1.

A process gas stream at 400oC is to be rapidly cooled to 2000C by direct

quenching with cold liquid benzene at 20oC. If the hot stream consist of
40% C6H6, 30% C6H5CH3. 10% CH4 and 20% H2 calculate the benzene
quench rate required for a gas feed rate of 1000 kgmol/h, assuming
quencing occurs adiabatically. (With Tref = 200oC)
Solution :

Diasumsikan Q = 0 Karena process terjadi secara adiabatik

W = 0 Karena tidak ada perubahan volume yang terjadi
Sehingga :
dQ dW

= outlet F [ H ( Ti )H ( Tr ) ] inlet F [H ( Ti ) H ( Tr ) ]
dt
dt
H 2 ( 200 oC ) ( H 2 ( 20 oC ) ] }
F2
F 1 ( H 1 ( 400 oC )H 1 (200 oC ) ] +
H 3 ( 200 oC )H 3 ( 200 oC ) {
0=F 3

Maka :
F 2 ( H 2 (200 oC )H 2 ( 20 oC ) ]
F 1 ( H 1 ( 400 oC )H 1 (200 oC ) ] =

F 1 ( H 1 ( 400 oC )H 1 (200 oC ) ] dianggap sebagai equation1

F 2 ( H 2 ( 200 oC )H 2 ( 20 oC ) ]

Dianggap sebagai equation 2

Menyelesaikan equation 1 :
673.2 K

F 1 ( H 1 ( 400 oC )H 1 (200 oC ) ]= F 1

Cp dT

473.2 K

673.2 K

T 22T 12
T 23T 13
T 24 T 14
T 25
F 1 Cp dT= (T 2T 1 ) F 1 a+ 2 F 1b + 3 F 1 c + 4 F 1d + 5
473.2 K

Memakai E ( sigma ) dikarenakan ada 4 gas yang masuk pada aliran, yakni
benzene,metana, toluen dan hidrogen.
ZAT
C6H6
C6H5CH3
CH4

A
18.587
31.820
38.387

B x 101
-0.11744
-0.16165
-0.73664

C x 102
0.12751
0.14447
0.029098

H2

17.639

0.67006

0.013149

D x 105
E x 108
-0.20798 0.10533
-0.22895 0.11357
0.008006
0.026385
8
0.010588 -0.002918

Flow
400
300
100
200

Langkah selanjutnya, dicari nilai masing-masing E(sigma)

F 1 a=F ( c 6 h 6 ) a ( c 6 h 6 )+ F (C 6 H 6 CH 3) a(C 6 H 6 CH 3)+ F (CH 4)a(CH 4)+ F( H 2) a(H 2)

400 x 18.587
F 1 a= ) + (300 x 31.820) + (100 x 38.387) + (200 x 17.639)

F 1 a=2.43473 x 104
Dengan cara yang sama, dicari
Dan didapatkan hasilnya :

F 1 b=3.5123

F 1 b , F 1 c , F 1 d dan F 1 e

 F 1 c=0.94625
F 1 d=1.5240 x 103
F 1 e=0.76420 x 106
Dan dimasukkan kepersamaan
673.2 K

F1

473.2 K

Cp dT= (T 2T 1 ) F 1 a+

( 200 K ) 2.43473 x 10 4 +

T 22T 12
T 23T 13
T 24 T 14
T 25
F 1b +
F1c+
F 1d +

2
3
4
5

673.22473.22
673.23473.23
673.24473.24
x3.5123+
0.94625+
x 1.5240 x 1
2
3
4

673.2 K

F1

Cp dT=2.5634 x 107 Kj/h

473.2 K

Maka didapatkanlah equation 1 = 2.5634 x 107 Kj / h

Kemudian dicara Equation 2
F 2 ( H 2(v ) ( 200 oC )H 2(l) ( 20 oC ) ]
F 2 ( H 2 ( 200 oC )H 2 ( 20 oC ) ] =

