I.

Analisis hasil pengamatan

1. Titrasi standarisasi NaOH dengan asam oksalat 0.02 M
Titrasi
V.awal

Volume titrasi (mL)

Vakhir
V. terpakai

ke
1
0
5,6
2
5,6
11
Volume rata rata terpakai

5,6
5,4
5,5

Perubahan warna
awal
akhir
Tidak

Merah

berwarna

muda

2. Titrasi standarisasi HCl dengan NaOH 0.02 M

Titrasi

Volume titrasi (mL)

V.awal
Vakhir
V. terpakai

ke
1
0
9.2
2
9.2
18,2
Volume rata rata terpakai

9.2
9,0
9,1

Perubahan warna
awal
akhir
Merah

Tidak

muda

berwarn
a

3. Titrasi campuran etil asetat dan NaOH + HCl dengan NaOH

Titrasi
menit ke
3
8
15
25
40

II.

Volume titrasi (mL)

V.awal
V.akhir
V. terpakai

Perubahan warna
awal
akhir

0
17.10
0
18.20
0

Tidak

Merah

berwarna

muda

17.10
34.70
18.20
37.00
19.70

17.10
17.60
18.20
18.80
19.70

Pengolahan data
1. Pembuatan larutan
a. Larutan CH3COOC2H5
M Mr V
Massa =
=
1000
b. Larutan NaOH
M Mr V
Massa =
1000
c. Larutan HCl
BJ 10
M=
Mr

V1 M1 = V2 M2

0.02 88 250
1000

= 0.44 gram

0.02 40 300
1000

= 0.24 gram

36 1.18 10
36.5

= 11.64 M

V1 =

0.02 250
11.64

= 0.429 mL
Volume aquades = 249.571 mL
2. Standarisasi NaOH dengan asam oksalat [ OH-]
NaOH = oksalat
V1 M1 eV = V2 M2 2 eV
10 x 0,02 Mx 2
M1 =
5,5
= 0,0727M
3. Standarisasi HCl dengan NaOH [H+]
V1 M1 = V2 M2
10 x 0,0727
M1 =
9.1
= 0.0799 M
4. Volume NaOH yang bereaksi dengan asam oksalat
+
H

20 [0.0799]
100
VNaOH
- [ OH) = 60-[
Vtitran ]
a. VNaOH
(t =: V
3bmenit

17.10]
10
[0.0727]

20
= 60 - [ 21.98 17.10 ] 10
= 60 - 48.8
= 11.2 mL
20 [0.0799]
100
b. VNaOH (t : 8 menit ) = 60- [ [0.0727]
17.60] 10

c. VNaOH

= 60 - [ 21.98 17.60 ] 10
= 60 43.8
= 16.2 mL
20 [0.0799]
(t : 15 menit ) = 60 -[ [0.0727] 18.20]

d. VNaOH

= 60 - [ 21.98 18.20 ] 10
= 60 - 37.8
= 22.2 mL
20 [0.0799]
(t : 25 menit ) = 60 -[ [0.0727]
18.80]
= 60 - [ 21.98 18.80 ] 10

100
10

100
10

= 60 - 31.8
= 28.2 mL
e. VNaOH (t : 40 menit ) = 60 - [

20 [0.0799]
[0.0727]

19.70]

100
10

= 60 - [ 21.98 19.70 ] 10
= 60 - 22.8
= 37.2 mL
5. NaOH saat bereaksi
X=
X1( t : 3 menit ) =

0.0727 M . 11.2 mL
100 mL

= 8,1424 x 10-3 M

X2( t : 8 menit ) =

0.0727 M . 16.2mL
100 mL

= 1,1778 x 10-2 M

X3( t : 15 menit ) =

0.0727 M . 22.2mL
100 mL

= 1,6139 x 10-2 M

X4( t : 25 menit ) =

0.0727 M . 28.2mL
100 mL

= 2,0501 x 10-2 M

X4( t : 40 menit ) =

0.0727 M . 37.2mL
100 mL

= 2,7044 x 10-2 M

6. Perhitungan a dan b
[ etil asetat ] . Va
a=
=
Vtotal
b=

[ NaOH ] .Vb
Vtotal

0.02 M . 40 mL
100 mL

= 8 x 10-3

0.0727 M . 60 mL
100 mL

= 0.0436

7. Perhitungan Y
Y=
Y1 =

1
ab

ln

1
3
( 8 x 10 )0,0436

1
= ( 3,56 x 102)

ln

ln

0,0436(8 x 103 8,1424 x 103 )

8 x 103 (0,04368,1424 x 103 )

6,2086 x 106
2,8366 104

= -28,0899 -ln 0,021887

= -28,0899 x 3,8219
= -107,3568
Y2 =

1
3
( 8 x 10 )0,0436

1
= ( 3,56 x 102)

ln

0,0436(8 x 103 1,1778 x 102)

8 x 103 (0,04361,1778 x 102)
4

ln

1,6472 x 10
4
2,5458 x 10

= -28,0899 -ln 0,6470

= -28,0899 x 0,4354
= -12,2303
Y3 =

1
3
( 8 x 10 )0,0436

1
= ( 3,56 x 102) ln

ln

0,0436(8 x 103 1,6139 x 102)

8 x 103 (0,04361,6139 x 102)
4

3,5486 x 10
4
2,1969 x 10

= -28,0899 -ln 1,6153

= -28,0899 x - 0,4795
= 13,4691

Y4 =

1
3
( 8 x 10 )0,0436

1
= ( 3,56 x 102) ln

ln

0,0436(8 x 103 2,0501 x 102)

8 x 103 (0,04362,0501 x 102)
4

5,4504 x 10
4
1,8479 x 10

= -28,0899 ln 2,9495
= -28,0899 x -1,0816
= 30,3820

Y5 =

1
3
( 8 x 10 )0,0436

1
= ( 3,56 x 102) ln

ln

0,0436(8 x 103 2,7044 x 102 )

8 x 103 (0,04362,7044 x 102 )

8,3032 x 104
4
1,3245 x 10

= -28,0899 -ln 6,2689

= -28,0899 x -1,8356
= 51,5618
8. Tabel titrasi
T
Menit
3
8
15
25
40

VNaOH
Sekon

(mL)
11.2
16.2
22.2
28.2
37.2

180
480
980
1500
2400

X
(M)
8,1424 x
1,1778 x
1,6139 x
2,0501 x
2,7044 x

Y
10
10-2
10-2
10-2
10-2

9. Perhitungan harga k
y=kt
y
maka ; k = t
k1 =

107,3568
180

k2 =

12,2303
480

k3 =

13,4691
980

= 0,0137m/s

k4 =

30,3820
1500

= 0,0203m/s

k5 =

51,5618
2400

= 0,0215m/s

10.

-3

= -0,5964 m/s
= -0,0255 m/s

Grafik niali y terhadap waktu

(M)
-107,3568
-12,2303
13,4691
30,3820
51,5618

Grafik nilai y terhadap waktu

80
60
40
20
0
-20 0
-40
-60
-80
-100
-120

f(x) = 0.06x - 70.75

R = 0.71

y
Linear (y)

500

1000

1500

2000

2500

3000