Tahun Kebutuhan (Kg/tahun) Kebutuhan (Ton/tahun) N

2015 18,801,100.00 18801.1 2

2016 18,807,346.00 18807.346 3
2017 21,539,635.00 21539.635 4
2018 22,351,788.00 22351.788 5
2019 21,733,294.00 21733.294 6
Ʃ
23000

22000 f(x) = 940.88299999992 x − 1877114.37839984

𝑥 ̅ R² = 0.758265913848172
Kebutuhan (Ton/tahun)

𝑦 ̅ a
21000

20000 b
19000

18000 y grafik
y=
17000
2014 2015 2016 2017 2018 2019 2020
Tahun
 X Y XY  X2 a = ∑ y . ∑ x2 - ∑ x . ∑xy
2015 18801.1 37884216.5 4060225 n ∑ x2 - (∑ x)2
2016 18807.346 37915609.54 4064256
2017 21539.635 43445443.8 4068289 b = n ∑xy - ∑x . ∑y
2018 22351.788 45105908.18 4072324 n ∑ x2 - (∑ x)2
2019 21733.294 43879520.59 4076361
10085 103233.163 208230698.6 20341455 y = a + bx

101707225
1680.8333333 a= -1877114.37839
17205.527167 b= 940.882999997
x= 2021
10.239052752
y= a + bx
y= -1877114.378394 + 940.883 X
y= -1877114.378394 + 1901524.543
-98481.52 y= 24410.16460066 ton
25000 ton/th
Kapasitas Produksi : 25000 ton/th
Waktu Operasi : 1 tahun = 330 hari
1 hari = 24 jam

Maka kapasitas produksi = 25000 ton/th x 1th / 330 hari x 1hari / 24 jam
= 3156.56566 kg/jam

Bahan baku yang dibutuhkan = 1000 kg/jam

Secara komersial Isopropil alkohol dengan konsentrasi 91 %

( Chemical & Process Technology Encyclopedia, Considine hal. 669 )

Sg IPA = 0.786
Sg H2O = 1 ( Chemical Engineering Condensed, Arthur & Rose )

Komponen BM
IPA 60.0961
H2O 18.0152
Aceton 58.0803
H2 2.0158
O2 32.0000
N2 28.0800
( Perry, ed. 6 cover)

Maka komposisi bahan baku adalah :

Bahan baku Komposisi % Berat Berat (Kg)
IPA 99.8% 998
Isopropyl
H2O 0.20% 2
Total 1000

(CH3)2CHOH (CH3)2CO + H2
m ###
r ### #VALUE! #VALUE!
s ### #VALUE! #VALUE!

IPA = Komposisi kg/jam = #VALUE! kgmol/jam

IPA yang bereaksi = 97% x #VALUE!
= #VALUE! kgmol/jam = #VALUE!
kg acetone = ### kg/jam
kg H2 = ### kg/jam

Kebutuhan Udara = #VALUE! kg/jam

= #VALUE! kgmol/jam
Komposisi :
N2 = ### = #VALUE!
O2 = ### = #VALUE!
### #VALUE!

Neraca Massa Reaktor Massa Masuk, kg/jam Massa keluar, kg/ja

Massa masuk (kg/jam) Liquid dari Heater : Gas ke Kondensor :
IPA = IPA = Komposisi IPA =
H20 = H2O = IPA H 2
O =
O2 = #VALUE! Aceton =
N2 = #VALUE! H2 =
N2 =
H20 =

Total = #VALUE! Total =

ri x 1hari / 24 jam

BM
C 12 IPA = 60
H 1 H20 = 18
O 16 Aceton = 58
N 14 N2 = 28
H2 = 2

H2 + 1/2 O2 H2O
m #VALUE! 3.6
r 7.2536 3.6 7.3
s 9.2536 0 7.3

H2 = 19 kg/jam
H2O= 131 kg/jam
kg/jam o2 = 116 kg/jam
 Massa keluar, kg/jam
e Kondensor :
#VALUE!
IPA
#VALUE!
#VALUE!
#VALUE!
130.5648

#VALUE!
Kapasitas Produksi : 25000 ton/th
Waktu Operasi : 1 tahun = 330 hari
1 hari = 24 jam

Maka kapasitas produksi = 25000 ton/th x 1th / 330 hari x 1hari / 24 jam
= 3156.565657 kg/jam

Bahan baku yang dibutuhkan = 1000 kg/jam

Secara komersial Isopropil alkohol dengan konsentrasi 99,8 %

( Chemical & Process Technology Encyclopedia, Considine hal. 669 )

Sg IPA = 0.786
Sg H2O = 1 ( Chemical Engineering Condensed, Arthur & Rose )

Komponen BM Ar Bm
IPA 60.0961 C 12 IPA = 60
H2O 18.0152 H 1 H20 = 18
Aceton 58.0803 O 16 Aceton = 58
H2 2.0158 N 14 N2 = 28
O2 32.0000 H2 = 2
N2 28.0800 udara = 29
O2 = 32
( Perry, ed. 6 cover)
Maka komposisi bahan baku adalah :
Bahan baku Komposisi % Berat Berat (Kg)
IPA 99.8% 998.0000
Isopropyl
H2O 0.20% 2.0000
Total 1000.0000

A.1 VAPORIZER

VAPORIZER

Fresh Feed masuk vaporizer :

