SDS - Rakhmad Rofiansyah B A - S1 Teknik Kimia Paralel - Dr. Rer. Nat. Ir. Yuswan Muharam, M.T.

No: F/QCL/008 Rev.
01
LEMBAR DATA KESELAMATAN BAHAN
Menurut peraturan ( UE ) no.1907/2006
AQUADEST
Revisi : 02 Revisi tanggal : 03.11.2021 No. MSDS : 031
Bagian 1 – Identitas Bahan dan Perusahaan
1.1 Mengidentifikasi Produk

Nama Produk : AQUADEST
Sinonim : Dihidrogen Oksida, Deionized water, Aqua, Aquadestilata
No. CAS : 7732-18-5
Kode HS : 2853 90 10
Kode Produk : A-1078
Merek : SMART-LAB
1.2 Penggunaan yang relevan dari bahan atau campuran dan penggunaan yang disarankan terhadap
Penggunaan yang teridentifikasi : Reagen untuk analisis, Produksi bahan kimia
1.3 Rincian penyuplai lembar data keselamatan
Perusahaan : PT.Smart-Lab Indonesia
Alamat : Ruko Boulevard TamanTeknoBlokE No.10 -11BSD Sektor XI Serpong,
Tangerang – Indonesia
Website : www.smartlab.co.id
Email : sales@smartlab.co.id
Untuk Informasi : Telp: +62-21- 7588 0205(Hunting) , fax:+62-21-7588 0198
Telpon Darurat : +62-21-7588 0205(Hunting)
Bagian 2 – Identifikasi Bahaya
2.1 Klasifikasi bahan atau campuran

Bahan ini tidak diklasifikasikan sebagai berbahaya menurut undang-undang Uni Eropa.
2.2 Elemen label

Pelabelan menurut Peraturan (EC) No 1272/2008
Bukan bahan atau campuran berbahaya menurut Peraturan (EC) No 1272/2008.
2.3 Bahaya lain

Bahaya lain yang tidak dihasilkan
dalam klasifikasi GHS: Tidak ada yang diketahui.
Bagian 3 – Komposisi dan Informasi Bahan
3.1 Bahan
Sinonim : Dihidrogen Oksida, Deionized water, Aqua, Aquadestilata
Rumus Kimia : H2O
Berat Molekul : 18.02 g/mol
No. CAS : 7732-18-5
No. EC : 231-791-2
Komentar
Tidak ada bahan berbahaya menurut Peraturan (EC) No. 1907/2006
3.2 Campuran
Tidak berlaku
Bagian 4 – Tindakan Pertolongan Pertama Pada Kecelakaan (P3K)
4.1 Penjelasan mengenai tindakan pertolongan pertama

Saran umum
PT.SMART-LAB INDONESIA LEMBAR DATA KESELAMATAN BAHAN – AQUADEST Page 1

No: F/QCL/008 Rev.01
AQUADEST
Tidak ada bahaya yang memerlukan tindakan pertolongan pertama yang khusus.
4.2 Kumpulan gejala/efek terpenting, baik akut maupun tertunda

Gejala yang berhubungan
dengan penggunaan Kami tidak memiliki penjelasan berbagai gejala toksik.
4.3 Indikasi pertolongan medis pertama dan perawatan khusus yang diperlukan
Tidak tersedia informasi
Bagian 5 – Tindakan Penanggulangan Kebakaran
5.1 Media pemadaman api

Media pemadaman yang sesuai Gunakan tindakan pemadaman kebakaran yang sesuai untuk situasi
lokal dan lingkungan sekeliling.
Media pemadaman yang tidak sesuai Untuk bahan/campuran ini, tidak ada batasan agen pemadaman
yang diberikan.
5.2 Bahaya khusus yang muncul dari bahan atau campuran

Tidak mudah terbakar.
5.3 Saran bagi petugas pemadam kebakaran

Alat pelindung khusus bagi petugas pemadam kebakaran
Tidak ada
5.4 Informasi lebih lanjut

tidak ada
Bagian 6 – Tindakan terhadap tumpahan dan kebocoran
6.1 Langkah-langkah pencegahan diri,alat pelindung dan prosedur tanggap darurat

Tidak ada
6.2 Tindakan pencegahan Lingkungan

Tidak ada tindakan pencegahan khusus diperlukan.
6.3 Metode dan bahan untuk penyimpanan dan pembersihan

Amati kemungkinan pembatasan bahan (lihat bagian 7 dan 10).
Tuangkan kedalam pipa saluran.
6.4 Rujukan ke bagian lainnya

Indikasi mengenai pengolahan limbah , lihat bagian 13.
Bagian 7 – Penyimpanan dan Penanganan Bahan
7.1 Kehati-hatian dalam menangani secara aman

Langkah-langkah pencegahan untuk penanganan yang aman
Taati label tindakan pencegahan.
Tindakan higienis
Tidak diperlukan

AQUADEST
7.2 Kondisi penyimpanan yang aman,termasuk adanya inkompatibilitas

Kondisi penyimpanan
Tertutup sangat rapat.
Suhu penyimpanan yang direkomendasikan, Simpan pada +5°C hingga +30°C
7.3 Penggunaan akhir khusus

Selain penggunaan yang disebutkan dalam bagian 1.2, tidak ada penggunaan spesifik lain yang diantisipasi
Bagian 8 – Pengendalian Pemaparan dan Perlindungan diri
8.1 Parameter Pengendalian

Tidak mengandung bahan-bahan yang mempunyai nilai batas eksposur pekerjaan.
8.2 Pengendalian Pemaparan

Pengendalian teknik/tindakan rekayasa yang sesuai untuk mengurangi paparan
Langkah-langkah teknis dan operasi kerja yang sesuai harus diberikan prioritas dalam penggunaan alat
pelindung diri.
Lihat bagian 7.1.
Tindakan perlindungan individual

Pakaian pelindung harus dipilih secara spesifik untuk tempat bekerja, tergantung konsentrasi dan jumlah
bahan berbahaya yang ditangani. Daya tahan pakaian pelindung kimia harus dipastikan dari masing-masing
suplier
Perlindungan mata/wajah
Tidak diperlukan
Perlindungan kulit / Tangan

Tidak diperlukan
Perlindungan tubuh
Tidak diperlukan
perlindungan pernapasan
Tidak diperlukan
Kontrol eksposur lingkungan

Tidak ada tindakan pencegahan khusus diperlukan.
Bagian 9 – Sifat-sifat Fisika dan Kimia
9.1 Informasi tentang sifat fisika dan kimia
Bentuk cair
Warna tidak berwarna
Bau Tak berbau
Ambang Bau Tidak berlaku
pH pada 20 °C
netral
Titik lebur 0 °C
Titik didih/rentang didih 100 °C
pada 1.013 hPa

AQUADEST
Titik nyala Tidak berlaku

Laju penguapan Tidak tersedia informasi.
Flamabilitas (padatan, gas) Tidak tersedia informasi.
Terendah batas ledakan Tidak berlaku
Tertinggi batas ledakan Tidak berlaku
Tekanan uap 23 hPa
pada 20 °C
Kerapatan (densitas) uap relatif Tidak tersedia informasi.
Densitas 1,00 g/cm3
pada 20 °C
Kerapatan (den-sitas) relatif Tidak tersedia informasi.
Kelarutan dalam air larut sepenuhnya
Koefisien partisi (n-oktanol/air) Tidak berlaku
Suhu dapat membakar sendiri Tidak berlaku
(auto-ignition temperature)
Suhu penguraian Dapat didistilasi dalam kondisi tidak terurai (undecomposed)
pada tekanan normal.
Viskositas, dinamis 0,952 mPa.s
pada 20 °C
Sifat peledak Tidak diklasifikasikan sebagai mudah meledak.
Sifat oksidator tidak ada
9.2 Data lain

Suhu menyala Tidak berlaku
Energi penyalaan api minimum Tidak berlaku
Bagian 10 – Reaktifitas dan Stabilitas
10.1 Reaktifitas
Lihat bagian 10.3.
10.2 Stabilitas Kimia

Produk ini stabil secara kimiawi di bawah kondisi ruangan standar (suhu kamar).
10.3 Reaksi berbahaya yang mungkin di bawah kondisi spesifik/khusus

Reaksi yang hebat dapat terjadi dengan :
Umumnya diketahui pasangan reaksi terhadap air.
10.4 Kondisi yang harus dihindari

Tidak ada
10.5 Bahan yang harus dihindari

Tidak ada informasi yang tersedia
10.6 Produk berbahaya hasil penguraian

Tidak ada
Bagian 11 – Informasi Toksikologi
11.1 Informasi tentang efek toksikologis

Toksisitas oral akut
Informasi ini tidak tersedia.

AQUADEST
Toksisitas inhalasi akut

Toksisitas kulit akut

Iritasi kulit
Iritasi mata
Sensitisasi
Mutagenisitas pada sel nutfah

Karsinogenisitas
Toksisitas terhadap Reproduksi

Teratogenisitas
Toksisitas pada organ sasaran spesifik - paparan tunggal

Toksisitas pada organ sasaran spesifik - paparan berulang

Bahaya aspirasi
11.2 Informasi lebih lanjut

Diharapkan tidak terdapat efek toksik jika produk ditangani dengan tepat.
Bagian 12 – Informasi Ekologi
12.1 Toksisitas
12.2 Persistensi dan penguraian oleh lingkungan

Tidak tersedia infomasi
12.3 Potensi bioakumulasi

Koefisien partisi (n-oktanol/air)
Tidak berlaku
12.4 Mobilitas dalam tanah


AQUADEST
12.5 Hasil dar asesmen PBT dan vPvB

Penilaian PBT/vPvB tidak dilakukan karena penilaian keamanan bahan kimia tidak diperlukan/tidak
dilakukan.
12.6 Efek merugikan lainnya

Informasi ekologis tambahan
Diharapkan tidak ada masalah ekologi jika produk ditangani dan digunakan dengan hati-hati dan penuh
perhatian.
Bagian 13 – Pembuangan Limbah
Metode penanganan limbah

Limbah harus dibuang sesuai dengan Petunjuk mengenai limbah 2008/98/EC s erta peraturan
nasional dan lokal lainnya. Tinggalkan bahan kimia dalam wadah aslinya. Jangan dicampurkan
dengan limbah lain. Tangani wadah koto r seperti produknya sendiri..
Bagian 14 – Informasi Pengangkutan
14.1 Nomor PBB

ADR/RID: - IMDG: - IATA: -
14.2 Nama pengapalan yang sesuai berdasarkan PBB
ADR/RID: Bukan bahan berbahaya
IMDG: Bukan bahan berbahaya
IATA: Bukan bahan berbahaya
14.3 Kelas bahaya transportasi
14.4 Kelompok pengemasan
14.5 Bahaya lingkungan
ADR/RID: no IMDG Bahan pencemar laut: no IATA: no
14.6 Tindakan kehati-hatian khusus bagi pengguna
No data available
Bagian 15 – Peraturan Perundang - undangan
15.1 Regulasi tentang lingkungan , kesehatan dan keamanan untuk produk tersebut
Perundang-undangan nasional
Kelas penyimpanan 10 - 13
15.2 Asesmen Keselamatan Kimia

Untuk produk ini, penilaian keselamatan kimia sesuai dengan peraturan EU REACH No 1907/2006 tidak
dilakukan.
Bagian 16 – Informasi Lain

AQUADEST
Nasehat pelatihan
Menyediakan informasi, instruksi dan pelatihan yang memadai bagi operator.
National Fire Protection Association (U.S.A.):

Kesehatan: 0
Mudah terbakar: 0
Reaktivitas: 0
Bahaya spesifik: -
Riwayat Revisi :
Tanggal Rev Keterangan

16 may 17 01 -
3 Nov 21 02 Revisi menyeluruh
Informasi lebih lanjut

Informasi di atas diyakini benar tetapi tidak dimaksudkan untuk menjadi semua inklusif dan harus
hanya digunakan sebagai panduan. Informasi dalam dokumen ini didasarkan pada pengetahuan terkini
kami dan berlaku untuk produk yang berkaitan dengan tindakan pencegahan dan keselamatan. Itu tidak
mewakili menjamin sifat dari produk. PT.SMART-LAB INDONESIA dan Afiliasinya tidak bertanggung
jawab atas segala kerusakan akibat penanganan atau dari kontak dengan produk di atas. dan / atau sisi
sebaliknya dari faktur atau slip kemasan untuk syarat dan ketentuan penjualan tambahan.

