2014 2015

Bulan Berat (kg) Berat (ton) Bulan Berat (kg)

Januari 7842980 7842.98 Januari 6237258
Februari 10512853 10512.853 Februari 7251446
Maret 8747558 8747.558 Maret 6929797
April 7369154 7369.154 April 8829777
Mei 10828522 10828.522 Mei 7086151
Juni 10367635 10367.635 Juni 6678737
Juli 6466584 6466.584 Juli 7316127
Agustus 12627548 12627.548 Agustus 7712210
September 9398222 9398.222 September 4154096
Oktober 12301183 12301.183 Oktober 6008091
November 6199351 6199.351 November 9156583
Desember 9202534 9202.534 Desember 5900725
Ʃ 111864.124 Ʃ 83260.998
Sumber = BPS 2014

data (n) tahun(x) Kapasitas Impor (y) x.y x^2

1 2015 18801.1 37884216.5 4060225
2 2016 18807.346 37915609.536 4064256
3 2017 21539.635
Kebutuhan
43445443.795
Asam Asetat Tahun 2015-2019
4068289
4 2018 22351.788
23000 45105908.184 4072324
5 2019 21733.294
22000 43879520.586 4076361
f(x) = 940.88299999992 x − 1877114.37839984
Ʃ 10085 R² = 0.758265913848172
103233.163 208230698.601 20341455
21000
Jumlah (Ton)

20000

19000

18000
a b x y
17000
-1877114.38 940.883 2021 24410
2014.5 2015 2015.5 2016 2016.5 2017 2017.5 2018 2018.5 201
Tahun
Jadi, untuk kapasitas produksi tahun 2021 adalah 24410.1646 ton/tahun
1 tahun = 330 hari kerja 25000.0000 ton/tahun
1 hari = 24 jam
1 ton = 1000 kg

14646.0988 ton/tahun
Pabrik memproduksi 60% dari kebutuhan per tahun. Sehingga,
kapasitas produksi Asam Asetat pada tahun 2021 adalah 2361.1111 kg/jam

39.3191 kgmol/jam
 2016
Berat (ton) Bulan Berat (kg) Berat (ton) Bulan
6237.258 Januari 3801734 3801.734 Januari
7251.446 Februari 7942475 7942.475 Februari
6929.797 Maret 6430643 6430.643 Maret
8829.777 April 5533717 5533.717 April
7086.151 Mei 4472648 4472.648 Mei
6678.737 Juni 6421014 6421.014 Juni
7316.127 Juli 3500307 3500.307 Juli
7712.21 Agustus 5601301 5601.301 Agustus
4154.096 September 2827513 2827.513 September
6008.091 Oktober 5057280 5057.28 Oktober
9156.583 November 4466492 4466.492 November
5900.725 Desember 3391621 3391.621 Desember
83260.998 Ʃ 59446.745 Ʃ
Sumber = BPS 2015 Sumber = BPS 2016

Tahun 2015-2019

114.37839984

2017 2017.5 2018 2018.5 2019 2019.5

hun

≈ 18700 ton/tahun
 2017 2018
Berat (kg) Berat (ton) Bulan Berat (kg) Berat (ton)
4873743 4873.743 Januari 6204652 6204.652
7944682 7944.682 Februari 6294723 6294.723
5977168 5977.168 Maret 6519903 6519.903
5200933 5200.933 April 4387111 4387.111
5660295 5660.295 Mei 7805722 7805.722
5489106 5489.106 Juni 6447311 6447.311
6147865 6147.865 Juli 5307428 5307.428
4630253 4630.253 Agustus 6328147 6328.147
7136582 7136.582 September 5415339 5415.339
6014057 6014.057 Oktober 5823639 5823.639
5381447 5381.447 November 5073025 5073.025
4916137 4916.137 Desember 5356870 5356.87
69372.268 Ʃ 70963.87
Sumber = BPS 2017 Sumber = BPS 2018
APPENDIX A
PERHITUNGAN NERACA MASSA

Kapasitas Produksi : 25000 ton/th Komponen

Waktu Operasi : 1 tahun = 330 hari (CH3)2CHOH
1 hari = 24 jam H2O
(CH3)2CO
Kapasitas Produksi (kg/jam) : 25000 x 1000 H2
330 x 24 O2
: 1818181.8182 kg/jamUdara
: 31347.9624 kgmol/ja N2
( Perry, ed. 6 cover)
Basis Bahan Baku : 1000 kg/jam
Komposisi Isopropil Alkohol Unsur
Bahan Baku % Berat Berat (Kg/jam) C
C3H8O 99.80% 998.0000 H
H2O 0.20% 2.0000 O
N

Maka umpan masuk Vapourizer adalah :

Massa Masuk Kg/Jam Massa Keluar Kg/Jam

a. Umpan Segar
IPA 998.0000 IPA 998.0000
H2O 2.0000 H2O 2.0000
Total 1000.0000 Total 0.0000

A.1 Vaporizer

VAPORIZER

Feed Masuk Vapourizer

Komposisi Kg/Jam Kgmol/Jam
IPA 998.0000 16.6333333333333
H2O 2.0000 0.1111

A.2. Reaktor
a.
(CH3)2CHOH Katalis (CH3)2CO + H2
Konversi = 97% (Krik Othmer)

(CH3)2CHOH awal = 16.6333 kgmol/jam = 998 kg/jam

(CH3)2CHOH bereaksi = 16.1343 kgmol/jam = 968.1 kg/jam
(CH3)2CHOH sisa = 0.4990 kgmol/jam = 29.94 kg/jam
(CH3)2CO terbentuk = 16.1343333333333 kgmol/jam = 935.7913 kg/jam
H2 terbentuk = 16.1343 kgmol/jam = 32.2687 kg/jam

Kebutuhan Udara
Perbandinga berat antara gas hidrogen dengan udara yang masuk reaktor 1:0,5
= 0.5 x 32.2687 kg/jam
Sehingga udara yang dibutuhkan = 16.1343 kg/jam
= 0.5564 kgmol/jam
Komposisi Udara
O2= 0.2100 x 0.5564 = 0.1168 kgmol/jam = 3.7387 kg/jam
N2= 0.79 x 0.5564 = 0.4395 kgmol/jam = 12.3066 kg/jam
b. 16.0453
H2 + 1/2 O2 Katalis H2O
m 16.1343 0.1168
r 0.233669655172 0.1168 0.2337
s 15.9007 + 0.0000 0.2337