Komposisi Kg/jam kgmol/jam
IPA 998.0000 59880.0000
H2O 2.0000 36.0000
Total 1000.0000 59916.0000
 Komposisi bahan baku yang berasal dari recycle :
Komposisi Kg/jam Kgmol/jam
IPA 0.0000 0.0000
H2O 0.0000 0.0000
Aceton 0.0000 0.0000
Total 0.0000 0.0000

Komposisi feed masuk campuran ke vaporizer :

Komposisi Kg/jam Kgmol/jam
IPA 998.0000 16.6333
H2O 2.0000 0.1111
Aceton 0.0000 0.0000
Total 1000.0000 16.7444

Komposisi feed keluar menuju Reaktor:

Komposisi Kg/jam Kgmol/jam
IPA 998.0000 16.6333
H2O 2.0000 0.1111
Aceton 0.0000 0.0000
Total 1000.0000 16.7444

Neraca Massa vaporizer

Massa masuk, kg/jam Massa keluar, kg/jam
Liquid Campuran ke Vaporizer: Uap dan liquid ke heater 1 :
IPA = 998.0000 IPA = 998.0000
H2 O = 2.0000 H 2
O = 2.0000
Aceton = 0.0000 Aceton = 0.0000

Total 1000.0000 Total 1000.0000

A.2 REAKTOR

Reaksi yang terjadi :

(CH3)2CHOH (CH3)2CO + H2
85% - 90% Yield (Keyes, )
Koversi = 97%
(Kirk Othmer Encyclopediaof Chemical Techonology 4th Edition, )
 (CH3)2CHOH katalis (CH3)2CO + H2
m 16.6333
r 16.1343 16.1343 16.1343
s 0.4990 16.1343 16.1343

(CH3)2CHOH awal = 16.6333 kgmol/jam = ### kg/jam

konversi = 97%
(CH3)2CHOH bereaksi = 16.1343 kgmol/jam = ### kg/jam
(CH3)2CHOH sisa = 0.4990 kgmol/jam = 29.9400 kg/jam
(CH3)2CO terbentuk = 16.1343 kgmol/jam = ### kg/jam
H2 terbentuk = 16.1343 kgmol/jam = 32.2687 kg/jam

Kebutuhan Udara
Perbandinga berat antara gas hidrogen dengan udara yang masuk reaktor 1:0,5
Sehingga udara yang = 0.5 x 32.2687 kg/jam
dibutuhkan = 16.1343 kg/jam
= 0.5564 kgmol/jam

Komposisi Udara
O2 = 21% x 0.56 = 0.1168 kgmol/jam = 3.73871 kg/jam
N2 = 79% x 0.56 = 0.4395 kgmol/jam = 12.30660 kg/jam
= 16.04532

H2 + 1/2 O2 katalis H2O

m 16.1343 0.1168
r 0.2337 0.1168 0.2337
s 15.9007 - 0.2337

Produk Keluar Reaktor :

(CH3)2CHOH sisa = 0.4990 kgmol/jam = ### kg/jam
(CH3)2CO = 16.1343 kgmol/jam = ### kg/jam
H2 = 15.9007 kgmol/jam = ### kg/jam
H2O = 0.2337 kgmol/jam = 4.2061 kg/jam
N2 = 0.4395 kgmol/jam = ### kg/jam
 Massa Masuk, kg/jam Massa keluar, kg/jam
Liquid dari Heater : Gas ke Kondensor :
IPA = 998.0000 IPA = 29.9400
H2 O = 2.0000 H2O = 6.2061
O2 = 3.7387 Aceton = 935.7913
N2 = 12.3066 2H = 31.8013
Acetone = 0.0000 N2 = 12.3066

Total = 1016.0453 Total = 1016.0453

A.3 FLASH DRUM

T Operasi= 40 C
= 313.15 K
P Operasi= 14.7 psi
= 760 mmHg

umpan masuk
IPA = 29.9400 kg/jam = 0.4990 kgmol/jam
H2 O = 6.2061 kg/jam = 0.3448 kgmol/jam
Aceton = 935.7913 kg/jam = 16.1343 kgmol/jam
H2 = 31.8013 kg/jam = 15.9007 kgmol/jam
N2 = 12.3066 kg/jam = 0.4395 kgmol/jam
TOTAL = 1016.0453 kg/jam = 33.3183 kgmol/jam

Mencari Tekanan Uap Komponen

Komponen A B C
IPA 18.6929 3640.2 -53.54
Acetone 16.6513 2983.07 -52.16
H2 13.6333 164.9 3.19
H2O 18.3036 3816.44 -46.13
N2 14.9542 588.72 -6.6

Ln Pi sat = A - B (Smith & Van Ness, ed 5, hal 436)

C+T

Ki = Pi sat (Smith & Van Ness, ed 5, hal 458)

P Operasi
 Komponen Kgmol/jam Zi Pi sat (mmHg) Ki=Pv/Pop Ki.Zi
IPA 0.4990 0.0150 106.8150 0.1405 0.0021
Acetone 16.1343 0.4842 185.2072 0.2437 0.1180
H2 15.9007 0.4772 494857.6488 651.1285 310.7414
H2O 0.3448 0.0103 55.1959 0.0726 0.0008
N2 0.4395 0.0132 457590.6362 602.0929 7.9426
Total 33.3183 1.0000 318.8048

Neraca Massa Komponen F. Zi = V.yi + L.xi (Perry ed. & hal 13-25)
f{ψ} =

keterangan :
F = aliran masuk dari reaktor
V = aliran uap keluar dari flash drum
L = aliran liquid keluar menuju distilasi
Karena nilai K yang didapatkan, diketahui bahwa terdapat nilai K >1 dan nilai K<1
disebut Independent composition
Trial nilai ψ = 0 dan 1

f ( 0 ) = 0.0150 ( 1- 0.1405 ) + ### ( 1- 0.2437 ) +

1+ 0( ### - 1) 1+ 0( ### - 1)

