H2O 8.2277 148.2223 0.0261

H2S 0.1368 4.6601 0.0004

H2 0.0212 0.0427 0.0001

CH3SH 142.9130 6,874.5423 0.4529

CS2 0.4402 33.5139 0.0014

CH4 0.0000 0.0000 0.0000

Total 315.5795 17240.4035 1.0000

Untuk menentukan tekanan uap masing-masing zat yang masuk KD-01 digunakan persamaan
Antoine :
Log10P = A + B/T + C Log10T + DT + ET2 (yaws carl)

Keterangan :

P = Tekanan uap, mm Hg

T = Temperatur, K

Ki = P*/P …(Pers, 9,19, Treyball 3th, 1981)

Yi = Ki , Xf
Komponen A B C D E

CH3SCH3 37.2604 -2425.1000 -11.3840 0.00581220000 8.59E-14

H2O 29.8605 -3152.2000 -7.3037 0.00000000242 1.81E-06

H2S 18.6383 -1344.6000 -4.1034 0.0000 2.47E-06

H2 9.1827 -107.9290 0.0000 0.16409900000 6.02E-04

CH3SH -1.7459 -1709.0000 6.6886 -0.02539700000 1.89E-05

CS2 25.1475 -2043.9000 -6.7794 0.00348280000 -1.01E-14

Komponen A B C D E

CH4 14.666 -570.9700 -3.3373 0.0000 1.31E-05

Ditetapkan : komponen light key = CH3SH

Komponen heavy key = CH3SCH3
Penentuan distribusi komponen di dalam distilat dan bottom produk dengan komponen referensi
air.
Relative Volatility :
Rumus

Komponen P* ki(mi) XF yi(xf*ki)

CH3SCH3 9943.20622892019 0.6542 0.5192 0.33962198

H2O 2588.60608219774 0.1703 0.0261 0.004440101

H2S 115099.20455926300 7.5723 0.0004 0.003281455

H2 25750.33723344690 1.6941 0.0001 0.000113818

CH3SH 21877.62418224980 1.4393 0.4529 0.651807496

CS2 7773.14973446288 0.5114 0.0014 0.000713358

CH4 5925638.90854499000 389.8447 0.0000 2.66748E-17

Total 6108671.037 401.8862524 1.0000 0.999978207

Distribusi komponen di distilat dan bottom produk = 99,99%

Light key : (x. CH3SH)D = 0,9999 x n. CH3SH
= 0,9999 x 142.9130

= 142.8986726

(x. CH3SH)B = 0,0001 x n. H2S

= 0,0001 x 142.9130
 = 0.014291296

Rumus

Heavy key : (x. CH3SCH3)D = 0,0001 x n. CH3SCH3

= 0,0001 x 163.8407
= 0.016384069

(x. CH3SCH3)B = 0,9999 x n. CH3SCH3

= 0,9999 x 163.8407
= 163.8243085

Rumus

Komposisi Destilat dan Kondensat pada KD-01

Komponen Y = log iD/iB iD/iB D (kmol) B (kmol)

CH3SCH3 -2.1919 0.0064 1.0465 162.79419

H2O -10.64773546 2.25042E-11 0.0000 8.22772

H2S 14.33393 2.1574E+14 0.1368 0.00000

H2 4.476375612 29948.537 0.0212 0.00000

CH3SH 2.9996 999.0000 142.7701 0.14291

CS2 -3.408976151 0.000389963 0.0002 0.44004

CH4 40.28054655 1.90786E+40 0.0000 0.00000

Kondisi operasi top Kolom Distilasi-02 (KD-02) didapat dari paten

Temperatur = 114.9845oC

= 388.1345 K

Tekanan = 19.0000 atm

= 14,440.0000 mmHg

komponen Kmol kg Xf ki xi = xf/ki

CH3SCH3 1.0465E+00 6.5019E+01 0.948657211 1.032096006 0.979105318

H2O 1.8516E-10 3.33566E-09 0.047945711 0.348402433 0.016704403

H2S 0.136756051 4.660099206 3.69392E-18 10.28746538 3.8001E-17

 komponen Kmol kg Xf ki xi = xf/ki

H2 0.021201412 0.042742046 4.12534E-09 1.689014096 6.96775E-09

CH3SH 142.7700509 6867.667758 0.000832803 2.180061728 0.001815561

CS2 0.0001716 0.013064082 0.002564271 0.821138165 0.002105621

CH4 2.15933E-17 3.46421E-16 6.59542E-60 767.6102428 5.06271E-57

total 143.9746856 6937.403062 1,0000 1,0000

Neraca Massa Kolom Distilasi-02 (KD-02)

Komponen Input (Kg) Output (Kg)

Top Bottom

Aliran 35 Aliran 37 Aliran 36

CH3SCH3 10179.4222 65.0194 10114.40283

H2O 148.2223 0.0000 148.2223228

H2S 4.6601 4.6601 2.16006E-14

H2 0.0427 0.0427 1.42718E-06

CH3SH 6874.5423 6867.6678 6.8745423

CS2 33.5139 0.0131 33.50078982

CH4 0.0000 0.0000 1.81576E-56

Subtotal 17240.403549 6937.4031 10303.00049

Total 17240.403549 17240.403549