Produk yang keluar dari reaktor

(CH3)2CHOH sisa = 0.4990 kgmol/jam = 29.9400 kg/jam
(CH3)2CO = 16.1343333333333 kgmol/jam = 935.7913 kg/jam
H2 sisa = 15.9007 kgmol/jam = 31.8013 kg/jam
H2O = 0.3448 kgmol/jam = 6.2061 kg/jam
N2 = 0.4395 kgmol/jam = 12.3066 kg/jam

Neraca Massa Reaktor

Massa Masuk (Kg/jamMassa Keluar (Kg/jam)
Liquid dari Heater Gas Ke Kondensor
IPA = 998.0000 (CH3)2CHOH sisa = 29.9400
H2O = 2.0000 (CH3)2CO = 935.7913
Udara masuk: H2 sisa = 31.8013
O2 = 3.7387 H2O = 6.2061
N2 = 12.3066 N2 = 12.3066
1016.0453 1016.0453

A.3 Flash Drum

T Operasi = 40 oC
= 313.15 K
P Operasi = 14.7 psi
= 760 mmHg
umpan masuk
(CH3)2CHOH = 29.9400 kg/jam = 0.4990 kgmol/jam
(CH3)2CO = 935.7913 kg/jam = 16.1343 kgmol/jam
H2 = 31.8013 kg/jam = 15.9007 kgmol/jam
H2O = 6.2061 kg/jam = 0.3448 kgmol/jam
N2 = 12.3066 kg/jam = 0.4395 kgmol/jam
Total = 1016.0453 kg/jam = 33.3183 kgmol/jam

Mencari Tekanan Uap Komponen

Komponen A B C
(CH3)2CHOH 18.6929 3640.2 -53.54
(CH3)2CO 16.6513 2983.07 -52.16
H2 13.6333 164.9 3.19
H2O 18.3036 3816.44 -46.13
N2 14.9542 588.72 -6.6

Ln Pi sat = A - B (Smith & Van Ness, ed 5, hal 436)

C+T

Ki = Pi sat (Smith & Van Ness, ed 5, hal 458)

P Operasi

Komponen Kgmol/jam Zi Pi sat (mmHg) Ki=Pv/Pop

(CH3)2CHOH 0.4990 0.0150 106.8150 0.1405
(CH3)2CO 16.1343 0.4842 185.2072 0.2437
H2 15.9007 0.4772 494857.6488 651.1285
H2O 0.3448 0.0103 55.1959 0.0726
N2 0.4395 0.0132 457590.6362 602.0929
Total 33.3183 1.0000

Neraca Massa Komponen F. Zi = V.yi + L.xi (Perry ed. & hal 13-25)
f{ψ} =

keterangan :
F = aliran masuk dari reaktor
V = aliran uap keluar dari flash drum
L = aliran liquid keluar menuju distilasi
Karena nilai K yang didapatkan, diketahui bahwa terdapat nilai K >1 dan nilai K<1
disebut Independent composition
Trial nilai ψ = 0 dan 1
f { 0} = 0.0150 ( 1- 0.1405 ) + 0.4842 ( 1
1 1

0.4772 ( 1- 651.1285 ) + 0.0103 ( 1

1 1
 0.0132 ( 1- 602.0929 ) = 0.012872 + 0.36624 + -310.2641677
1 + -7.92937 = -317.805

f { 1} = 0.0150 ( 1- 0.14055 ) + 0.4842 ( 1-

0.1405 0.2437

0.4772 ( 1- 651.1285 ) + 0.0103 ( 1-

651.1285 0.0726

0.0132 ( 1- 602.0929 ) = 0.091584 + 1.502871 + -0.476502218

602.0929 + -0.01317 = 1.23692

0= 0.0150 ( 1- 0.14055 ) + 0.4842 ( 1-

0.449065437696203 0.515186028552386

0.4772 ( 1- 651.1285 ) + 0.0103 ( 1-

417.750933554173 0.405526849827645

0.0132 ( 1- 602.092942421 ) = 0.028664 + 0.710889 + -0.742701315

386.317749620417 + -0.02053 = -9.7E-06 ψ

0= 0.0000

V/F = ψ = 0.6410

Komposisi Vapour Komposisi Liquid

V = F x ψ L = F - V
= 33.3182992720306 x 0.6410 = 33.3183 - 21.35798
= 21.3579817539952 kgmol = 11.9603 kgmol

Menentukan Fraksi Vapour dan Liquid

xi = Zi yi = xi x Ki
1+ψ(Ki-1)
Dapat diketahui Fraksi Mol Masing-Masing Komponen
Komponen xi yi
(CH3)2CHOH 0.0334 0.0047
(CH3)2CO 0.9399 0.2291
H2 0.0011 0.7438
H2O 0.0255 0.0019
N2 0.0000 0.0206
Total 1.0000 1.0000
Berat masing - masing komponen
Berat (Kgmol) Berat (Kg/jam)
Komponen BM
Liquid Vapour Liquid Vapour
(CH3)2CHOH 0.3989 0.1001 60.00 23.93327 6.006729
(CH3)2CO 11.2421 4.8922 58.00 652.0409 283.7505
H2 0.0137 15.8870 2.00 0.027327 31.774
H2O 0.3052 0.0396 18.00 5.493584 0.712469
N2 0.0004 0.4391 28.00 0.011435 12.29517
Total 11.9602 21.3581 681.5065 334.5388

Neraca Massa Flash Drum

Masuk Keluar
Gas dan Liquid dari Reaktor Menuju Tangki Destilasi I
(CH3)2CHOH 29.9400 (CH3)2CHOH 23.93327
(CH3)2CO 935.791 (CH3)2CO 652.0409
H2 31.8013 H2 0.027327
H2O 6.2061 H2O 5.493584
N2 12.3066 N2 0.011435
Menuju Scrubber
(CH3)2CHOH 6.006729
(CH3)2CO 283.7505
H2 31.774
H2O 0.712469
N2 12.29517
Total ### Total 1016.0453

A.3 Scrubber

Massa Masuk
(CH3)2CHOH 6.0067 kg/jam = 6006.729 gr/jam
(CH3)2CO 283.7505 kg/jam = 283750 gr/jam
H2 31.7740 kg/jam = 31774 gr/jam
H2O 0.7125 kg/jam = 712.4693 gr/jam
N2 12.2952 kg/jam = 12295.17 gr/jam

Data Kelarutan
(CH3)2CHOH 100
(CH3)2CO 100
H2 0.0001474 = 0
H2O 0
N2 0.001624 = 0
Gas yang terserap
(CH3)2CHOH = 6006.7295 gr/jam = 6.00673 kg/jam
(CH3)2CO = 283750.4510 gr/jam = 283.75045 kg/jam
H2 = 0.0001 gr/jam = 0.00000 kg/jam
H2O = 0.0000 gr/jam = 0.00000 kg/jam
N2 = 0.0016 gr/jam = 0.00000 kg/jam
Total Kebutuhan Air = 289757.1822 gr/jam = 289.75718 kg/jam