0.4772 ( 1- 651.1285 ) + 0.0103 ( 1- 0.0726 ) +

1+ 0( ### - 1) 1+ 0( 0.0726 -1 )

0.0132 ( 1- 602.0929 )
1+ 0( ### - 1)

= 0.01287 + 0.36624 + -310.2641677 + 0.009596549 + -7.92937437

= -317.80483

f ( 1 ) = 0.0150 ( 1- 0.1405 ) + ### ( 1- 0.2437 ) +

1+ 1( ### - 1) 1+ 1( ### - 1)

0.4772 ( 1- 651.1285 ) + 0.0103 ( 1- 0.0726 ) +

1+ 1( ### - 1) 1+ 1( 0.0726 -1 )

0.0132 ( 1- 602.0929 )
1+ 1( ### - 1)

= 0.09158 + 1.50287 + -0.476502218 + 0.132136317 + -0.01316968

= 1.23692
 0= 0.0150 ( 1- 0.1405 ) + ### ( 1- 0.2437 ) +
1+ 1( ### - 1) 1+ 1( ### - 1)

0.4772 ( 1- 651.1285 ) + 0.0103 ( 1- 0.0726 ) +

1+ 1( ### - 1) 1+ 1( 0.0726 -1 )

0.0132 ( 1- 602.0929 )
1+ 1( ### - 1)

= 0.02866 + 0.71089 + -0.742696253 + 0.023664634 + -0.02052538

= 0.00000 ψ

0= 0.0000

V/F = ψ = 0.6410

Komposisi Vapour Komposisi Liquid

V = F x ψ L = F - V
= 33.3183 x 0.6410 = 33.3183 - 21.3581
= 21.3581 kgmol = 11.9602 kgmol

Menentukan Fraksi Vapour dan Liquid

xi = Zi yi = xi x Ki
1+ψ(Ki-1)
Dapat diketahui Fraksi Mol Masing-Masing Komponen
Komponen xi yi
IPA 0.0334 0.0047
Acetone 0.9400 0.2291
H2 0.0011 0.7438
H2O 0.0255 0.0019
N2 0.0000 0.0206
Total 1.0000 1.0000

Berat masing - masing komponen

Berat (Kgmol) Berat (Kg/jam)
Komponen BM
Liquid Vapour Liquid Vapour
IPA 0.3989 0.1001 60.00 23.9332 6.0068
Acetone 11.2420 4.8923 58.00 652.037 283.7542
H2 0.0137 15.8870 2.00 0.0273 31.7740
H2O 0.3052 0.0396 18.00 5.4936 0.7125
N2 0.0004 0.4391 28.00 0.0114 12.2952
Komponen 11.9602 21.3581 681.5026 334.5427
 Neraca Massa Flash Drum
Masuk (kg/jam) Keluar (kg/jam)
Gas dan Liquid dari Reaktor Menuju Tangki Destilasi
IPA 29.9400 IPA 23.9332
Acetone 935.7913 Acetone 652.0371
H2 31.8013 H2 0.0273
H2O 6.2061 H2O 5.4936
N2 12.3066 N2 0.0114
Menuju Scrubber
IPA 6.0068
Acetone 283.7542
H2 31.7740
H2O 0.7125
N2 12.2952
Total 1016.0453 Total 1016.0453

SCRUBBER

Kondisi Operasi : 1 atm (atmospheric pressure)

45 °C (ulrich :427)

Feed Masuk Scrubber (dari Flash Drum)

Komponen Berat (Kg/jam) Mol (Kgmol/jam)
IPA 6.0068 0.1001
Acetone 283.7542 4.8923
H2 31.7740 15.8870
H2O 0.7125 0.0396
N2 12.2952 0.4391
Total 334.5427 21.3581

Asumsi efisiensi penyerapan = 99%

Gas yang terserap = 99%
Gas yang lolos = 1%

Komponen Gas Terserap (Kg/jam) Gas lolos (kg/jam)

IPA 5.9468 0.0601
Acetone 280.9167 2.8375
H2O 0.7054 0.0071
Total 287.5688 2.9047
 Data Kelarutan
IPA 100%
Acetone 100%
H2 0.0001474 CC/100g H20 ρ H2 = 0.088 gr/L
H2O 100% ρ N2 = 1.165 gr/L
N2 0.001624 CC/100g H20

Kebutuhan Air pada Scrubber

Komponen Gas Terlarut (Kg/jam) Kebutuhan Air(kg/jam)
IPA 5.9468 5.9468
Acetone 280.9167 280.9167
H2O 0.7054 0.7054
Total 287.5688 287.5688

Neraca Massa Scrubber

Bahan Masuk (kg/jam) Bahan Keluar (Kg/jam)
Dari Flash Drum : Ke udara :
IPA 6.0068 IPA = 0.0601
Acetone 283.7542 Acetone = 2.8375
H2 31.7740 H2 = 31.7740
H2O 0.7125 H2O = 0.0071
N2 12.2952 N2 = 12.2952
334.5427 Ke Distilasi :
Kebutuhan air 287.5688 IPA = 5.9468
Acetone = 280.9167
H2O = 288.2741

