e.

Penentuan kalor reaksi Zn + CuSO4

Zn(s) + CuSO4

ZnSO4(aq) + Cu(s)

Massa larutan = x V = 1.14 x 40 = 45.60 gram

Ar Zn= 65
T CuSO4 = 27.5 C = 300.5 K
M CuSO4 = 0.5 M
V CuSO4 = 40 mL = 0.04 L
n CuSO4 = M x V
= 0.5 x 0.04
= 0.02 mol
Kalor yang diserap calorimeter (Q1) = C x T
= 151.2 (303-298)
= 756 J
Kalor yang diserap larutan (Q2) = m x c x T
= 45.6 x 3.52 x (303-298)
= 802.56 J
Kalor yang dihasilkan oleh reaksi(Q3) = Q1+Q2
= 756 + 802.56
= 1558.56

Q3
mol

Kalor reaksi (Q4) =

1558.56
0.02

= 77928 J/mol
f. Penentuan kalor pelarutan etanol dalam air

 Komposisi A
V air = 2 mL
V etanol = 8 mL
Mr etanol = 46

metanol
Mr

n etanol =

6.344
46
= 0.138 mol

air = 1 gr/mL
etanol = 0.793 gr/mL
c air = 4.2 J/gK
c etanol = 1.92 J/gK
T air = 26 C = 299 K
T etanol = 25 C = 298 K
T konstan = 28C = 301 K
Ta

= T konstan T air
= 301 299
=2K

Tc

= T konstan Tc
= 301 298
=3K

m air = air x V air

= 1 gr/mL x 2 mL
= 2 gram
m etanol = etanol x V etanol
= 0.793 gr/mL x 8 mL
= 6.344 gram

Q7 = Qair
= ma x ca x Ta
= 2 x 4.2 x 2
= 16.8 J
Q8 = Qetanol
= me x ce x Te
= 6.344 x 1.92 x 3
= 36.54 J
Q9 = K x Ta
= 214.188 x 2
= 428.376 J
Q10 = Q7 + Q8 +Q9
=16.8 + 26.54 + 428.376
= 481.716 J

H =

Q10
n etanol

481.716
0.138

= 3490.699 J/mol
= 3.491 KJ/mol

Komposisi B
Vair= 4 ml
V etanol= 6 ml
M air = air x V air
= 1 gr/ml x 4 ml
=4 gr
M etanol = etanol x V etanol
= 0.793 x 6
=4.758 gr
Tkonstan = 27.75C = 300.75 K
Ta = Tkonstan Tair
= 300.75 299
= 1.75 K
Te = Tkonstan Tetanol
= 300.75 298
= 2.75 K
Mol etanol =
=

m
Mr

4.758
46

= 0.103 mol

Q7 = Qair
= ma x ca x Ta
= 4 x 4.2 x 1.75
= 29.4 J
Q8 = Qetanol
= me x ce x Te
= 4.758 x 1.92 x 2.75
= 25.121 J
Q9 = K x Ta
= 214.188 x 1.75
= 374.829 J
Q10 = Q7 + Q8 +Q9
=29.4 + 25.121 +374.829
= 429.35 J
H =

Q10
n etanol

429.35
0.103

= 4168.447 J/mol
= 4.168 KJ/mol

Komposisi C

Vair= 6 ml
V etanol= 4 ml
M air = air x V air
= 1 gr/ml x 6 ml
=6 gr
M etanol = etanol x V etanol
= 0.793 x 4
=3.172 gr

28+ 27.75
2

Tkonstan =

= 27.875C = 300.875 K

Ta = Tkonstan Tair
= 300.875 299
= 1.875 K
Te = Tkonstan Tetanol
= 300.875 298
= 2.875 K
Mol etanol =

m
Mr
3.172
46

= 0.069 mol
Q7 = Qair
= ma x ca x Ta
= 6 x 4.2 x 1.875
= 47.25 J
Q8 = Qetanol
= me x ce x Te
= 3.172 x 1.92 x 2.875
= 17.509 J
Q9 = K x Ta
= 214.188 x 1.875
= 401.602 J
Q10 = Q7 + Q8 +Q9
=47.25 + 17.509 + 401.602
= 466.361 J
H =

Q10
n etanol

466.36
0.069

= 6758.855 J/mol

= 6.759 KJ/mol
Komposisi D

Vair= 8 ml
V etanol= 2 ml
M air = air x V air
= 1 gr/ml x 8 ml
=8 gr
M etanol = etanol x V etanol
= 0.793 x 2
=1.568 gr

28+ 27.75
2

Tkonstan =

= 27C = 300 K

Ta = Tkonstan Tair
= 300 299
=1K
Te = Tkonstan Tetanol
= 300 298
=2K
Mol etanol =
=

m
Mr

1.586
46

= 0.034 mol
Q7 = Qair
= ma x ca x Ta
= 8 x 4.2 x 1
= 33.6 J
Q8 = Qetanol
= me x ce x Te
= 2 x 1.92 x 2
= 7.68 J
Q9 = K x Ta
= 214.188 x 1
= 214.188 J
Q10 = Q7 + Q8 +Q9
=33.6 + 7.68 + 214.188
= 255.468 J
H =
=

Q10
n etanol

255.468
0.034

= 7513.7647 J/mol

= 7.513 KJ/mol