MATERIAL SAFETY DATA SHEET
ETHANOL ABSOLUTE
Revision : 02 Date: November 3rd, 2021 MSDS Number : 076
Section 1 - Chemical Product and Company Identification
1.1 Product Name : ETHANOL ABSOLUTE

Synonyms : Ethyl alcohol, Spirit of wine, Ethyl hydrate, Ethyl hydroxide, Methylcarbinol
CAS No. : 64-17-5
HS Code : 2207 10 00
Molecular Weight : 46.07 g/mol
Chemical Formula : C2H5OH C2H6O Hill
Product Code : A-1035
Brand : SMART-LAB
1.2 Manufacturer :PT.Smart-Lab Indonesia
Address : Ruko Boulevard Taman Tekno Blok E No.10-11,BSD Sektor XI Serpong,
Tangerang - Indonesia
Website :www.smartlab.co.id
Email :sales@smartlab.co.id
For information :Telp: +62-21- 7588 0205(Hunting) , fax:+62-21-7588 0198
1.3 Application : General Chemical reagent
Emergency Telephone: +62-21-7588 0205(Hunting)
Section 2 - Hazards Identification
2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Eye irritation (Category 2), H319
For the full text of the H-Statements mentioned in this Section, see Section 16
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Danger

Hazard statement(s)
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P370 + P378 In case of fire: Use dry powder or dry sand to extinguish.
P403 + P235 Store in a well-ventilated place. Keep cool.
PT.SMART-LAB INDONESIA MSDS – ETHANOL ABSOLUTE Page 1

ETHANOL ABSOLUTE
Supplemental Hazard Statements none
2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Section 3 - Composition, Information on Ingredients
3.1 Substances
Synonyms : Ethyl alcohol, Spirit of wine, Absolute alcohol, ETOH
Formula : C2H5OH C2H6O Hill
Molecular weight : 46.07 g/mol
CAS-No. : 64-17-5
EC-No. : 200-578-6
Index-No. : 603-002-00-5
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration

Ethanol
CAS-No. 64-17-5
Flam. Liq. 2; Eye Irrit. 2; H225, H319 <=100 %
EC-No. 200-578-6
Index-No. 603-002-00-5
For the full text of the H-Statements mentioned in this Section, see Section 16.
Section 4 - First Aid Measures
4.1 Description of first aid measures

General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact

Wash off with soap and plenty of water. Consult a physician.
In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.
Consult a physician
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available

ETHANOL ABSOLUTE
Section 5 - Firefighting Measures
5.1 Extinguishing media

Suitable extinguishing media
Dry powder Dry sand
Unsuitable extinguishing media

Do NOT use water jet.
5.2 Special hazards arising from the substance or mixture

Carbon oxides
Combustible.
5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information

Use water spray to cool unopened containers.
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form
explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.
6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal according to local / national regulations (see section
13).
6.4 Reference to other sections

For disposal see section 13.
Section 7 - Handling and Storage
7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition -
No smoking.Take measures to prevent the build up of electrostatic charge.
7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be
carefully resealed and kept upright to prevent leakage. Store in cool place. hygroscopic
7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

ETHANOL ABSOLUTE
Section 8 - Exposure Controls, Personal Protection
8.1 Control parameters

8.2 Exposure controls
Appropriat engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good
laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC
and the standard EN 374 derived from it.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0,3 mm
Break through time: 480 min
Material tested:Butoject®
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,2 mm
Break through time: 38 min
Material tested:Dermatril® P
Body Protection
Impervious clothing, Flame retardant antistatic protective clothing., The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use (EN 143)
respirator cartridges as a backup to engineering controls. If th full-face supplied air
respirator. Use respirators and components tested and approved under appropriate
government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Section 9 - Physical and Chemical Properties
9.1 Information on basic physical and chemical properties

Appearance Form: liquid

ETHANOL ABSOLUTE
Colour: colourless
Odour No data available
Odour Threshold No data available
pH 7,0 at 10 g/l at 20 °C
Melting point/freezingpoint Melting point/range: -114 °C
Initial boiling point and boiling range 78 °C
Flash point 14.0 °C - closed cup
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability or Upper explosion limit: 13,5 %(V)
Lower explosion limit: 2,5 %(V)
explosive limits No data available
Vapour pressure 0,57 hPa at 19,6 °C
Vapour density 1,6
Relative density 0,789 g/mL at 25 °C
Water solubility 1.000 g/l at 20 °C - completely miscible
Partition coefficient: noctanol/water log Pow: -0,35 at 24 °C - Bioaccumulation is not expected.
Auto-ignition temperature 455 °C at 1.013 hPa - DIN 51794
Decomposition temperature No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available
9.2 Other safety information

Conductivity < 1 µS/cm Surface tension 72,75 mN/m at 20 °C Relative vapour density 1,6
Section 10 - Stability and Reactivity
10.1 Reactivity
No data available
10.2 Chemical stability

Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions

No data available
10.4 Conditions to avoid

Heat, flames and sparks.
10.5 Incompatible materials

rubber, various plastics
10.6 Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition
products - No data available In the event of fire: see section 5
Section 11 - Toxicological Information
11.1 Information on toxicological effects

Acute toxicity
LD50 Oral - Rat - male and female - 10.470 mg/kg (OECD Test Guideline 401)

ETHANOL ABSOLUTE
LC50 Inhalation - Rat - male and female - 4 h - 124,7 mg/l (OECD Test Guideline 403)
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 24 h (OECD Test Guideline 404)
Serious eye damage/eye irritation

Eyes - Rabbit
Result: Causes serious eye irritation. (OECD Test Guideline 405)
Respiratory or skin sensitisation

Maximisation Test - Guinea pig
Result: negative (OECD Test Guideline 406)
Remarks: (in analogy to similar products)
Germ cell mutagenicity

Ames test Salmonella typhimurium
Result: negative In vitro mammalian cell gene mutation test mouse lymphoma cells
Result: negative OECD Test Guideline 478
Mouse - male
Result: Positive results were obtained in some in vivo tests.
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure

No data available(Ethanol)
Specific target organ toxicity - repeated exposure

No data available
Aspiration hazard
No data available
Additional Information
Repeated dose toxicity - Rat - male - Oral - No observed adverse effect level - 1.730 mg/kg - Lowest
observed adverse effect level - 3.200 mg/kg RTECS: KQ6300000 irritant effects, respiratory paralysis,
Dizziness, narcosis, inebriation, euphoria, Nausea, Vomiting To the best of our knowledge, the chemical,
physical, and toxicological properties have not been thoroughly investigated.
Section 12 - Ecological Information
12.1 Toxicity
Toxicity to fish
flow-through test LC50 - Pimephales promelas (fathead minnow) - 15.300 mg/l - 96 h (US-EPA)
Toxicity to daphnia and other aquatic invertebrates

static test LC50 - Ceriodaphnia dubia (water flea) - 5.012 mg/l - 48 h Remarks: (ECHA)

ETHANOL ABSOLUTE
Toxicity to algae
static test ErC50 - Chlorella vulgaris (Fresh water algae) - 275 mg/l - 72 h
(OECD Test Guideline 201)
Toxicity to bacteria
static test IC50 - activated sludge - > 1.000 mg/l - 3 h (OECD Test Guideline 209)
12.2 Persistence and degradability

Biodegradability aerobic - Exposure time 15 d
Result: ca.95 % - Readily biodegradable. (OECD Test Guideline 301E)
Biochemical Oxygen Demand (BOD) 930 - 1.670 mg/g
Remarks: (Lit.)
Theoretical oxygen demand 2.100 mg/g
Remarks: (Lit.)
12.3 Bioaccumulative potential

Due to the distribution coefficient n-octanol/water, accumulation in organisms is not expected.
12.4 Mobility in soil

No data available(Dibutyl phthalate)
12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects

Additional ecological information No data available
Section 13 - Disposal Considerations
13.1 Waste treatment methods

Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be
disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local
regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned
containers like the product itself.
Contaminated packaging
Dispose of as unused product.
Section 14 - Transport Information
14.1 UN number
ADR/RID: 1170 IMDG: 1170 IATA: 1170
14.2 UN proper shipping name
ADR/RID: ETHANOL
IMDG: ETHANOL
IATA: Ethanol
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: I I IMDG: II IATA: II

ETHANOL ABSOLUTE
14.5 Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
Further information
No data available
Section 15 - Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
Section 16 - Additional Information
Full text of H-Statements referred to under sections 2 and 3.

H225 Highly flammable liquid and vapour.
National Fire Protection Association (U.S.A.):

Health: 2
Flammability: 3
Reactivity: 0
Revision history :
Date Rev Description

16 may 17 01 -
3 Nov 21 02 thorough revision
Further information
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as
a guide. The information in this document is based on the present state of our knowledge and is applicable to
the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties
of the product. PT. Smartlab Indonesia Corporation and its Affiliates shall not be held liable for any damage
resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse
side of invoice or packing slip for additional terms and conditions of sale.

Phosphate Buffer pH 6.2-6.5, for Chlorine
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 12/17/2013 Revision date: 01/24/2018 Supersedes: 01/24/2018 Version: 1.2
SECTION 1: Identification
1.1. Identification
Product form : Mixtures
Product name : Phosphate Buffer pH 6.2-6.5, for Chlorine
Product code : LC18540
Synonyms : Phosphate Buffer for Chlorine / Phosphate Buffer for Chlorine Dioxide
1.2. Recommended use and restrictions on use
Use of the substance/mixture : For laboratory and manufacturing use only.
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Supplier
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
info@labchem.com - www.labchem.com
1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887
SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS-US classification
Hazardous to the aquatic H402 Harmful to aquatic life
environment - Acute
Hazard Category 3
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements

Not classified as a hazardous chemical.
Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
Water (CAS-No.) 7732-18-5 92.918 Not classified
Potassium Phosphate, Monobasic (CAS-No.) 7778-77-0 4.6 Not classified
Sodium Phosphate, Dibasic, Anhydrous (CAS-No.) 7558-79-4 2.4 Eye Irrit. 2B, H320
EDTA, Disodium, Dihydrate (CAS-No.) 6381-92-6 0.08 Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
STOT SE 3, H335
Mercuric Chloride (CAS-No.) 7487-94-7 0.002 Acute Tox. 1 (Oral), H300
Acute Tox. 1 (Dermal), H310
Carc. 2, H351
Repr. 2, H361
STOT RE 2, H373
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
01/24/2018 EN (English US) Page 1

Safety Data Sheet
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persists.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use.
4.3. Immediate medical attention and special treatment, if necessary
Obtain medical assistance.
SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
No additional information available
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Safety glasses. Gloves.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
01/24/2018 EN (English US) 2/8

Safety Data Sheet
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Water (7732-18-5)
Not applicable
Sodium Phosphate, Dibasic, Anhydrous (7558-79-4)

Not applicable
EDTA, Disodium, Dihydrate (6381-92-6)

Not applicable
Potassium Phosphate, Monobasic (7778-77-0)

Not applicable
Mercuric Chloride (7487-94-7)

ACGIH ACGIH TWA (mg/m³) 0.025 mg/m³ (Mercury, Inorganic forms, as Hg; USA;
Time-weighted average exposure limit 8 h; TLV -
Adopted Value)
OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³
IDLH US IDLH (mg/m³) 10 mg/m³
NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³
NIOSH NIOSH REL (ceiling) (mg/m³) 0.1 mg/m³
8.2. Appropriate engineering controls

Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure. Provide adequate general and local exhaust ventilation.
8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:
Gloves. Safety glasses.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses
Respiratory protection:
Respiratory protection not required in normal
conditions
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Colorless
Odor : None.
Odor threshold : No data available
pH : 6.2 - 6.5
01/24/2018 EN (English US) 3/8

Safety Data Sheet
Melting point : No data available

Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 1 g/ml
Solubility : Miscible with water.
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
SECTION 10: Stability and reactivity

10.1. Reactivity
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
mercury. Phosphorus oxides. Nitrogen oxides.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Likely routes of exposure : Skin and eye contact

Acute toxicity : Not classified
Water (7732-18-5)
LD50 oral rat ≥ 90000 mg/kg
ATE US (oral) 90000 mg/kg body weight
LD50 oral rat 5950 mg/kg
LD50 dermal rabbit ≥ 7940 mg/kg
ATE US (dermal) 7940 mg/kg body weight
LD50 oral rat 2000 mg/kg
01/24/2018 EN (English US) 4/8

