Neraca Massa 1

NERACA MASSA
Sodium hipoklorit (NaOCl)

Kemurnian = 60%
Air (H2O) = 40%
Propanon (CH3OCH3)
Kemurnian = 99%
Air (H2O) = 1%
Tabel 1. Titik didih masing-masing komponen

Berat Molekul Titik
Komponen Rumus Kimia
(kg/kmol) Didih(K)
Sodium Hipoklorit NaOCl 74.5
Propanon CH3OCH3 58
Air H2O 18
Kloroform CHCl3 119.5
Natrium hidroksida NaOH 40
Asam Asetat CH3COONa 82
Basis = 100 kmol/jam
Reaksi =
3A + B " C + D + 2E
Rasio mol = NaOCl : CH3OCH3

3 1
Konversi (XA) = 99% terhadap NaOCl

Kemurnian NaOCl = 99%
Umpan NaOCl masuk reaktor = 100 kmol/jam
FA0 = 100 kmol/jam
= 7450 kg/jam
Umpan CH3OCH3 masuk reaktor =

1 x massa NaOCl
3
= 1 x 100 kmol/jam
3
FB0 = 33.3333 kmol/jam
= 1933.33333 kg/jam
Reaksi =
XA = 99%
LR = NaOCl
Tabel 2. Tabel stoikiometri
mula-mula 100 33.33333

reaksi 99 33 33 33 66
sisa 1 0.333333 33 33 66
Massa Air = ( 40% x massa NaOCl ) + ( 1% x massa CH3OCH3

)
60% 99%
= ( 40% x 100 kmol/jam) + ( 1% x 33.3333 kmol/jam
)
60% 99%
= 67.0034 kmol/jam
= 1206.0606 kg/jam
I. REAKTOR
Kondisi Operasi
P = 2 atm
T = 70 ◦C
Tabel 3. Umpan masuk reaktor

Komposisi Umpan Masuk
Masuk
Komponen BM
Mol(kmol/jam) Massa(kg/jam) Fraksi Mol
NaOCl 100 7450.0000 0.3009 74.50
CH3OCH3 33.3333 1933.3333 0.1003 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 332.3367 19878.894 1.0000
Tabel 4. Umpan keluar reaktor

Komposisi Umpan Keluar
Keluar
Komponen BM
NaOCl 1 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028
II. DECANTER
Kondisi Operasi
P = 2 atm
T = 50 ◦C
Tabel 5. Umpan masuk decanter

Masuk
Komponen BM
NaOCl 1.0000 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33.0000 3943.5000 0.0993 119.50
NaOH 66.0000 2640.0000 0.1986 40.00
CH3COONa 33.0000 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028 0.00
Tabel 6. Densitas massa masing-masing komponen pada suhu 50◦C

Komponen A B n Tc gr/ml kg/m3 urutan
NaOCl 1.2100 1210.0000 3
CH3OCH3 0.2773 0.2576 0.299 508.2 0.7560 756.0273 1
H2O 0.3471 0.274 0.2857 647.13 1.0044 1004.4359 2
CHCl3 0.4981 0.2527 0.2877 536.4 1.4307 1430.7392 4
NaOH 0.1998 0.0979 0.2538 2820 1.9016 1901.6488 6
CH3COONa 1.4500 1450.0000 5
Tabel 7. Data kelarutan komponen dalam air pada suhu 50◦C

Komponen Kelarutan
NaOCl 151.01 gram dalam 100 ml air

CH3OCH3 larut
H2O -
CHCl3 0.82 gram dalam 100 ml air
NaOH 150.7 gram dalam 100 ml air
CH3COONa 97 gram dalam 100 ml air
Tabel 8. Data viskositas masing-masing komponen pada suhu 50 oC
Diasumsikan NaOCl, CH3COCH3, dan NaOH terlarutkan sebagian dalam air sehingga
viskositas (cP) mendekati cP H2O
Komponen A B C D cP
NaOCl 0.53524
CH3OCH3 -7.2126 9.03E+02 1.84E-02 -2.04E-05 0.25001
H2O -10.2158 1.79E+03 1.77E-02 -1.26E-05 0.53524
CHCl3 -4.7831 6.99E+02 1.09E-02 -1.22E-05 0.42547
NaOH 0.53524
CH3COONa 0.53524
Tabel 9. Kelarutan dalam air
kg/(kg
Komponen kg/(L H20) (kg/L) H2O
H2O) urutan
NaOCl 1.5101 1.50344 1
CH3OCH3 1.00443 3
H2O 1 1.00000
1.00443
CHCl3 0.0093 0.00926 5
NaOH 1.507 1.50035 2
CH3COONa 0.97 0.96572 4
Tabel 10.
diasumsikan H2O, CH3OCH3, dan CHCl3 yang terbawa fase bera kebutuhan
1% massa
densitas
masuk urutan kelarutan h2o
Komponen (kg/jam) 50oC densitas terhadap air melarutkan
(kg/m3) (kg/j)
NaOCl 74.5000 1210.0000 3 1.50344 49.5530
CH3OCH3 19.3333 756.0273 1 1.00443 19.2481
H2O 1206.0606 1004.4359 2 1.00000
CHCl3 3943.5000 1430.7392 4 0.00926 425910.721
NaOH 2640.0000 1901.6488 6 1.50035 1759.5854
CH3COONa 2706.0000 1450.0000 5 0.96572 2802.0491
430541.16
perkiraan hasil 1% massa kira hasil atas hasil bawah

Komponen bawah hasil bawah (kg/jam) (kg/jam)
NaOCl 0.0000 74.5000 0.0000
CH3OCH3 19.2481 0.1925 0.1925 19.1409
H2O 4611.18749 46.1119 46.1119 1159.9487
CHCl3 425910.721 4259.1072 4259.1072 -315.6072
NaOH 0.0000 2640.0000 0.0000
CH3COONa 0.0000 2706.0000 0.0000
NERACA MASSA

Kemurnian = 60%
Air (H2O) = 40%
Propanon (CH3OCH3)
Kemurnian = 99%
Air (H2O) = 1%

Berat Molekul Titik
(kg/kmol) Didih(K)
Propanon CH3OCH3 58
Air H2O 18
Reaksi =
3A + B " C + D + 2E

3 1

FA0 = 100 kmol/jam
= 7450 kg/jam

1 x massa NaOCl
3
= 1 x 100 kmol/jam
3
= 1933.33333 kg/jam
Reaksi =
XA = 99%
LR = NaOCl
mula-mula 100 33.33333

reaksi 99 33 33 33 66
sisa 1 0.333333 33 33 66

)
60% 99%
)
60% 99%
= 67.0034 kmol/jam
= 1206.0606 kg/jam
I. REAKTOR
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 100 7450.0000 0.3009 74.50
CH3OCH3 33.3333 1933.3333 0.1003 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 332.3367 19878.894 1.0000

Keluar
Komponen BM
NaOCl 1 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028
II. DECANTER
Kondisi Operasi
P = 2 atm
T = 50 ◦C

Masuk
Komponen BM
NaOCl 1.0000 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33.0000 3943.5000 0.0993 119.50
NaOH 66.0000 2640.0000 0.1986 40.00
CH3COONa 33.0000 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028 0.00
Tabel 6. Rapat massa masing-masing komponen pada suhu 50◦C

Komponen A B n Tc gr/ml kg/m3
NaOCl 1.2100 1210.0000
CH3OCH3 0.2773 0.2576 0.299 508.2 0.7560 756.0273
H2O 0.3471 0.274 0.2857 647.13 1.0044 1004.4359
CHCl3 0.4981 0.2527 0.2877 536.4 1.4307 1430.7392
NaOH 0.1998 0.0979 0.2538 2820 1.9016 1901.6488
CH3COONa 1.4500 1450.0000

Komponen Kelarutan

CH3OCH3 larut
H2O -
Tabel 8. Massa komponen yang terlarut dalam air

Komponen kg/jam
NaOCl 1505.1836
CH3OCH3 19.3333
H2O
CHCl3 6.9123
NaOH 955.7671
CH3COONa 806.8130
Total 3294.0092
Tabel 9. Umpan keluar decanter

Diasumsikan H2O, CH3OCH3, dan CHCl3 yang terbawa fase berat 1% massa
Fase berat Fase ringan
Komponen BM
Mol(kmol/jam) Massa(kg/jam) Mol(kmol/jam) Massa(kg/jam)
NaOCl 74.50 0.000 0.000 1.00 74.50000
CH3OCH3 58.00 0.003 0.193 0.33 19.14000
H2O 18.00 0.670 12.061 66.33 1194.00000
CHCl3 119.50 32.670 3904.065 0.33 39.43500
NaOH 40.00 0.000 0.000 66.00 2640.00000
CH3COONa 82.00 0.000 0.000 33.00 2706.00000
Total 392.00 33.343 3916.319 166.993 6673.075
10589.3939
NERACA MASSA

Kemurnian = 60%
Air (H2O) = 40%
Propanon (CH3OCH3)
Kemurnian = 99%
Air (H2O) = 1%
Tabel 1. Berat molekul masing-masing komponen

Berat Molekul
(kg/kmol)
Propanon CH3OCH3 58
Air H2O 18
Reaksi =
3A + B " C + D + 2E

3 1

FA0 = 100 kmol/jam
= 7450 kg/jam

1 x massa NaOCl
3
= 1 x 100 kmol/jam
3
= 1933.33333 kg/jam
Reaksi =
XA = 99%
LR = NaOCl
mula-mula 100 33.33333

reaksi 99 33 33 33 66
sisa 1 0.333333 33 33 66

)
60% 99%
)
60% 99%
= 67.0034 kmol/jam
= 1206.0606 kg/jam
I. REAKTOR
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 100 7450.0000 0.3009 74.50
CH3OCH3 33.3333 1933.3333 0.1003 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 332.3367 19878.894 1.0000

Keluar
Komponen BM
NaOCl 1 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028
II. DECANTER
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 1.0000 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33.0000 3943.5000 0.0993 119.50
NaOH 66.0000 2640.0000 0.1986 40.00
CH3COONa 33.0000 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028 0.00

NaOCl 1.2100 1210.0000
CH3OCH3 0.2773 0.2576 0.299 508.2 0.7310 730.9792
H2O 0.3471 0.274 0.2857 647.13 0.9854 985.3744
CHCl3 0.4981 0.2527 0.2877 536.4 1.3892 1389.2124
NaOH 0.1998 0.0979 0.2538 2820 1.8929 1892.9326
CH3COONa 1.4500 1450.0000

Komponen Kelarutan

CH3OCH3 larut
H2O -

Komponen kg/jam
NaOCl 3508.4104
CH3OCH3 19.3333
H2O -
CHCl3 11.8938
NaOH 1883.5731
CH3COONa 2486.9801
Total 7910.1908

Fase ringan Fase berat
Komponen BM
NaOCl 74.50 1.00 74.50000 0.000 0.0000
CH3OCH3 58.00 0.33 19.14000 0.003 0.1933
H2O 18.00 66.33 1194.00000 0.670 12.0606
CHCl3 119.50 32.67 3904.06500 0.330 39.4350
NaOH 40.00 66.00 2640.00000 0.000 0.0000
CH3COONa 82.00 33.00 2706.00000 0.000 0.0000
Total 392.00 199.333 10537.705 1.003 51.6889
10589.3939
III. MENARA DISTILASI

Tabel 10. Umpan masuk dan keluar menara distilasi
Umpan Masuk Hasil atas Hasil Bawah
Komponen BM (%) (%)
Kmol/jam Kg/jam Kmol/jam Kg/jam Kmol/jam Kg/jam
CH3OCH3 58.00 0.330 19.140 0.0033 0.1933 0.00374 0.3267 18.947 0.0037
H2O 18.00 66.333 1194.00 0.6700 12.0606 0.23333 65.6633 1181.94 0.2333
CHCl3 119.50 32.670 3904.07 0.3300 39.44 0.76293 32.340 3864.6 0.7629
Total 99.333 5117.21 1.0034 51.69 1.000 98.330 5065.5 1.000
5117.205
Kapasitas produksi = 55000 ton/tahun
Kecepatan produksi = 6944.44444 kg/jam
Faktor pengali = 1.3709
I. REAKTOR
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 137.093 10213.3940 0.3009 74.50
CH3OCH3 45.698 2650.4557 0.1003 58.00
H2O 91.857 1653.4191 0.2016 18.00
CHCl3 45.241 5406.2442 0.0993 119.50
NaOH 90.481 3619.2430 0.1986 40.00
CH3COONa 45.241 3709.7240 0.0993 82.00
Total 455.6088 27252.480 1.3709