Total 622.1115 Total 622.1115

DESTILASI 1

Umpan Masuk
Komponen BM Massa (kg/jam) Mol (kmol/jam) xf
Dari Flash + Scrubber
IPA 60.00 29.8799 0.4980 0.0151
Acetone 58.00 932.9538 16.0854 0.4887
H2 2.00 0.0273 0.0137 0.0004
H2O 18.00 293.7677 16.3204 0.4958
N2 28.00 0.0114 0.0004 0.0000
Total 1256.6402 32.9179 1.0000
Perhitungan Boiling point feed dengan Pers Antoine
Komponen A B C
IPA 18.6929 3640.2 -53.54
Acetone 16.6513 2983.07 -52.16
H2 13.6333 164.9 3.19
H2O 18.3036 3816.44 -46.13
N2 14.9542 588.72 -6.6

Ln Pi sat = A - B (Smith & Van Ness, ed 5, hal 436)

C+T

Ki = Pi sat (Smith & Van Ness, ed 5, hal 458)

P Operasi

Trial Suhu Boiling Point

Trial Suhu = 349.9895 K = 76.8395 C
Tek. Op = 760 mmHg = 1 atm
Komponen Pv Ki xi yi
IPA 610.0703 0.8027 0.0151 0.0121
Acetone 761.4826 1.0020 0.4887 0.4896
H2 522509.5857 687.5126 0.0004 0.2854
H2O 312.2226 0.4108 0.4958 0.2037
N2 562283.8217 739.8471 0.0000 0.0092
1.0000 1.0000

Distribusi produk atas

IPA = 0%
Acetone = 100%
H2 = 100%
H2O = 0%
N2 = 100%

Distribusi Mol masing-masing komponen

Komponen Feed xf Distillat xd Bottom xb Distillat
(kmol) kmol kmol kgmol
IPA 0.4980 0.0151 0.0000 0.0000 0.4980 0.0296 0
Acetone 16.0854 0.4887 16.0854 0.9991 0.0000 0.0000 932.954
H2 0.0137 0.0004 0.0137 0.0008 0.0000 0.0000 0.02733
H2O 16.3204 0.4958 0.0000 0.0000 16.3204 0.9704 0
N2 0.0004 0.0000 0.0004 0.0000 0.0000 0.0000 0.01144
32.9179 1.0000 16.0995 1.0000 16.8184 1.0000 932.993
Perhitungan Suhu operasi pada bagian atas dan bawah distilasi
Trial Suhu dew point destilat
Trial Suhu = 349.9045 K = 76.7545 C
Tek. Op = 760 mmHg = 1 atm
Komponen Pv Ki yi xi
IPA 607.9255 0.799901987 0.0000 0.0000
Acetone 759.3084 0.999089944 0.9991 1.0000
H2 522450.8607 687.435343 0.0008 0.0000
H2O 311.1272 0.40937789 0.0000 0.0000
N2 562045.1919 739.5331472 0.0000 0.0000
1.0000 1.0000

Trial Suhu bubble point bottom

Trial Suhu = 372.3740 K = 99.2240 C
Tek. Op = 760 mmHg = 1 atm
Komponen Pv Ki xi yi
IPA 1444.7239 1.9010 0.0296 0.0563
Acetone 1533.6967 2.0180 0.0000 0.0000
H2 537254.4151 706.9137 0.0000 0.0000
H2O 739.1379 0.9725 0.9704 0.9438
N2 624484.3537 821.6899 0.0000 0.0000
1.0000 1.0000

Neraca Massa Destilasi I

Masuk Keluar
Dari Flash Tank dan ScrubbeMenuju Tangki Acetone
IPA 29.8799 Acetone 932.9538
Acetone 932.9538 H2 0.0273
H2 0.0273 N2 0.0114
H2O 293.7677 Menuju Destillasi II
N2 0.0114 IPA 29.87993179
H2O 293.7677101
Total 1256.6402 Total 1256.6402
AKUMULATOR I
Perhitungan Refluks Min
Trial Ѳ q = 1

Trial Ѳ = 1.40909
Komponen xf Pv Ki αi 1-q
IPA 0.0151 610.0703 0.8027 1.9540 0.0543
Acetone 0.4887 761.4826 1.0020 2.4389 1.1573
H2 0.0004 522509.5857 687.5126 1673.5165 0.0004
H2O 0.4958 312.2226 0.4108 1.0000 -1.2119
N2 0.0000 562283.8217 739.8471 1800.9071 0.0000
0.0000
+
Bottom
kgmol
29.8799
0
0
293.768
0
323.648
 APPENDIKS B
PERHITUNGAN NERACA PANAS

Kapasitas produksi : 25000 kg/jam

Waktu operasi : 330 hari/tahun
: 24 jam/hari
Satuan panas : kJ/jam
Suhu referance : 25 o
C = 298.15 K

Komponen BM Titik Didih (oC)

IPA ### 82.5
H2O ### 100
Aceton ### 56.5
H2 ### -252.7
N2 28
O2 32
( Perry, ed. 7)
Cp = A + B.T + C.T + D.T3 2

∫ Cp dT = A.T + 1/2.B.T2 + 1/3.C.T3 1/4.D.T + 4

Heat Capacity Coefficient of Liquids(J/Kmol K)

Komponen A B C D E
IPA 723550 -8095 36.662 -0.066395 4.4064E-05
H2O 276370 -2090.1 8.125 -0.014116 9.3701E-06
Acetone 135600 -177 0.2837 0.000689 0
H2 66.653 6765.9 -123.63 478.27 0
N2 281970 -12281 248 -2.2182 0.0074902
(Perry Edisi 7, Chapter 2 Table 2-196)

Heat Capacity Coefficient of Gases (kkal/kmol.K)