Safety Data Sheet

LD50 dermal rabbit 4640 mg/kg
LD50 oral rat 1 mg/kg (Rat)
LD50 dermal rat 41 mg/kg (Rat)
Skin corrosion/irritation : Not classified
pH: 6.2 - 6.5
Serious eye damage/irritation : Not classified
pH: 6.2 - 6.5
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

IARC group 2B - Possibly carcinogenic to humans
Reproductive toxicity : Not classified
Specific target organ toxicity – single exposure : Not classified
Specific target organ toxicity – repeated : Not classified

exposure
Aspiration hazard : Not classified
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
SECTION 12: Ecological information

12.1. Toxicity
LC50 fish 1 99.92 mg/l

LC50 fish 1 ≥ 100 mg/l
EC50 Daphnia 1 ≥ 100 mg/l
LC50 fish 1 >= 500 mg/l

LC50 fish 1 0.03 mg/l (LC50; 96 h)
EC50 Daphnia 2 0.003 mg/l (EC50; 48 h)
Threshold limit algae 2 0.07 mg/l (EC0)
12.2. Persistence and degradability

Persistence and degradability Not established.
Water (7732-18-5)
01/24/2018 EN (English US) 5/8

Safety Data Sheet

Persistence and degradability Biodegradability: not applicable. No test data on mobility of the substance available.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
12.3. Bioaccumulative potential
Bioaccumulative potential Not established.
Water (7732-18-5)
BCF fish 1 10000 (BCF)
BCF fish 2 500 - 4620 (BCF)
BCF other aquatic organisms 1 10000 (BCF)
Log Pow 0.1 - 0.22 (Calculated)
Bioaccumulative potential Potential for bioaccumulation (500 ≤ BCF ≤ 5000).
12.4. Mobility in soil

12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

13.1. Disposal methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT
Not regulated
SECTION 15: Regulatory information

15.1. US Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of
1986 and 40 CFR Part 372.
Mercuric Chloride CAS-No. 7487-94-7 0.002%
01/24/2018 EN (English US) 6/8
Safety Data Sheet

RQ (Reportable quantity, section 304 of EPA's 5000 lb
List of Lists)

Listed on the United States SARA Section 302
RQ (Reportable quantity, section 304 of EPA's 500 lb
List of Lists)
SARA Section 302 Threshold Planning 500 lb
Quantity (TPQ)
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
15.2. International regulations

CANADA
Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations
National regulations

Not listed on the Canadian IDL (Ingredient Disclosure List)
Not listed on the Canadian IDL (Ingredient Disclosure List)

Listed on the Canadian IDL (Ingredient Disclosure List)
15.3. US State regulations
This product can expose you to Mercuric Chloride, which is known to the State of California to cause birth defects or other
reproductive harm. For more information go to www.P65Warnings.ca.gov.

U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significant risk
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - level (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
No Yes No No
SECTION 16: Other information

Revision date : 01/24/2018
Other information : None.
01/24/2018 EN (English US) 7/8

Safety Data Sheet
Full text of H-phrases: see section 16:

--- H300 Fatal if swallowed
---
--- H302 Harmful if swallowed
---
--- H310 Fatal in contact with skin
---
--- H315 Causes skin irritation
---
--- H319 Causes serious eye irritation
---
--- H320 Causes eye irritation
---
--- H335 May cause respiratory irritation
---
--- H351 Suspected of causing cancer
---
--- H361 Suspected of damaging fertility or the unborn child
---
--- H373 May cause damage to organs through prolonged or repeated exposure
---
--- H400 Very toxic to aquatic life
---
--- H402 Harmful to aquatic life
---
--- H410 Very toxic to aquatic life with long lasting effects
---
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 0 - Materials that will not burn under typical dire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity : 0 - Material that in themselves are normally stable, even
under fire conditions.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : B
B - Safety glasses, Gloves
SDS US LabChem
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.
01/24/2018 EN (English US) 8/8

Safety Data Sheet
According to Regulation (EC)
No. 1907/2006 (REACH) Manufacturing Limited
Cellulase - A01776
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name: Cellulase
Product No.: A01776

SDS No.: 906015
Material No. 025393
CAS No.: Not applicable.

EC No.: Not applicable.
Index No.: Not applicable.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified use(s): Enzymatic mixture for use in educational science experiments.

Professional use only.
Uses advised against: Follow supplier’s recommendations on correct use of the product.
1.3 Details of the supplier of the safety data sheet
Supplier: Philip Harris Manufacturing Ltd.

Unit 72, Gazelle Road
Weston Industrial Estate
Weston-super-Mare
BS24 9BJ
Telephone: +44 (0)1934 413 606
Fax: +44 (0)1934 626 421
E-mail: sdsinfo@philipharrismanufacturing.co.uk
1.4 Emergency telephone number
In case of emergency, call: +44 (0)1934 413 606

Monday – Thursday: 08:30 – 17:00 UK time
Friday: 08:30 – 13:00 UK time
SECTION 2: Hazard Identification
2.1.1. Classification according to Regulation (EC) No. 1272/2008 (CLP)

Resp. Sens. 1; H334
2.1.2. Classification according to Directive 67/548/EEC & Directive 1999/45/EC

Xn; R42
Version: 1.0 Cellulase SDS No.: 906015

Date: 21/01/2014 A01776 Page 1 of 11
Safety Data Sheet
2.2 Label elements
2.2.1. Label according to Regulation (EC) No. 1272/2008 (CLP)
Hazard pictogram(s):
Signal Word: Danger.
Hazard Statement(s): H334: May cause allergy or asthma symptoms or breathing

difficulties if inhaled.
Precautionary Statement(s): P261: Avoid breathing dust.

P284: Wear respiratory protection.
P304 + P340: IF INHALED: Remove person to fresh air and keep
comfortable for breathing.
P342 + P311: If experiencing respiratory symptoms: Call a
POISON CENTER or doctor.
P501: Dispose of contents/container to hazardous waste collection
point for disposal in accordance with local, regional, national or
international regulations.
Supplemental Hazard None.

information (EU):
2.3 Other hazards
The product does not meet the criteria for PBT or vPvB substances.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Chemical name % w/w CAS No. EC No. Index No. Classification Classification
(Regulation (EC) No. (Directive
1272/2008 (CLP)) 67/548/EEC)
Cellulase 1-10 9012-54-8 232-734-4 647-002-00-3 Resp. Sens . 1; H334 Xn; R42
See Section 16 for full description of R phrases and H statements.
SECTION 4: First Aid Measures
INHALATION: Remove person to fresh air and keep in a position comfortable for breathing. Keep warm
and at rest. If experiencing respiratory symptoms, obtain immediate medical attention.

Date: 21/01/2014 A01776 Page 2 of 11
Safety Data Sheet
SKIN CONTACT: Take off immediately all contaminated clothing. Rinse skin with plenty of water. If irritation
develops and persists, get medical attention. Contaminated clothing should be washed
before reuse.
EYE CONTACT: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present
and easy to do. Continue rinsing, making sure to rinse under eyelids. If eye irritation
persists, get medical attention.
INGESTION: Do not induce vomiting. Provided the patient is conscious, rinse mouth out with water and
give 200-300 mL of water to drink. Never give anything by mouth to an unconscious
person. If symptoms develop, get medical attention.
4.2 Most important symptoms and effects, both acute and delayed:
Inhalation may cause allergy or asthma symptoms or breathing difficulties if inhaled. Shortness of breath,
wheezing and coughing. The effect of inhalation may be delayed. Skin contact may cause slight irritation. Eye
contact may cause slight irritation and redness. Ingestion may cause gastrointestinal irritation.
4.3 Indication of any immediate medical attention and special treatments needed:
In case of accident or if you feel unwell, seek medical advice immediately. Show this Safety Data Sheet to the
doctor in attendance. If breathing is laboured, oxygen should be administered by qualified personnel.
SECTION 5: Fire-fighting Measures
5.1 Extinguishing Media
Suitable extinguishing media: Use extinguishant suitable for surrounding fire. Water spray,
alcohol-resistant foam, CO2 or dry powder.
Unsuitable extinguishing media: None identified.
Containers exposed to fire may burst due to a build-up of pressure.
May cause allergy or asthma symptoms or breathing difficulties if inhaled. Combustion may liberate toxic
fumes: Carbon monoxide, carbon dioxide, nitrogen oxides, sulphur oxides.
5.3 Advice for fire-fighters
A self-contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Keep
fire exposed containers cool by spraying with water. Do not allow to enter drains, sewers or watercourses.
SECTION 6: Accidental Release Measures
6.1.1 For non-emergency personnel

Provide adequate ventilation to minimise exposure to dust. Avoid formation of dust clouds. Do not
breathe dust. Avoid contact with skin, eyes or clothing. Wear suitable personal protective equipment.
Wear appropriate respirator when ventilation is inadequate (See Section 8).

Date: 21/01/2014 A01776 Page 3 of 11
Safety Data Sheet
6.1.2 For emergency responders

Keep unnecessary personnel away. Wear suitable protective clothing (See Section 8). Take off
contaminated clothing and wash it before reuse.
Do not allow to enter watercourses or surface water drainage (storm drains). Spillages or uncontrolled
discharges into watercourses must be alerted to the Environment Agency or other appropriate regulatory
body.
6.3 Methods and materials for containment and clearing up
6.3.1 For containment

Avoid generation of dust clouds.
6.3.2 For cleaning up

Collect spilled material mechanically, preferably using a vacuum cleaner fitted with a high efficiency
filter. Dispose of contaminated material as waste according to Section 13. Wash spill area with large
amounts of water (discharge to foul sewer only).
6.3.3 Other advice

None.
See Section 8 for personal protective equipment. See Section 13 for waste disposal.
SECTION 7: Handling and Storage
Provide adequate ventilation to minimise exposure to dust. Avoid formation of dust clouds. Do not breathe dust.
Avoid contact with skin, eyes or clothing. Wear suitable personal protective equipment (See Section 8).
Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Take off contaminated
clothing and wash it before reuse.
Keep container tightly closed. Store in a well-ventilated place. Keep cool. Storage in a refrigerator will prolong
useful life. Protect from direct sunlight.
Keep away from: strong oxidising agents.
Enzymatic mixture for use in educational science experiments. Professional use only.

Date: 21/01/2014 A01776 Page 4 of 11
Safety Data Sheet
SECTION 8: Exposure Controls/Personal Protection
Workplace exposure limits

nd
Source: EH40/2005, 2 Ed., 2011.
No occupational exposure limits assigned.
DMELs (Workers)
Acute/short-term exposure Long-term exposure

Substance Route
Systemic effects Local effects Systemic effects Local effects
Cellulase Inhalation - - 0.00006 mg/m³ 0.00006 mg/m³
Dermal - - - -
PNECs
Aqua Aqua Sewage Sediment Sediment
Aqua (fresh
Substance (marine (intermittent Treatment (fresh (marine Soil Oral
water)
water) releases) Plants water) water)
Cellulase 0.0237 mg/L 0.00237 0.237 mg/L 65 mg/L Exposure Exposure - No
mg/L not expected not expected bioaccum-
ulation
potential.
8.2.1 Appropriate engineering controls

Provide adequate ventilation to minimise exposure to dust.
8.2.2 Personal protection

Eye protection: If eye-protection is not integral to the respirator being worn, wear
goggles or safety glasses with side shields giving complete
protection to eyes (EN 166).
Skin protection:
Hand protection: Chemical-resistant gloves conforming (EN 374). Nitrile rubber, butyl
rubber, natural rubber (latex) and polyvinyl chloride are
recommended materials. Contact glove supplier to confirm suitable
glove material, thickness and breakthrough times.
Other: Long sleeve protective clothing.
Respiratory protection: If case of insufficient ventilation, wear a respirator (EN 140) with a
P3 particle filter or better (EN 143).
Thermal hazards: Not applicable.
8.2.3 Environmental exposure controls

Inform environmental manager of all incidents involving this product.