Neraca Massa Scrubber

Masuk Keluar
Aliran dari Flash Tank Ke Udara
(CH3)2CHOH 6.0067 H2 31.7740
(CH3)2CO 283.7505 H2O 0.7125
H2 31.7740 N2 12.2952
H2O 0.7125 Aliran Menuju Destilasi I
N2 12.2952 (CH3)2CHOH 6.0067
(CH3)2CO 283.7505
Air Proses H2O 289.7571822
H2O 289.7571822
Total 624.2960 Total 624.2960

Kolom Distilasi 1

Umpan Masuk
Komponen BM Massa (kg/jam) Mol (kmol/jam) xf
Dari Flash + Scrubber
(CH3)2CHOH 60.00 29.9400 0.4990 0.0151
(CH3)2CO 58.00 935.7913 16.1343 0.4882
H2 2.00 0.0273 0.0137 0.0004
H2O 18.00 295.2508 16.4028 0.4963
N2 28.00 0.0114 0.0004 0.0000
Total 1261.0209 33.0502 1

Perhitungan Boiling point feed dengan Pers Antoine

Komponen A B C
(CH3)2CHOH 18.6929 3640.2 -53.54
(CH3)2CO 16.6513 2983.07 -52.16
H2 13.6333 164.9 3.19
H2O 18.3036 3816.44 -46.13
N2 14.9542 588.72 -6.6
 Ln Pi sat = A - B (Smith & Van Ness, ed 5, hal 436)
C+T

Ki = Pi sat (Smith & Van Ness, ed 5, hal 458)

P Operasi

Trial Suhu Boiling Point

Trial Suhu = 350.0468 K = 76.8968 C
Tek. Op = 760 mmHg= 1 atm
Komponen Pv Ki xi yi
(CH3)2CHOH 611.5192 0.8046 0.0151 0.0121
(CH3)2CO 762.9506 1.0039 0.4882 0.4901
H2 522549.1479 687.5647 0.0004 0.2842
H2O 312.9625 0.4118 0.4963 0.2044
N2 562444.6232 740.0587 0.0000 0.0091
1.0000 1.0000

Diharapkan = Kemurnian

Asumsi distribusi komponen

Distribusi produk atas

(CH3)2CHOH = 0%
(CH3)2CO = ###
H2 = ###
H2O = 0%
N2 = ###

Distribusi Mol masing-masing komponen

Komponen Feed xf Distillat xd Bottom xb Distillat
(kmol) kmol kmol kgmol
(CH3)2CHOH 0.4990 0.0151 0.0000 0.0000 0.4990 0.0295 0
(CH3)2CO 16.1343 0.4882 16.1343 0.9991 0.0000 0.0000 935.7913
H2 0.0137 0.0004 0.0137 0.0008 0.0000 0.0000 0.027327
H2O 16.4028 0.4963 0.0000 0.0000 16.4028 0.9705 0
N2 0.0004 0.0000 0.0004 0.0000 0.0000 0.0000 0.011435
33.0502 1.0000 16.1484 1.0000 16.9018 1 935.8301

Perhitungan Suhu operasi pada bagian atas dan bawah distilasi

Trial Suhu dew point destilat
Trial Suhu = 349.9045 K = 76.7545 C
Tek. Op = 760 mmHg= 1 atm
Komponen Pv Ki yi xi
(CH3)2CHOH 607.9255 0.7999 0.0000 0.0000
(CH3)2CO 759.3084 0.9991 0.9991 1.0000
H2 522450.8607 687.4353 0.0008 0.0000
H2O 311.1272 0.4094 0.0000 0.0000
N2 562045.1919 739.5331 0.0000 0.0000
1.0000 1.0000
Trial Suhu bubble point bottom
Trial Suhu = 372.3740 K = 99.2240 C
Tek. Op = 760 mmHg= 1 atm
Komponen Pv Ki xi yi
(CH3)2CHOH 1444.7239 1.9010 0.0295 0.0561
(CH3)2CO 1533.6967 2.0180 0.0000 0.0000
H2 537254.4151 706.9137 0.0000 0.0000
H2O 739.1379 0.9725 0.9705 0.9438
N2 624484.3537 821.6899 0.0000 0.0000
1.0000 1.0000

Neraca Massa Destilasi I

Masuk Keluar
Dari Flash Tank dan Scrubber Menuju Tangki Acetone
(CH3)2CHOH 29.9400 (CH3)2CO 935.7913333
(CH3)2CO 935.7913 H2 0.027326732
H2 0.0273 N2 0.011435453
H2O 295.2508 Menuju Destillasi II
N2 0.0114 (CH3)2CHOH 29.94
H2O 295.2507667
Total 1261.0209 Total 1261.0209

Akumulator D 1

Perhitungan Refluks Min

Trial Ѳ q = 1

Trial Ѳ = 0.00119
Komponen xf Pv Ki αi 1-q
(CH3)2CHOH 0.0151 611.5192 0.8046 0.0012 -0.9857
(CH3)2CO 0.4882 762.9506 1.0039 2.4378 0.4884
H2 0.0004 522549.148 687.5647 1669.686 0.0004
H2O 0.4963 312.9625 0.4118 1.0000 0.4969
N2 0.0000 562444.623 740.0587 1797.163 0.0000
0.0000

Reffluks Minimum
Komponen xdi Ki dew αi αi-Ѳ Rmin+1
(CH3)2CHOH 0.0000 0.7999 1.9539 1.953 0
(CH3)2CO 0.9991 0.9991 2.4405 2.4393 0.99962
H2 0.0008 687.4353 1679.2195 1679.218 0.00085
H2O 0.0000 0.4094 1.0000 0.9988118 0
N2 0.0000 739.5331 1806.4804 1806.4792 0.000
Total 1.0000 1.0005

Rmin+1 = 1.0005
Rmin = 0.0005
Ropt = 1.5 x 0.0005
= 0.00073
= L/D = D = 16.1484 kmol
L = 0.01179 Kmol

Komposisi Refluks (L)

Komponen xl kmol kg/jam
(CH3)2CHOH 0.0000 0 0.0000
(CH3)2CO 0.9991 0.01178 0.6831
H2 0.0008 0.0000 0.0000
H2O 0.0000 0 0.0000
N2 0.0000 0.0000 0.0000

Uap Keluar Menara Destilasi (V)

