SURVEY OF

SPECTRA (1100)
WAVELENGTH (mm)
2.5 4 5 5.5 6.1 6.5 15.4

O-H C-H C N C=O C=N C-Cl

Very C-O
N-H C C few C=C
C-N
bands
X=C=Y C-C
(C,O,N,S) N=O N=O *

4000 2500 2000 1800 1650 1550 650

FREQUENCY (cm-1)
IR

O-H 3600
N-H 3400
C-H 3000

C=N
= 2250
C=C
= 2150

ALKOHOL C=O 1715

C=C 1650
ETER
(C-O STRETCHING) C-O 1100
IR C-O STRETCHING

WAVELENGTH (mm) C-O

2.5 4 5 5.5 6.1 6.5 15.4

O-H C-H C N C=O C=N C-Cl

Very C-O
N-H C C few C=C
C-N
X=C=Y bands C-C
(C,O,N,S) N=O N=O *

4000 2500 2000 1800 1650 1550 650

FREQUENCY (cm-1)
IR C-O STRETCHING

•Pita serapan C-O muncul pada daerah 1300 -

1000 cm-1

•Carilah satu atau lebih pita serapan yang kuat

yang muncul pada daerah ini!

•Eter, alkohol, ester, asam karboksilat memiliki

pita serapan C-O
IR Dibutil Eter (eter) ETHER

BASE = 1100

CH2 CH3
C-H bending
C-O

CH3 CH2 CH2 CH2 O CH2 CH2 CH2 CH3

IR Anisol (aromatik eter)
BASE = 1100

C-H
aromatic

O CH3

oops
benzene
C-O
IR Sikloheksanol (alkohol)
BASE = 3600
BASE = 1100

CH2
bend

OH OH

C-O

C-H
IR Asam-2-metilpropanoat
CARBOXYLIC ACID

OH

C-O C
CH C=O CH3 CH OH

CH3
IR Etil Butanoat (ester) ESTER

CH
O
C-O
C=O CH3 CH2 CH2
C
O CH2 CH3
IR N=O STRETCHING

WAVELENGTH (mm)
N-O
2.5 4 5 5.5 6.1 6.5 15.4

O-H C-H C N C=O C=N C-Cl

Very C-O
N-H C C few C=C
C-N
X=C=Y bands C-C
(C,O,N,S) N=O N=O *

4000 2500 2000 1800 1650 1550 650

FREQUENCY (cm-1)
IR N=O STRETCHING

◼ Streching N=O -- 1550 dan 1350 cm-1 (streching

asimetrik dan simetrik)

◼ Seringkali puncak 1550 cm-1 lebih kuat

dibandingkan yang lainnya
IR 2-Nitropropan

C-H

N=O

NO2
gem-dimethyl
CH
CH3 CH3 N=O