Date: 21/01/2014 A01776 Page 5 of 11
Safety Data Sheet
SECTION 9: Physical and Chemical Properties
Appearance: Powder.
Odour: Characteristic.
Odour threshold: Not available.
pH: Not available.
Melting/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Evaporation rate: Not available.
Flammability (solid; gas): Not available.
Upper/lower flammability or explosive limits: Not available.
Vapour pressure: Not available.
Vapour density: Not available.
Relative density: Not available.
Cellulase: 1.33 – 14.2 (estimated) (water = 1)
Solubility(ies): Soluble in water.
Cellulase: 1 – 100 g/L
Partition coefficient: n-octanol/water: Not available.
Cellulase: Log Pow = -2.95 – -3.1 (estimated)
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Viscosity: Not applicable.
Explosive properties: Not explosive.
Oxidising properties: Not oxidising.
9.2 Other information

None known.
SECTION 10: Stability and Reactivity
10.1 Reactivity Reacts with oxidising agents.
10.2 Chemical stability Stable under normal conditions.
10.3 Possibility of hazardous reactions No hazardous reactions expected during normal use.
10.4 Conditions to avoid Avoid extreme temperatures. Storage in a refrigerator will prolong
useful life. Protect from direct sunlight.
10.5 Incompatible materials Strong oxidising agents.

Date: 21/01/2014 A01776 Page 6 of 11
Safety Data Sheet
10.6 Hazardous decomposition products Combustion may liberate toxic fumes: Carbon monoxide, carbon
dioxide, nitrogen oxides, sulphur oxides.
SECTION 11: Toxicological Information
11.1 Information on toxicological effects
Acute toxicity Not classified. May cause discomfort if swallowed.
No data are available for the mixture. The following data are for the
ingredients:
Cellulase:
LD50 (oral/rat): > 2,880 mg/kg
LC50 (inhalation/rat/4 h): > 4.86 mg/L air (analytical)
Skin corrosion/irritation May cause slight skin irritation.
Serious eye damage/irritation May cause slight eye irritation.
Skin sensitisation Not classified. The product does not contain substances classified
as skin sensitisers above the classification thresholds.
Respiratory sensitisation May cause allergy or asthma symptoms or breathing difficulties if

inhaled.
Germ cell mutagenicity Not classified. The product does not contain substances classified
as mutagenic above the classification thresholds.
Carcinogenicity Not classified. The product does not contain substances classified
as carcinogenic above the classification thresholds.
Reproductive toxicity Not classified. The product does not contain substances classified
as toxic to reproduction above the classification thresholds.
Specific Target Organ Toxicity – Not classified. The product does not contain substances classified
single exposure for specific target organ toxicity following a single exposure above
the classification thresholds.
Specific Target Organ Toxicity – Not classified. The product does not contain substances classified
repeated exposure for specific target organ toxicity following repeated exposure above
the classification thresholds.
Aspiration hazard Not classified. Based on available data, the classification criteria are
not met.
Information on likely routes of exposure
Inhalation May cause allergy or asthma symptoms or breathing difficulties if

inhaled.
Skin contact May cause slight skin irritation.
Eye contact May cause slight eye irritation.

Date: 21/01/2014 A01776 Page 7 of 11
Safety Data Sheet
Ingestion May cause gastrointestinal irritation.
Symptoms related to the physical, chemical Inhalation may cause allergy or asthma symptoms or breathing
and toxicological characteristics difficulties if inhaled. Shortness of breath, wheezing and coughing.
The effect of inhalation may be delayed. Skin contact may cause
slight irritation. Eye contact may cause slight irritation and redness.
Ingestion may cause gastrointestinal irritation.
Mixture versus substance Information No data available.
Other information None.
SECTION 12: Ecological Information
12.1 Toxicity Not classified.
No data are available for the mixture. The following data are for the
ingredients:
Cellulase:
LC50 (Oncorhynchus mykiss): > 52.1 mg/L active enzyme protein,
96h
NOEC (Oncorhynchus mykiss): 23.7 mg/L active enzyme protein,
96h
EC50 (Daphnia magna): > 52.1 mg/L active enzyme protein, 48 h
NOEC (Daphnia magna): ≥ 52.1 mg/L active enzyme protein, 48 h
EC50 (Desmodesmus subspicatus): ≥ 52.1 mg/L active enzyme
protein, 72 h (growth rate)
EC50 (Desmodesmus subspicatus): ≥ 52.1 mg/L active enzyme
protein, 72 h (biomass)
NOEC (Desmodesmus subspicatus): ≥ 52.1 mg/L active enzyme
protein, 72 h (yield)
12.2 Persistence and degradability Cellulase:

Readily biodegradable.
12.3 Bioaccumulative potential No potential to bioaccumulate.
12.4 Mobility in soil No data available.
12.5 Results of PBT and vPvB The product does not contain substances assessed to be PBT or
assessment vPvB.
12.6 Other adverse effects None known.
SECTION 13: Disposal Considerations

To be disposed of as hazardous waste. Disposal should be in accordance with local, state or national
legislation.

Date: 21/01/2014 A01776 Page 8 of 11
Safety Data Sheet
SECTION 14: Transport Information
ADR
14.1 UN Number Not classified.
14.2 UN Proper shipping name -
14.3 Transport hazard class(es) -
14.4 Packing group -
14.5 Environmental hazards -
14.6 Special precautions for the user -
ADN
RID
IATA/ICAO
IMDG
14.7 Transport in bulk according to Annex The product is not intended to be transported in bulk.
II of MARPOL 73/78 and the IBC code

Date: 21/01/2014 A01776 Page 9 of 11
Safety Data Sheet
SECTION 15: Regulatory Information

This Safety Data Sheet was prepared in accordance with EC Regulation (EC) No. 1907/2006 as amended.
The product has been classified in accordance with Regulation (EC) No. 1272/2008 (CLP), Directive
67/548/EEC & Directive 1999/45/EC.
15.2 Chemical Safety Assessment

A chemical safety assessment has not been carried out.
SECTION 16: Other Information
Full text of relevant R-phrases and/or H-statements:
Hazard Statement(s): H334: May cause allergy or asthma symptoms or breathing

difficulties if inhaled.
Supplemental Hazard None.

information (EU):
Risk phrase(s): R42: May cause sensitisation by inhalation.
Abbreviations:
CAS: Chemical Abstracts Service;
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level
EINECS: European Inventory of Existing Commercial Chemical Substances
EC50: Effective Concentration 50%
EL50: Effective Loading rate 50%
EbC50: Concentration at which 50% reduction in biomass is observed
ErC50: Concentration at which 50% reduction in growth rate is observed
IC50: Inhibitory Concentration 50%
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
LL50: Lethal Loading rate 50%
LCLo: Lowest lethal concentration
LOEL: Lowest Observed Effect Level
NOEC: No Observed Effect Concentration
NOEL: No Observed Effect Level
PBT: Persistent, Bioaccumulative and Toxic
PNEC: Predicted No Effect Concentration
vPvB: Very Persistent and Very Bioaccumulative
References:
Supplier’s Safety Data Sheets for ingredients
ECHA disseminated REACH dossiers
ECHA Classification & Labelling Inventory
Approved Classification and Labelling Guide (Sixth edition)
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP)

Date: 21/01/2014 A01776 Page 10 of 11
Safety Data Sheet
Regulation (EC) No. 1272/2008 on classification, labelling and packaging of substances and mixtures (CLP)
Disclaimer:
THE INFORMATION PRESENTED HEREIN IS BELIEVED TO BE ACCURATE, BUT IS NOT WARRANTED TO BE,
WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM, IN
ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR
CIRCUMSTANCES.
Version history:
SDS Number: 906015

Version: 1.0
Issue date: 21/01/2014
Previous Version: -
Issue date of previous version: -
Sections changed from previous version: -

Date: 21/01/2014 A01776 Page 11 of 11
Ammonium Sulfate
Safety Data Sheet
Date of issue: 06/20/2013 Revision date: 12/06/2016 Supersedes: 06/20/2013 Version: 1.1
SECTION 1: Identification
1.1. Identification
Product form : Substance
Substance name : Ammonium Sulfate
CAS No : 7783-20-2
Product code : LC11298
Formula : N2H8O4S
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : For laboratory and manufacturing use only.
Restrictions on use : Not for food, drug or household use
1.3. Details of the supplier of the safety data sheet
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
info@labchem.com - www.labchem.com
1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887
SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS-US classification
Hazardous to the aquatic environment - Acute Hazard Category 3 H402
Full text of H statements : see section 16
2.2. Label elements

GHS-US labeling
Hazard statements (GHS-US) : H402 - Harmful to aquatic life
Precautionary statements (GHS-US) : P273 - Avoid release to the environment
P501 - Dispose of contents/container to comply with local, state and federal regulations
2.3. Other hazards

Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients

3.1. Substance
Substance type : Mono-constituent
Name Product identifier % GHS-US classification
Ammonium Sulfate (CAS No) 7783-20-2 100 Aquatic Acute 3, H402
(Main constituent)
Full text of hazard classes and H-statements : see section 16

3.2. Mixture
Not applicable
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse.
12/06/2016 EN (English US) Page 1

Ammonium Sulfate
Safety Data Sheet
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.
4.3. Indication of any immediate medical attention and special treatment needed
None. Obtain medical assistance.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Not flammable.
Explosion hazard : Not applicable.
Reactivity : None.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Wear chemically protective gloves, lab coat or apron to prevent prolonged or repeated skin
contact.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away
from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible
materials. Keep container closed when not in use.
Incompatible products : Strong bases. Strong oxidizers.
Incompatible materials : Sources of ignition. Direct sunlight.
Storage area : Store at room temperature.

8.1. Control parameters
12/06/2016 EN (English US) 2/6
Ammonium Sulfate
Safety Data Sheet
8.2. Exposure controls

Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.
Personal protective equipment : Avoid all unnecessary exposure. Gloves. Safety glasses.
Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.

9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Powder.
Color : white
Odor : Odorless
Odor threshold : No data available
pH : No data available
pH solution : 5 - 6 132 g/L @ 25°C
Melting point : 280 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 1.77 g/ml
Molecular mass : 132.14 g/mol
Solubility : Soluble in water.
Water: 75 g/100ml
Log Pow : -5.1
Auto-ignition temperature : No data available
Decomposition temperature : 280 °C
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : Not applicable.
Oxidizing properties : None.
9.2. Other information

10.1. Reactivity
None.
10.2. Chemical stability
Not established.
12/06/2016 EN (English US) 3/6

Ammonium Sulfate
Safety Data Sheet
10.3. Possibility of hazardous reactions

Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong oxidizers. Strong bases.
10.6. Hazardous decomposition products
Gaseous ammonia. Sulfur compounds.

11.1. Information on toxicological effects
Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified
Skin corrosion/irritation : Not classified

(Conclusive but not sufficient for classification)
Serious eye damage/irritation : Not classified
(Conclusive but not sufficient for classification)
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms

12.1. Toxicity
Ecology - water : Harmful to aquatic life.
Ammonium Sulfate (7783-20-2)
LC50 fish 1 36.7 mg/l
EC50 Daphnia 1 433 mg/l
12.2. Persistence and degradability

12.3. Bioaccumulative potential

Log Pow -5.1
12.4. Mobility in soil

12.5. Other adverse effects
Other information : Avoid release to the environment.
12/06/2016 EN (English US) 4/6

Ammonium Sulfate
Safety Data Sheet

13.1. Waste treatment methods
Waste disposal recommendations : Dispose of contents/container to comply with local, state and federal regulations.
Ecology - waste materials : Avoid release to the environment.

Department of Transportation (DOT)
In accordance with DOT
Not regulated

15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40
CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372.
15.2. International regulations

CANADA
WHMIS Classification Uncontrolled product according to WHMIS classification criteria
EU-Regulations
National regulations
Listed on the Canadian IDL (Ingredient Disclosure List)
15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer,
developmental and/or reproductive harm

Revision date : 12/06/2016
Other information : None.
Full text of H-phrases: see section 16:
------ H402 Harmful to aquatic life
NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard
beyond that of ordinary combustible materials.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.
12/06/2016 EN (English US) 5/6

Ammonium Sulfate
Safety Data Sheet
HMIS III Rating

Health : 0 Minimal Hazard - No significant risk to health
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : A
A - Safety glasses
SDS US LabChem
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.
12/06/2016 EN (English US) 6/6

Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Gallic acid ≥98 %, p.a., ACS, anhydrous
article number: 2699 date of compilation: 2016-05-19

Version: 2.0 en Revision: 2021-12-22
Replaces version of: 2016-05-19
Version: (1)
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
Identification of the substance Gallic acid ≥98 %, p.a., ACS, anhydrous
Article number 2699
Registration number (REACH) It is not required to list the identified uses be-
cause the substance is not subject to registration
according to REACH (< 1 t/a).
EC number 205-749-9
CAS number 149-91-7
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for products which come into contact
with foodstuffs. Do not use for private purposes
(household).
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany
Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: sicherheit@carlroth.de
Website: www.carlroth.de
Competent person responsible for the safety data :Department Health, Safety and Environment
sheet:
e-mail (competent person): sicherheit@carlroth.de
Name Street Postal Telephone Website
code/city
National Poisons Information Dudley Rd B187QH 844 892 0111

Service Birmingham
City Hospital
United Kingdom (en) Page 1 / 15

Safety data sheet
article number: 2699
SECTION 2: Hazards identification

Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Cat- Hazard class and Hazard
egory category statement
3.2 Skin corrosion/irritation 2 Skin Irrit. 2 H315
3.3 Serious eye damage/eye irritation 2 Eye Irrit. 2 H319
3.8R Specific target organ toxicity - single exposure (respirat- 3 STOT SE 3 H335
ory tract irritation)
For full text of abbreviations: see SECTION 16
2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word Warning
Pictograms
GHS07
Hazard statements
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statements
Precautionary statements - prevention
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P280 Wear protective gloves/eye protection
Precautionary statements - response
P302+P352 IF ON SKIN: Wash with plenty of water
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
Labelling of packages where the contents do not exceed 125 ml

Signal word: Warning
Symbol(s)

Safety data sheet
2.3 Other hazards

Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB.