V = D + L
= 16.1602 kmol/jam
Komposisi Uap (V)
Komponen yv kmol kg/jam
(CH3)2CHOH 0.0000 0.0000 0.0000
(CH3)2CO 0.9991 16.1461 936.4745
H2 0.0008 0.0137 0.0273
H2O 0.0000 0.0000 0.0000
N2 0.0000 0.0004 0.0114

Neraca Massa Akumulator

Masuk Keluar
Dari Destilasi I Rerfluks Destilasi I
(CH3)2CHOH 0.0000 (CH3)2CHOH 0.0000
(CH3)2CO 936.4745 (CH3)2CO 0.6831
H2 0.0273 H2 0.0000
H2O 0.0000 H2O 0.0000
N2 0.0114 N2 0.0000
Menuju Tangki Aceton
(CH3)2CHOH 935.7913
H2 0.0273
N2 0.0114

Total 936.5133 Total 936.5133

 Reboiler D 1

Neraca Massa Reboiler

L' = F + L
dimana
L' = Aliran Masuk Reboiler
F = Aliran Feed
L = Aliran Refluks

diketahui
F = 33.0502 kmol
L = 0.0117885 kmol
L' = 33.0620 kmol

V' = L' + B
dimana
V' = Uap Keluar Reboiler
B = Hasil Bottom

diketahui
B = 16.9018 kmol
maka
V = 16.1602 kmol

Komposisi Bottom
Komponen xb kmol kg/jam
(CH3)2CHOH 0.0295 0.4990 29.94
(CH3)2CO 0.0000 0 0
H2 0.0000 0 0
H2O 0.9705 16.4028 295.250767
N2 0.0000 0 0

Komposisi feed reboiler

Komponen xb kmol kg/jam
(CH3)2CHOH 0.0295 0.9761 58.5662773
(CH3)2CO 0.0000 0.0000 0
H2 0.0000 0.0000 0
H2O 0.9705 32.0859 577.546369
N2 0.0000 0.0000 0

Komposisi Uap reboiler

Komponen xb kmol kg/jam
(CH3)2CHOH 0.0295 0.4771 28.6262773
(CH3)2CO 0.0000 0.0000 0
H2 0.0000 0.0000 0
H2O 0.9705 15.6831 282.295602
N2 0.0000 0.0000 0
Neraca Massa Reboiler
Masuk Keluar
Dari Destilasi I Refluks Ke Destilasi I
(CH3)2CHOH 58.566277 (CH3)2CHOH 28.6262773032
(CH3)2CO 0 (CH3)2CO 0
H2 0 H2 0
H2O 577.54637 H2O 282.295601917
N2 0 N2 0
Menuju Destilasi II
(CH3)2CHOH 29.94
(CH3)2CO 0
H2 0
H2O 295.250766695
N2 0
Total 636.11265 Total 636.11265

Distillasi II

Feed Masuk distillasi = Produk bawah distilasi I

= 325.1908 kg/jam
Komponen BM Massa (kg/jam) Mol (kmol/jam) xf

(CH3)2CHOH 60.00 29.9400 0.4990 0.0295

(CH3)2CO 58.00 0.0000 0.0000 0.0000
H2 2.00 0.0000 0.0000 0.0000
H2O 18.00 295.2508 16.4028 0.9705
N2 28.00 0.0000 0.0000 0.0000
Total 325.1908 16.9018 1.0000

Perhitungan Boiling point feed dengan Pers Antoine

Komponen A B C
(CH3)2CHOH 18.6929 3640.2 -53.54
(CH3)2CO 16.6513 2983.07 -52.16
H2 13.6333 164.9 3.19
H2O 18.3036 3816.44 -46.13
N2 14.9542 588.72 -6.6

Ln Pi sat = A - B (Smith & Van Ness, ed 5, hal 436)

C+T

Ki = Pi sat (Smith & Van Ness, ed 5, hal 458)

P Operasi
Trial Suhu Boiling Point
Trial Suhu = 372.3760 K = 99.2260 C
Tek. Op = 760 mmHg= 1 atm
Komponen Pv Ki xi yi
(CH3)2CHOH 1444.8273 1.9011 0.0295 0.0561
(CH3)2CO 1533.7859 2.0181 0.0000 0.0000
H2 537255.6713 706.9154 0.0000 0.0000
H2O 739.1909 0.9726 0.9705 0.9439
N2 624489.8496 821.6972 0.0000 0.0000
1.0000 1.0000
 BM
60.0000
18.0000
58.0000
2.0000
32
29
28
ed. 6 cover)

Ar
12.0000
1.0000
16.0000
14.0000
kg/jam
kg/jam

kg/jam
kg/jam
 Ki.Zi
0.002105
0.118008
310.7414
0.000752
7.942566
318.8048

. & hal 13-25)

- 0.2437 ) +
1

- 0.0726 )
1
 -310.2641677 + 0.0095965

0.2437 ) +
0.2437

0.0726 )
0.0726

-0.476502218 + 0.1321363

0.2437 ) +
15186028552386

0.0726 )
05526849827645

-0.742701315 + 0.0236644
Bottom
kgmol
29.94
0
0
295.2508
0
325.1908
 C4H10 =97,5%
C5H12 =2,5%

C4H10 = 97,5%
Reaktor
C5H12 = 2,5% Heater

n-C4H10 =0,7203%
C5H12 =0,0185%
Udara O2 =23,30% CH3COOH =28,3153%
Heater
N2 =76,7% HCOOH =0,6726%
H2O =4,3250%
CO2 =0,2144%
CO =0,1365%
O2 =0,2015%
H2 =0,0195%
N2 =65,3664%
 O2 =0,3054%
N2 =99,0772%
CO =0,2068%
CO2 =0,3250%
H2 =0,0295%
n-C4H10 =0,0546%
C5H12 =0,0014%

Flash Drum
Kondensor

=0,7203% n-C4H10 =2,0111%

=0,0185% C5H12 =0,0516%
=28,3153% CH3COOH =83,2197%
=0,6726% HCOOH =1,9768%
=4,3250% H2O =12,7408%
=0,2144%
=0,1365%
=0,2015%
=0,0195%
=65,3664%
 #REF! =5,6545%
#REF! =10,6041%
#REF! =83,7514%

Destilasi I

CH3COOH =84,9725%
HCOOH =2,0184%
H2O =13,0091%
#REF! =99%
#REF! =0,5%
#REF! =0,5%
 Neraca Panas