Keluar
Komponen BM
NaOCl 1.3709 102.1339 0.0041 74.50
CH3OCH3 0.4570 26.5046 0.0014 58.00
H2O 91.8566 1653.4191 0.2764 18.00
CHCl3 45.2405 5406.2442 0.1361 119.50
NaOH 90.4811 3619.2430 0.2723 40.00
CH3COONa 45.2405 3709.7240 0.1361 82.00
Total 274.6467 14517.2687 0.8264
II. DECANTER
Kondisi Operasi
P = 2 atm
T = 70 ◦C
Masuk
Komponen BM
Komponen BM
NaOCl 1.3709 102.1339 0.0041 74.50
CH3OCH3 0.4570 26.5046 0.0014 58.00
H2O 91.8566 1653.4191 0.2764 18.00
CHCl3 45.2405 5406.2442 0.1361 119.50
NaOH 90.4811 3619.2430 0.2723 40.00
CH3COONa 45.2405 3709.7240 0.1361 82.00
Total 274.6467 14517.2687 0.8264
NaOCl 1.2100 1210.0000
CH3OCH3 0.2773 0.2576 0.299 508.2 0.7310 730.9792
H2O 0.3471 0.274 0.2857 647.13 0.9854 985.3744
CHCl3 0.4981 0.2527 0.2877 536.4 1.3892 1389.2124
NaOH 0.1998 0.0979 0.2538 2820 1.8929 1892.9326
CH3COONa 1.4500 1450.0000

Komponen Kelarutan

CH3OCH3 larut
H2O -

Komponen kg/jam
NaOCl 2063.4943
CH3OCH3 26.5046
H2O -
CHCl3 9.7595
NaOH 1316.3187
CH3COONa 1106.0803
Total 4522.1574

Komponen BM
NaOCl 74.50 1.37 102.13394 0.000 0.0000
CH3OCH3 58.00 0.45 26.23951 0.005 0.2650
H2O 18.00 90.94 1636.88488 0.919 16.5342
CHCl3 119.50 44.79 5352.18173 0.452 54.0624
NaOH 40.00 90.48 3619.24296 0.000 0.0000
CH3COONa 82.00 45.24 3709.72403 0.000 0.0000
Total 392.00 273.271 14446.407 1.376 70.8617
14517.2687

Komponen BM (%) (%)
CH3OCH3 58.00 0.452 26.240 0.0046 0.2650 0.00513 0.4478 25.974 0.0051
H2O 18.00 90.938 1636.88 0.9186 16.5342 0.31988 90.0195 1620.35 0.3199
CHCl3 119.50 44.788 5352.18 0.4524 54.06 1.04592 44.336 5298.1 1.0459
Total 136.179 7015.31 1.3755 70.86 1.371 134.803 6944.4 1.371
7015.306
NERACA MASSA
Kapasitas produksi = 55000 ton/tahun

Kecepatan produksi = 6944.44444 kg/jam

Kemurnian = 60%
Air (H2O) = 40%
Propanon (CH3OCH3)
Kemurnian = 99%
Air (H2O) = 1%

Berat Molekul Titik
(kg/kmol) Didih(K)
Propanon CH3OCH3 58
Air H2O 18
Reaksi =
3A + B " C + D + 2E

3 1

FA0 = 100 kmol/jam
= 7450 kg/jam
Umpan CH3OCH3 masuk reaktor = 1 x massa NaOCl

3
= 1 x 100 kmol/jam
3
= 1933.33333 kg/jam
Reaksi =
XA = 99%
LR = NaOCl
mula-mula 100 33.33333

reaksi 99 33 33 33 66
sisa 1 0.333333 33 33 66

)
60% 99%
)
60% 99%
= 67.0034 kmol/jam
= 1206.0606 kg/jam
I. REAKTOR
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 100 7450.0000 0.3009 74.50
CH3OCH3 33.3333 1933.3333 0.1003 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 332.3367 19878.894 1.0000

Keluar
Komponen BM
NaOCl 1 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028
II. DECANTER
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 1.0000 74.5000 0.0030 74.50
CH3OCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33.0000 3943.5000 0.0993 119.50
NaOH 66.0000 2640.0000 0.1986 40.00
CH3COONa 33.0000 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028 0.00

NaOCl 1.2100 1210.0000
CH3OCH3 0.2773 0.2576 0.299 508.2 0.7310 730.9792
H2O 0.3471 0.274 0.2857 647.13 0.9854 985.3744
CHCl3 0.4981 0.2527 0.2877 536.4 1.3892 1389.2124
NaOH 0.1998 0.0979 0.2538 2820 1.8929 1892.9326
CH3COONa 1.4500 1450.0000

Komponen Kelarutan

CH3OCH3 larut
H2O -

Komponen kg/jam
NaOCl 1505.1836
CH3OCH3 19.3333
H2O -
CHCl3 7.1189
NaOH 960.1680
CH3COONa 806.8130
Total 3298.6168

Komponen BM
NaOCl 74.50 1.00 74.50000 0.000 0.0000
CH3OCH3 58.00 0.33 19.14000 0.003 0.1933
H2O 18.00 66.33 1194.00000 0.670 12.0606
CHCl3 119.50 32.67 3904.06500 0.330 39.4350
NaOH 40.00 66.00 2640.00000 0.000 0.0000
CH3COONa 82.00 33.00 2706.00000 0.000 0.0000
Total 392.00 199.333 10537.705 1.003 51.6889
10589.3939

Komponen BM (%) (%)
CH3OCH3 58.00 0.330 19.140 0.0033 0.1933 0.00374 0.3267 18.947 0.0037
H2O 18.00 66.333 1194.00 0.6700 12.0606 0.23333 65.6633 1181.94 0.2333
CHCl3 119.50 32.670 3904.07 0.3300 39.44 0.76293 32.340 3864.6 0.7629
Total 99.333 5117.21 1.0034 51.69 1.000 98.330 5065.5 1.000
5117.205
NERACA MASSA

Kemurnian = 60%
Air (H2O) = 40%
Propanon (CH3OCH3)
Kemurnian = 99%
Air (H2O) = 1%

Berat Molekul Titik
(kg/kmol) Didih(K)
Propanon CH3OCH3 58
Air H2O 18
Reaksi =
3A + B " C + D + 2E

3 1

FA0 = 100 kmol/jam
= 7450 kg/jam

1 x massa NaOCl
3
= 1 x 100 kmol/jam
3
= 1933.33333 kg/jam
Reaksi =
XA = 99%
LR = NaOCl
mula-mula 100 33.33333

reaksi 99 33 33 33 66
sisa 1 0.333333 33 33 66

)
60% 99%
)
60% 99%
= 67.0034 kmol/jam
= 1206.0606 kg/jam
I. REAKTOR 1
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 100 7450.0000 0.4992 74.50
CH3OCH3 33.3333 1933.3333 0.1664 58.00
H2O 67.0034 1206.0606 0.3345 18.00
CHCl3 0 0.0000 0.0000 119.50
NaOH 0 0.0000 0.0000 40.00
CH3COONa 0 0.0000 0.0000 82.00
Total 200.3367 10589.394 1.0000

Keluar
Komponen BM
NaOCl 1 74.5000 0.0050 74.50
CH3OCH3 0.3333 19.3333 0.0017 58.00
H2O 67.0034 1206.0606 0.3345 18.00
CHCl3 33 3943.5000 0.1647 119.50
NaOH 66 2640.0000 0.3294 40.00
CH3COONa 33 2706.0000 0.1647 82.00
Total 200.3367 10589.3939 1.0000
II. REAKTOR 2
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 1.0000 74.5000 0.0050 74.50
CH3OCH3 0.3333 19.3333 0.0017 58.00
H2O 67.0034 1206.0606 0.3345 18.00
CHCl3 33.0000 3943.5000 0.1647 119.50
NaOH 66.0000 2640.0000 0.3294 40.00
CH3COONa 33.0000 2706.0000 0.1647 82.00
Total 200.3367 10589.3939 1.0000

Keluar
Komponen BM
NaOCl 0.0100 0.7450 0.0000 74.50
CH3OCH3 0.0033 0.1933 0.0000 58.00
H2O 67.0034 1206.0606 0.3345 18.00
CHCl3 33.0033 3943.8983 0.1647 119.50
NaOH 66.0067 2640.2667 0.3295 40.00
CH3COONa 33.0033 2706.2733 0.1647 82.00
Total 199.0300 10497.4373 0.9935
II. DECANTER
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 1.0000 74.5000 0.0050 74.50
CH3OCH3 0.3333 19.3333 0.0017 58.00
H2O 67.0034 1206.0606 0.3345 18.00
CHCl3 33.0000 3943.5000 0.1647 119.50
NaOH 66.0000 2640.0000 0.3294 40.00
CH3COONa 33.0000 2706.0000 0.1647 82.00
Total 200.3367 10589.3939 1.0000 0.00

NaOCl 1.2100 1210.0000
CH3OCH3 0.2773 0.2576 0.299 508.2 0.7310 730.9792
H2O 0.3471 0.274 0.2857 647.13 0.9854 985.3744
CHCl3 0.4981 0.2527 0.2877 536.4 1.3892 1389.2124
NaOH 0.1998 0.0979 0.2538 2820 1.8929 1892.9326
CH3COONa 1.4500 1450.0000

Komponen Kelarutan

CH3OCH3 larut
H2O -

Komponen kg/jam
NaOCl 1505.1836
CH3OCH3 19.3333
H2O
CHCl3 7.1189
NaOH 960.1680
CH3COONa 806.8130
Total 3298.6168

Komponen BM
NaOCl 74.50 1.00 74.50000 0.000 0.0000
CH3OCH3 58.00 0.33 19.14000 0.003 0.1933
H2O 18.00 66.33 1194.00000 0.670 12.0606
CHCl3 119.50 32.67 3904.06500 0.330 39.4350
NaOH 40.00 66.00 2640.00000 0.000 0.0000
CH3COONa 82.00 33.00 2706.00000 0.000 0.0000
Total 392.00 199.333 10537.705 1.003 51.6889
10589.3939

Komponen BM (%) (%)
CH3OCH3 58.00 0.330 19.140 0.0033 0.1933 0.00374 0.3267 18.947 0.0037
H2O 18.00 66.333 1194.00 0.6700 12.0606 0.23333 65.6633 1181.94 0.2333
CHCl3 119.50 32.670 3904.07 0.3300 39.44 0.76293 32.340 3864.6 0.7629
Total 99.333 5117.21 1.0034 51.69 1.000 98.330 5065.5 1.000
5117.205
NERACA MASSA
Isobutana (i-C4H10)
Kemurnian = 95%
Pengotor = Propana (C3H8) = 2.00%
n-Butane (C4H10) = 3.00%
Butena (C4H8)
Kemurnian = 99%
Pengotor = n-Butane (C4H10) = 1.00%

Berat Molekul Titik
(kg/kmol) Didih(K)
Propana C3 H 8 44.10 231.11
Isobutana i-C4H10 58.12 261.43
Butena C4 H 8 56.11 266.90
n-Butane n-C4H10 58.12 272.65
Air H2O 18.00 373.15
Isooktana i-C8H18 114.23 392.08
Dodekana C12H26 170.34 489.47
Asam Sulfat H2SO4 98.00 610.00
Basis = 100 kg/jam

Rasio mol = i-C4H10 : C4 H 8
7 1
Konversi (XA) = 80.0% terhadap C4H8
Kemurnian C4H8 = 99%
Umpan C4H8 masuk reaktor = 100 kg/jam
FA0 = 100 kg/jam = 1.782 kmol/jam
Umpan i-C4H10 masuk reaktor = 7 x massa Butena

1
= 7 x 1.782 kmol/jam
1
= 725.0757 kg/jam
Umpan C3H8 masuk reaktor = 2.0% x massa i-C4H10

95%
= 2.0% x 725.076 kg/jam
95%
= 15.265 kg/jam
= 0.346 kmol/jam
Umpan n-C4H10 masuk reaktor = 3.0% x massa i-C4H10

95%
= 3.0% x 725.076 kg/jam
95%
= 22.89713 kg/jam
= 0.393963 kmol/jam
Umpan n-C4H10 masuk reaktor = 1% massa C4H8

x
99%
= 1% 100 kg/jam
x
99%
= 1.010101 kg/jam
= 0.01738 kmol/jam
R1𝐻_(8 )+ 〖𝑖−𝐶〗 _4 𝐻_10 → 〖𝑖−𝐶〗 _8 𝐻_18
𝐶_4
A + B → C
R−2 𝐶〗 _8 𝐻_18+ 𝐶_4 𝐻_8 → 𝐶_12 𝐻_26
〖𝑖
C + A D
Komponen Mula-Mula Bereaksi Hasil
C4H8 FA0 -(FA0.X1 + FA0.X2) FA = FA0.(1-X1-X2)
i-C4H10 FB0 -(FA0.X1) FB = FB0 - (FA0.X1)
i-C8H18 FC0 +FA0.X1 - FA0.X2 FC= FC0 + FA0(X1-X2)
C12H26 FD0 +FA0.X2 FD = FD0 + FA0.X2
C3H8 - - -
n-C4H10 - - -
H2SO4 - - -
H2O - - -
X1= 80% = 0.8000 Selectivity= 85%
X2= 14% = 0.141
Perhitungan setiap arus dalam mol (kmol/jam)
FA = FA0 x (1-X1-X2)
= 1.782 x (1- 0.8 - 0.141 )
= 0.104836 kmol/jam
= 5.882 kg/jam
FB = FB0 - (FA0 x X1)
= 12.475 - ( 1.782 x 0.8 )
= 11.04972 kmol/jam
= 642.2099 kg/jam
FC = FC0 + FA0 (X1-X2)
= 0 + 1.782 x ( 0.800 - 0.141 )
= 1.174164 kmol/jam
= 134.1248 kg/jam
FD = FD0 + FA0 x X2
= 0 + 1.782 x 0.141
= 0.25 kmol/jam
= 42.86 kg/jam
Massa Catalyst = Massa C8H18 = Catalyst Productivity
Massa Catalyst
= 134.125 kg/jam = 6
x
= 22.35413 kg/jam
= 0.228103 kmol/jam
Massa Air = 2.0% x Massa Catalyst
98%
= 2.0% x 22.35413 kg/jam
98%
= 0.456207 kg/jam
= 0.025345 kmol/jam
1. Reaktor
Kondisi Operasi
P = 30 Psia = 2.04 atm
T = 50 ◦F = 10 ◦C

