DATA PRAKTIKUM

Konsentrasi Etanol 90 %
Volume Etanol 300 ml
Massa pikno kosong 11.873 gram
Volume pikno 10 ml

Percobaan Massa Pikno Isi Distilat Massa Pikno Isi Bottom Tw (°C)
1 19.8413 21.392 77
2 19.8221 21.421 76
3 19.7913 21.465 77
4 19.7615 21.523 76

1a. Pembuatan Etanol

%_1 𝑥 𝑉_1=%_2 𝑥
𝑉_2
V2 300 ml
Persen 2 90
Persen 1 96
V1 281.25 ml

1b. Kebutuhan Entrainer

Kelarutan NaCl 36 gram/100 ml

Sisa Kadar Etanol 30 ml
Kebutuhan 10.8 gram

2. Perhitungan Densitas
Percobaan Massa Pikno Isi Distilat (gr) Massa Pikno Isi Bottom (gr) ρ distilat (gr/ml)
1 19.8413 21.392 0.79683
2 19.8221 21.421 0.79491
3 19.7913 21.465 0.79183
4 19.7615 21.523 0.78885

3. Suhu Rata-Rata
Percobaan Tw (°C) Td (°C)
1 77 63
2 76 63
3 77 63
4 76 63
Rata-rata 76.5 63
Rata-rata (K) 349.65 336.15

4. Tekanan parsial ethanol air

Untuk tekanan parsial air pada tabel 2-5 Untuk tekanan parsial etanol pada tabel 2-8
 C1 C2 C3 C4
73.304 -7112.3 -7.1424 2.8853E-06

a. Distilat
P air 0.022885 Mpa 0.22585732855
P Etanol 55303.5945278735 Pa 0.5458040417259

a. Bottom
x x1 x2 y1
76.5 76 77 0.040239

P air 0.04109 Mpa 0.4055266607

P Etanol 97050.6780085828 Pa 0.9578157217723
5. Perhitungan Konsentrasi
Percobaan ρ distilat (gr/ml) ρ bottom (gr/ml) % distilat
1 0.79683 0.9519 94.542857142857
2 0.79491 0.9548 95.225352112676
3 0.79183 0.9592 96.303448275862
4 0.78885 0.965 97.323232323232
Rata-rata 0.793105 0.957725 95.848722463657

ρ distilat (x) % distilat (y) ρ bottom (x)

0.79835 94 0.96547
0.79555 95 0.96395
0.79271 96 0.96242
0.78981 97 0.96087
0.78684 98 0.95929
0.95769
0.95607
0.95442
0.95272
0.95098
6. Perhitungan Relative Volatility

α distilat 2.41658769821603
α bottom 2.36190567623596
α 2.38909024558271

7. Kurva Kesetimbangan Percobaan

Kurva Kesetimbangan Ethano

1.2

1
 Kurva Kesetimbangan Ethano
Xd Yd 1.2
0 0
1
0.1 0.209770068905137
0.2 0.373932775051108 0.8
0.3 0.50590342133839
0.6

Yd
0.4 0.614305684548276
0.5 0.704935564550579 0.4
0.6 0.781832558737165
0.2
0.7 0.847898194271288
0.8 0.905270386104284 0
0 0.2 0.4 0.6
0.9 0.955559134941819
Xd
1 1

7. Kurva Kesetimbangan Literatur

X Y
0 0
Kurva Kesetimbangan Ethanol A
0.0035 0.0205
1.2
0.0045 0.0275
0.0175 0.1315 1
0.0585 0.305
0.8
0.068 0.3615
0.0935 0.411 0.6
Yd

0.165 0.52
0.4
0.2125 0.5455
0.241 0.5675 0.2
0.3615 0.606
0
0.474 0.6505 0 0.2 0.4 0.6
0.4985 0.6555 Xd
0.5815 0.697
0.646 0.729
0.654 0.731
0.723 0.776
0.79 0.82
0.837 0.852
0.8731 0.8817
0.883 0.8885
0.888 0.893
0.8973 0.9012
0.9489 0.9502
0.9707 0.9715
0.9825 0.9835
1 1
 TD (°C)
63
63
63
63

ρ bottom (gr/ml)
0.9519
0.9548
0.9592
0.965
 C5
2

atm
atm

y2
0.041941

atm
atm

% bottom
27.4712643678161
25.769696969697
23.05625
19.3092105263158
23.9016054659572

% bottom (y)
19
20
21
22
23
24
25
26
27
28

Kesetimbangan Ethanol Air Percobaan

Kesetimbangan Ethanol Air Percobaan

0.4 0.6 0.8 1 1.2

Xd

esetimbangan Ethanol Air Literatur

0.4 0.6 0.8 1 1.2

Xd