Satuan = kkal / jam

Waktu Operasi = 1 jam
Suhu Referrence = 25 oC = 298.15 K

Persamaan panas untuk kondisi aliran steady ; Q = ∆H

∆H = n . Cp . ∆T = n . T
Cp dT (Himmelblau.1996)
∫
Tref

Dimana : ∆H = panas = kkal

n = berat bahan = kgmol
Cp = spesific heat = kkal/kgmol Kelvin
Treff = suhu refference = kelvin
T = suhu bahan = kelvin

Cp = A + B . T + C.T2 + D.T3 Appendix A(Sherwood.1964)

Dimana : Cp = Spesific heat ( kkal/kgmol.K )
A,B,C,D = Konstanta spesific heat
T = Suhu bahan (Kelvin)

Penyederhanaan Integrasi ∆H
Cp = A + B.T + C.T2 + D.T3 Appendix A(Sherwood.1964)
Cp = kkal/kgmol.kelvin

H = T
Cp dT = T
( A + BT + CT2 + DT3) dT
∫ ∫
T ref T ref

B ( T -Tref ) + C ( T -Tref ) + D ( T -Tref )

2 2 3 3 4 4
= A ( T-Tref ) +
2 3 4
= kkal x K = kkal / kgmol
Kgmol / K

Komponen A,B,C,D diperoleh dari Appendix A(Sherwood.1964)

Komponen A B C D
n-C4H10 2.266 3.96E-02 -8.82E-06 -1.62E-10
C5H12 -0.866 5.82E-02 -2.05E-05 3.17E-09
CH3COOH 1.156 3.04E-02 -1.40E-05 -2.95E-09
HCOOH 2.798 1.66E-02 -6.99E-06 1.20E-09
H2 O 7.701 4.60E-04 2.52E-06 -8.59E-10
CO2 4.728 1.734E-02 -1.34E-05 4.10E-09
CO 7.373 -3.07E-03 6.66E-06 -3.04E-09
O2 6.713 -8.79E-03 4.17E-06 -2.54E-09
H2 6.483 2.22E-03 -3.30E-06 1.83E-10
N2 7.44 -3.24E-03 6.40E-06 -2.79E-10
1. Heater Butana
Steam
200°C

30°C
HEATER 170°C

160°C Kondensat

T masuk = 30 o
C = 303.15 K
T reff = 25 o
C = 298.15 K

T Cp dT n-C4H10 = 2.266 (303.15-298.15) + 3.96E-02 (303,152-298,152)

∫
T ref 2
+ -8.82E-06 (303,15 -298,15 ) + -1.62E-10 (303,154-298,154)
3 3

3 4
= 66.7889 kkal/kgmol

T Cp dT C5H12 = -0.866 (303.15-298.15) + 5.82E-02 (303,152-298,152)

∫ T ref 2
+ -2.05E-05 (303,15 -298,15 ) + 3.17E-09 (303,154-298,154)
3 3

3 4
= 74.3062 kkal/kgmol

Komponen n(kgmol) CpdT (kkal/kgmol) ∆H = n.Cp.∆T(kkal)

n-C4H10 #REF! 66.7889 #REF!
C5H12 #REF! 74.3062 #REF!
Total #REF! #REF!

Panas keluar (∆H2)

T masuk = 170 o
C = 443.15 K
T reff = 25 o
C = 298.15 K
T Cp dT n-C4H10 = 2.266 (443.15-298.15) + 3.96E-02 (443,152-298,152)
∫
T ref 2
+ -8.82E-06 (443,15 -298,15 ) + -1.62E-10 (443,154-298,154)
3 3

3 4
= 2275.4547 kkal/kgmol

∫ T Cp dT C5H12 = -0.866 (443.15-298.15) + 5.82E-02 (443,152-298,152)

 T ref 2
+ -2.05E-05 (443,153-298,153) + 3.17E-09 (443,154-298,154)
3 4
= 2612.2421 kkal/kgmol
Komponen n(kgmol) CpdT (kkal/kgmol) ∆H=n.Cp.∆T (kkal)
n-C4H10 #REF! 2275.4547 #REF!
C5H12 #REF! 2612.2421 #REF!
Total #REF! #REF!

Neraca Panas Total : ∆H = ∆H keluar - ∆H masuk

= #REF! kkal/jam
Karena (+) maka reaksi terjadi endoterm yaitu memerlukan panas

Neraca Panas Total :

H masuk + Q steam = H keluar + Q loss
Q loss = 5% Q steam (losses maksimum = 10%) (Ulrich.1974)
Q steam = ( H keluar - H masuk ) / 95 % = #REF! kkal/jam
Q loss = #REF! kkal/jam

Kebutuhan steam :
Digunakan steam pada suhu 200 oC :
λ = 1938.6 KJ/Kg = 1938.6 : 4.184 = 463.33652 kkal/kg
(Smith .1974)
ed.5

Q steam = M steam x λ = M steam = #REF! kg

Neraca panas heater butana

Masuk Keluar
Komponen kkal/jam Komponen kkal/jam
DH1 ∆H2
∆H n-C4H10 = #REF! ∆H n-C4H10 = #REF!
∆H C5H12 = #REF! ∆H C5H12 = #REF!
Q steam = #REF! Q loss = #REF!

Jumlah = #REF! Jumlah = #REF!

2. Heater udara
Steam
200°C

30°C
HEATER 170°C

160°C Kondensat
 160°C Kondensat
Panas masuk (∆H1)
T masuk = 30 o
C = 303.15 K
T reff = 25 o
C = 298.15 K

T Cp dT O2 = 6.713 (303.15-298.15) + -8.79E-03 (303,152-298,152)

∫
T ref 2
+ 4.17E-06 (303,15 -298,15 ) + -2.54E-09 (303,154-298,154)
3 3

3 4
= 21.8910 kkal/kgmol

T Cp dT N2 = 7.44 (303.15-298.15) + -3.24E-03 (303,152-298,152)

∫
T ref 2
+ 6.40E-06 (303,15 -298,15 ) + -2.79E-10 (303,154-298,154)
3 3

3 4
= 35.1841 kkal/kgmol

Komponen n(kgmol) CpdT (kkal/kgmol) ∆H=n.Cp.∆T(kkal)

O2 #REF! 21.8910 #REF!
N2 #REF! 35.1841 #REF!
Total #REF! #REF!