Masuk
Komponen Mr
C3H8 0.346 15.265 0.0227 44.10
i-C4H10 12.475 725.076 0.8171 58.12
C4H8 1.782 100.000 0.1167 56.11
n-C4H10 0.411 23.907 0.0269 58.12
H2O 0.025 0.456 0.0017 18.00
i-C8H18 0.000 0.000 0.0000 114.23
C12H26 0.000 0.000 0.0000 170.34
H2SO4 0.228 22.354 0.0149 98.00
Total 15.269 887.058 1.0000
Keluar
Komponen Mr
C3H8 0.346 15.265 0.025 44.10
i-C4H10 11.050 642.210 0.813 58.12
C4H8 0.105 5.882 0.008 56.11
n-C4H10 0.411 23.907 0.030 58.12
H2O 0.025 0.456 0.002 18.00
i-C8H18 1.174 134.125 0.086 114.23
C12H26 0.252 42.859 0.019 170.34
H2SO4 0.228 22.354 0.017 98.00
Total 13.591 887.058 1.000
2. Decanter
Kondisi Operasi
P = 2 atm
T = 20 ◦C

Masuk
Komponen Mol(kmol/jam) Massa(kg/jam) Fraksi Mol Mr
C3H8 0.346 15.265 0.025 44.10
i-C4H10 11.050 642.210 0.813 58.12
C4H8 0.105 5.882 0.008 56.11
n-C4H10 0.411 23.907 0.030 58.12
H2O 0.025 0.456 0.002 18.00
i-C8H18 1.174 134.125 0.086 114.23
C12H26 0.252 42.859 0.019 170.34
H2SO4 0.228 22.354 0.017 98.00
Total 13.591 887.058 1.000
Tabel 6. Rapat massa masing-masing komponen pada su 20 °C

Komponen ρ (g/ml)
C3H8 0.5013
i-C4H10 0.5586
C4H8 0.5945
n-C4H10 0.5790
H2O 1.0321
i-C8H18 0.6947
C12H26 0.7486
H2SO4 1.8392
Tabel 7.Data kelarutan komponen dalam air pada suh 20 ˚C

Komponen Kelarutan
C3H8 0,007 gr dalam 100 ml air

i-C4H10 tidak larut dalam air
C4H8 tidak larut dalam air
n-C4H10 0,0061 gr dlm 100 ml air
H2O -
i-C8H18 tidak larut dalam air
C12H26 tidak larut dalam air
H2SO4 larut dalam air pada semua perbandingan
Massa C3H8 yang larut dalam air = 0.000064 kg/jam

Massa n-C4H10 yang larut dalam air= 0.0000481 kg/jam

Komponen
C3H8 0.346 15.265 1.445E-06 6.371E-05
i-C4H10 11.050 642.210 0.000 0.000
C4H8 0.105 5.882 0.000 0.000
n-C4H10 0.411 23.907 8.270E-07 4.806E-05
H2O 0.000 0.000 0.0253 0.4562
i-C8H18 1.174 134.125 0.000 0.000
C12H26 0.252 42.859 0.000 0.000
H2SO4 0.000 0.000 0.2281 22.3541
Total 13.338 864.248 0.253 22.810
887.058
3. Menara Distilasi 1 (MD-01)

Fungsi: Untuk memisahkan C3H8
Tabel 9. Umpan masuk dan keluar menara distilasi 1 (MD-01)
Kompon Umpan Masuk Hasil atas Hasil Bawah
Mr (%) (%)
en Kmol/jam Kg/jam Kmol/jam Kg/jam Kmol/jam Kg/jam
C3H8 44.10 0.346 15.265 0.0748 3.3000 0.29203 0.2713 11.965 0.014027
i-C4H10 58.12 11.050 642.210 0.0000 0.00001 0.00000 11.0497 642.210 0.752930
C4H8 56.11 0.105 5.882 0.0000 0.00005 0.00000 0.1048 5.882 0.006896
n-C4H10 58.12 0.411 23.907 0.1376 8.0000 0.70796 0.2737 15.907 0.018650
H2O 18.00 0.000 0.000 0.0000 0.0000 0.00000 0.0000 0.000 0.000000
i-C8H18 114.23 1.174 134.125 0.0000 0.0000 0.00000 1.1742 134.125 0.157249
C12H26 170.34 0.252 42.859 0.0000 0.0000 0.00000 0.2516 42.859 0.050248
H2SO4 98.00 0.000 0.000 0.0000 0.0000 0.00000 0.0000 0.000 0.000000
Total 13.338 864.248 0.2125 11.300 1.00000 13.1253 852.948 1.00000
864.248
Fungsi: Untuk recycle i-C4h10 dan C4H8 hasil atas

Mr (%) (%)
C3H8 44.10 0.2713 11.965 0.2713 11.965 0.01783 0.0000 0.000 0.000000
i-C4H10 58.12 11.0497 642.210 11.0496 642.200 0.95702 0.0002 0.010 0.000055
C4H8 56.11 0.1048 5.882 0.1048 5.880 0.00876 0.0000 0.002 0.000013
n-C4H10 58.12 0.2737 15.907 0.1893 11.000 0.01639 0.0844 4.907 0.026977
H2O 18.00 0.0000 0.000 0.0000 0.000 0.00000 0.0000 0.000 0.000000
i-C8H18 114.23 1.1742 134.125 0.0000 0.000 0.00000 1.1742 134.125 0.737343
C12H26 170.34 0.2516 42.859 0.0000 0.000 0.00000 0.2516 42.859 0.235613
H2SO4 98.00 0.0000 0.000 0.0000 0.000 0.00000 0.0000 0.000 0.000000
Total 13.1253 852.948 11.6149 671.045 1.00000 1.510 181.903 100.00%
852.948

Fungsi : Untuk mendapatkan kemurnian i-C8H18 96.88%

Mr (%) (%)
C3H8 44.10 0.000 0.000 0.0000 0.000 0.00000 0.00000000 0.0000 0.000000
i-C4H10 58.12 0.000 0.010 0.0002 0.010 0.00007 0.00000000 0.0000 0.000000
C4H8 56.11 0.000 0.002 0.0000 0.002 0.00002 0.00000000 0.0000 0.000000
n-C4H10 58.12 0.084 4.907 0.0740 4.300 0.03106 0.01044704 0.6072 0.013969
H2O 18.00 0.000 0.000 0.0000 0.000 0.00000 0.00000000 0.0000 0.000000
i-C8H18 114.23 1.174 134.125 1.1741 134.120 0.96881 0.00004181 0.0048 0.000110
C12H26 170.34 0.252 42.859 0.0000 0.005 0.00004 0.25157726 42.8537 0.985921
H2SO4 98.00 0.000 0.000 0.0000 0.000 0.00000 0.00000000 0.0000 0.000000
Total 1.510 181.903 1.2483 138.437 1.00000 0.26206611 43.466 1.000000
181.903
Komponen umpan masuk reaktor tanpa katalis = 864.248 kg/jam

Komponen umpan masuk recycle = 671.045 kg/jam
Tabel 12. Komponen Recycle
Recycle
Komponen
Kg/jam Kmol/jam Fraksi massa BM
C3H8 11.965 0.271 0.0178 44.100
i-C4H10 642.200 11.050 0.9570 58.120
C4H8 5.880 0.105 0.0088 56.110
n-C4H10 11.000 0.189 0.0164 58.120
Total 671.045 11.615 1.0000
Recycle = 80% = 536.836 Kg/jam
Purging = 20% = 134.209 Kg/jam
Tabel 13. Komponen Recycle dan Purging

Recycle Purging
Komponen
Kg/jam Kmol/jam Kg/jam Kmol/jam
C3H8 9.571751 0.217 2.3929 0.054
i-C4H10 503.525000 8.664 128.4400 2.210
C4H8 7.604000 0.136 1.1760 0.021
n-C4H10 16.135249 0.278 2.2000 0.038
Total 536.836 9.294 134.2089 2.323
Umpan segar baru = Umpan masuk reaktor - Recycle

= 864.248 Kg/jam - 536.836 Kg/jam
= 327.412 Kg/jam
Komponen i-C4H10 = 95%

Impurity C3H8 = 2%
n-C4H10 = 3%
Tabel 14. Komponen Umpan segar baru Isobutana

Komponen Kg/jam Kmol/jam Koreksi
Komponen
C3H8 5.6930 0.129 2.43%
i-C4H10 221.5507 3.812 94.58%
n-C4H10 6.9963 0.120 2.99%
Total 234.2401 4.061 100.00%
Komponen C4H8 = 99%

Impurity n-C4H10 = 1%
Tabel 15. Komponen Umpan Segar Baru Butena

Koreksi
Komponen Kg/jam Kmol/jam
Komponen
C4H8 92.3960 1.647 99.00%
n-C4H10 0.9333 0.016 1.00%
Total 93.3293 1.663 100.00%
Tabel 16. Umpan masuk reaktor mula-mula

Masuk %
Komponen Mr
C3H8 0.346 15.265 0.0227 44.10 0.017
i-C4H10 12.475 725.076 0.8171 58.12 0.817
C4H8 1.782 100.000 0.1167 56.11 0.113
n-C4H10 0.411 23.907 0.0269 58.12 0.027
H2O 0.025 0.456 0.0017 18.00 0.001
i-C8H18 0.000 0.000 0.0000 114.23 0.000
C12H26 0.000 0.000 0.0000 170.34 0.000
H2SO4 0.228 22.354 0.0149 98.00 0.025
Total 15.269 887.058 1.0000 1.000
Tabel 17. Umpan masuk setelah recycle

Umpan Recycle Umpan Fresh Feed Umpan Masuk Baru
Komponen %
Kg/jam Kmol/jam Kg/jam Kmol/jam Kg/jam Kmol/jam
C3H8 9.571751 0.217 5.6930 0.129 15.265 0.346 0.017
i-C4H10 503.525000 8.664 221.5507 3.812 725.076 12.475 0.817
C4H8 7.604000 0.136 92.3960 1.647 100.000 1.782 0.113
n-C4H10 16.135249 0.278 7.9296 0.136 24.065 0.414 0.027
H2O 0.000000 0.000 0.4562 0.025 0.456 0.025 0.001
i-C8H18 0.000000 0.000 0.0000 0.000 0.000 0.000 0.000
C12H26 0.000000 0.000 0.0000 0.000 0.000 0.000 0.000
H2SO4 0.000000 0.000 22.3541 0.228 22.354 0.228 0.025
Total 536.836000 9.294 350.3797 5.978 887.216 15.271 1.000
MENENTUKAN FAKTOR PENGALI
Kapasitas produksi 50000 ton/tahun

Faktor Pengali = (Kapasitas x 1000:330 hari x 24 jam)/mol product
Faktor Pengali = 45.603

Umpan masuk reaktor berdasarkan kapasitas
Massa C4H8 masuk reaktor = Faktor pengali x Massa C4H8 masuk reaktor
= 45.603 x 100 kg/jam
= 4560.28 kg/jam
Massa i-C4H10 masuk reaktor = Faktor pengali x Massa i C4H10 masuk reaktor
= 45.603 x 725.0757 kg/jam
= 33065.5 kg/jam
Jika Kapasitas 50.000 ton/tahun maka produksi 2,2,4 Trimethilpentane per jam=6313.131 kg/jam
Tabel 18. Berat

Mrmolekul tiap komponen
Kompon (kg/kmol
en )
C3H8 44.10
i-C4H10 58.12
C4H8 56.11
n-C4H10 58.12
H2O 18.00
i-C8H18 114.23
C12H26 170.34
H2SO4 98.00
1. Reaktor
Umpan Masuk C4H8 = C4H8 masuk reaktor x Faktor pengali
= 100.000 Kg/jam x 45.603
= 4560.2841 Kg/jam
= 81.2740 Kmol/jam
Impuritis = n-C4H10 = 1%
Massa n-C4H10 = 46.0635 kg/jam
Mol n-C4H10 = 0.7926 kmol/jam
Umpan masuk i-C4H10 = i-C4H10 masuk reaktor x Faktor Pengali

