NAMA : SYAFAIYAH DJ HALIDA

NIM : 442415002

UTS ELSUS

Jawaban.
1. ASAM LEMAK PALMITAT(C16H32O2)
a. DBE

Untuk Menentukan Struktur Dari Asam Lemak Palmitat(C 16H32O2) Pertama Kita gunakan
Rumus DBE yaitu :

DBE = ΣC - - + +1

= 16 - + 1 = 1.

b. Reaksi Fragmentasi
C. Tabel Interpretasi
No. Harga m/z Rumus Struktur Nama Iupac Referensi
Peak
Asam Jurnal
Heksadekanoat Karakterisasi
dan
256
komposisi
minyak Biji
Alkesa
Asam
213 Pentadekanoat

199

2. SENYAWA KARBOHIDRAT C12H22O11

A. DBE

Untuk Menentukan Struktur Dari senyawa karbohidrat C 12H22O11 Pertama Kita gunakan
Rumus DBE yaitu :

DBE = ΣC - - + +1

= 12 - +1= 2

B. Reaksi Fragmentasi
 OH
OH
OH
HO HO OH OH

O
HO HO OH
O
OH

HO O O OH
HO O O
HO
HO
(2R,3R,4S,5S,6R)-2-(((2S,3S,4S,5R)-3,4-dihydroxy-2,5-bis(hydroxymethyl)tetrahydrof uran-2-yl)oxy)-6-
(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
Exact Mass: 342.12
Molecular Weight: 342.30
m/z: 342.12 (100.0%), 343.12 (13.7%), 344.12 (3.1%)
Elemental Analysis: C, 42.11; H, 6.48; O, 51.42

OH
OH

HO HO OH

OH

HO O O

HO

(2R,3R,4S,5S,6R)-2-(((1S,2S,3R,4R)-2,3-dihydroxy-1,4-bis(hydroxymethyl)cyclopentyl)oxy)-6-
(hydroxymethyl)tetrahydro-2H -pyran-3,4,5-triol
Chemical Formula: C13H24O10
Exact Mass: 340.14
Molecular Weight: 340.32
m/z: 340.14 (100.0%), 341.14 (14.7%), 342.14 (3.0%)

C. Tabel Interpretasi
No. Harga Rumus Struktur Nama Iupac Referensi
Peak m/z
(2R,3R,4S,5S,6R)-2- Buku Elusidasi
[(2S,3S,4S,5R)-3,4- Struktur
dihydroxy-2,5- Senyawa
343 bis(hydroxymethyl)oxolan-2- Organik
yl]oxy-6-
(hydroxymethyl)oxane-3,4,5-
triol
(2R,3R,4S,5S,6R)-2- Buku Elusidasi
[(1S,2S,3R,4R)-2,3- Struktur
dihydroxy-1,4- Senyawa
342 bis(hydroxymethyl)cyclopenty Organik
l)oxy)-6-
(hydroxymethyl)tetrahydro-
2H-pyran-3,4,5-triol