Panas keluar (∆H2)

T masuk = 170 o
C = 443.15 K
T ref = 25 o
C = 298.15 K

T Cp dT O2 = 6.713 (443.15-298.15) + -8.79E-03 (443,152-298,152)

∫
T ref 2
+ 4.17E-06 (443,15 -298,15 ) + -2.54E-09 (443,154-298,154)
3 3

3 4
= 565.6286 kkal/kgmol

T Cp dT N2 = 7.44 (443.15-298.15) + -3.24E-03 (303,152-298,152)

∫
T ref 2
+ 6.40E-06 (443,15 -298,15 ) + -2.79E-10 (443,154-298,154)
3 3

3 4
= 1031.6457 kkal/kgmol

Komponen n(kgmol) CpdT (kkal/kgmol) ∆H=n.Cp.∆T(kkal)

O2 #REF! 565.6286 #REF!
N2 #REF! 1031.6457 #REF!
Total #REF! #REF!
∆H =∆H keluar - ∆H masuk
= #REF! kkal/jam
Karena (+) maka reaksi terjadi endoterm yaitu memerlukan panas

Neraca Panas Total :

H masuk + Q steam = H keluar + Q loss
Q loss = 5% Q steam (losses maksimum = 10%)
Q steam = ( H keluar - H masuk ) : 95 % = #REF! kkal/jam
Q loss = #REF! kkal/jam
Kebutuhan steam :
Digunakan steam pada suhu 200 oC
λ = 1938.6 KJ/Kg = 1938.6 : 4.184 = 463.33652 kkal/kg
(Smith .1974)
ed.5

Q steam = M steam x λ = M steam = #REF! kg

Neraca panas heater udara

Masuk Keluar
Komponen kkal/jam Komponen kkal/jam
DH1 ∆H2
DH O2 = #REF! ∆H O2 = #REF!
DH N2 = #REF! ∆H N2 = #REF!
Q steam = #REF! Q loss = #REF!
Jumlah = #REF! Jumlah = #REF!

3. Reaktor
H3∆

HS∆

Hloss∆ HR
HC∆

H1∆

DH2

Massa masuk
Dari heater : Acetone = #REF! kgmol/jam
IPA = #REF! kgmol/jam
Dari udara : O2 = #REF! kgmol/jam
N2 = #REF! kgmol/jam

Panas Masuk
Dari tangki butana : ∆H1 = #REF! kkal/jam
Dari udara : ∆H2 = #REF! kkal/jam

Diagram Fase
Reaktan 170 oC _______ Produk 170 oC
n-C4H10 ∆H CH3COOH H2
C5H12 ∆HR ∆Hp HCOOH H2O
O2 CO
∆H298 CO2

Panas Pembentukan reaksi 1 :

a. 1/2 n-C4H10 + 5/4 O2 CH3COOH + 1/2 H2O

∆Hf CH3COOH = -104.72 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam

∆Hf H2O = -57.7979 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam
∆Hf n-C4H10 = -29.812 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam
∆Hf O2 = 0 kkal/jam

∆Hf298 = ∆Hf CH3COOH + ∆Hf H2O - ∆Hf n-C4H10

= #REF! kkal/jam

Reaksi terjadi pada suhu 170 oC = 443.15 K

T reff = 25 oC = 298.15 K

n-C4H10 bereaksi = #REF! kgmol/jam Panas Laten

O2 bereaksi = #REF! kgmol/jam n-C4H10 = 78 kkal/kmol

Panas yang di hasilkan

T Cp dT n-C4H10 = 2.266 (443.15-298.15) +
3.96E-02 (443,152-298,152)
∫
T ref 2
+ -8.82E-06 (443,15 -298,15 ) + -1.62E-10 (443,154-298,154)
3 3

3 4
= 2275.4547 kkal/kgmol

T Cp dT O2 = 6.713 (443.15-298.15) +
-8.79E-03 (443,152-298,152)
∫
T ref 2
+ 4.17E-06 (443,15 -298,15 ) + -2.54E-09 (443,154-298,154)
3 3

3 4
= 565.6286 kkal/kgmol
Komponen n(kgmol) CpdT (kkal/kgmol) n.λ (kkal) ∆H=n.Cp.∆T+n.λ(kkal)
n-C4H10 #REF! 2275.4547 #REF! #REF!
O2 #REF! 565.6286 #REF!
Total #REF! #REF!

Panas yang dihasilkan pada suhu 170 oC = 443.15 K

T ref = 25 oC = 298.15 K

CH3COOH terbentuk = #REF! kgmol/jam

H2O terbentuk = #REF! kgmol/jam

Panas yang dihasilkan

T Cp dT CH3COOH = 1.156 (443.15-298.15) + 3.04E-02 (443,152-298,152)
∫
T ref 2
+ -1.40E-05 (443,15 -298,15 ) + -2.95E-09 (443,154-298,14)
3 3

3 4
= 1497.1966 kkal/kgmol

T Cp dT H2O = 7.701 (443.15-298.15) + 4.60E-04 (443,152-298,152)

∫
T ref 2
+ 2.52E-06 (443,15 -298,15 ) + -8.59E-10 (443,154-298,14)
3 3

3 4
= 1185.6150 kkal/kgmol

Komponen n(kgmol) CpdT (kkal/kgmol) ∆H=n.Cp.∆T (kkal)

CH3COOH #REF! 1497.1966 #REF!
H2 O #REF! 1185.6150 #REF!
Total #REF! #REF!

∆H = ∆Hf298 + ∆H produk - ∆H reaktan

= #REF! kkal/jam

Panas Pembentukan reaksi 2

b. C5H12 + 5O2 3HCOOH + CO + CO2 + 2H2 + H2O

∆Hf HCOOH = -86.67 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam

∆Hf CO = -26.416 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam
∆Hf CO2 = -99.052 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam
∆Hf H2 = 0 kkal/jam
∆Hf H2O = -57.7979 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam
∆Hf C5H12 = -35 kkal/mol x #REF! kgmol/jam = #REF! kkal/jam
∆Hf O2 = 0 kkal/jam

∆H 298 = ∆Hf HCOOH + ∆Hf CO + ∆Hf CO2 + ∆Hf H2 + ∆Hf H2O - ∆Hf C5H12
= #REF! kkal/jam

Reaksi terjadi pada suhu 170 oC = 443.15 K

T ref = 25 oC = 298.15 K

C5H12 bereaksi = #REF! kgmol/jam Panas Laten

O2 bereaksi = #REF! kgmol/jam C5H12 = 66.2 kkal/kmol

Panas yang bereaksi

T Cp dT C5H12 = -0.866 (443.15-298.15) + 5.82E-02 (443,152-298,152)
∫
T ref 2
+ -2.05E-05 (443,15 -298,15 ) + 3.17E-09 (443,154-298,154)
3 3

3 4
= 2612.2421 kkal/kgmol

T Cp dT O2 = 6.713 (443.15-298.15) + -8.79E-03 (443,152-298,152)

∫
T ref 2
+ 4.17E-06 (443,15 -298,15 ) + 4.90E+01 (443,154-298,154)
3 3

3 4
= 565.6286 kkal/kgmol

Komponen n(kgmol) CpdT (kkal/kgmol) n.λ (kkal) ∆H=n.Cp.∆T+n.λ(kkal)

C5H12 #REF! 2612.2421 #REF! #REF!
O2 #REF! 565.6286 #REF!
Total #REF! #REF!