= 725.076 Kg/jam x 45.603
= 33065.514 Kg/jam
= 568.918 Kmol/jam
Kemurnian i-C4H10 = 95%
Impuritis = C3H8 = 2%
n-C4H10 = 3%
Massa C3H8 = 696.1161 kg/jam
= 15.7849 kmol/jam
Massa n-C4H10 = 1044.1741 kg./jam
= 17.9658 kmol/jam
R1𝐻_(8 )+ 〖𝑖−𝐶〗 _4 𝐻_10 → 〖𝑖−𝐶〗 _8 𝐻_18

𝐶_4
A + B → C
R−2 𝐶〗 _8 𝐻_18+ 𝐶_4 𝐻_8 → 𝐶_12 𝐻_26
〖𝑖
C + A D
i-C8H18 FC0 +FA0.X1 - FA0.X2 FC= FC0 + FA0(X1-X2)
C12H26 FD0 +FA0.X2 FD = FD0 + FA0.X2
C3H8 - - -
n-C4H10 - - -
H2SO4 - - -
H2O - - -
X1= 80% = 0.8000 Selectivity= 85%
X2= 14% = 0.141
FA = FA0 x (1-X1-X2)
= 81.274 x (1- 0.8 - 0.141 )
= 4.780823 kmol/jam
= 268.252 kg/jam
FB = FB0 - (FA0 x X1)
= 568.918 - ( 81.274 x 0.8 )
= 503.8988 kmol/jam
= 29286.6 kg/jam
FC = FC0 + FA0 (X1-X2)
= 0 + 81.274 x ( 0.800 - 0.141 )
= 53.54522 kmol/jam
= 6116.471 kg/jam
FD = FD0 + FA0 x X2
= 0 + 81.274 x 0.141
= 11.474 kmol/jam
= 1954 kg/jam
Massa Catalyst
= 6116.471 kg/jam = 6
x
= 1019.412 kg/jam
= 10.40216 kmol/jam
98%
= 2.0% x 1019.41180 kg/jam
98%
= 20.80432 kg/jam
= 1.155796 kmol/jam
NERACA MASSA SESUAI KAPASITAS
1. Reaktor
Kondisi Operasi
P = 30 Psia = 2.04 atm
T = 50 ◦F = 10 ◦C
Tabel 20. Umpan masuk reaktor berdasarkan kapasitas

Kompon Masuk Keluar
%
en Kmol/jam Kg/jam Kmol/jam Kg/jam
C3H8 15.7849 696.1161 15.7849 696.1161 1.7%
i-C4H10 568.9180 33065.5137 503.8988 29286.5979 81.7%
C4H8 81.2740 4560.2841 4.7808 268.2520 11.3%
n-C4H10 18.7584 1090.2376 18.7584 1090.2376 2.7%
H2O 1.1558 20.8043 1.1558 20.8043 0.1%
i-C8H18 0.0000 0.0000 53.5452 6116.4708 0.0%
C12H26 0.0000 0.0000 11.4740 1954.4771 0.0%
H2SO4 10.4022 1019.4118 10.4022 1019.4118 2.5%
Total 696.2933 40452.3676 619.8001 40452.3676 100.0%
2. Dekanter
Kondisi Operasi
P = 2 atm
T = 20 ◦C
Massa C3H8 yang larut dalam air = 0.00290519 kg/jam
Massa n-C4H10 yang larut dalam air = 0.00219187 kg/jam
Tabel 21. Komponen masuk dan keluar decanter berdasarkan kapasitas

Kompon Masuk Fase ringan Fase Berat
C3H8 15.7849 696.1161 15.7849 696.1132 0.00006588 0.0029
i-C4H10 503.8988 29286.5979 503.8988 29286.5979 0.00000000 0.0000
C4H8 4.7808 268.2520 4.7808 268.2520 0.00000000 0.0000
n-C4H10 18.7584 1090.2376 18.7584 1090.2354 0.00003771 0.0022
H2O 1.1558 20.8043 0.0000 0.0000 1.15579569 20.8043
i-C8H18 53.5452 6116.4708 53.5452 6116.4708 0.00000000 0.0000
C12H26 11.4740 1954.4771 11.4740 1954.4771 0.00000000 0.0000
H2SO4 10.4022 1019.4118 0.0000 0.0000 10.4021612 1019.4118
Total 619.8001 40452.3676 608.2420 39412.1464 11.5580605 1040.2212
40452.3676

Fungsi: Untuk memisahkan C3H8
Tabel 22. Umpan masuk (MD-01) berdasarkan kapasitas

Kompon Masuk Hasil atas Hasil bawah
C3H8 15.785 696.1132 3.412 150.4894 12.3724 545.6238
i-C4H10 503.899 29286.5979 0.000 0.0005 503.8988 29286.5974
C4H8 4.781 268.2520 0.000 0.0023 4.7808 268.2497
n-C4H10 18.758 1090.2354 6.277 364.8227 12.4813 725.4127
H2O 0.000 0.0000 0.000 0.0000 0.0000 0.0000
i-C8H18 53.545 6116.4708 0.000 0.0000 53.5452 6116.4708
C12H26 11.474 1954.4771 0.000 0.0000 11.4740 1954.4771
H2SO4 0.000 0.0000 0.000 0.0000 0.0000 0.0000
Total 608.242 39412.1464 9.690 515.3148 598.5525 38896.8316
39412.1464

Fungsi: Untuk recycle i-C4h10 dan C4H8 hasil atas
Tabel 23. Umpan masuk dan keluar (MD-02) berdasarkan kapasitas

C3H8 12.3724 545.6238 12.3724 545.6238 0.0000 0.0000
i-C4H10 503.8988 29286.5974 503.8910 29286.1444 0.0078 0.4531
C4H8 4.7808 268.2497 4.7789 268.1447 0.0019 0.1050
n-C4H10 12.4813 725.4127 8.6310 501.6312 3.8503 223.7814
H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
i-C8H18 53.5452 6116.4708 0.0000 0.0000 53.5452 6116.4708
C12H26 11.4740 1954.4771 0.0000 0.0000 11.4740 1954.4771
H2SO4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Total 598.5525 38896.8316 529.6733 30601.5441 68.8792 8295.2874
38896.8316

Fungsi : Untuk mendapatkan kemurnian i-C8H18 97%
Tabel 24. Umpan masuk dan keluar (MD-03) berdasarkan kapasitas

C3H8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
i-C4H10 0.0078 0.4531 0.0078 0.4531 0.0000 0.0000
C4H8 0.0019 0.1050 0.0019 0.1050 0.0000 0.0000
n-C4H10 3.8503 223.7814 3.3739 196.0922 0.4764 27.6892
H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
i-C8H18 53.5452 6116.4708 53.5433 6116.2530 0.0019 0.2178
C12H26 11.4740 1954.4771 0.0013 0.2280 11.4726 1954.2491
H2SO4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Total 68.8792 8295.2874 56.9282 6313.1313 11.9510 1982.1561
8295.2874
Komponen umpan masuk reaktor tanpa katalis = 39412.151 kg/jam

Komponen umpan masuk recycle = 30601.544 kg/jam
Tabel 25. Komponen Recycle
Recycle
Komponen
Kg/jam Kmol/jam Fraksi massa BM
C3H8 545.624 12.372 0.0178 44.100
i-C4H10 29286.144 503.891 0.9570 58.120
C4H8 268.145 4.779 0.0088 56.110
n-C4H10 501.631 8.631 0.0164 58.120
Total 30601.544 529.673 1.0000
Recycle = 80% = 24481.2 Kg/jam
Purging = 20% = 6120.31 Kg/jam
Tabel 26. Komponen Recycle dan Purging

Recycle Purging
Komponen
Kg/jam Kmol/jam Kg/jam Kmol/jam
C3H8 436.4990 9.898 109.1248 2.474
i-C4H10 22962.1704 395.082 5857.2289 100.778
C4H8 346.7640 6.180 53.6289 0.956
n-C4H10 735.8132 12.660 100.3262 1.726
Total 24481.2 423.820 6120.31 105.935
Umpan segar baru = Umpan masuk reaktor - Recycle
= 39412.151 Kg/jam - 24481.235 Kg/jam
= 14930.916 Kg/jam
Komponen i-C4H10 = 95%

Impurity C3H8 = 2%
n-C4H10 = 3%
Tabel 27. Komponen Umpan segar baru Isobutana

Komponen Kg/jam Koreksi
Kmol/jam
Komponen
C3H8 259.6170 5.887 2.43%
i-C4H10 10103.3433 173.836 94.58%
n-C4H10 319.0529 5.490 2.99%
Total 10682.0133 185.212 100.00%
Komponen C4H8 = 99%
Impurity n-C4H10 = 1%
Tabel 28. Komponen Umpan Segar Baru Butena

Koreksi
Komponen Kg/jam Kmol/jam
Komponen
C4H8 4213.5201 75.094 99.00%
n-C4H10 42.5608 0.732 1.00%
Total 4256.0809 75.826 100.00%
Tabel 29. Umpan masuk reaktor mula-mula

Masuk %
Komponen Mr
C3H8 15.785 696.116 0.0227 44.10 0.017
i-C4H10 568.918 33065.514 0.8171 58.12 0.817
C4H8 81.274 4560.284 0.1167 56.11 0.113
n-C4H10 18.758 1090.238 0.0269 58.12 0.027
H2O 1.156 20.804 0.0017 18.00 0.001
i-C8H18 0.000 0.000 0.0000 114.23 0.000
C12H26 0.000 0.000 0.0000 170.34 0.000
H2SO4 10.402 1019.412 0.0149 98.00 0.025
Total 696.293 40452.368 1.0000 1.000
Tabel 30. Umpan masuk setelah recycle

Umpan Recycle Umpan Fresh Feed Umpan Masuk Baru
Komponen %
Kg/jam Kmol/jam Kg/jam Kmol/jam Kg/jam Kmol/jam
C3H8 436.4990 9.898 259.6170 5.887 696.1161 15.785 0.017
i-C4H10 22962.1704 395.082 10103.3433 173.836 33065.5137 568.918 0.817
C4H8 346.7640 6.180 4213.5201 75.094 4560.2841 81.274 0.113
n-C4H10 735.8132 12.660 361.6138 6.222 1097.4269 18.882 0.027
H2O 0.0000 0.000 20.8043 1.156 20.8043 1.156 0.001
i-C8H18 0.0000 0.000 0.0000 0.000 0.0000 0.000 0.000
C12H26 0.0000 0.000 0.0000 0.000 0.0000 0.000 0.000
H2SO4 0.0000 0.000 1019.4118 10.402 1019.4118 10.402 0.025
Total 24481.2467 423.820 15978.3103 272.597 40459.5570 696.417 1.00
CEK BALANCE ATAU TIDAK
Umpan Masuk
Tabel 31. Masuk umpan 1 (i-C4H10)
Komponen % kg/jam
i-C4H10 95% 33065.514
C3H8 2% 696.116
n-C4H10 3% 1044.174
Total 34805.804
Tabel 32.Masuk umpan 2 (n-C4H8)
Komponen % kg/jam
n-C4H8 99% 4560.284
n-C4H10 1% 46.063
Total 4606.348
Tabel 33. Masuk umpan 3 (H2SO4)

Komponen % kg/jam
H2SO4 98% 1019.412
H20 2% 20.804
Total 1040.216
Total Umpan Masuk

Umpan i-C4H10 + Umpan n-C4H10 + Umpan H2SO4
34805.804 kg/jam + 4606.348 kg/jam + 1040.216 kg/jam
40452.368 kg/jam
Umpan Keluar
Tabel 34. Hasil Atas MD 1 Tabel 35. Hasil Atas MD 3 Tabel 36. Hasil Bawah MD 3
Komponen kg/jam Komponen kg/jam Komponen kg/jam
C3H8 150.4894 C3H8 0.0000 C3H8 0.0000
i-C4H10 0.0005 i-C4H10 0.4531 i-C4H10 0.0000
C4H8 0.0023 C4H8 0.1050 C4H8 0.0000
n-C4H10 364.8227 n-C4H10 196.0922 n-C4H10 27.6892
H2O 0.0000 H2O 0.0000 H2O 0.0000
i-C8H18 0.0000 i-C8H18 6116.2530 i-C8H18 0.2178
C12H26 0.0000 C12H26 0.2280 C12H26 1954.2491
H2SO4 0.0000 H2SO4 0.0000 H2SO4 0.0000
Total 515.3148 Total 6313.1313 Total 1982.1561
Tabel 37. Hasil Atas MD 2 Tabel 38. Fraksi Berat Dekanter