3.1 Substances
Name of substance Gallic acid
Molecular formula C₇H₆O₅
Molar mass 170,1 g/mol
CAS No 149-91-7
EC No 205-749-9

General notes
Take off contaminated clothing.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
Rinse skin with water/shower. In case of skin irritation, consult a physician.
Following eye contact
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of
eye irritation consult an ophthalmologist.
Following ingestion
Rinse mouth. Call a doctor if you feel unwell.
Irritation, Cough, Dyspnoea
none

Safety data sheet


co-ordinate firefighting measures to the fire surroundings
water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder
water jet
Combustible.
Hazardous combustion products
In case of fire may be liberated: Carbon monoxide (CO), Carbon dioxide (CO₂)
In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas-
onable distance. Wear self-contained breathing apparatus.

For non-emergency personnel

Avoid contact with skin, eyes and clothes. Do not breathe dust.
Keep away from drains, surface and ground water.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains. Take up mechanically.
Advice on how to clean up a spill
Take up mechanically. Control of dust.
Other information relating to spills and releases
Place in appropriate containers for disposal.
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

Safety data sheet

Provision of sufficient ventilation. Avoid dust formation.
Measures to prevent fire as well as aerosol and dust generation
Removal of dust deposits.
Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
Store in a dry place. Keep container tightly closed. Direct light irradiation. Hygroscopic solid.
Incompatible substances or mixtures
Observe hints for combined storage.
Consideration of other advice:
Ventilation requirements
Use local and general ventilation.
Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C
No information available.

National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Coun Name of agent CAS No Identifi- TWA STEL Ceil- Nota- Source
try er [mg/ [mg/ ing-C tion
m³] m³] [mg/
m³]
GB dust WEL 10 i EH40/2005
GB dust WEL 4 r EH40/2005
Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
i Inhalable fraction
r Respirable fraction
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)

Individual protection measures (personal protective equipment)
Eye/face protection

Safety data sheet
Use safety goggle with side protection.

Skin protection
• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. The times are approximate values from
measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances,
body heat etc. and a reduction of the effective layer thickness by stretching can lead to a consider-
able reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times
larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply
only to the pure substance. When transferred to substance mixtures, they may only be considered as
a guide.
• type of material
NBR (Nitrile rubber)
• material thickness
>0,11 mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P2 (filters at
least 94 % of airborne particles, colour code: White).
Environmental exposure controls

Physical state solid
Form powder
Colour whitish - beige
Odour odourless
Melting point/freezing point 252 °C
Boiling point or initial boiling point and boiling not determined
range

Safety data sheet
Flammability this material is combustible, but will not ignite

readily
Lower and upper explosion limit not determined
Flash point 250 °C
Auto-ignition temperature not determined
Decomposition temperature 210 – 431 °C
pH (value) not applicable
Kinematic viscosity not relevant

Solubility(ies)
Water solubility 11,9 g/l at 20 °C (ECHA)

Partition coefficient
Partition coefficient n-octanol/water (log value): 0,7 (TOXNET) (exp.)

Vapour pressure not determined

Density and/or relative density
Density 1,69 g/cm³ at 20 °C
Relative vapour density information on this property is not available

Particle characteristics No data available.

Other safety parameters
Oxidising properties none
Information with regard to physical hazard hazard classes acc. to GHS
classes: (physical hazards): not relevant
Other safety characteristics: There is no additional information.

10.1 Reactivity
The product in the delivered form is not dust explosion capable; the enrichment of fine dust however
leads to the danger of dust explosion.
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
Violent reaction with: strong oxidiser

Safety data sheet

Keep away from heat. Decompostion takes place from temperatures above: 210 – 431 °C. Direct light
irradiation. Protect from moisture.
bases, acids
Hazardous combustion products: see section 5.

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Shall not be classified as acutely toxic.
Acute toxicity
Exposure route Endpoint Value Species Method Source
oral LD50 >5.000 mg/kg mouse ECHA
Causes skin irritation.
Causes serious eye irritation.
Shall not be classified as a respiratory or skin sensitiser.
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Shall not be classified as a reproductive toxicant.
May cause respiratory irritation.
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
Data are not available.
• If in eyes

Safety data sheet
Causes serious eye irritation

• If inhaled
Irritation to respiratory tract, cough, Dyspnoea
• If on skin
causes skin irritation
• Other information
none
11.2 Endocrine disrupting properties
Not listed.
11.3 Information on other hazards
There is no additional information.

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
.
Aquatic toxicity (acute)
Endpoint Value Species Source Exposure

time
LC50 >100 mg/l fish ECHA 96 h
EC50 19,1 mg/l aquatic invertebrates ECHA 48 h
Biodegradation
The substance is readily biodegradable.
12.2 Process of degradability
Theoretical Oxygen Demand: 1,129 mg/mg
Theoretical Carbon Dioxide: 1,811 mg/mg
Does not significantly accumulate in organisms.
n-octanol/water (log KOW) 0,7 (TOXNET) (Exp.)

Not listed.

Safety data sheet

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process. Waste catalogue ordinance (Germany).
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.

14.1 UN number or ID number not subject to transport regulations
14.2 UN proper shipping name not assigned
14.3 Transport hazard class(es) none
14.4 Packing group not assigned
14.5 Environmental hazards non-environmentally hazardous acc. to the dan-
gerous goods regulations
14.7 Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.
14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Not subject to ADR, RID and ADN.
International Maritime Dangerous Goods Code (IMDG) - Additional information
Not subject to IMDG.
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Not subject to ICAO-IATA.

Safety data sheet

Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII
Dangerous substances with restrictions (REACH, Annex XVII)
Name of substance Name acc. to inventory CAS No Restriction No
Gallic acid substances in tattoo inks and perman- R75 75

ent make-up
Legend
R75 1. Shall not be placed on the market in mixtures for use for tattooing purposes, and mixtures containing any such sub-
stances shall not be used for tattooing purposes, after 4 January 2022 if the substance or substances in question is or
are present in the following circumstances:
(a) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as carcinogen category
1A, 1B or 2, or germ cell mutagen category 1A, 1B or 2, the substance is present in the mixture in a concentration
equal to or greater than 0,00005 % by weight;
(b) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as reproductive toxicant
category 1A, 1B or 2, the substance is present in the mixture in a concentration equal to or greater than 0,001 % by
weight;
(c) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as skin sensitiser cat-
egory 1, 1A or 1B, the substance is present in the mixture in a concentration equal to or greater than 0,001 % by
weight;
(d) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as skin corrosive cat-
egory 1, 1A, 1B or 1C or skin irritant category 2, or as serious eye damage category 1 or eye irritant category 2, the
substance is present in the mixture in a concentration equal to or greater than:
(i) 0,1 % by weight, if the substance is used solely as a pH regulator;
(ii) 0,01 % by weight, in all other cases;
(e) in the case of a substance listed in Annex II to Regulation (EC) No 1223/2009 (*1), the substance is present in the
mixture in a concentration equal to or greater than 0,00005 % by weight;
(f) in the case of a substance for which a condition of one or more of the following kinds is specified in column g
(Product type, Body parts) of the table in Annex IV to Regulation (EC) No 1223/2009, the substance is present in the
mixture in a concentration equal to or greater than 0,00005 % by weight:
(i) “Rinse-off products”;
(ii) “Not to be used in products applied on mucous membranes”;
(iii) “Not to be used in eye products”;
(g) in the case of a substance for which a condition is specified in column h (Maximum concentration in ready for use
preparation) or column i (Other) of the table in Annex IV to Regulation (EC) No 1223/2009, the substance is present in
the mixture in a concentration, or in some other way, that does not accord with the condition specified in that column;
(h) in the case of a substance listed in Appendix 13 to this Annex, the substance is present in the mixture in a concen-
tration equal to or greater than the concentration limit specified for that substance in that Appendix.
2. For the purposes of this entry use of a mixture “for tattooing purposes” means injection or introduction of the mix-
ture into a person’s skin, mucous membrane or eyeball, by any process or procedure (including procedures com-
monly referred to as permanent make-up, cosmetic tattooing, micro-blading and micro-pigmentation), with the aim of
making a mark or design on his or her body.
3. If a substance not listed in Appendix 13 falls within more than one of points (a) to (g) of paragraph 1, the strictest
concentration limit laid down in the points in question shall apply to that substance. If a substance listed in Appendix
13 also falls within one or more of points (a) to (g) of paragraph 1, the concentration limit laid down in point (h) of
paragraph 1 shall apply to that substance.
4. By way of derogation, paragraph 1 shall not apply to the following substances until 4 January 2023:
(a) Pigment Blue 15:3 (CI 74160, EC No 205-685-1, CAS No 147-14-8);
(b) Pigment Green 7 (CI 74260, EC No 215-524-7, CAS No 1328-53-6).
5. If Part 3 of Annex VI to Regulation (EC) No 1272/2008 is amended after 4 January 2021 to classify or re-classify a sub-
stance such that the substance then becomes caught by point (a), (b), (c) or (d) of paragraph 1 of this entry, or such
that it then falls within a different one of those points from the one within which it fell previously, and the date of ap-
plication of that new or revised classification is after the date referred to in paragraph 1 or, as the case may be, para-
graph 4 of this entry, that amendment shall, for the purposes of applying this entry to that substance, be treated as
taking effect on the date of application of that new or revised classification.
6. If Annex II or Annex IV to Regulation (EC) No 1223/2009 is amended after 4 January 2021 to list or change the listing
of a substance such that the substance then becomes caught by point (e), (f) or (g) of paragraph 1 of this entry, or
such that it then falls within a different one of those points from the one within which it fell previously, and the
amendment takes effect after the date referred to in paragraph 1 or, as the case may be, paragraph 4 of this entry,
that amendment shall, for the purposes of applying this entry to that substance, be treated as taking effect from the
date falling 18 months after entry into force of the act by which that amendment was made.
7. Suppliers placing a mixture on the market for use for tattooing purposes shall ensure that, after 4 January 2022, the
mixture is marked with the following information:
(a) the statement “Mixture for use in tattoos or permanent make-up”;
(b) a reference number to uniquely identify the batch;
(c) the list of ingredients in accordance with the nomenclature established in the glossary of common ingredient
names pursuant to Article 33 of Regulation (EC) No 1223/2009, or in the absence of a common ingredient name, the
IUPAC name. In the absence of a common ingredient name or IUPAC name, the CAS and EC number. Ingredients shall
be listed in descending order by weight or volume of the ingredients at the time of formulation. “Ingredient” means
any substance added during the process of formulation and present in the mixture for use for tattooing purposes. Im-
purities shall not be regarded as ingredients. If the name of a substance, used as ingredient within the meaning of