Panas pembentukan pada suhu 170 oC = 443.15 K

T ref = 25 oC = 298.15
= K

HCOOH terbentuk = #REF! kgmol/jam

CO terbentuk = #REF! kgmol/jam
CO2 terbentuk = #REF! kgmol/jam
H2 terbentuk = #REF! kgmol/jam
H2O terbentuk = #REF! kgmol/jam

Panas yang dihasilkan

T Cp dT HCOOH = 2.798 (443.15-298.15) + 1.66E-02 (443,152-298,152)
∫
T ref 2
 + -6.99E-06 (443,153-298,153) + 1.20E-09 (443,154-298,154)
3 4
= 1166.0756 kkal/kgmol

T Cp dT CO = 7.373 (443.15-298.15) + -3.07E-03 (443,152-298,152)

∫
T ref 2
+ 6.66E-06 (443,15 -298,15 ) + -3.04E-09 (443,154-298,154)
3 3

3 4
= 1015.2102 kkal/kgmol

T Cp dT CO2 = 4.728 (443.15-298.15)1.73E-02 (443,152-298,152)

+
∫
T ref 2
+ -1.34E-05 (443,15 -298,15 ) + 4.10E-09 (443,154-298,154)
3 3

3 4
= 1378.95979686 kkal/kgmol

T Cp dT H2 = 6.483 (443.15-298.15) + 2.22E-03 (443,152-298,152)

∫
T ref 2
+ -3.30E-06 (443,15 -298,15 ) + 1.83E-10 (443,154-298,154)
3 3

3 4
= 993.9060 kkal/kgmol

T Cp dT H2O = 7.701 (443.15-298.15) + 4.60E-04 (443,152-298,152)

∫ T ref 2
+ 2.52E-06 (443,15 -298,15 ) + -8.59E-10 (443,154-298,154)
3 3

3 4
= 1185.6150 kkal/kgmol

Komponen n(kgmol) CpdT (kkal/kgmol) ∆H=n.Cp.∆T (kkal)

HCOOH #REF! 1166.0756 #REF!
CO #REF! 1015.2102 #REF!
CO2 #REF! 1378.9598 #REF!
H2 #REF! 993.9060 #REF!
H2 O #REF! 1185.6150 #REF!
Total #REF! #REF!

∆H = ∆Hf298 + ∆H produk - ∆H reaktan

= #REF! kkal/jam

å∆H = ∆H reaksi 1 + ∆H reaksi 2

= #REF! + #REF!
 = #REF! kkal/jam

Panas keluar
T masuk = 170 o
C= 443.15 K
T ref = 25 o
C= 298.15 K

Komponen n(kgmol) CpdT (kkal/kgmol) ∆H=n.Cp.∆T (kkal)

n-C4H10 #REF! 2275.4547 #REF!
C5H12 #REF! 2612.2421 #REF!
CH3COOH #REF! 1497.1966 #REF!
HCOOH #REF! 1166.0756 #REF!
CO #REF! 1015.2102 #REF!
CO2 #REF! 1378.9598 #REF!
H2 #REF! 993.9060 #REF!
H2 O #REF! 1185.6150 #REF!
O2 #REF! 565.6286 #REF!
N2 #REF! 1031.6457 #REF!
Total #REF! #REF!
∆H = ∆H keluar - ∆H masuk + å∆H
= #REF! kkal/jam
Karena (+) maka reaksi terjadi endoterm yaitu memerlukan panas

Neraca Panas Total :

H masuk + Q steam = H keluar + H reaksi + Q loss
Q loss = 5% Q steam (losses maksimum = 10%)
Q steam = ( H keluar - H masuk + H reaksi ) : 95 % = #REF! kkal/jam
Q loss = #REF! kkal/jam

Kebutuhan steam :
Digunakan steam pada suhu 200 oC
λ = 1938.6 KJ/Kg = 1938.6 : 4.184 = 463.33652 kkal/kg
(Smith .1974)
ed.5

Q steam = M steam x λ = M steam = #REF! kg

Neraca panas reaktor

 Masuk Keluar
Komponen kkal/jam Komponen kkal/jam
Dari tagki butana ∆H keluar
∆H1 = #REF! ∆H n-C4H10 = #REF!
Dari udara ∆H C5H12 = #REF!
∆H2 = #REF! ∆HCH3COOH = #REF!
Q steam = #REF! ∆H HCOOH = #REF!
∆H CO = #REF!
∆H CO2 = #REF!
∆H H2 = #REF!
∆H H2O = #REF!
∆H O2 = #REF!
∆H N2 = #REF!
∆Hreaksi = #REF!
Q loss = #REF!

Jumlah = #REF! Jumlah = #REF!

rwood.1964)

rwood.1964)
303,154-298,154)

303,154-298,154)

443,154-298,154)
443,154-298,154)
 kkal/jam
kkal/jam
kkal/jam

,152-298,152)

443,154-298,154)

,152-298,152)

443,154-298,154)
443,152-298,152)

(443,154-298,14)

443,152-298,152)

(443,154-298,14)
kkal/kmol
 APPENDIKS B
PERHITUNGAN NERACA PANAS

Kapasitas produksi : 25000 kg/jam

Waktu operasi : 330 hari/tahun
: 24 jam/hari
Satuan panas : kJ/jam
Suhu referance : 25 o
C = 298 K

Komponen BM Titik Didih (oC)

IPA ### 82.5
H2O ### 100
Aceton ### 56.5
H2 2.0158 -252.7
( Perry, ed. 7)

Cp = A + B.T + C.T2 + D.T3

∫ Cp dT = A.T + 1/2.B.T2 + 1/3.C.T3 + 1/4.D.T4

Heat Capacity Coefficient of Liquid(J/Kmol K)

Komponen A B C D E
IPA 723550 -8095 36.662 -0.066395 4.4064E-05
H2O 276370 -2090.1 8.125 -0.014116 9.3701E-06
Acetone 135600 -177 0.2837 0.000689 0
H2 66.653 6765.9 -123.63 478.27 0
(Perry Edisi 7, Chapter 2 Table 2-196)

Heat Capacity Coefficient of Gases (kkal/kmol.K)

Komponen A B C D
IPA 7.745 0.045 0.0000152 -2.2120E-08
H2 O 7.701 0.00046 0.0000025 -8.3900E-09
Aceton 1.505 0.06224 ### 4.8670E-09
H2 6.483 0.00222 ### 1.8240E-09
(Sherwood, hal 631)