Komponen A B C D
IPA 7.745 0.045 0.0000152 -2.2120E-08
H2O 7.701 0.00046 0.0000025 -8.3900E-09
Aceton 1.505 0.06224 -0.0000299 4.8670E-09
H2 6.483 0.00222 -0.0000033 1.8240E-09
N2 7.44 -0.0032 6.4E-06 -2.79E-09
O2 6.713 -9E-07 4.17E-06 -2.544E-09
(Sherwood, hal 631)
Enthalpi Vaporation (kJ/kmol)
Komponen ΔHvap (kJ/kmol)
IPA 39.9
H2 O 40.66
Aceton 29.1
H2 0.904
(Lange's Handbook Tabel 6-2,6-4)
Enthalpi Pembentukan (kJ/kmol)
Komponen ΔoHf (kJ/kmol)
IPA (l) -318.1
IPA (g) -272.6
H2O (l) -285.83
H2O (g) -241.826
Aceton (l) -248.4
Aceton (g) -217.1
H2 0
O2 0
(Lange's Handbook Tabel 6-1 ,6-3)
B.1 VAPORIZER

1. Feed Masuk

Feed Isopropyl Alcohol (liquid)

T = 30 °C = 303.15 K
Tref = 25 °C = 298.15 K

KomponenMassa (kg/jam)Mol (kmol/jam) ∫CpdT (J/kmol) ∆H (kJ/Jam)

IPA 998.0000 16.6333 3518079.7367 58517.3930
H2O 2.0000 0.1111 1356060.0919 150.6733
Total 1000.0000 16.7444 4874139.8286 58668.0663

∆H1 = ∆H IPA + ∆H H2O

= 58517.3930 + 150.6733
= 58668.0663 kJ/Jam

Feed liquid dari Recycle (Distilasi 2)

T = 100 °C = 373.15 K
Tref = 25 °C = 298.15 K

KomponenMassa (kg/jam)Mol (kmol/jam)∫ Cp dT (J/kmol) ∆H (kJ/Jam)

IPA 0.0000 0.0000 36150374.6133 0.0000
H2O 0.0000 0.0000 15884709.2467 0.0000
Aceton 0.0000 0.0000 9717532.9102 0.0000
Total 0.0000 0.0000 61752616.7701 0.0000

∆H2 = ∆H IPA + ∆H H2O + ∆H Aceton

= 0.0000 + 0.0000 + 0.0000
= 0.0000 kJ/Jam

∆H masuk total = ∆H1 + ∆H2

= 58668.0663 + 0.0000
= 58668.0663 kJ/Jam

2. Feed Keluar

Feed (gas) keluar menuju Heater 1

T = 123 °C = 395.65 K
Tref = 25 °C = 298.15 K
KomponenMassa (kg/jam)Mol (kmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam)
IPA 998.0000 16.6333 973.2245 67730.4542
H2O 2.0000 0.1111 753.6209 350.3500
Aceton 0.0000 0.0000 433.4443 0.0000
Total 1000.0000 16.7444 2160.2896 68080.8042

∆H1 = ∆H IPA + ∆H H2O + ∆H Aceton

= 67730.4542 + 350.3500 + 0.0000
= 68080.8042 kJ/Jam

Enthalpy Penguapan
KomponenMassa (kg/jam)Mol (kmol/jam) Hvap (kJ/kmol) ∆H (kJ/Jam)
IPA 998.0000 16.6333 39.9000 663.6700
H2O 2.0000 0.1111 40.6600 4.5178
Aceton 0.0000 0.0000 29.1000 0.0000
Total 1000.0000 16.7444 109.6600 668.1878

∆H2 = ∆H IPA + ∆H H2O + ∆H Aceton

= 663.6700 + 4.5178 + 0.0000
= 668.1878 kJ/Jam

∆H keluar total = ∆H1 + ∆H2

= 68080.8042 + 668.1878
= 68748.9920 kJ/Jam

Q masuk = Q keluar
58,668.0663 + Qsupply = 68,748.9920 + Qloss
Asumsi Qloss = 5% Qsupply (Ulrich hal 432)
Qsupply = 10611.50071 kJ/jam
Qloss = 530.5750355 kJ/jam

Kebutuhan Steam
Dipakai steam dengan tekanan 4.5 bar (Ulrich 429)
Maka suhu yang diperlukan = 148 oC = 421.15 K (Ulrich 426)
= 298.4 o
F
 λ Steam = 911.5840 BTU/lb Interpolasi λ Steam = 911.5840
= 2120.1965 kJ/kg (Mc Graw Hill, hal 1095)
Qsteam = Msteam x λ Steam
Qsteam
Msteam =
λ Steam
= 10611.501 kJ/jam
2120.1965 kJ/kg
= 5.004961 kg

Neraca Panas Vaporizer

Neraca Masuk (kJ/jam) Neraca Keluar (kJ/jam)
Fresh Feed Menuju Heater
IPA 58517.3930 IPA 67730.4542
H2 O 150.6733 H2O 350.3500
58668.0663 Aceton 0.0000
Recycle dari Distilasi 2 68080.8042
IPA 0.0000 Enthalpi Penguapan
H2 O 0.0000 IPA 663.6700
Aceton 0.0000 H2O 4.5178
0.0000 Aceton 0.0000
668.1878
Qsupply 10611.50070913 Qloss 530.575035456553
Total 69279.5670 Total 69279.5670
B.2 HEATER
1. Feed Masuk (gas)
Feed Masuk dari vaporizer
T = 122.5 °C = 396 K
Tref = 25 °C = 298 K