Safety data sheet

Legend
this entry, is already required to be stated on the label in accordance with Regulation (EC) No 1272/2008, that ingredi-
ent does not need to be marked in accordance with this Regulation;
(d) the additional statement “pH regulator” for substances falling under point (d)(i) of paragraph 1;
(e) the statement "Contains nickel. Can cause allergic reactions." if the mixture contains nickel below the concentra-
tion limit specified in Appendix 13;
(f) the statement "Contains chromium (VI). Can cause allergic reactions." if the mixture contains chromium (VI) below
the concentration limit specified in Appendix 13;
(g) safety instructions for use insofar as they are not already required to be stated on the label by Regulation (EC) No
1272/2008.
The information shall be clearly visible, easily legible and marked in a way that is indelible.
The information shall be written in the official language(s) of the Member State(s) where the mixture is placed on the
market, unless the Member State(s) concerned provide(s) otherwise.
Where necessary because of the size of the package, the information listed in the first subparagraph, except for point
(a), shall be included instead in the instructions for use.
Before using a mixture for tattooing purposes, the person using the mixture shall provide the person undergoing the
procedure with the information marked on the package or included in the instructions for use pursuant to this para-
graph.
8. Mixtures that do not contain the statement “Mixture for use in tattoos or permanent make-up” shall not be used for
tattooing purposes.
9. This entry does not apply to substances that are gases at temperature of 20 °C and pressure of 101,3 kPa, or gener-
ate a vapour pressure of more than 300 kPa at temperature of 50 °C, with the exception of formaldehyde (CAS No 50-
00-0, EC No 200-001-8).
10. This entry does not apply to the placing on the market of a mixture for use for tattooing purposes, or to the use of
a mixture for tattooing purposes, when placed on the market exclusively as a medical device or an accessory to a
medical device, within the meaning of Regulation (EU) 2017/745, or when used exclusively as a medical device or an
accessory to a medical device, within the same meaning. Where the placing on the market or use may not be exclus-
ively as a medical device or an accessory to a medical device, the requirements of Regulation (EU) 2017/745 and of this
Regulation shall apply cumulatively.
List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list

Not listed.
Seveso Directive
2012/18/EU (Seveso III)
No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements
not assigned
Deco-Paint Directive
VOC content 0%
, 0 g/l
Industrial Emissions Directive (IED)
VOC content 0%
VOC content 0 g/l
Directive on the restriction of the use of certain hazardous substances in electrical and
electronic equipment (RoHS)
not listed
Regulation concerning the establishment of a European Pollutant Release and Transfer
Register (PRTR)
not listed
Water Framework Directive (WFD)
not listed
Regulation on the marketing and use of explosives precursors
not listed

Safety data sheet

Regulation on drug precursors
not listed
Regulation on substances that deplete the ozone layer (ODS)
not listed
Regulation concerning the export and import of hazardous chemicals (PIC)
not listed
Regulation on persistent organic pollutants (POP)
not listed
Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un-
der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
National inventories
Country Inventory Status
AU AICS substance is listed
CA DSL substance is listed
CN IECSC substance is listed
EU ECSI substance is listed
EU REACH Reg. substance is listed
JP CSCL-ENCS substance is listed
KR KECI substance is listed
MX INSQ substance is listed
NZ NZIoC substance is listed
PH PICCS substance is listed
TW TCSI substance is listed
US TSCA substance is listed
Legend
AICS Australian Inventory of Chemical Substances
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act

No Chemical Safety Assessment has been carried out for this substance.

Safety data sheet

Indication of changes (revised safety data sheet)
Alignment to regulation: Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU
Restructuring: section 9, section 14

Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant
2.1 Classification according to Regulation (EC) No yes

1272/2008 (CLP):
change in the listing (table)
2.1 Remarks: yes

For full text of Hazard- and EU Hazard-state-
ments: see SECTION 16.
2.2 Pictograms: yes

2.2 Precautionary statements - prevention: yes

2.3 Other hazards: Other hazards yes

2.3 Results of PBT and vPvB assessment: yes

According to the results of its assessment, this
substance is not a PBT or a vPvB.
Abbreviations and acronyms

Abbr. Descriptions of used abbreviations
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)
ADR Accord relatif au transport international des marchandises dangereuses par route (Agreement concern-
ing the International Carriage of Dangerous Goods by Road)
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
Ceiling-C Ceiling value
CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
DGR Dangerous Goods Regulations (see IATA/DGR)
EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing
50 % changes in response (e.g. on growth) during a specified time interval
EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)
EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-

cence/)
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions
IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

Safety data sheet
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods Code
LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval
LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval
NLP No-Longer Polymer
PBT Persistent, Bioaccumulative and Toxic
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)
STEL Short-term exposure limit
SVHC Substance of Very High Concern
TWA Time-weighted average
VOC Volatile Organic Compounds
vPvB Very Persistent and very Bioaccumulative
WEL Workplace exposure limit
Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Mari-
time Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).
List of relevant phrases (code and full text as stated in section 2 and 3)
Code Text
H315 Causes skin irritation.
H335 May cause respiratory irritation.
Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

Safety data sheet
Folin-Ciocalteu's reagent 2 mol/l, for determination of phenols
article number: 1EPY date of compilation: 2020-11-02

Version: (1)

undertaking
Identification of the substance Folin-Ciocalteu's reagent 2 mol/l, for determina-
tion of phenols
Article number 1EPY
Registration number (REACH) not relevant (mixture)
Relevant identified uses: Laboratory and analytical use
Laboratory chemical
Uses advised against: Do not use for squirting or spraying. Do not use
for products which come into direct contact with
the skin. Do not use for products which come in-
to contact with foodstuffs. Do not use for private
purposes (household).
D-76185 Karlsruhe
Germany
Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
sheet:
code/city
National Poisons Information Beaumont Road Dublin 9 01 809 2166 https://

Centre www.poisons.ie/
Beaumont Hospital

Ireland (en) Page 1 / 21

Safety data sheet
article number: 1EPY

2.16 Substance or mixture corrosive to metals 1 Met. Corr. 1 H290
3.1O Acute toxicity (oral) 4 Acute Tox. 4 H302
3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314
3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318
The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi-
dermis and into the dermis.
2.2 Label elements
Signal word Danger
Pictograms
GHS05, GHS07
Hazard statements
H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
Precautionary statements - prevention
P280 Wear protective gloves/eye protection
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower]
P310 Immediately call a POISON CENTER/doctor
Hazardous ingredients for labelling: Lithium sulphate, Ortho-Phosphoric acid, Hydro-
chloric acid .... %, Sodium tungstate dihydrate

Signal word: Danger
Symbol(s)
H314 Causes severe skin burns and eye damage.

Safety data sheet

P280 Wear protective gloves/eye protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
contains: Lithium sulphate, Ortho-Phosphoric acid, Hydrochloric acid .... %, Sodium tungstate dihydrate
2.3 Other hazards

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

3.1 Substances
not relevant (mixture)
3.2 Mixtures
Description of the mixture
Name of sub- Identifier Wt% Classification acc. to Pictograms Notes
stance GHS
Lithium sulphate CAS No 9 – 30 Acute Tox. 4 / H302

10377-48-7 Eye Irrit. 2 / H319
EC No
233-820-4
Sodium tungstate di- CAS No 5 – 9 Acute Tox. 4 / H302

hydrate 10213-10-2
EC No
236-743-4
ortho-Phosphoric acid CAS No 5 – 9 Met. Corr. 1 / H290 B(a)

7664-38-2 Acute Tox. 4 / H302 GHS-HC
Skin Corr. 1B / H314 IOELV
EC No Eye Dam. 1 / H318
231-633-2
Index No
015-011-00-6
Hydrochloric acid .... % CAS No 1 – 5 Met. Corr. 1 / H290 B(a)

7647-01-0 Skin Corr. 1B / H314 GHS-HC
Eye Dam. 1 / H318 IOELV
EC No STOT SE 3 / H335
231-595-7
Index No
017-002-01-X
Notes
B(a): The classification refers to an aqueous solution
GHS-HC: Harmonised classification (the classification of the substance corresponds to the entry in the list according to 1272/
2008/EC, Annex VI)
IOELV: Substance with a community indicative occupational exposure limit value
Name of sub- Identifier Specific Conc. Limits M-Factors ATE Exposure

stance route
Lithium sulphate CAS No - - 613 mg/kg oral

10377-48-7
EC No
233-820-4

Safety data sheet
Name of sub- Identifier Specific Conc. Limits M-Factors ATE Exposure

stance route
Sodium tung- CAS No - - 1.373 mg/kg oral

state dihydrate 10213-10-2
EC No
236-743-4
ortho-Phosphor- CAS No Skin Corr. 1B; H314: C ≥ 25 % - >300 mg/kg oral

ic acid 7664-38-2 Skin Irrit. 2; H315: 10 % ≤ C < 25 %
Eye Dam. 1; H318: C ≥ 25 %
EC No Eye Irrit. 2; H319: 10 % ≤ C < 25 %
231-633-2
Index No
015-011-00-6
Hydrochloric CAS No Met. Corr. 1; H290: C ≥ 0,1 % - -

acid .... % 7647-01-0 Skin Corr. 1B; H314: C ≥ 25 %
Skin Irrit. 2; H315: 10 % ≤ C < 25 %
EC No Eye Dam. 1; H318: C ≥ 25 %
231-595-7 Eye Irrit. 2; H319: 10 % ≤ C < 25 %
STOT SE 3; H335: C ≥ 10 %
Index No
017-002-01-X

General notes
Take off immediately all contaminated clothing.
After contact with skin, wash immediately with plenty of water. Immediate medical treatment re-
quired because corrosive injuries that are not treated are hard to cure.
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist. Protect uninjured eye.
Following ingestion
Rinse mouth immediately and drink plenty of water. Rinse mouth with water (only if the person is
conscious). Call a physician immediately. If swallowed danger of perforation of the esophagus and
the stomach (strong corrosive effects).
Corrosion, Vomiting, Risk of blindness, Gastric perforation, Risk of serious damage to eyes
none

Safety data sheet


water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)
water jet
Non-combustible.
In case of fire may be liberated: Phosphorus oxides (PxOy), Hydrogen chloride (HCl)
onable distance. Wear self-contained breathing apparatus. Wear full chemical protective clothing.


Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not
breathe vapour/spray.
Keep away from drains, surface and ground water. The product is an acid. Before discharge into
sewage plants the product normally needs to be neutralised.
Covering of drains.
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Place in appropriate containers for disposal. Ventilate affected area.

Safety data sheet

Handle and open container with care. Clear contaminated areas thoroughly.
Keep container tightly closed.

Cou Name of agent CAS No Identi- TW TWA STE STEL Ceil Ceil- Nota- Source
ntr fier A [mg/ L [mg/ ing- ing-C tion
y [pp m³] [pp m³] C [mg/
m] m] [pp m³]
m]
EU hydrogen chloride 7647-01- IOELV 5 8 10 15 2000/39/

0 EC
EU orthophosphoric 7664-38- IOELV 1 2 2000/39/

acid 2 EC
IE hydrogen chloride 7647-01- OELV 5 8 10 15 S.I. No.

0 619 of
2001
IE orthophosphoric 7664-38- OELV 1 2 S.I. No.

acid 2 619 of
2001
Notation

Safety data sheet
Relevant DNELs of components of the mixture
Name of sub- CAS No End- Threshol Protection Used in Exposure time

stance point d level goal, route of
exposure
Lithium sulphate 10377-48-7 DNEL 10 mg/m³ human, inhalat- worker (industry) chronic - systemic
ory effects
Lithium sulphate 10377-48-7 DNEL 95 mg/kg human, dermal worker (industry) chronic - systemic
bw/day effects
Sodium tungstate 10213-10-2 DNEL 3 mg/m³ human, inhalat- worker (industry) chronic - systemic
dihydrate ory effects
Sodium tungstate 10213-10-2 DNEL 0,85 mg/kg human, dermal worker (industry) chronic - systemic
dihydrate bw/day effects
Hydrochloric acid .... 7647-01-0 DNEL 8 mg/m³ human, inhalat- worker (industry) chronic - local ef-
% ory fects
Hydrochloric acid .... 7647-01-0 DNEL 15 mg/m³ human, inhalat- worker (industry) acute - local ef-
% ory fects
Relevant PNECs of components of the mixture
Name of sub- CAS No End- Threshol Organism Environmental Exposure time

stance point d level compartment
Lithium sulphate 10377-48-7 PNEC 13,5 mg/l aquatic organ- freshwater short-term (single
isms instance)
Lithium sulphate 10377-48-7 PNEC 1,35 mg/l aquatic organ- marine water short-term (single
isms instance)
Lithium sulphate 10377-48-7 PNEC 182 mg/l aquatic organ- sewage treatment short-term (single
isms plant (STP) instance)
Lithium sulphate 10377-48-7 PNEC 350,1 mg/ aquatic organ- freshwater sedi- short-term (single
kg isms ment instance)
Lithium sulphate 10377-48-7 PNEC 35,01 mg/ aquatic organ- marine sediment short-term (single
kg isms instance)
Lithium sulphate 10377-48-7 PNEC 64,77 mg/ terrestrial organ- soil short-term (single
kg isms instance)
Sodium tungstate 10213-10-2 PNEC 0,338 mg/l aquatic organ- freshwater short-term (single
dihydrate isms instance)
Sodium tungstate 10213-10-2 PNEC 0,034 mg/l aquatic organ- marine water short-term (single
Sodium tungstate 10213-10-2 PNEC 5,86 mg/l aquatic organ- sewage treatment short-term (single
dihydrate isms plant (STP) instance)
Sodium tungstate 10213-10-2 PNEC 960 mg/kg aquatic organ- freshwater sedi- short-term (single
dihydrate isms ment instance)
Sodium tungstate 10213-10-2 PNEC 96 mg/kg aquatic organ- marine sediment short-term (single
Sodium tungstate 10213-10-2 PNEC 2,17 mg/kg terrestrial organ- soil short-term (single

Safety data sheet

Eye/face protection
Use safety goggle with side protection. Wear face protection.