Komponen kg/jam Komponen kg/jam
C3H8 545.6238 C3H8 0.0029
i-C4H10 29286.1444 i-C4H10 0.0000
C4H8 268.1447 C4H8 0.0000
n-C4H10 501.6312 n-C4H10 0.0022
H2O 0.0000 H2O 20.8043
i-C8H18 0.0000 i-C8H18 0.0000
C12H26 0.0000 C12H26 0.0000
H2SO4 0.0000 H2SO4 1019.4118
Total 30601.5441 Total 1040.22122
Total Umpan Keluar
Hasil Atas MD 1 + Hasil Atas MD 2 + Hasil Atas MD 3+ Hasil Bawah MD 3
+ Fraksi Berat dekanter
515.315 kg/jam + 30601.544 kg/jam + 6313.131 kg/jam
+ 1982.156 kg/jam + 1040.221 kg/jam
40452.368 kg/jam
NERACA MASSA REAKTOR 1
Konversi pada R1 = X1= 56% = 0.5575 Selectivity= 85%

X2= 10% = 0.098
Basis = 100 kg/jam
Rasio mol = i-C4H10 : C4 H 8
7 1
Konversi (XA) = 80.0% terhadap C4H8
Umpan C4H8 masuk reaktor = 100 kg/jam
Umpan i-C4H10 masuk reaktor = 7 x massa Butena

1
= 7 x 1.782 kmol/jam
1
= 725.0757 kg/jam
Umpan C3H8 masuk reaktor = 2.0% x massa i-C4H10

95%
= 2.0% x 725.076 kg/jam
95%
= 15.265 kg/jam
= 0.346 kmol/jam
Umpan n-C4H10 masuk reaktor = 3.0% x massa i-C4H10

95%
= 3.0% x 725.076 kg/jam
95%
= 22.89713 kg/jam
= 0.393963 kmol/jam
Umpan n-C4H10 masuk reaktor = 1% massa C4H8

x
99%
= 1% 100 kg/jam
x
99%
= 1.010101 kg/jam
= 0.01738 kmol/jam
R1𝐻_(8 )+ 〖𝑖−𝐶〗 _4 𝐻_10 → 〖𝑖−𝐶〗 _8 𝐻_18
𝐶_4
A + B → C
R−2 𝐶〗 _8 𝐻_18+ 𝐶_4 𝐻_8 → 𝐶_12 𝐻_26
〖𝑖
C + A D
C4H8 FC0 +FA0.X1 - FA0.X2 FC= FC0 + FA0(X1-X2)
n-C4H10 FD0 +FA0.X2 FD = FD0 + FA0.X2
H2O - - -
i-C8H18 - - -
C12H26 - - -
H2SO4 - - -
X1= 56% = 0.5575 Selectivity= 85%
X2= 10% = 0.098
FA = FA0 x (1-X1-X2)
= 1.782 x (1- 0.558 - 0.098 )
= 0.613291 kmol/jam
= 34.412 kg/jam
FB = FB0 - (FA0 x X1)
= 12.475 - ( 1.782 x 0.558 )
= 11.48191 kmol/jam
= 667.3286 kg/jam
FC = FC0 + FA0 (X1-X2)
= 0 + 1.782 x ( 0.558 - 0.098 )
= 0.818246 kmol/jam
= 93.4682 kg/jam
FD = FD0 + FA0 x X2
= 0 + 1.782 x 0.098
= 0.18 kmol/jam
= 29.87 kg/jam
Massa Catalyst
= 93.468 kg/jam = 6
x
= 15.57803 kg/jam
= 0.15896 kmol/jam
98%
= 2.0% x 15.57803 kg/jam
98%
= 0.317919 kg/jam
= 0.017662 kmol/jam

Masuk
Komponen Mr
C3H8 0.346 15.265 0.0227 44.10
i-C4H10 12.475 725.076 0.8171 58.12
C4H8 1.782 100.000 0.1167 56.11
n-C4H10 0.411 23.907 0.0269 58.12
H2O 0.025 0.456 0.0017 18.00
i-C8H18 0.000 0.000 0.0000 114.23
C12H26 0.000 0.000 0.0000 170.34
H2SO4 0.228 22.354 0.0149 98.00
Total 15.269 887.058 1.0000

Keluar
Komponen Mr
C3H8 0.346 15.265 0.025 44.10
i-C4H10 11.482 667.329 0.814 58.12
C4H8 0.613 34.412 0.043 56.11
n-C4H10 0.411 23.907 0.029 58.12
H2O 0.025 0.456 0.002 18.00
i-C8H18 0.818 93.468 0.058 114.23
C12H26 0.175 29.867 0.012 170.34
H2SO4 0.228 22.354 0.016 98.00
Total 14.100 887.058 1.000
NERACA MASSA REAKTOR 1 SESUAI KAPASITAS

Masuk
Komponen Mr
C3H8 15.785 696.116 0.0227 44.10
i-C4H10 568.918 33065.514 0.8171 58.12
C4H8 81.274 4560.284 0.1167 56.11
n-C4H10 18.758 1090.238 0.0269 58.12
H2O 1.156 20.804 0.0017 18.00
i-C8H18 0.000 0.000 0.0000 114.23
C12H26 0.000 0.000 0.0000 170.34
H2SO4 10.402 1019.412 0.0149 98.00
Total 696.293 40452.368 1.0000

Keluar
Komponen Mr
C3H8 15.785 696.116 0.025 44.10
i-C4H10 523.608 30432.082 0.814 58.12
C4H8 27.968 1569.274 0.043 56.11
n-C4H10 18.758 1090.238 0.029 58.12
H2O 1.156 20.804 0.002 18.00
i-C8H18 37.314 4262.416 0.058 114.23
C12H26 7.996 1362.026 0.012 170.34
H2SO4 10.402 1019.412 0.016 98.00
Total 642.987 40452.368 1.000
Komponen Masuk (kg/jam) Keluar (kg/jam)

C3H8 696.116 696.116
i-C4H10 33065.514 30432.082
C4H8 4560.284 1569.274
n-C4H10 1090.238 1090.238
H2O 20.804 20.804
i-C8H18 0.000 4262.416
C12H26 0.000 1362.026
H2SO4 1019.412 1019.412
Total 40452.368 40452.368
Komponen Masuk (kg/jam) Keluar (kg/jam)

C3H8 696.116 696.1161
i-C4H10 30432.082 29286.5979
C4H8 1569.274 268.2520
n-C4H10 1090.238 1090.2376
H2O 20.804 20.8043
i-C8H18 4262.416 6116.4708
C12H26 1362.026 1954.4771
H2SO4 1019.412 1019.4118
Total 40452.368 40452.368
Kg/jam
Total Umpan keluar

Kg/jam
515.3148 + = 99%
515.3148 = 1%
Umpan masuk reaktor tanpaKmol/jam

Umpan masuk reaktor -68.1731
-0.6648
Fresh feed -68.8379
### Kg/jam
Kg/jam
Umpan C4H8 = ###= 95%
Kemurnian C4H8 = 2%
Impurities n-C4H10 = 3%
Tabel 18. C4H8 recycle Kmol/jam

KomponenKg/jam -460.708037
C4H8 ### -12.7826
n-C4H10 ### -14.5487
Total ### -488.039312
Umpan i-C4H10= ###

Kemurnian i-C4H10
Impurities C3H8
Impurities n-C4H10 Kg/jam
Tabel 19. i-C4H10 recycle -563.7127
KomponenKg/jam 2509.7933
i-C4H10 ### -3557.0483
C3H8 ### -382.5760
n-C4H10 ### 0.0000
Total ### 0.0000
0.0000
0.0000
Tabel 20. Massa Fresh feed -1993.5437
Kompon Masuk
Mr
en Kmol/jam
C3H8 44.10 ###
i-C4H10 58.12 ###
C4H8 56.11 ###
n-C4H10 58.12 ###
H2O 18.00 ###
i-C8H18 114.23 ###
C12H26 170.34 ###
H2SO4 58.00 ###
Total ###
FEED
Tabel 21. Feed masing-masing komponen

kg/jam kg/jam
Komponen
C3H8 ###
i-C4H10 ###
C4H8 ### recycle
n-C4H10 ###
H2O 21 29286.144
i-C8H18 0 501.631
C12H26 0 29787.776
H2SO4 ### -29748.2129
total ###
Fresh feed = ###
recycle
Tabel 22. Komponen masuk 268.145
kg/jam #REF!
Komponen
fresh feed
C3H8 ###
i-C4H10 ###
n-C4H10 ###
total ### kmol/jam % massa
Fresh feed-recycle = 15.7849 #REF!
Tabel 23. komponen C4H8 a568.9180 #REF!
kg/jam 81.2740 #REF!
komponen
fresh feed 18.7584 #REF!
C4H8 ### 1.1558 #REF!
Fresh feed-recycle = 0.0000 #REF!
0.0000 #REF!
10.4022 #REF!
Umpan masuk reaktor sebe 696.2933 #REF!
KomponenKg/jam
C3H8 ### Kmol.jam %massa
i-C4H10 ### 12.3724 2.34%
C4H8 ### 503.8910 95.13%
n-C4H10 ### 4.7789 0.90%
H2O ### 8.6310 1.63%
i-C8H18 ### 0.0000 0.00%
C12H26 ### 0.0000 0.00%
H2SO4 ### 0.0000 0.00%
TOTAL ### 0.0000 0.00%
529.6733 100.00%
Umpan Recycle
KomponenKg/jam
C3H8 ### Kmol/jam %massa BM
i-C4H10 ### 3.412523353 #REF! 44.10
C4H8 ### 65.02700214 #REF! 58.12
n-C4H10 ### 76.49508782 #REF! 56.11
H2O ### 10.12743194 #REF! 58.12
i-C8H18 ### 1.155795693 #REF! 18.00
C12H26 ### 0 #REF! 114.23
H2SO4 ### 0 #REF! 170.34
TOTAL ### 10.40216123 #REF! 98.00
166.6200022 #REF!
Umpan fresh feed
KomponenKg/jam
C3H8 ###
i-C4H10 ### Kmol/jam %massa
C4H8 ### 3% 7148.38329402802
n-C4H10 ### 77% 225.738419811
H2O ### 11%
i-C8H18 ### 91.27%
C12H26 ###
H2SO4 ### ###
TOTAL ### Kmol/jam %massa
#DIV/0!
#DIV/0!
Umpan fresh feed i-C4H1 #DIV/0!
KomponenKg/jam
C3H8 ###
i-C4H10 ###
n-C4H10 ###
TOTAL ###
Umpan fresh feed C4H8

KomponenKg/jam
C4H8 ###
n-C4H10 ###
TOTAL ###
+ Recycle (Decanter +MD 2)

Masuk Keluar
Kmol/jam Kg/jam Kmol/jam Kg/jam
12.7185627 560.88861
516.3664851 ###
6.561124648 368.14470
9.042300874 525.53853
0.050689636 0.91241
0 0.00000
0 0.00000
Neraca Massa recycle0.456206721 44.70826
Feed = Jumlah U 545.1953697 ###
Komponen Mr
C3H8 44.100
i-C4H10 58.120
C4H8 56.110
n-C4H10 58.120
H2O 18.000
i-C8H18 114.230
C12H26 170.340
H2SO4 98.000
Total
(Lk: C3H8
(Hk: i-C4H10
Neraca Massa Sesuai Kapasitas
85.314%
= 0.048% x mol umpan C3H8

= 0.048% x 0.105 kmol/jam
= 0.000
= ### kg/jam
1. Kondisi operasi
a. Komponen kunci
Komponen kunci ringan
komponen kunci berat
b.Recovery
Dirancang recovery komponen kunci i-C8H18
komponen kunci ringan yg terpungut sebagai hasil atas

c3### #REF!
ic4### #REF!
c4### #REF!
ic4### ic4### #REF!
c4### c4 80 #REF!
nc4### nc4### #REF!

ic8### ic8 68 #REF!
c12### ### #REF!
tota
###
c4######
nc4######
c8######
c12######
######
0###
0.957015
c4 7 0.0011
nc4### 0.0249
c4### c8### 0.9739
nc4### c12 0 0.0001
c8### ### 100.00%
c12###
### nc4######
c8######
c12######
327.5694
setelah
C3H8 -563.7
i-C4H10 2509.8
C4H8 -3557.0
n-C4H10 -382.6
H2O 1.2
i-C8H18 0.0
C12H26 0.0
H2SO4 10.4
-1982.0
Keluar (kg/jam)
Komponen Masuk (kg/jam)
Fasa ringan Fasa Berat
C3H8 696.1161 696.1132 0.0029
i-C4H10 29286.5979 29286.5979 0.0000
C4H8 268.2520 268.2520 0.0000
n-C4H10 1090.2376 1090.2354 0.0022
H2O 20.8043 0.0000 20.8043
i-C8H18 6116.4708 6116.4708 0.0000
C12H26 1954.4771 1954.4771 0.0000
H2SO4 1019.4118 0.0000 1019.4118
Total 40452.3676 40452.3676
ic4### #REF!
c4### #REF!
Keluar (kg/jam)
Hasil Atas Hasil Bawah
C3H8 696.1132 150.4894 545.6238
i-C4H10 29286.5979 0.0005 29286.5974
C4H8 268.2520 0.0023 268.2497
n-C4H10 1090.2354 364.8227 725.4127
H2O 0.0000 0.0000 0.0000
i-C8H18 6116.4708 0.0000 6116.4708
C12H26 1954.4771 0.0000 1954.4771
H2SO4 0.0000 0.0000 0.0000
515.3148 38896.8316
Total 39412.1464
39412.1464
ic4### ic4### #REF!