Perhitungan Panas
Komponen Massa (kg/jam) Mol (kmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam)
IPA 998.0000 16.6333 973.2245 67730.4542
H2O 2.0000 0.1111 753.6209 350.3500
Aceton 0.0000 0.0000 433.4443 0.0000
Total 1000.0000 16.7444 2160.2896 68080.8042

∆H1 = ∆H IPA + ∆H H2O + ∆H Aceton

= 67730.4542 + 350.3500 + 0.0000
= 68080.8042 kJ/Jam
Feed Masuk dari Reaktor
T = 327 °C = 600 K
Tref = 25 °C = 298 K

Perhitungan Panas
Komponen Massa (kg/jam) Mol (kmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam)
IPA 29.9400 0.4990 4484.6348 9363.0923
H2O 6.2061 0.3448 2352.3546 3393.4190
Aceton 935.7913 16.1343 3028.3817 204434.0853
H2 31.8013 15.9007 2032.3879 135211.4687
N2 12.3066 0.4395214943 2152.0873 3957.5980
Total 1016.0453 33.3183 14049.8462 356359.6633
∆H2 = ∆H IPA + ∆H H2O + ∆H Aceton + ∆H H2 + ∆H N2
= 9363.0923 + 3393.4190 + 204434.0853 + 135211.4687 + 3957.5980
= 356359.6633 kJ/Jam

2. Feed Keluar (gas)

Feed Keluar ke Reaktor
T = 300 °C = 573 K
Tref = 25 °C = 298 K
Perhitungan Panas
Komponen Massa (kg/jam) Mol (kmol/jam)∫CpdT (kkal/kmol) ∆H (kkal/Jam)
IPA 998.0000 16.6333 3905.1815 271776.6796
H2O 2.0000 0.1111 2140.6303 995.1552
Aceton 0.0000 0.0000 2567.0082 0.0000
Total 1000.0000 16.7444 8612.8200 272771.8348

∆H1 = ∆H IPA + ∆H H2O + ∆H Aceton

= 271776.6796 + 995.1552 + 0.0000
= 272771.8348 kJ/Jam

Feed Keluar ke Kondensor

T = 319 °C = 592 K
Tref = 25 °C = 298 K

Perhitungan Panas
Komponen Massa (kg/jam) Mol (kmol/jam) Cp (J/kmol) ∆H (kJ/Jam)
IPA 29.9400 0.4990 4309.2794 2.1503
H2O 6.2061 0.3448 2289.6366 0.7894
Aceton 935.7913 16.1343 2888.1741 46.5988
H2 31.8013 15.9007 1977.2003 31.44
N2 12.3066 0.4395214943 2096.3352 0.92
Total 1016.0453 33.3183 13560.63 81.90
∆H2 = ∆H IPA + ∆H H2O + ∆H Aceton + ∆H H2 + ∆H N2
= 2.1503 + 0.7894 + 46.5988 + 31.4388 + 0.92
= 81.9 kJ/Jam

Q masuk = Q keluar
424,440.4675 = 272,853.734 + Qloss
Qloss = 151,586.7340 kJ/jam
Neraca Panas Heater 1
Neraca Masuk (kJ/jam) Neraca Keluar (kJ/jam)
Feed dari Vaporizer Menuju Reaktor
IPA 67730.4542 IPA 271776.6796
H2 O 350.3500 H2O 995.1552
Aceton 0.0000 Aceton 0.0000
68080.8042 272771.8348
Feed dari Reaktor Menuju Condensor
IPA 9363.0923 IPA 2.1503
H2 O 3393.4190 H2O 0.7894
Aceton 204434.0853 Aceton 46.5988
H2 135211.4687 H2 31.4388
N2 3957.5980 N2 0.9214
356359.6633 81.8987
Qloss 151,586.7340
Total 424440.47 Total 424440.47
B.3 REAKTOR B.4 FLASH DRUM
Feed Masuk dari Heater (gas) Feed Masuk dar
T = 327 °C = 600 K T
Tref = 25 °C = 298 K Tref

Perhitungan Panas
∫CpdT (kkal/kmol) ∆H (kJ/Jam)
Komponen Massa (kg/jam)Mol (kmol/jam) Enthalphi bahan
IPA 998.0000 16.6333 4484.6348 312103.0765
H2O 2.0000 0.1111 2352.3546 1093.5835
Aceton 0.0000 0.0000 3028.3817 0.0000
O2 3.7387 0.1168 2060.2812 1007.1415
N2 12.3066 0.4395 2152.08729376 3957.5980
Total 1016.0453 17.3008 14077.7395 318161.3995

∆H1 = ∆H IPA + ∆H H2O + ∆H Aceton + ∆H O2 + ∆H N2

= 312103.0765 + 1093.5835 + 0.0000 + 1007.1415 + 3957.5980
= 318161.3995 kJ/Jam

Feed Keluar dari Reaktor (gas)

T = 327 °C = 600 K
Tref = 25 °C = 298 K

Perhitungan Panas
∫CpdT (kkal/kmol)
Komponen Massa (kg/jam)Mol (kmol/jam) ∆H (kJ/Jam)
IPA 29.9400 8.4900 4484.6348 159304.7925
H2O 6.2061 0.0365 2352.3546 359.4481
Aceton 935.7913 54.5162 3028.3817 690760.8924
H2 31.8013 54.3527 2032.3879 462188.6435
N2 12.306601839 0.4395 2152.0873 3957.5980
Total 3786.7572 117.3954 20277.9079 1316571.3745

