DAFTAR ISI

Halaman
HALAMAN PERSETUJUAN PEMBIMBING .......................................... iii
HALAMAN PERSETUJUAN PENGUJI .................................................... iv
LEMBAR PERNYATAAN ........................................................................... v
KATA PENGANTAR .................................................................................... vi
SUMMARY .................................................................................................... vii
RINGKASAN ................................................................................................. viii
DAFTAR ISI ................................................................................................... ix
DAFTAR GAMBAR ...................................................................................... xi
DAFTAR TABEL .......................................................................................... xii
DAFTAR LAMPIRAN .................................................................................. xiii
BAB I PENDAHULUAN ........................................................................... 1
1.1. Latar Belakang.......................................................................... 1
1.2. Perumusan Masalah .................................................................. 2
1.3. Tujuan Penelitian ...................................................................... 3
1.4. Tempat dan Waktu Penelitian................................................... 3
BAB II TINJAUAN PUSTAKA ................................................................. 4
2.1. Jerami Padi (Oryza sativa L.) ................................................... 4
2.2. Arang Aktif ............................................................................... 4
2.3. Adsorpsi .................................................................................... 9
2.4. Logam Berat ............................................................................. 10
2.4.1. Timbal (Pb) ..................................................................... 11
2.4.2. Kadmium (Cd) ................................................................ 12
2.5. Spektroskopi UV-Vis ............................................................... 13
2.6. Spektrofotometri Serapan Atom (SSA) .................................... 16
BAB III METODOLOGI PENELITIAN .................................................. 19
3.1. Alat dan Bahan ......................................................................... 19
3.1.1. Alat ................................................................................. 19
3.1.2. Bahan .............................................................................. 19
3.2. Persiapan Sampel ...................................................................... 19
3.2.1. Proses karbonisasi .......................................................... 19

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 3.2.2. Persiapan pembuatan arang aktif jerami padi ................. 20
3.3. Karakterisasi arang aktif dari jerami padi................................. 20
3.3.1. Kandungan air (SNI 06-3730-1995) ............................... 20
3.3.2. Kandungan abu (SNI 06-3730-1995) ............................. 20
3.3.3. Adsorpsi terhadap metilen biru (SNI 06-3730-1995) ..... 21
3.3.4. Adsorpsi terhadap Iodium (SNI 06-3730-1995)............. 22
3.4. Penentuan Daya Serap Bubuk Arang Aktif Jerami padi .......... 23
3.4.1. Logam Timbal ................................................................ 23
3.4.2. Logam kadmium ............................................................ 23
3.5. Analisis Sampel ........................................................................ 23
3.5.1. Analisis timbal dengan SSA (SNI-6989-8-2009) .......... 23
3.5.2. Analisis kadmium dengan SSA (SNI-6989-16-2009) .... 24
3.6. Analisis struktur arang aktif jerami padi menggunakan
Spektrofotometer Inframerah ................................................... 24
3.7. Analisis Data ............................................................................ 24
BAB IV HASIL DAN PEMBAHASAN ..................................................... 25
4.1. Hasil .......................................................................................... 25
4.1.1. Karakterisasi Arang Aktif Jerami Padi ........................... 25
4.1.2. Penentuan Gugus Fungsi Arang Aktif Jerami Padi ........ 25
4.1.3. Hasil adsorpsi arang aktif jerami padi terhadap variasi
konsentrasi ion timbal (Pb2+) ......................................... 26
4.1.4. Hasil adsorpsi arang aktif jerami padi terhadap variasi
konsentrasi ion kadmium (Cd2+) .................................... 27
4.2. Pembahasan .............................................................................. 28
4.2.1. Pembuatan arang aktif jerami padi ................................. 28
4.2.2. Karakterisasi arang aktif jerami padi .............................. 29
4.2.3. Adsorpsi arang aktif jerami padi terhadap ion timbal
(Pb2+) dan ion kadmium (Cd2+) ...................................... 32
BAB V KESIMPULAN DAN SARAN ...................................................... 35
5.1. Kesimpulan ............................................................................... 35
5.2. Saran ......................................................................................... 35
DAFTAR PUSTAKA ..................................................................................... 36

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 DAFTAR GAMBAR
Halaman

Gambar 2.1. Instrumen Spektrofotometer UV-Vis ........................................ 14

Gambar 2.2. Skema Alat Spektrofotometer Serapan Atom............................ 17
Gambar 4.1. Perbandingan Hasil Analisis FTIR Arang Aktif Jerami Padi
dan Arang Jerami Padi .............................................................. 26
Gambar 4.2. Perbandingan Efisiensi Adsorpsi Arang Aktif Jerami Padi dan
Arang Jerami Padi Terhadap Ion timbal (Pb2+) ........................ 32
Gambar 4.3. Perbandingan Efisiensi Adsorpsi Arang Aktif Jerami Padi dan
Arang Jerami Padi Terhadap Ion kadmium (Cd2+)................... 34

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 DAFTAR TABEL
Halaman
Tabel 2.1. Kandungan Jerami Padi .................................................................. 4
Tabel 4.1. Hasil karakterisasi arang jerami padi menggunakan aktivator
asam sulfat dengan variasi konsentrasi 0%, 2,5%, 5% dan 7,5%... 25
Tabel 4.2. Efisiensi adsorpsi arang aktif jerami padi terhadap ion logam
timbal (Pb2+) berdasarkan variasi konsentrasi dengan aktivator
H2SO4 5% ....................................................................................... 26
Tabel 4.3. Efisiensi adsorpsi arang jerami padi tanpa aktivasi terhadap
variasi konsentrasi ion timbal (Pb2+) ............................................. 27
Tabel 4.4. Efisiensi adsorpsi arang aktif jerami padi terhadap ion logam
kadmium (Cd2+) berdasarkan variasi konsentrasi .......................... 27
Tabel 4.5. Efisiensi adsorpsi arang jerami padi tanpa aktivasi terhadap
Variasi konsentrasi ion kadmium (Cd2+)....................................... 27

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 DAFTAR LAMPIRAN
Halaman
Lampiran 1. Skema Kerja............................................................................... 39
Lampiran 2. Pembuatan Larutan .................................................................... 40
Lampiran 3. Karakterisasi Arang Aktif Jerami Padi ...................................... 49
Lampiran 4. Hasil Anaisis Gugus Fungsi Arang Menggunakan FTIR .......... 57
Lampiran 5. Adsorpsi Arang Aktif Terbaik Terhadap Variasi
Konsentrasi Ion timbal (Pb2+) ................................................... 59 H

Lampiran 6. Adsorpsi Arang Aktif Terbaik Terhadap Variasi

Konsentrasi Ion kadmium (Cd2+) .............................................. 62
Lampiran 7. Data Syarat Mutu Arang Aktif (SNI No. 06-3730-1995) .......... 65
Lampiran 8. Dokumentasi Penelitian ............................................................. 66

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