c4### c4 80 #REF!
Keluar (kg/jam)
C3H8 545.6238 545.6238 0.0000
i-C4H10 29286.5974 29286.1444 0.4531
C4H8 268.2497 268.1447 0.1050
n-C4H10 725.4127 501.6312 223.7814
H2O 0.0000 0.0000 0.0000
i-C8H18 6116.4708 0.0000 6116.4708
C12H26 1954.4771 0.0000 1954.4771
H2SO4 0.0000 0.0000 0.0000
30601.5441 8295.2874
Total 38896.8316
38896.8316
Keluar (kg/jam)
C3H8 0.0000 0.0000 0.0000
i-C4H10 0.4531 0.4531 0.0000
C4H8 0.1050 0.1050 0.0000
n-C4H10 223.7814 196.0922 27.6892
H2O 0.0000 0.0000 0.0000
i-C8H18 6116.4708 6116.2530 0.2178
C12H26 1954.4771 0.2280 1954.2491
H2SO4 0.0000 0.0000 0.0000
6313.1313 1982.1561
Total 8295.2874
8295.2874
0.969
14938.0942
+
NERACA MASSA PABRIK ETIL AKRILAT DARI ASAM AKRILAT DAN ETANOL

Kecepatan produksi 3787.87878788 kg/jam
NERACA MASSA BASIS 100 KMOL/JAM CH2=CHCOOH
REAKTOR
C3 H 4 O 2 + C 2 H 6 O C 5H8O2 + H 2O
Perbandingan reaktan masuk reaktor

CH2=CHCOOH : C2H5OH = 1 : 1.5
Kemurnian CH2=CHCOOH = 99.7% : 0.30%
Kemurnian C2H5OH = 97.00% : 3.00%
Komponen BM Kmol/Jam Kg/Jam % massa

C3H4O2 72.06 100.0000 7206.0000 0.5021
C2H6O 46.07 150.0000 6910.5000 0.4815
H2O 18.015 13.0674 235.4099 0.0164
Total 263.0674 14351.9099 1.0000
H2SO4 98% YANG DIGUNAKAN 8% DARI MASSA REAKSI TOTAL

Massa H2SO4 98% = 8% x massa total masuk
= 8% x 14388,8229 kg/jam
= 1148.1528 kg/jam
Massa H2SO4 = 98% x massa H2SO4 98%
= 98% x 1151,1058 kg/jam
= 1125.1897 kg/jam
Massa H2O dalam H2SO4 = Massa H2SO4 98% - Massa H2SO4
= (1151,1058 - 1128,0837) kg/jam
= 22.9631 kg/jam
2. Total Umpan Masuk Reaktor

Komponen BM Kmol/Jam Kg/Jam Fraksi Massa
C3H4O2 72.06 100.0000 7206.0000 0.4649
C2H6O 46.07 150.0000 6910.5000 0.4458
H2O 18.015 14.3421 258.3729 0.0167
H2SO4 98.0734 11.4729 1125.1897 0.0726
Total 275.8150 15500.0626 1.0000
Konversi X= 90% ; LR: C3H4O2

C3 H 4 O 2 C2 H 6 O C5 H 8 O 2
M 100 150 0
R 90 90 90
S 10 60 90
3. Komponen Hasil Reaksi

C3H4O2 72.06 10.0000 720.6000 0.0465
C2H6O 46.07 60.0000 2764.2000 0.1783
H2O 18.015 104.3421 1879.7229 0.1213
H2SO4 98.0734 11.4729 1125.1897 0.0726
C5H8O2 100.12 90.0000 9010.8000 0.5813
Total 275.8150 15500.5126 1.0000
NEUTRALIZER
DIGUNAKAN NAOH 48%
Reaksi Netralisasi :
1) C3 H 4 O 2 NaOH C2H3COONa
M 10.0000 10.0000 0.0000
R 10.0000 10.0000 10.0000
S 0.0000 0.0000 10.0000
2) H2SO4 2NaOH Na2SO4

M 11.4729 22.9459 0.0000
R 11.4729 22.9459 11.4729
S 0.0000 0.0000 11.4729
1. Umpan masuk Netralizer

C3H4O2 72.06 10.0000 720.6 0.0395
C2H6O 46.07 60.0000 2764.2 0.1515
H2O 18.015 183.5844 3307.2738 0.1813
H2SO4 98.0734 11.4729 1125.1897 0.0617
C5H8O2 100.12 90.0000 9010.8 0.4939
NaOH 39.9971 32.9459 1317.7392 0.0722
Total 388.0032 18245.8027 1.0000
2. Hasil Netralisasi
C3H4O2 72.06 0.0000 0.0000 0.0000
C2H6O 46.07 60.0000 2764.2000 0.1515
H2O 18.015 216.5303 3900.7936 0.2138
H2SO4 98.0734 0.0000 0.0000 0.0000
C5H8O2 100.12 90.0000 9010.8000 0.4939
NaOH 39.9971 0.0000 0.0000 0.0000
C2H3COONa 94.04 10.0000 940.4000 0.0515
Na2SO4 142.04 11.4729 1629.6157 0.0893
Total 388.0032 18245.8093 1.0000
DEKANTER
1. Umpan Masuk Dekanter

Komponen BM Kmol/Jam Kg/Jam
C2H6O 46.07 60.0000 2764.2000
H2O 18.015 216.5303 3900.7936
C5H8O2 100.12 90.0000 9010.8000
C2H3COONa 94.04 10.0000 940.4000
Na2SO4 142.04 11.4729 1629.6157
Total 388.0032 18245.8093
Komponen µ (cP) ρ (kg/L)

C2H6O 1.17 0.7893
H2O 0.8949 0.998
C5H8O2 0.48 0.888
C2H3COONa 1.9227 1.22
Na2SO4 2.48 2.671
X
2. Data Kelarutan Komponen terhadap Air
Komponen Kelarutan Kg/L H2O
C2H6O 0.999
H2O -
C5H8O2 0.02
C2H3COONa fully soluble
Na2SO4 0.44547
3. Data Kelarutan Komponen terhadap Etanol

Komponen Kelarutan etanol
C2H6O -
H2O miscible
C5H8O2 soluble
C2H3COONa insoluble
Na2SO4 insoluble
light +heavy water 3900.7936 kg/jam 3908.6108 L/jam

Menghitung H2O yang ikut keatas bersama produk 0.0461 L/jam
Sisa air 3908.5647 L/jam
Berdasarkan data kelarut C5H8O2 tidak larut dalam air tetapi larut dalam etanol , sedangkan atanol larut dalam produk dan air
tetapi jika dilihan etanol lebih cenderung ikut ke air karena air dan etanol bila dicampurkan akan membentuk larutan azeotrof y
Menghitung Kebutuhan air yang ikut larut di dalam etanol 2766.96696696697 L/jam
Menghitung kebutuhan H2O Untuk melarutkan Na2So4 1741.16886500942 L/jam
Menghitung H2O untuk melarutkan C2H3COONa 938.5192 L/jam
5446.65503197639 L/jam
Massa keluar (kg/jam) Fraksi (X)

Komponen
Fase Ringan Fase Berat Fase Ringan Fase Berat
C2H6O 2764.2000 0.0000 0.2328 0.0000
H2O 179.0106 3721.7830 0.0151 0.5843
C5H8O2 8932.6278 78.1722 0.7522 0.0123
C2H3COONa 0.0000 940.4000 0.0000 0.1476
Na2SO4 0.0000 1629.6157 0.0000 0.0000
Total 11875.8384 6369.9709 1.0000 0.7442
Menghitung Densitas Campuran

Fase Ringan rho.X Fase Berat rho.X
C2H6O 0.1837 H2O 0.5831
H2O 0.0150 C5H8O2 0.0109
C5H8O2 0.6679 C2H3COONa 0.1801
Total 0.1988 Na2SO4 0.0000
Total 0.7741
Menghitung QL dan QH
QL (L/Jam) QH (L/jam)
Komponen Q (massa keluar larut/rho) Komponen
C2H6O 3502.0905 H2O
H2O 179.3693 C5H8O2
C5H8O2 10059.2655 C2H3COONa
Total 3681.4598 Na2SO4
Total
Menghitung Viskositas Campuran (Viskos.X)

Fase Ringan Viskos.X Fase Berat Viskos.X
C2H6O 0.2723 H2O 0.6836
H2O 0.0135 C5H8O2 0.0110
C5H8O2 0.3610 C2H3COONa 0.0709
Total 0.2858 Na2SO4 0.0000
Total 0.7654
Kecepatan volumetrik Fase Berat (QH) = 4588.0930 L/jam

Kecepatan volumetrik Fase Ringan (QL) = 3681.4598 L/jam
Rapat massa Fase Berat (ρH) = 0.7741 kg/L
Rapat massa Fase Ringan (ρL) = 0.1988 kg/L
Viskositas Fase Berat (µH) = 0.7654 CP
Viskositas Fase Ringan (µL) = 0.2858 CP
"3681,4434 " /"4629,6993 " (("0,1988 " 𝑥

"0,7675 " ))/("0,7750 " 𝑥 "0,2858 " ))^0,3
ɵ= 0.7171
Dikarenakan ϴ < 3, maka fase ringan terdispersi
Maka :
Asumsi komponen di fase ringan terdispersi sebanyak 1%
fase ringan awal

Komponen BM Output (kg/jam) Output (kgmol/jam) Fraksi massa X
C2H6O 46.07 2764.2000 60.0000 0.2328
H2O 18.015 179.0106 9.9368 0.0151
C5H8O2 100.12 8932.6278 89.2192 0.7522
Total 11875.8384 159.1560 1.0000
Fase ringan terdispersi sebanyak 1% yaitu sebagai berikut :

C2H6O 46.07 27.6420 0.6000 0.2328
H2O 18.015 1.7901 0.0994 0.0151
C5H8O2 100.12 89.3263 0.8922 0.7522
Total 118.7584 1.5916 1.0000
Maka Fase berat total setelah ditambah 1% komponen Fase ringan menjadi :
C2H6O 46.07 27.6420 0.6000 0.0043
H2O 18.015 3723.5731 206.6929 0.5739
C5H8O2 100.12 167.4985 1.6730 0.0258
C2H3COONa 94.04 940.4000 10.0000 0.1449
Na2SO4 142.04 1629.6157 11.4729 0.2511
Total 6488.7293 230.4388 1.0000
Maka Fase ringan setelah dikurangi 1% yang ikut bersama Fase berat menjadi :
C2H6O 46.07 2736.5580 59.4000 0.2328
H2O 18.015 177.2205 9.8374 0.0151
C5H8O2 100.12 8843.3015 88.3270 0.7522
Total 11757.0800 157.5644 1.0000
4. Komponen Hasil Dekantasi
Masuk Keluar (kg/jam)
Komponen BM
kg/jam kmol/jam Hasil atas
C2H6O 46.07 2764.2000 60.0000 2736.5580
H2O 18.015 3900.7936 216.5303 177.2205
C5H8O2 100.12 9010.8000 90.0000 8843.3015
C2H3COONa 94.04 940.4000 10.0000 0.0000
Na2SO4 142.04 1629.6157 11.4729 0.0000
Total 18245.8093 388.0032 11757.07997668
MENARA DISTILASI I
Masuk
Komponen BM Titik Didih
Kmol/Jam Kg/Jam
C2H5OH 46.07 78.32 59.4000 2736.5580
H2O 18.015 100 9.8374 177.2205
C5H8O2 100.12 99.4 88.3270 8843.3015
Total 157.5644 11757.0800
MENARA DISTILASI II
Masuk
Kmol/Jam Kg/Jam
C2H5OH 46.07 78.32 59.4000 2736.5580
H2O 18.015 100 4.9285 88.7875
C5H8O2 100.12 99.4 0.8833 88.4330
Total 65.2118 2913.7785
MIXER
Fresh Feed Recycle

Komponen BM
kmol/jam kg/jam kmol/jam
C3H4O2 72.06 100.0000 7206.0000 0.0000
C2H5OH 46.07 90.6000 4173.9420 59.4000
H2O 18.015 9.6070 173.0695 4.9285
C5H8O2 100.12 0.0000 0.0000 0.8833
Total 200.2070 11553.0115 65.2118
(impurities)
(impurities)
H2O
0
90
90
H2O
0.0000
10.0000
10.0000
2 H2O
0.0000
22.9459
22.9459
= 1737.6865
0.0460 kg/jam
n atanol larut dalam produk dan air
akan membentuk larutan azeotrof yang sngat sulit sekali dipsahkan
2761.433033 kg/jam
Q (massa keluar tdk larut/rho)