∆H2 = ∆H IPA + ∆H H2O + ∆H Aceton + ∆H H2 + ∆H N2

= 159304.7925 + 359.4481 + 690760.8924 + 462188.6435 + 3957.5980
= 1316571.3745 kJ/Jam
 (CH3)2CHOH (CH3)2CO + H2
Isoprophyl Alcohol Acetone Hydrogen

Perhitungan Panas Reaksi ∆H298

Komponen Mol Reaksi (kmol/jam) ΔoHf (kJ/mol) ΔHf (kJ/jam)
IPA 16.1343333333333 -272.6 -14816.54155
Aceton 16.1343333333333 -217.1 -11799.96761
H2 16.1343333333333 0 0

ΔHR298 = ƩHf Produk - ƩHf Reaktan

= 3,016.5739 KJ/jam Reaksi Endoterm

H2 + 1/2 O2 H2O
Hydrogen Oxygen Water

Perhitungan Panas Reaksi ∆H298

Komponen Mol Reaksi (kmol/jam) ΔoHf (kJ/mol) ΔHf (kJ/jam)
H2 0.233669655172414 0 0
O2 0.116834827586207 0 0
H2O 0.233669655172414 -241.826 -56.50739803

ΔHR298 = ƩHf Produk - ƩHf Reaktan

= -56.5074 KJ/jam Reaksi Eksotermis

Neraca Energi Total

∆H masuk + ∆H reaksi + Qsupply = ∆H keluar + Qloss
318161.40 + 2960.07 + Qsupply = 1316571.3745 + Qloss
Asumsi Qloss = 5% Qsupply (Ulrich hal 432)
Qsupply = 1047842.0089 kJ/jam
Qloss = 52392.1004 kJ/jam
Kebutuhan Steam
Dipakai steam dengan tekanan 4.5 bar (Ulrich 429)
Maka suhu yang diperlukan = 148 C = 421.15 K (Ulrich 426)
o

= 298.4 oF
λ Steam = 911.58 BTU/lb Interpolasi λ Steam = 911.5840
= 2120.187 kJ/kg (Mc Graw Hill, hal 1095)
Qsteam = Msteam x λ Steam
Msteam = Qsteam
λ Steam
= 1047842.0089 kJ/jam
2120.18716931 kJ/kg
= 494.2215 kg

Neraca Panas Reaktor

Neraca Masuk (kJ/jam) Neraca Keluar (kJ/jam)
Feed dari Heater 1 Feed keluar dari Reaktor
IPA 312103.0765 IPA 159304.7925
H2 O 1093.5835 H2O 359.4481
Aceton 0.0000 Aceton 690760.8924
313196.6600 H2 462188.6435
Feed udara di Reaktor N2 3957.5980
O2 1007.1415 1316571.3745
N2 3957.5980
4964.739500238

ΔH298 2960.0665
Qsupply 1047842.0089 Qloss 52392.1004
Total 1368963.4750 Total 1368963.4750
B.4 FLASH DRUM B.5 Scrubber
Feed Masuk dari Reaktor (gas)
= 327 °C = 600 K Neraca Panas to
Tref = 25 °C = 298 K ∆H1

Keterangan :
Enthalphi bahan keluar : ∆H1
T2 ∆H2
H = ∫ T1 Cp . dT + ( n . Λ + ∫ Cp . Dt ∆H3
Tref T1 ∆H4

Panas Masuk Flash Drum suhu bahan masu

Komponen Mol (kgmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam) suhu produk kelu
IPA 0.4990 4484.6348 9363.0923 suhu air masuk
H2O 0.3448 2352.3546 3393.4190
Acetone 16.1343 3028.3817 204434.0853
H2 15.9007 2032.3879 135211.4687 1 Panas bahan ma
N2 0.4395 2152.0873 3957.5980 T
TOTAL 356359.6633 Treff
∆H1 = ∆H IPA + ∆H H2O + ∆H Aceton + ∆H H2 + ∆H N2
= 9363.0923 + 3393.4190 + 204434.0853 + 135211.4687 + 3957.5980 Komponen
= 356359.6633 kJ/Jam IPA
H2O
Acetone
Feed Keluar dari Flash Drum (gas dan liquid) H2
T = 80 °C = 353 K N2
Tref = 25 °C = 298 K
∆H1
Panas Keluar Flash Drum menuju Distilasi
Komponen Mol (kgmol/jam) ∫ Cp dT (J/kmol) ∆H (kJ/Jam) 2 Panas yang terk
IPA 0.3989 29437322.3245 11742.1451 T
H2O 0.3052 12458323.3177 3802.2612 Treff
Acetone 11.2420 7207597.2243 81027.9471
H2 0.0137 1097498130.6025 14995.2337 Komponen
N2 0.0004 6366465.1980 2.6001 H20
TOTAL 111570.1872
∆H2 = ∆H IPA + ∆H H 2
O + ∆H Aceton + ∆H H2 + ∆H N2 ∆H2
= 11742.1451 + 3802.2612 + 81027.9471 + ### + 2.6001
= 111570.1872 kJ/Jam
Feed Keluar dari Flash Drum (gas dan liquid) 3 Panas yang terk
T = 80 °C = 353 K T
Tref = 25 °C = 298 K Treff