Enthalpi Vaporation (kJ/kmol)

Komponen ΔHvap (kJ/kmol)
IPA 40
H2 O 41
Aceton 29
 H2 1
(Lange's Handbook Tabel 6-2,6-4)
Enthalpi Pembentukan (kJ/kmol)
KomponenΔoHf (kJ/kmol)
IPA (l) -318.1
IPA (g) -272.6
H2O (l) -285.83
H2O (g) -241.826
Aceton (l) -248.4
Aceton (g) -217.1 (Lange's Handbook Tabel 6-1 ,6-3)
H2 0
B.1 VAPORIZER B.2 HEATER
1. Feed Masuk (g
1. Feed Masuk Feed Masuk dari v
T
Feed Isopropyl Alcohol (liquid) Tref
T = 30 °C = 303.15 K
Tref = 25 °C = 298.15 K Perhitungan Pana
Komponen
KomponenMassa (kg/jam)Mol (kmol/jam) ∫CpdT (J/kmol) ∆H (kJ/Jam) IPA
IPA 998.0000 16.6333 3518079.7367 58517.3930 H2O
H2O 2.0000 0.1111 1356060.0919 150.6733 Aceton
Total 1000.0000 16.7444 4874139.8286 58668.0663 Total

∆H1 = ∆H IPA + ∆H H2O ∆H1

= 58517.3930 + 150.6733
= 58668.0663 kJ/Jam
Feed Masuk dari R
T
Feed liquid dari Recycle (Distilasi 2) Tref
T = 100 °C = 373.15 K
Tref = 25 °C = 298.15 K Perhitungan Pana
Komponen
KomponenMassa (kg/jam)Mol (kmol/jam) ∫ Cp dT (J/kmol) ∆H (kJ/Jam) IPA
IPA 0.0000 36150374.6133 0.0000 H2
H2O 0.0000 21763115.4967 0.0000 Aceton
Aceton 0.0000 2348277.5189 0.0000 H
Total 0.0000 60261767.6289 0.0000 Total

∆H2 = ∆H IPA + ∆H H2O + ∆H Aceton ∆H2 =

= 0.0000 + 0.0000 + 0.0000 =
= 0.0000 kJ/Jam =

∆H masuk total = ∆H1 + ∆H2

= 58668.0663 + 0.0000
= 58668.0663 kJ/Jam

2. Feed Keluar

Feed (gas) keluar menuju Heater 1

T = 123 °C = 395.65 K
Tref = 25 °C = 298.15 K
KomponenMassa (kg/jam)Mol (kmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam)
IPA 998.0000 16.6067 973.2245 67622.1461
H2O 2.0000 0.1110 753.6209 350.0544
Aceton 0.0000 0.0000 433.4443 0.0000
Total 1000.0000 16.7178 2160.2896 67972.2005

∆H1 = ∆H IPA + ∆H H2O + ∆H Aceton

= 67622.1461 + 350.0544 + 0.0000
= 67972.2005 kJ/Jam

Enthalpy Penguapan
KomponenMassa (kg/jam)Mol (kmol/jam) Hvap (kJ/kmol) ∆H (kJ/Jam)
IPA 998.0000 16.6067 39.9000 662.6087
H2O 2.0000 0.1110 40.6600 4.5140
Aceton 0.0000 29.1000 0.0000
Total 1000.0000 16.7178 109.6600 667.1227

∆H2 = ∆H IPA + ∆H H2O + ∆H Aceton

= 662.6087 + 4.5140 + 0.0000
= 667.1227 kJ/Jam

∆H keluar total = ∆H1 + ∆H2

= 67972.2005 + 667.1227
= 68639.3231 kJ/Jam

Q masuk = Q keluar
58,668.0663 + Qsupply = 68,639.3231 + Qloss
Asumsi Qloss = 5% Qsupply (Ulrich hal 432)
Qsupply = 10496.0598366 kJ/jam
Qloss = 524.8029918317 kJ/jam

Kebutuhan Steam
Dipakai steam dengan tekanan 4.5 bar (Ulrich 429)
Maka suhu yang diperlukan = 148 o
C = 421.15 K (Ulrich 426)
= 298.4 o
F
λ Steam = 911.58 BTU/lb
= 2120.1872 kJ/kg
Qsteam = Msteam x λ Steam
Qsteam
Msteam =
λ Steam
= 0 0
2120.1872 kJ/kg
= 0 kg

Neraca Panas Vaporizer

Neraca Masuk (kJ/jam) Neraca Keluar (kJ/jam)
Fresh Feed Menuju Heater
IPA 58517.3930 IPA 67622.1461
H2 O 150.6733 H2O 350.0544
58668.0663 Aceton 0.0000
Recycle dari Distilasi 2 67972.2005
IPA 0.0000 Enthalpi Penguapan
H2 O 0.0000 IPA 662.6087
Aceton 0.0000 H2O 4.5140
0.0000 Aceton 0.0000
667.1227
Qsupply 10496.059836634 Qloss 524.8029918317
Total 69164.1261 Total 69164.1261
B.2 HEATER
1. Feed Masuk (gas)
Feed Masuk dari vaporizer
= 298 °C = 571 K
= 25 °C = 298 K

Perhitungan Panas
KomponenMassa (kg/jam)Mol (kmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam)
IPA 67622.1461 1125.2335 3866.7667 18204648.8144
H2O 350.0544 19.4311 2126.1196 172852.5517
Aceton 0.0000 0.0000 2536.6356 0.0000
Total 67972.2005 1144.6646 8529.5220 18377501.3661

= ∆H IPA + ∆H H2O + ∆H Aceton

= 18204648.8144 + 172852.5517 + 0.0000
= 18377501.3661 kJ/Jam
Feed Masuk dari Reaktor
= 327 °C = 600 K
= 25 °C = 298 K

Perhitungan Panas
KomponenMassa (kg/jam)Mol (kmol/jam)∫CpdT (kkal/kmol) ∆H (kJ/Jam)
IPA 0.0000 #DIV/0! 0.0000 #DIV/0!
H2O 0.0000 #DIV/0! 0.0000 #DIV/0!
Aceton 0.0000 #DIV/0! 0.0000 #DIV/0!
H2 109.5641 54.3527 0.0000 0.0000
Total 109.5641 #DIV/0! 0.0000 #DIV/0!

∆H IPA + ∆H H2O + ∆H Aceton + ∆H H2

#DIV/0! + #DIV/0! + #DIV/0! + 0.0000
#DIV/0! kJ/Jam