Skin protection
• hand protection
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. The times are approximate values from measurements at 22 ° C and permanent con-
tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-
ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in
doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective
breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred
to substance mixtures, they may only be considered as a guide.
>0,3 mm
recommended.
Respiratory protection necessary at: Aerosol or mist formation. Type: E (against acidic gases like sul-
phur dioxide or hydrogen chloride, colour code: Yellow).

Safety data sheet

Physical state liquid
Colour clear - yellow
Odour characteristic
Melting point/freezing point not determined
range
Flammability non-combustible
Flash point not determined
Decomposition temperature not relevant
pH (value) <2 (20 °C)
Kinematic viscosity not determined

Solubility(ies)
Water solubility miscible in any proportion

Partition coefficient n-octanol/water (log value): not relevant (inorganic)


Density 1,21 g/cm³

Particle characteristics not relevant (liquid)

Information with regard to physical hazard
classes:
Corrosive to metals category 1: corrosive to metals
Other safety characteristics:
Miscibility completely miscible with water

Safety data sheet

10.1 Reactivity
Substance or mixture corrosive to metals.
Violent reaction with: Aldehydes, Aluminium, Amines, Metals, Permanganates, for example potassi-
um permanganate, Sulphuric acid, Strong alkali, Zinc
There are no specific conditions known which have to be avoided.
different metals
Release of flammable materials with
Metals, Light metals (due to the release of hydrogen in an acid/alkaline medium)

Test data are not available for the complete mixture.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity
formula).
Acute toxicity
Harmful if swallowed.
Acute toxicity estimate (ATE) of components of the mixture
Name of substance CAS No Exposure route ATE
Lithium sulphate 10377-48-7 oral 613 mg/kg
Sodium tungstate dihydrate 10213-10-2 oral 1.373 mg/kg
ortho-Phosphoric acid 7664-38-2 oral >300 mg/kg
Acute toxicity of components of the mixture
Name of substance CAS No Exposure Endpoint Value Species

route
Lithium sulphate 10377-48-7 oral LD50 613 mg/kg rat
Lithium sulphate 10377-48-7 dermal LD50 >3.000 mg/kg rabbit
Sodium tungstate dihydrate 10213-10-2 oral LD50 1.373 mg/kg rat

Safety data sheet
Acute toxicity of components of the mixture
Name of substance CAS No Exposure Endpoint Value Species

route
Sodium tungstate dihydrate 10213-10-2 inhalation: LC50 >5,01 mg/l/4h rat

dust/mist
Sodium tungstate dihydrate 10213-10-2 dermal LD50 >2.000 mg/kg rat
ortho-Phosphoric acid 7664-38-2 oral LD50 >300 – 2.000 rat

mg
/kg
ortho-Phosphoric acid 7664-38-2 oral LD50 1.530 mg/kg rat
ortho-Phosphoric acid 7664-38-2 dermal LD50 2.740 mg/kg rabbit
Causes severe skin burns and eye damage.
Causes serious eye damage.
Carcinogenicity
Shall not be classified as a specific target organ toxicant (single exposure).
Aspiration hazard

• If swallowed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects)
• If in eyes
causes burns, Causes serious eye damage, risk of blindness
• If inhaled
irritant effects
• If on skin
causes severe burns, causes poorly healing wounds
none

Safety data sheet

None of the ingredients are listed.

12.1 Toxicity
.
Aquatic toxicity (acute) of components of the mixture
Name of sub- CAS No Endpoint Value Species Exposure

stance time
Lithium sulphate 10377-48-7 LC50 30,3 mg/l fish 96 h
Lithium sulphate 10377-48-7 EC50 33,2 mg/l aquatic invertebrates 48 h
Lithium sulphate 10377-48-7 ErC50 >400 mg/l algae 72 h
Sodium tungstate di- 10213-10-2 LC50 >181 mg/l fish 96 h

hydrate
Sodium tungstate di- 10213-10-2 EC50 >163 mg/l aquatic invertebrates 48 h

hydrate
Sodium tungstate di- 10213-10-2 ErC50 >17,7 mg/l algae 72 h

hydrate
ortho-Phosphoric acid 7664-38-2 EC50 >100 mg/l aquatic invertebrates 48 h
ortho-Phosphoric acid 7664-38-2 ErC50 >100 mg/l algae 72 h
Aquatic toxicity (chronic) of components of the mixture
Name of sub- CAS No Endpoint Value Species Exposure

stance time
Lithium sulphate 10377-48-7 EC50 >1,7 mg/l aquatic invertebrates 21 d
Sodium tungstate di- 10213-10-2 EC50 78,7 mg/l aquatic invertebrates 21 d

hydrate
ortho-Phosphoric acid 7664-38-2 EC50 >1.000 mg/l microorganisms 3h
Biodegradation
The methods for determining the biological degradability are not applicable to inorganic substances.
Bioaccumulative potential of components of the mixture
Name of substance CAS No BCF Log KOW BOD5/COD
Sodium tungstate dihydrate 10213-10-2 >0 – <1,23

Safety data sheet


Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.3 Remarks

14.1 UN number or ID number
ADR/RID/ADN UN 3264
IMDG-Code UN 3264
ICAO-TI UN 3264
14.2 UN proper shipping name
ADR/RID/ADN CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
IMDG-Code CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
ICAO-TI Corrosive liquid, acidic, inorganic, n.o.s.
Technical name (hazardous ingredients) Hydrochloric acid .... %, Ortho-Phosphoric acid
14.3 Transport hazard class(es)
ADR/RID/ADN 8
IMDG-Code 8

Safety data sheet

ICAO-TI 8
14.4 Packing group
ADR/RID/ADN II
IMDG-Code II
ICAO-TI II
Provisions for dangerous goods (ADR) should be complied within the premises.

information
Proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Particulars in the transport document UN3264, CORROSIVE LIQUID, ACIDIC, INORGAN-
IC, N.O.S., (contains: Hydrochloric acid .... %, or-
tho-Phosphoric acid), 8, II, (E)
Classification code C1
Danger label(s) 8
Special provisions (SP) 274

Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restriction code (TRC) E
Hazard identification No 80
Proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Particulars in the shipper's declaration UN3264, CORROSIVE LIQUID, ACIDIC, INORGAN-
IC, N.O.S., (contains: Hydrochloric acid .... %, or-
tho-Phosphoric acid), 8, II
Marine pollutant -
Danger label(s) 8
Special provisions (SP) 274


Safety data sheet

Limited quantities (LQ) 1L
EmS F-A, S-B
Stowage category B
Segregation group 1 - Acids
Proper shipping name Corrosive liquid, acidic, inorganic, n.o.s.
Particulars in the shipper's declaration UN3264, Corrosive liquid, acidic, inorganic, n.o.s.,
(contains: Hydrochloric acid .... %, ortho-Phos-
phoric acid), 8, II
Danger label(s) 8
Special provisions (SP) A3

Limited quantities (LQ) 0,5 L

Folin-Ciocalteu's reagent this product meets the criteria for R3 3

classification in accordance with Reg-
ulation No 1272/2008/EC
Hydrochloric acid .... % substances in tattoo inks and perman- R75 75

ent make-up
ortho-Phosphoric acid substances in tattoo inks and perman- R75 75

ent make-up
Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in orna-
mental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume,
or both, if they:
— can be used as fuel in decorative oil lamps for supply to the general public, and
— present an aspiration hazard and are labelled with H304.
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the
European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation
(CEN).
5. Without prejudice to the implementation of other Union provisions relating to the classification, labelling and pack-
aging of substances and mixtures, suppliers shall ensure, before the placing on the market, that the following require-
ments are met:
(a) lamp oils, labelled with H304, intended for supply to the general public are visibly, legibly and indelibly marked as
follows: “Keep lamps filled with this liquid out of the reach of children”; and, by 1 December 2010, “Just a sip of lamp oil
– or even sucking the wick of lamps – may lead to life-threatening lung damage”;
(b) grill lighter fluids, labelled with H304, intended for supply to the general public are legibly and indelibly marked by
1 December 2010 as follows: ‘Just a sip of grill lighter fluid may lead to life threatening lung damage’;
(c) lamps oils and grill lighters, labelled with H304, intended for supply to the general public are packaged in black
opaque containers not exceeding 1 litre by 1 December 2010.’;

Safety data sheet

Legend
weight;
weight;
1272/2008.
graph.
tattooing purposes.

Safety data sheet

Legend
00-0, EC No 200-001-8).

Seveso Directive
quirements
not assigned
VOC content 0%
VOC content 0%
none of the ingredients are listed
Register (PRTR)
List of pollutants (WFD)
Name of substance Name acc. to inventory CAS No Listed in Remarks
Sodium tungstate dihydrate Metals and their compounds A)
Lithium sulphate Metals and their compounds A)
Legend
A) Indicative list of the main pollutants

Name of substance CAS No Classification CN Code Threshold
level
Hydrochloric acid .... % 7647-01-0 Category 3 2806 10 00

Safety data sheet

Other information
UN Convention against Illicit Traffic in Narcotic Drugs and Psychotropic Substances
Name of substance CAS No Listed in HS code
Hydrochloric acid .... % 7647-01-0 Table II 2806.10
AU AICS all ingredients are listed
CA DSL not all ingredients are listed
CN IECSC all ingredients are listed
EU ECSI all ingredients are listed
EU REACH Reg. all ingredients are listed
JP CSCL-ENCS not all ingredients are listed
KR KECI not all ingredients are listed
MX INSQ not all ingredients are listed
NZ NZIoC all ingredients are listed
PH PICCS all ingredients are listed
TR CICR not all ingredients are listed
TW TCSI all ingredients are listed
US TSCA not all ingredients are listed
Legend
CICR Chemical Inventory and Control Regulation

Chemical safety assessments for substances in this mixture were not carried out.

Safety data sheet


relev-
ant

1272/2008 (CLP):
2.1 The most important adverse physicochemical, yes

human health and environmental effects:
Skin corrosion produces an irreversible dam-
age to the skin; namely, visible necrosis through
the epidermis and into the dermis.
2.2 Pictograms: yes

2.2 Hazard statements: yes

2.2 Hazardous ingredients for labelling: Hazardous ingredients for labelling: yes
ortho-Phosphoric acid, Hydrochloric acid .... % Lithium sulphate, Ortho-Phosphoric acid, Hy-
drochloric acid .... %, Sodium tungstate di-
hydrate
2.2 Labelling of packages where the contents do yes

not exceed 125 ml:
2.2 contains: contains: yes

Ortho-Phosphoric acid, Hydrochloric acid .... % Lithium sulphate, Ortho-Phosphoric acid, Hy-
drochloric acid .... %, Sodium tungstate di-
hydrate


This mixture does not contain any substances
that are assessed to be a PBT or a vPvB.