3729.2415
88.0318
770.8197
610.1144
4588.0930
Keluar (kg/jam) Keluar (kmol/jam) Fraksi Massa
Hasil Bawah Hasil atas Hasil Bawah Atas Bawah
27.6420 59.4000 0.6000 0.2328 0.0043
3723.5731 9.8374 206.6929 0.0151 0.5739
167.4985 88.3270 1.6730 0.7522 0.0258
940.4000 0.0000 10.0000 0.0000 0.1449
1629.6157 0.0000 11.4729 0.0000 0.2511
6488.7293 157.5644 230.4388 1.0000 1.0000
suk Hasil Atas Hasil Bawah

% Massa Kmol/Jam Kg/Jam % Massa Kmol/Jam Kg/Jam % Massa
0.2328 59.4000 2736.5580 0.9392 0.0000 0.0000 0.0000
0.0151 4.9285 88.7875 0.0305 4.9089 88.4330 0.0100
0.7522 0.8833 88.4330 0.0303 87.4438 8754.8685 0.9900
1.0000 65.2118 2913.7785 1.0000 92.3526 8843.3015 1.0000
direcycle
suk Hasil Atas Hasil Bawah
% Massa Kmol/Jam Kg/Jam % Massa Kmol/Jam Kg/Jam % Massa
0.9392 57.6180 2654.4613 0.9700 1.7820 82.0967 0.4632
0.0305 0.0000 0.0000 0.0000 4.9285 88.7875 0.5010
0.0303 0.8200 82.0967 0.0300 0.0633 6.3363 0.0358
1.0000 58.4380 2736.5580 1.0000 6.7738 177.2205 1.0000
Recycle Umpan Reaktor

kg/jam kmol/jam kg/jam fraksi massa
0.0000 100.0000 7206.0000 0.4981
2736.5580 150.0000 6910.5000 0.4777
88.7875 14.5355 261.8570 0.0181
88.4330 0.8833 88.4330 0.0061
2913.7785 265.4188 14466.7900 1.0000
NERACA MASSA

Kemurnian = 60%
Air (H2O) = 40%
Propanon (CH3COCH3)
Kemurnian = 99%
Air (H2O) = 1%

Berat Molekul Titik
(kg/kmol) Didih(K)
Propanon CH3COCH3 58
Air H2O 18
Reaksi =
3A + B " C + D + 2E
Rasio mol = NaOCl : CH3COCH3

3 1

FA0 = 100 kmol/jam
= 7450 kg/jam
Umpan CH3COCH3 masuk reaktor = 1 x massa NaOCl

3
= 1 x 100 kmol/jam
3
= 1933.33333 kg/jam
Reaksi =
XA = 99%
LR = NaOCl
mula-mula 100 33.33333

reaksi 99 33 33 33 66
sisa 1 0.333333 33 33 66

)
60% 99%
)
60% 99%
= 67.0034 kmol/jam
= 1206.0606 kg/jam
I. REAKTOR
Kondisi Operasi
P = 2 atm
T = 70 ◦C

Masuk
Komponen BM
NaOCl 100 7450.0000 0.3009 74.50
CH3COCH3 33.3333 1933.3333 0.1003 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 332.3367 19878.894 1.0000

Keluar
Komponen BM
NaOCl 1 74.5000 0.0030 74.50
CH3COCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33 3943.5000 0.0993 119.50
NaOH 66 2640.0000 0.1986 40.00
CH3COONa 33 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028
II. DECANTER
Kondisi Operasi
P = 2 atm
T = 50 ◦C

Masuk
Komponen BM
NaOCl 1.0000 74.5000 0.0030 74.50
CH3COCH3 0.3333 19.3333 0.0010 58.00
H2O 67.0034 1206.0606 0.2016 18.00
CHCl3 33.0000 3943.5000 0.0993 119.50
NaOH 66.0000 2640.0000 0.1986 40.00
CH3COONa 33.0000 2706.0000 0.0993 82.00
Total 200.3367 10589.3939 0.6028 0.00
Tabel 6. Viskositas dan densitas massa masing-masing komponen pada suhu 50◦C
NaOCl 0.5530 1.2100
CH3COCH3 0.2500 0.7559
H2O 0.5530 1.0044
CHCl3 0.4255 1.4305
NaOH 0.5530 1.4500
CH3COONa 0.5530 1.9006

Komponen Kelarutan (kg/L H2O)
NaOCl 1.5101
CH3COCH3 larut seluruhnya
H2O -
CHCl3 0.0093
NaOH 1.507
CH3COONa 0.97
light + heavy water = 1206.0606 kg/jam

= 1200.74307 L/jam
H2O yang ikut keatas bersama produk 5.5055 L/jam
= 5.5299 kg/jam
sisa air = 1200.5307 kg/jam
Tabel 8.
Massa keluar (kg/jam) Fraksi Massa
Komponen
Fase Ringan Fase Berat Fase Ringan Fase Berat
NaOCl 74.5000 0.0000 0.008 0.00
CH3COCH3 0.0000 19.3333 0.000 0.02
H2O 36.5129 1169.5478 0.004 0.98
CHCl3 3943.5000 0.0000 0.419 0.00
NaOH 2640.0000 0.0000 0.281 0.00
CH3COONa 2706.0000 0.0000 0.288 0.00
total 9400.5129 1188.8811 1.000 1.00
Tabel 9. Menghitung densitas campuran

Fase Ringan Fase Ringan
Komponen rho.X Komponen rho.X
NaOCl 0.0096 CH3COCH3 0.0123
H2O 0.0039 H2O 0.9881
CHCl3 0.6001 Total 1.0004
NaOH 0.4072
CH3COONa 0.5471
Total 1.5679
Tabel 10. Menghitung QL dan QH

QL (L/jam) QH (L/jam)
Komponen Q Komponen Q
NaOCl 7769.0189 CH3COCH3 1572.6985
H2O 9359.0659 H2O 1183.6393
CHCl3 6571.3268 Total 2756.3378
NaOH 6483.1123
CH3COONa 4946.0821
Total 35128.6060
Menghitung densitas
Komponen BM A B
NaOCl 74.5
CH3COCH3 58 0.2773 0.2576
H2O 18 0.3471 0.2740
CHCl3 119.5 0.4981 0.2527
CH3COONa 82
NaOH 40 0.1998 0.0979
total
Data Kelarutan
Komponen oC gram/100 ml kg/L

NaOCl 0 26.0000 0.26
20
ekstrapolasu 50 1.5101
CH3COONa 0
20
50 0.97
NaOH 0
20
50 1.507
diasumsikan NaOCI, nat asetate dan NaOH terlarutkan sebagian dalam air sehingga viskositas (cP) mendekati cP H2O
Komponen T (oC) T (K) A
NaOCl 50 323
CH3COCH3 50 323 -7.2126
H2O 50 323 -10.2158
CHCl3 50 323 -4.7831
CH3COONa 50 323
NaOH 50 323
kelarutan dalam air 50 C

Komponen kg/ (L H2O) (kg/L) H2O kg/ (kg H2O)
NaOCl 1.5101 1.50344
CH3COCH3 1.00443
H2O 1 1
1.00443
CHCl3 0.0093 0.00926
CH3COONa 0.97 0.96572
NaOH 1.507 1.50036
Diasumsikan H2O, C3H6O, dan CHCl3 yang terbawa fase berat sebesar 1
Komponen Masuk (kg/jam) densitas 50 C (kg/m3) urutan densitas

NaOCl 74.5 1210 3
CH3COCH3 19.3333 755.9498 1
H2O 4986.1953 1004.4285 2
CHCl3 3943.5 1430.5350 4
CH3COONa 2706 1450 5
NaOH 2640 1900.5978 6
14369.5286
n Tc T K gr/ml
50 323 1.2100
0.2990 508.2 0.7559
0.2857 647.13 1.0044
0.2877 536.4 1.4305
1.4500
0.2538 2820 1.9006
viskositas (cP) mendekati cP H2O

B C D viskositas (cP)
0.55303
9.03E+02 1.84E-02 -2.04E-05 0.25001
1.79E+03 1.77E-02 -1.26E-05 0.55303
6.99E+02 1.09E-02 -1.22E-05 0.42547
0.55303
0.55303
BM s kmol/m3 ksp
1 74.5
3 58
18
5 119.5
4 82
2 40
% massa kebutuhan H2O

untuk melarutkan 1 % massa perkiraan
kelarutan dalam air k kg/jam Perkiraan hasil bawah hasil bawah hasil atas kg/jam
1.5101 49.3344811601881 0 74.5
19.3333 0.1933 0.1933
394.5974 3.9460 3.9460
0.747887952422149 0.7479 3943.5 39.435 39.435
0.97 2789.6907 0 2706
1.507 1751.8248 2640 26.4 2640
4591.5979 5464.0743
14369.5286
kg/m3
1210 3
755.9498 1
1004.4285 2
1430.5350 4
1450 5
1900.5978 6
Hasil bawah (kg/jam)

0
19.1400
4982.2493
3904.0650
0
0
8905.4543
14369.5286
pc (bar) VC (cm3/mol) RHOC (g/cm )
3
Tf(K) Tb (K) TC (K) ZC omega
NaOCl
CH3COCH3 178.45 329.44 508.2 47.02 209 0.2779 0.233 0.306
H2O 273.15 373.15 647.13 220.55 56 0.322 0.229 0.345
CHCl3 209.63 334.33 536.4 54.72 239 0.4995 0.293 0.213
NaOH 596 1663.15 2820 253.31 200 0.2 0.216 0.477
CH3COONa
CP = A + BT + CT2 + DT3 + ET4

A B C D E Tmin Tmax
NaOCl
CH3COCH3 (g) 35.918 9.3896E-02 1.8730E-04 -2.1643E-07 6.2174E-11 100 1500
CH3COCH3 (l) 46.878 6.2652E-01 -2.0761E-03 2.9583E-06 179 457
CH3COCH3 (s) -3.893 9.3523E-01 -2.1879E-03 30 178
H2O (g) 33.933 -8.4186E-03 2.9906E-05 -1.7825E-08 3.6934E-12 100 1500
H2O (l) 92.053 -3.9953E-02 -2.1103E-04 5.3469E-07 273 615
H2O (s) 9.695 7.4955E-02 -1.5584E-05 150 273
CHCl3 (g) 22.487 1.9823E-01 -2.1676E-04 1.1636E-07 -2.4555E-11 100 1500
CHCl3 (l) 28.296 6.5897E-01 -2.0353E-03 2.5901E-06 211 483
NaOH (g) 22.246 1.4234E-01 -2.4264E-04 1.8054E-07 -4.8026E-11 100 1500
NaOH (l) 87.639 -4.8368E-04 -4.5423E-06 1.1863E-09 600 2700
NaOH (s) 51.234 1.3088E-02 2.3359E-05 250 500
CH3COONa
Hvap = A (1- T/Tc)n kJ/mol

A Tc n Tmin Tmax Tb Hvap @Tb
NaOCl
CH3COCH3 49.244 508.200 0.481 260.000 508.200 329.440 29.79
H2O 52.053 647.130 0.321 273.210 647.130 373.150 39.5
CHCl3 42.953 536.40 0.375 209.630 536.400 334.330 29.79
NaOH 281.536 2820.000 0.380 596.000 2820.000 1663.150 200.67
CH3COONa
HAL 140
Tmax Cp @25C Cp @Tmin Cp @Tmax
1500
457 127.53
178 22.195 93.325
1500
615 75.55 20.588 29.006
273
1500
483 112.49
1500
2700
500 57.213 55.966 63.618
Hvap @Tb
29.79
39.5
29.79
200.67
NERACA MASSA

Kemurnian = 60%
Air (H2O) = 40%
Propanon (CH3OCH3)
Kemurnian = 99%
Air (H2O) = 1%

Berat Molekul Titik
(kg/kmol) Didih(K)
Propanon CH3OCH3 58
Air H2O 18
Basis = 100 kg/jam

3 1

Umpan NaOCl masuk reaktor = 100 kg/jam
Umpan CH3OCH3 masuk reaktor =1 x massa NaOCl

3
= 1 x 1.3423 kmol/jam
3
= 25.95078 kg/jam

)
60% 99%
= ( 40% x 100 kg/jam ) + ( 1% x 25.95078 kg/jam
)
60% 99%
= 66.9288 kg/jam
NERACA MASSA PABRIK KLOROFORM DARI SODIUM HIPOKLORIT DAN PROPANON

Kecepatan produksi 6313.13131313 kg/jam
NERACA MASSA BASIS 100 KMOL/JAM NaOCl
REAKTOR
3 NaOCl + CH3COCH3 CHCl3 + CH3COONa + 2 NaOH
Perbandingan reaktan masuk reaktor

NaOCl : CH3COCH3 = 3 : 1
Kemurnian CH2=CHCOOH = 60% : 40%
Kemurnian C2H5OH = 99% : 1%
1. Total Umpan Masuk Reaktor

NaOCl 74.5 100.0000 7450.0000 0.5185
CH3COCH3 58 33.3333 1933.3333 0.1345
H2O 18 277.0108 4986.1953 0.3470
Total 410.3442 14369.5286 1.0000
Konversi X= 99% ; LR: NaOCl