Dengan data : Normal Boilling point of benzene is 353.26 K, dan ada benzen
yang berubah fasa dari gas-cair
473.2 K

F 2 ( H 2 ( v )( 200 oC )H 2 ( l ) ( 20 oC ) ] =F 2(

353.3 K

353.2 K

Cp ( V ) dT +

Cp ( L ) dT + Hvl (353.3 K))

293.2 K

Hvl (353.3 K ) =30,763.4 Kj /kg mol

473.2 K

3
3
473.22353.32
473
2 473.2 353.3
x1.174 x 10 +
1.2751 x 103 +
Cp ( V ) dT =( 473.2353.3 ) 18.587+
2
3
353.2 K

Sehingga

473.2 K

Cp ( V ) dT =1.3808 x 104 kj/ kgmol

353.2 K

353.3. K

Cp ( L ) dT =( 353.3293.2 )7.273+

293.2 K

353.3 293.2
353.3 293.2
353
7.705 x 101 +
x1.6481 x 103 +
2
3

353.3. K

Cp ( L ) dT =8.0979 x 103 kj/ kgmol

293.2 K

Maka :
F 2 ( H 2 ( v )( 200 oC )H 2 ( l ) ( 20 oC ) ] =F 2(30,673.4

Kj
x 104 kj
kj
+1.3808
+ 8.0979 x 103
)
kgmol
kgmol
kgmol

F 2 ( H 2 ( v )( 200 oC )H 2 ( l ) ( 20 oC ) ] =F 2 ( 5.2669 x 104 ) kj/kgmol

Diketahui tadi bahwa equation 1= equation 2

Atau
F 2 ( H 2 (200 oC )H 2 ( 20 oC ) ]
F 1 ( H 1 ( 400 oC )H 1 (200 oC ) ] =

Maka
F 1 ( H 1 ( 400 oC )H 1 (200 oC ) ]

F 2=

F 2=

2.5634 x 107 kj/h

=486.7 kgmol/h
4
5.2669 x 10 kj / kgmol

2. A process gas stream at 400oC is to be rapidly cooled to 200pC by direct

quenching with cold liquid benzene at 20oC. If the hot stream consist of
40% C6H6, 30% C6H5CH3. 10% CH4 and 20% H2 calculate the benzene
quench rate required for a gas feed rate of 1000 kgmol/h, assuming
quencing occurs adiabatically. (With Tref = 20oC)

Solution :

Diasumsikan Q = 0 Karena process terjadi secara adiabatik

W = 0 Karena tidak ada perubahan volume yang terjadi
Sehingga :
dQ dW

= outlet F [ H ( Ti )H ( Tr ) ] inlet F [H ( Ti ) H ( Tr ) ]
dt
dt
H 2 ( 20 oC ) ( H 2 ( 20 oC ) ] }
F2
F 1 ( H 1 ( 400 oC )H 1 (20 oC ) ] +
H 3 ( 200 oC )H 3 ( 20 oC ) {
0=F 3

Maka :
F 3 ( H 2 ( 200 oC )H 2 ( 20 oC ) ]
F 1 ( H 1 ( 400 oC )H 1 (20 oC ) ] =

F 1 ( H 1 ( 400 oC )H 1 (20 oC ) ] dianggap sebagai equation1

F 3 ( H 3 ( 200 oC )H 3 ( 20 oC ) ]

Menyelesaikan equation 1 :

Dianggap sebagai equation 2

673.2 K

353.2 K

Cp ( V ) dT +

353.3 K

Cp ( L ) dT + Hvl (353.3 K )

293.2 K

F 1 ( H 1 ( 400 oC )H 1 ( 20 oC ) ] = F 1

673.2 K

1
F 1 Cp dT =( T 2T 1 ) F 1 a+ T 2 T
2
293.2 K

1
F 1 b+ T 2 T
3

1
F 1 c + T 2 T
4

Memakai E ( sigma ) dikarenakan ada 4 gas yang masuk pada aliran, yakni
benzene,metana, toluen dan hidrogen.
ZAT
C6H6
C6H5CH3
CH4