Panas Keluar Flash Drum menuju Scrubber Komponen

Komponen Mol (kgmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam) IPA
IPA 0.1001 494.8299 207.2722 H
H2O 0.0396 424.3706 70.2810 Aceton
Acetone 11.2420 175.2659 8243.9150 Total
H2 15.8870 359.7365 23912.1178 ∆H3
N2 0.4391 404.6481 743.4393
TOTAL 33177.0253
∆H3 = ∆H IPA + ∆H H2O + ∆H Aceton + ∆H H2 + ∆H N2 4 Panas yang terk
= 207.2722 + 70.2810 + 8243.9150 + 23912.1178 + 743.4393 T
= 33177.0253 kJ/Jam Treff

Total Panas Keluar = ∆H2 + ∆H3 Komponen

= 111570.1872 + 33177.0253 IPA
= 144747.2124 kJ/Jam H2O
Acetone
H2
Neraca Energi total N2
H bahan masuk = H bahan keluar + Qloss
356359.6633 = 144747.2124 + Qloss ∆H4
Q loss = 211612.4509 kJ/Jam

Neraca Panas To
∆H
28520.7061

Neraca Panas Scr

Panas M

∆H2

Total
 Neraca Energi Flash Drum
Masuk (kJ/jam) Keluar (kJ/jam)
Gas dan Liquid dari Reaktor Menuju Tangki Destilasi
IPA 9363.0923 IPA 11742.1451
H2O 3393.4190 H2O 3802.2612
Acetone 204434.0853 Acetone 81027.9471
H2 135211.4687 H2 14995.2337
N2 3957.5980 N2 2.6001
356359.6633 111570.1872
Menuju Scrubber
IPA 207.2722
H2O 70.2810
Acetone 8243.9150
H2 23912.1178
N2 743.4393
33177.0253
Q loss 211612.4509
Total 356359.6633 Total 356359.6633
B.5 Scrubber B.6 DISTILASI 1

Neraca Panas total 1. Feed Masuk

+ ∆H2 = ∆H3 + ∆H4 + Q T = 55
Tref = 25
Keterangan :
= Panas bahan masuk Perhitungan Panas
= Panas yang terkandung pada H2O masuk Komponen
= Panas yang terkandung pada produk bawah IPA (l)
= Panas yang terkandung pada produk atas H2O (l)
Aceton (l)
suhu bahan masuk = 80 °C = 353.15 K H2 (l)
suhu produk keluar = 55 °C = 328.15 K N2 (l)
suhu air masuk = 30 °C = 303.15 K Total
∆H1 = 386618.64

Panas bahan masuk dari Flash Drum (∆H1)

= 80 °C = 353.15 K
= 25 °C = 298.15 K

Komponen Mol (kgmol/jam) ∫CpdT (kkal/kmol) ∆H (kJ/Jam)

IPA 0.1001 494.8299 207.2722
H2O 0.0396 424.3706 70.2810
Acetone 4.8923 175.2659 3587.5958
H2 15.8870 359.7365 23912.1178
N2 0.4391 404.6481 743.4393
TOTAL 28520.7061
∆H1 = 28520.7061 kJ/jam

Panas yang terkandung pada H2O masuk (∆H2)

= 30 °C = 303.15 K
= 25 °C = 298.15 K

Komponen Mol (kgmol/jam) ∫ Cp dT (J/kmol) ∆H (kJ/Jam)

H20 15.9760 1356060.0919 21664.4749
Total 21664.4749
= 21664.4749 kJ/jam
Panas yang terkandung pada produk bawah (∆H3)
= 55 °C = 328.15 K
= 25 °C = 298.15 K

Komponen Massa (kg/jam) Mol (kmol/jam) ∫ Cp dT (J/kmol) ∆H (kJ/Jam)

IPA 5.9468 0.0991 18380477.1635 1821.7359
H2 O 288.2741 16.0152 7420867.0487 118846.8916
Aceton 280.9167 4.8434 3991042.8225 19330.1805
Total 575.1376 20.9577 29792387.0347 139998.8080
= 139998.8080 kJ/jam

Panas yang terkandung pada produk atas (∆H4)

= 55 °C = 328.15 K
= 25 °C = 298.15 K

Komponen Mol (kgmol/jam) ∫CpdT (kkal/kmol) ∆H (kJ/Jam)

IPA 0.0010 252.7323 1.0586
H2O 0.0004 231.2578 0.3830
Acetone 0.0489 72.8899 14.9202
H2 15.8870 195.4574 12992.2924
N2 0.4391 221.7990 407.5001
TOTAL 13416.1543
= 13416.1543 kJ/jam

Neraca Panas Total

∆H1 + ∆H2 = ∆H3 + ∆H4
+ Q
28520.7061 + 21664.4749 = 139998.8080 + 13416.1543 + Q
Q = -103229.7813 kJ/jam

Neraca Panas Scrubber

Panas Masuk (kJ/jam) Panas Keluar (kJ/jam)
∆H1 = 28520.7061 ∆H3 = 139998.8080
∆H2 = 21664.4749 ∆H4 = 13416.1543
Q = -103229.7813
50185.1810 Total 50185.1810
B.6 DISTILASI 1 B.7 COOLER

1. Feed Masuk
55 °C = 328 K
25 °C = 298 K

Perhitungan Panas
Massa (kg/jam) Mol (kmol/jam) ∫CpdT (J/kmol) ∆H (kJ/Jam)
29.8799 0.4980 3991042.8225 1987.5348
932.9538 51.8308 7420867.0487 384629.2248
0.0273 0.0005 3991042.8225 1.8803
293.7677 146.8839 98783659.5900 14509724.7389
0.0114 0.0004 4751866.8720 1.9407
1256.6402 39.2700 15402952.6937 386618.64
386618.64
B.7 COOLER