3 NaOCl CH3COCH3 CHCl3
M 100.0000 33.3333 0
R 99 33 33
S 1 0.3333 33
2. Komponen Hasil Reaksi

NaOCl 74.5 1.0000 74.5000 0.0052
CH3COCH3 58 0.3333 19.3333 0.0013
H2O 18 277.0108 4986.1953 0.3470
CHCl3 119.5 33.0000 3943.5000 0.2744
CH3COONa 82 33.0000 2706.0000 0.1883
NaOH 40 66.0000 2640.0000 0.1837
Total 410.3442 14369.5286 1.0000
DEKANTER
1. Umpan Masuk Dekanter

Komponen BM Kmol/Jam Kg/Jam
NaOCl 74.5 1.0000 74.5000
CH3COCH3 58 0.3333 19.3333
H2O 18 277.0108 4986.1953
CHCl3 119.5 33.0000 3943.5000
CH3COONa 82 33.0000 2706.0000
NaOH 40 66.0000 2640.0000
Total 410.3442 14369.5286

NaOCl 0,75 cP 1.173
CH3COCH3 32 mPa 58.08
H2O 0.8949 0.998 hemas
CHCl3 0,563 cP 1.489
CH3COONa 1.9227 1.22 hems
NaOH 1.892 ngarang cuk X
2. Data Kelarutan Komponen terhadap Air

Komponen Kelarutan Kg/L H2O
NaOCl 1.5101
CH3COCH3 fully soluble
H2O -
CHCl3 fully soluble
CH3COONa 0.00381 gue ngarang anjir
NaOH exothermically soluable in water
19.3721 L/jam
light +heavy water 19.3333 kg/jam 0.5322
Menghitung H2O yang ikut keatas bersama produk
Sisa air 18.8399 L/jam
Berdasarkan data kelarut C5H8O2 tidak larut dalam air tetapi larut dalam etanol , sedangkan atanol larut dalam produk dan air
tetapi jika dilihan etanol lebih cenderung ikut ke air karena air dan etanol bila dicampurkan akan membentuk larutan azeotrof y
49.3344811601881
Menghitung Kebutuhan air yang ikut larut di dalam etanol 0.07380761523046 L/jam
Menghitung kebutuhan H2O Untuk melarutkan Na2So4 229038.48 L/jam
Menghitung H2O untuk melarutkan C2H3COONa 229087.888288775
Fraksi (X)
Massa keluar (kg/jam) Fase Ringan
Komponen
Fase Ringan Fase Berat #VALUE!
C2H6O 74.5000 0.0000 #VALUE! L/jam
H2O #VALUE! #VALUE! #VALUE! L/jam
C5H8O2 #VALUE! #VALUE! #VALUE! L/jam
C2H3COONa 0.0000 3943.5000 #VALUE! L/jam
Na2SO4 0.0000 2706.0000 #VALUE!
Total #VALUE! #VALUE!
Fase Berat
Menghitung Densitas Campuran Fase Berat #VALUE!
Fase Ringan rho.X H2O #VALUE!
C2H6O #VALUE! C5H8O2 #VALUE!
H2O #VALUE! C2H3COONa #VALUE!
C5H8O2 #VALUE! Na2SO4 #VALUE!
Total #VALUE! Total #VALUE!
Menghitung QL dan QH rho.X

QL (L/Jam) #VALUE!
Komponen Q (massa keluar larut/rho) #VALUE!
C2H6O 63.5124 #VALUE!
H2O #VALUE! #VALUE!
C5H8O2 #VALUE! #VALUE!
Total #VALUE!
QH (L/jam)
Menghitung Viskositas Campuran (Viskos.X) Fase Berat Komponen
Fase Ringan Viskos.X H2O H2O
C2H6O #VALUE! C5H8O2 C5H8O2
H2O #VALUE! C2H3COONa C2H3COONa
C5H8O2 #VALUE! Na2SO4 Na2SO4
Total #VALUE! Total Total
L/jam
umetrik Fase Berat (QH) = #VALUE! L/jam Viskos.X
Kecepatan volumetrik Fase Ringan (QL) = #VALUE! kg/L #VALUE!
Rapat massa Fase Berat (ρH) = #VALUE! kg/L #VALUE!
massa Fase Ringan (ρL) = #VALUE! CP #VALUE!
Viskositas Fase Berat (µH) = #VALUE! CP #VALUE!
Viskositas Fase Ringan (µL) = #VALUE! #VALUE!
"3681,4434 " /"4629,6993 " (("0,1988 " 𝑥 Q (massa keluar tdk larut/rho)
"0,7675 " ))/("0,7750 " 𝑥 "0,2858 " ))^0,3
ɵ= #VALUE!
Dikarenakan ϴ < 3, maka fase ringan terdispersi
Maka :
Asumsi komponen di fase ringan terdispersi sebanyak 1%
fase ringan awal Output (kgmol/jam)

Komponen BM Output (kg/jam) 1.6171
C2H6O 46.07 74.5000 #VALUE!
H2O 18.015 #VALUE! #VALUE!
C5H8O2 100.12 #VALUE! #VALUE!
Total #VALUE!
Fase ringan terdispersi sebanyak 1% yaitu sebagai berikut : Output (kgmol/jam)

Komponen BM Output (kg/jam) 0.0162 Fraksi massa X
C2H6O 46.07 0.7450 #VALUE! #VALUE!
H2O 18.015 #VALUE! #VALUE! #VALUE!
C5H8O2 100.12 #VALUE! #VALUE! #VALUE!
Output
Maka Fase berat total setelah ditambah 1% komponen Fase ringan (kgmol/jam)
menjadi :
Komponen BM Output (kg/jam) 0.0162 Fraksi massa X
C2H6O 46.07 0.7450 #VALUE! #VALUE!
C5H8O2 100.12 #VALUE! 41.9343 #VALUE!
C2H3COONa 94.04 3943.5000 19.0510 #VALUE!
Na2SO4 142.04 2706.0000 #VALUE!
Total #VALUE!
Fraksi massa X
Maka Fase ringan setelah dikurangi 1% yang ikut bersama Fase Output (kgmol/jam)
berat menjadi : #VALUE!
Komponen BM Output (kg/jam) 1.6009 #VALUE!
C2H6O 46.07 73.7550 #VALUE! #VALUE!
C5H8O2 100.12 #VALUE! #VALUE! #VALUE!
4. Komponen Hasil Dekantasi

Masuk kmol/jam Fraksi massa X
Komponen BM
kg/jam 1.6171 #VALUE!
C2H6O 46.07 74.5000 1.0732 #VALUE!
H2O 18.015 19.3333 49.8022 #VALUE!
C5H8O2 100.12 4986.1953 41.9343 #VALUE!
C2H3COONa 94.04 3943.5000 19.0510
Na2SO4 142.04 2706.0000 113.4777
Total 11729.5286 Keluar (kg/jam)
Hasil atas
73.7550
MENARA DISTILASI I #VALUE!
Masuk #VALUE!
Kmol/Jam 0.0000
1.6009 0.0000
C2H5OH 46.07 78.32 #VALUE! #VALUE!
H2O 18.015 100 #VALUE!
C5H8O2 100.12 99.4 #VALUE!
Total
MENARA DISTILASI II Masuk

Kmol/Jam Kg/Jam
1.6009 73.7550
C2H5OH 46.07 78.32 #VALUE! #VALUE!
H2O 18.015 100 #VALUE! #VALUE!
C5H8O2 100.12 99.4 #VALUE! #VALUE!
Total
MIXER
Fresh Feed kg/jam Kg/Jam

Komponen BM
kmol/jam 7450.0000 73.7550
C3H4O2 72.06 100.0000 1859.5783 #VALUE!
C2H5OH 46.07 31.7324 89.8631 #VALUE!
H2O 18.015 4.9882 0.0000 #VALUE!
C5H8O2 100.12 0.0000 9399.4414
Total 136.7206
Recycle
kmol/jam
0.0000
1.6009
#VALUE!
#VALUE!
#VALUE!
DAN PROPANON
(impurities)
(impurities)
CH3COONa 2 NaOH
0 0
33 66
33 66
n atanol larut dalam produk dan air
akan membentuk larutan azeotrof yang sngat sulit sekali dipsahkan
=
30.9103
2865.3466658
0.0737
Q (massa keluar tdk larut/rho)

#VALUE!
#VALUE!
2648.4218
2218.0328
#VALUE!
kg/jam
kg/jam
Hasil Bawah
0.7450
#VALUE!
#VALUE!
3943.5000
2706.0000
#VALUE!
% Massa
#VALUE!
#VALUE!
#VALUE!
#VALUE!
% Massa
#VALUE!
#VALUE!
#VALUE!
#VALUE!
kg/jam
0.0000
73.7550
#VALUE!
#VALUE!
#VALUE!
Keluar (kmol/jam) Fraksi Massa

Hasil atas Hasil Bawah Atas Bawah
1.6009 0.0162 #VALUE! #VALUE!
#VALUE! #VALUE! #VALUE! #VALUE!
0.0000 41.9343 #VALUE! #VALUE!
0.0000 19.0510 #VALUE! #VALUE!

Kmol/Jam Kg/Jam % Massa Kmol/Jam Kg/Jam % Massa
1.6009 73.7550 #VALUE! 0.0000 0.0000 #VALUE!
#VALUE! #VALUE! #VALUE! #VALUE! #VALUE! #VALUE!
direcycle
Kmol/Jam Kg/Jam % Massa Kmol/Jam Kg/Jam % Massa
1.5529 71.5424 0.9700 0.0480 2.2126 #VALUE!
0.0000 0.0000 0.0000 #VALUE! #VALUE! #VALUE!
Umpan Reaktor
kmol/jam kg/jam fraksi massa
100.0000 7450.0000 #VALUE!
33.3333 1933.3333 #VALUE!
#VALUE! #VALUE! #VALUE!

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NERACA MASSA

Sodium hipoklorit (NaOCl)

Tabel 1. Titik didih masing-masing komponen

Basis = 100 kmol/jam

Rasio mol = NaOCl : CH3OCH3

Konversi (XA) = 99% terhadap NaOCl

Umpan CH3OCH3 masuk reaktor =

Tabel 2. Tabel stoikiometri

mula-mula 100 33.33333

Massa Air = ( 40% x massa NaOCl ) + ( 1% x massa CH3OCH3

Tabel 3. Umpan masuk reaktor

Tabel 4. Umpan keluar reaktor

Tabel 5. Umpan masuk decanter

Tabel 6. Densitas massa masing-masing komponen pada suhu 50◦C

Tabel 7. Data kelarutan komponen dalam air pada suhu 50◦C

NaOCl 151.01 gram dalam 100 ml air

perkiraan hasil 1% massa kira hasil atas hasil bawah

Sodium hipoklorit (NaOCl)

Tabel 1. Titik didih masing-masing komponen

Basis = 100 kmol/jam

Rasio mol = NaOCl : CH3OCH3

Konversi (XA) = 99% terhadap NaOCl

Umpan CH3OCH3 masuk reaktor =

Tabel 2. Tabel stoikiometri

mula-mula 100 33.33333

Massa Air = ( 40% x massa NaOCl ) + ( 1% x massa CH3OCH3

Tabel 3. Umpan masuk reaktor

Tabel 4. Umpan keluar reaktor

Tabel 5. Umpan masuk decanter

Tabel 6. Rapat massa masing-masing komponen pada suhu 50◦C

Tabel 7. Data kelarutan komponen dalam air pada suhu 50◦C

NaOCl 151.01 gram dalam 100 ml air

Tabel 8. Massa komponen yang terlarut dalam air

Tabel 9. Umpan keluar decanter

Sodium hipoklorit (NaOCl)

Tabel 1. Berat molekul masing-masing komponen

Basis = 100 kmol/jam

Rasio mol = NaOCl : CH3OCH3

Konversi (XA) = 99% terhadap NaOCl

Umpan CH3OCH3 masuk reaktor =

Tabel 2. Tabel stoikiometri

mula-mula 100 33.33333

Massa Air = ( 40% x massa NaOCl ) + ( 1% x massa CH3OCH3

Tabel 3. Umpan masuk reaktor

Tabel 4. Umpan keluar reaktor

Tabel 5. Umpan masuk decanter

Tabel 6. Rapat massa masing-masing komponen pada suhu 70◦C

Tabel 7. Data kelarutan komponen dalam air pada suhu 70◦C

NaOCl 351.987 gram dalam 100 ml air

Tabel 8. Massa komponen yang terlarut dalam air

Tabel 9. Umpan keluar decanter

III. MENARA DISTILASI

Tabel 3. Umpan masuk reaktor

Tabel 4. Umpan keluar reaktor

Tabel 7. Data kelarutan komponen dalam air pada suhu 70◦C

NaOCl 151.01 gram dalam 100 ml air

Tabel 8. Massa komponen yang terlarut dalam air

Tabel 9. Umpan keluar decanter

III. MENARA DISTILASI

Kapasitas produksi = 55000 ton/tahun

Sodium hipoklorit (NaOCl)

Tabel 1. Titik didih masing-masing komponen

Basis = 100 kmol/jam

Rasio mol = NaOCl : CH3OCH3