A
18.587
31.820
38.387

B x 101
-0.11744
-0.16165
-0.73664

C x 102
0.12751
0.14447
0.029098

H2

17.639

0.67006

0.013149

D x 105
E x 108
-0.20798 0.10533
-0.22895 0.11357
0.008006
0.026385
8
0.010588 -0.002918

Flow
400
300
100
200

Langkah selanjutnya, dicari nilai masing-masing E(sigma)

F 1 a=F ( c 6 h 6 ) a ( c 6 h 6 )+ F (C 6 H 6 CH 3) a(C 6 H 6 CH 3)+ F (CH 4)a(CH 4)+ F( H 2) a(H 2)

400 x 18.587
F 1 a= ) + (300 x 31.820) + (100 x 38.387) + (200 x 17.639)

F 1 a=2.43473 x 104
Dengan cara yang sama, dicari
Dan didapatkan hasilnya :

F 1 b=3.5123

F 1 c=0.94625
F 1 d=1.5240 x 103

F 1 b , F 1 c , F 1 d dan F 1 e

F 1 d + T 2 5

 F 1 e=0.76420 x 106
Dan dimasukkan kepersamaan
673.2 K

T 22T 12
T 23 T 13
T 24T 14
F 1 Cp dT (v)=( T 2T 1 ) F 1 a+ 2 F 1b+ 3 F 1 c + 4 F 1d + T
293.2 K
( 673.2293.2 ) 2.43473 x 104 +

673.22293.22
673.23293.23
673.2 4293.24
x3.5123+
0.94625+
x1.5
2
3
4

673.2 K

F1

Cp dT (v)=4.2256 x 107 Kj/h

293.2 K

Kemudian dicara Equation 2

F 3 ( H 3(v ) ( 200 oC )H 3(l) ( 20 oC ) ]
F 3 ( H 3 ( 200 oC )H 3 ( 20 oC ) ] =

Dengan data : Normal Boilling point of benzene is 353.26 K, dan ada benzen
yang berubah fasa dari gas-cair
473.2 K

F 3 ( H 3 ( v )( 200 oC )H 3 ( l )( 20 oC ) ] =F 3 (

353.2 K

Cp ( V ) dT +

353.3 K

Cp ( L ) dT + Hvl (353.3 K ))

293.2 K

Hvl (353.3 K ) =30,763.4 Kj /kg mol

473.2 K

Cp ( V ) dT =( 473.2353.3 ) 18.587+

353.2 K

473.22353.32
473.23 353.33
473
x1.174 x 102+
1.2751 x 103 +
2
3

Sehingga
473.2 K

Cp ( V ) dT =1.3808 x 104 kj/ kgmol

353.2 K

353.3. K

293.2 K

Cp ( L ) dT =( 353.3293.2 )7.273+

353.3 293.2
353.3 293.2
353
7.705 x 101 +
x1.6481 x 103 +
2
3

353.3. K

Cp ( L ) dT =8.0979 x 103 kj/ kgmol

293.2 K

Maka :
F 3 ( H 3 ( v )( 200 oC )H 3 ( l )( 20 oC ) ] =F 3 (30,673.4

Kj
x 10 4 kj
kj
+1.3808
+ 8.0979 x 103
)
kgmol
kgmol
kgmol

F 3 ( H 3 ( v )( 200 oC )H 3 ( l )( 20 oC ) ] =F 3 ( 5.2669 x 10 4 ) kj/kgmol

Diketahui tadi bahwa equation 1= equation 2

Atau
F 3 ( H 3 ( 200 oC )H 3 ( 20 oC ) ]
F 1 ( H 1 ( 400 oC )H 1 (200 oC ) ] =

Maka
F 1 ( H 1 ( 400 oC )H 1 (20 oC ) ]

F 3=

F 3=

4.2256 x 107 Kj /h
=801.97 kgmol/h
5.2669 x 10 4 kj/ kgmol