2000/39/EC Commission Directive establishing a first list of indicative occupational exposure limit values in imple-
mentation of Council Directive 98/24/EC
Acute Tox. Acute toxicity
land Waterways)
ADR/RID/ADN Agreements concerning the International Carriage of Dangerous Goods by Road/Rail/Inland Waterways
(ADR/RID/ADN)
ATE Acute Toxicity Estimate
BCF Bioconcentration factor

Safety data sheet
BOD Biochemical Oxygen Demand
CN Code Combined Nomenclature
COD Chemical oxygen demand
DNEL Derived No-Effect Level
EmS Emergency Schedule
ErC50 ≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either
growth (EbC50) or growth rate (ErC50) relative to the control
Eye Dam. Seriously damaging to the eye
Eye Irrit. Irritant to the eye
tions
HS Harmonized Commodity Description and Coding System (Harmonized System, drawn up by the World
Customs Organisation)
ICAO-TI Technical instructions for the safe transport of dangerous goods by air
IMDG-Code International Maritime Dangerous Goods Code
index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation
(EC) No 1272/2008
IOELV Indicative occupational exposure limit value
log KOW n-Octanol/water
Met. Corr. Substance or mixture corrosive to metals

Safety data sheet
PNEC Predicted No-Effect Concentration
ppm Parts per million
S.I. No. 619 of Safety, Health and Welfare at Work (Chemical Agents) Regulations 2001
2001
Skin Corr. Corrosive to skin
Skin Irrit. Irritant to skin
STOT SE Specific target organ toxicity - single exposure

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Mari-
time Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).
Classification procedure
Physical and chemical properties. The classification is based on tested mixture.
Health hazards. Environmental hazards. The method for classification of the mixture is based on in-
gredients of the mixture (additivity formula).
Code Text
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
Disclaimer

Safety data sheet
Sodium carbonate ≥99,5 %, Ph.Eur., USP, BP, anhydrous
article number: P028 date of compilation: 2015-06-03

Version: (4)

undertaking
Identification of the substance Sodium carbonate ≥99,5 %, Ph.Eur., USP, BP, an-
hydrous
Article number P028
Registration number (REACH) 01-2119485498-19-xxxx
Index number in CLP Annex VI 011-005-00-2
EC number 207-838-8
CAS number 497-19-8
Alternative name(s) Soda
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for products which come into contact
with foodstuffs. Do not use for private purposes
(household).
D-76185 Karlsruhe
Germany
Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
sheet:
code/city
National Poisons Information Beaumont Road Dublin 9 01 809 2166 https://

Centre www.poisons.ie/
Beaumont Hospital

Safety data sheet
article number: P028

3.3 Serious eye damage/eye irritation 2 Eye Irrit. 2 H319
2.2 Label elements

Signal word Warning
Pictograms
GHS07
Hazard statements
H319 Causes serious eye irritation
P337+P313 If eye irritation persists: Get medical advice/attention

Signal word: Warning
Symbol(s)
2.3 Other hazards

According to the results of its assessment, this substance is not a PBT or a vPvB.

Safety data sheet

3.1 Substances
Name of substance Sodium carbonate
Molecular formula Na₂CO₃
Molar mass 106 g/mol
REACH Reg. No 01-2119485498-19-xxxx

CAS No 497-19-8
EC No 207-838-8
Index No 011-005-00-2

General notes
Take off contaminated clothing.
Rinse skin with water/shower.
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of
eye irritation consult an ophthalmologist.
Following ingestion
Rinse mouth. Call a doctor if you feel unwell.
Irritation
none


water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder

Safety data sheet

water jet
Non-combustible.
In case of fire may be liberated: Carbon monoxide (CO), Carbon dioxide (CO₂)
onable distance. Wear self-contained breathing apparatus.


Avoid contact with skin, eyes and clothes. Do not breathe dust.
Covering of drains. Take up mechanically.
Take up mechanically. Control of dust.
Place in appropriate containers for disposal.

Avoid dust formation.
Measures to prevent fire as well as aerosol and dust generation
Removal of dust deposits.
Store in a dry place.

Safety data sheet

Protect against external exposure, such as
humidity
Ventilation requirements
Use local and general ventilation.

Coun Name of agent CAS No Identifi- TWA STEL Ceil- Nota- Source
try er [mg/ [mg/ ing-C tion
m³] m³] [mg/
m³]
IE dusts non-specific OELV 10 i S.I. No. 619

of 2001
IE dusts non-specific OELV 4 r S.I. No. 619

of 2001
Notation
i Inhalable fraction
r Respirable fraction

Eye/face protection
Use safety goggle with side protection.

Skin protection

Safety data sheet

• hand protection
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. The times are approximate values from
measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances,
body heat etc. and a reduction of the effective layer thickness by stretching can lead to a consider-
able reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times
larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply
only to the pure substance. When transferred to substance mixtures, they may only be considered as
a guide.
>0,11 mm
recommended.
Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P1 (filters at
least 80 % of airborne particles, colour code: White).

Physical state solid
Form powder
Colour white
Odour odourless
Melting point/freezing point 851 °C (ECHA)
range
Flammability non-combustible
Flash point not applicable
Decomposition temperature >400 °C (ECHA)

Safety data sheet
pH (value) 11 – 11,5 (in aqueous solution: 4 g/l, 25 °C)
Kinematic viscosity not relevant

Solubility(ies)
Water solubility 212,5 g/l at 20 °C (ECHA)

Partition coefficient n-octanol/water (log value): not relevant (inorganic)


Density 2,532 g/cm³ at 20 °C (ECHA)

Bulk density ~1.100 kg/m³

Particle characteristics No data available.

Information with regard to physical hazard hazard classes acc. to GHS
classes: (physical hazards): not relevant
Other safety characteristics: There is no additional information.

10.1 Reactivity
This material is not reactive under normal ambient conditions.
Violent reaction with: Alkali metals, Alkaline earth metal, Nitro compound, Sulphuric acid, Strong
acid
Humidity. Keep away from heat. Decompostion takes place from temperatures above: >400 °C.
aluminium, zinc, Light metals

Safety data sheet

Acute toxicity
Shall not be classified as acutely toxic.
Acute toxicity
Exposure route Endpoint Value Species Method Source
oral LD50 2.800 mg/kg rat ECHA
dermal LD50 >2.000 mg/kg rabbit ECHA
Shall not be classified as corrosive/irritant to skin.
Causes serious eye irritation.
Carcinogenicity
Shall not be classified as a specific target organ toxicant (single exposure).
Aspiration hazard

• If swallowed
• If in eyes
Causes serious eye irritation
• If inhaled
Inhalation of dust may cause irritation of the respiratory system
• If on skin
Frequently or prolonged contact with skin may cause dermal irritation

Safety data sheet

none
Not listed.

12.1 Toxicity
.
Aquatic toxicity (acute)
Endpoint Value Species Source Exposure

time
LC50 300 mg/l fish ECHA 96 h
EC50 227 mg/l aquatic invertebrates ECHA 48 h
Biodegradation
The methods for determining the biological degradability are not applicable to inorganic substances.
Theoretical Carbon Dioxide: 0,4152 mg/mg
Not listed.


Safety data sheet

13.3 Remarks

14.1 UN number or ID number not subject to transport regulations
14.2 UN proper shipping name not assigned
14.3 Transport hazard class(es) none
14.4 Packing group not assigned

information
Not subject to ADR, RID and ADN.
Not subject to IMDG.
Not subject to ICAO-IATA.

Sodium carbonate substances in tattoo inks and perman- R75 75

ent make-up
Legend
weight;

Safety data sheet

Legend
weight;
1272/2008.
graph.
tattooing purposes.
00-0, EC No 200-001-8).

Safety data sheet

Not listed.
Seveso Directive
quirements
not assigned
VOC content 0%
0 g/l
VOC content 0%
VOC content 0 g/l
not listed
Register (PRTR)
not listed
List of pollutants (WFD)
Name of substance Name acc. to inventory CAS No Listed in Remarks
Sodium carbonate Metals and their compounds a)
Legend
A) Indicative list of the main pollutants

not listed
not listed
not listed
not listed
not listed

Safety data sheet
Other information
AU AICS substance is listed
CA DSL substance is listed
CN IECSC substance is listed
EU ECSI substance is listed
EU REACH Reg. substance is listed
JP CSCL-ENCS substance is listed
JP ISHA-ENCS substance is listed
KR KECI substance is listed
MX INSQ substance is listed
NZ NZIoC substance is listed
PH PICCS substance is listed
TR CICR substance is listed
TW TCSI substance is listed
US TSCA substance is listed
Legend
CICR Chemical Inventory and Control Regulation
ISHA-ENCS Inventory of Existing and New Chemical Substances (ISHA-ENCS)

No Chemical Safety Assessment has been carried out for this substance.


Safety data sheet

relev-
ant

1272/2008 (CLP):


According to the results of its assessment, this
substance is not a PBT or a vPvB.

land Waterways)
tions
index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation
(EC) No 1272/2008

Safety data sheet
S.I. No. 619 of Safety, Health and Welfare at Work (Chemical Agents) Regulations 2001
2001

Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). Regulations
concerning the International Carriage of Dangerous Goods by Rail (RID). International Maritime Dan-
gerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).
Code Text
Disclaimer

SDS - Rakhmad Rofiansyah B A - S1 Teknik Kimia Paralel - Dr. Rer. Nat. Ir. Yuswan Muharam, M.T.

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SDS - Rakhmad Rofiansyah B A - S1 Teknik Kimia Paralel - Dr. Rer. Nat. Ir. Yuswan Muharam, M.T.

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Format Tersedia

No: F/QCL/008 Rev.

Bagian 1 – Identitas Bahan dan Perusahaan

1.1 Mengidentifikasi Produk

Bagian 2 – Identifikasi Bahaya

2.1 Klasifikasi bahan atau campuran

2.2 Elemen label

2.3 Bahaya lain

Bagian 3 – Komposisi dan Informasi Bahan

Bagian 4 – Tindakan Pertolongan Pertama Pada Kecelakaan (P3K)

4.1 Penjelasan mengenai tindakan pertolongan pertama

PT.SMART-LAB INDONESIA LEMBAR DATA KESELAMATAN BAHAN – AQUADEST Page 1

4.2 Kumpulan gejala/efek terpenting, baik akut maupun tertunda

Bagian 5 – Tindakan Penanggulangan Kebakaran

5.1 Media pemadaman api

5.2 Bahaya khusus yang muncul dari bahan atau campuran

5.3 Saran bagi petugas pemadam kebakaran

5.4 Informasi lebih lanjut

Bagian 6 – Tindakan terhadap tumpahan dan kebocoran

6.1 Langkah-langkah pencegahan diri,alat pelindung dan prosedur tanggap darurat

6.2 Tindakan pencegahan Lingkungan

6.3 Metode dan bahan untuk penyimpanan dan pembersihan

6.4 Rujukan ke bagian lainnya

Bagian 7 – Penyimpanan dan Penanganan Bahan

7.1 Kehati-hatian dalam menangani secara aman

PT.SMART-LAB INDONESIA LEMBAR DATA KESELAMATAN BAHAN – AQUADEST Page 2

7.2 Kondisi penyimpanan yang aman,termasuk adanya inkompatibilitas

7.3 Penggunaan akhir khusus

Bagian 8 – Pengendalian Pemaparan dan Perlindungan diri

8.1 Parameter Pengendalian

8.2 Pengendalian Pemaparan

Tindakan perlindungan individual

Perlindungan kulit / Tangan

Kontrol eksposur lingkungan

Bagian 9 – Sifat-sifat Fisika dan Kimia

9.1 Informasi tentang sifat fisika dan kimia

PT.SMART-LAB INDONESIA LEMBAR DATA KESELAMATAN BAHAN – AQUADEST Page 3

Titik nyala Tidak berlaku

9.2 Data lain

Bagian 10 – Reaktifitas dan Stabilitas

10.2 Stabilitas Kimia

10.3 Reaksi berbahaya yang mungkin di bawah kondisi spesifik/khusus

10.4 Kondisi yang harus dihindari

10.5 Bahan yang harus dihindari

10.6 Produk berbahaya hasil penguraian

Bagian 11 – Informasi Toksikologi

11.1 Informasi tentang efek toksikologis

PT.SMART-LAB INDONESIA LEMBAR DATA KESELAMATAN BAHAN – AQUADEST Page 4

Toksisitas inhalasi akut

Toksisitas kulit akut

Mutagenisitas pada sel nutfah

Toksisitas terhadap Reproduksi

Toksisitas pada organ sasaran spesifik - paparan tunggal

Toksisitas pada organ sasaran spesifik - paparan berulang

11.2 Informasi lebih lanjut

Bagian 12 – Informasi Ekologi

12.2 Persistensi dan penguraian oleh lingkungan

12.3 Potensi bioakumulasi

12.4 Mobilitas dalam tanah

PT.SMART-LAB INDONESIA LEMBAR DATA KESELAMATAN BAHAN – AQUADEST Page 5

12.5 Hasil dar asesmen PBT dan vPvB

12.6 Efek merugikan lainnya

Bagian 13 – Pembuangan Limbah

Metode penanganan limbah