Nama : Ezra

NIM : 1515041 Tugas Termodinamika

Sistem binari asetonitril dan nitrometana sesuai dengan sistem tertutup hukum Raoult's.
Tekanan uap murni dari persamaan Antonie Ln P:
a) Gambar grafik yang menjelaskan Ρ vs 𝜒_11 dan Ρ vs Υ_1 untuk temperature 77℃
b) Gambar grafik yang menjelaskan t vs 𝜒_1dan t vs Υ_1 pada tekanan 72 KPa

Bagian A
T℃ TK ln P1 sat P1 sat ln P2 P2 sat
77 350.15 4.486785 88.83541 3.810454 45.17093487

Grafik Pxy asetonitril dan nitrometana pada temperature 77 °C

X1 Y1 P1 X2 Y2 P2 100
0 0 45.170935 0 0 88.83541
80
0.05 0.0937989573 47.354159 0.05 0.026064508 86.65219
0.1 0.1793300522 49.537383 0.1 0.053476367 84.46897 60

P/kPa
0.15 0.2576402906 51.720607 0.15 0.082342822 82.28574 40 X1
0.2 0.3296070545 53.903831 0.2 0.112782808 80.10252 Y1
20
0.25 0.395971115 56.087055 0.25 0.144928593 77.91929
0.3 0.457362225 58.270279 0.3 0.178927694 75.73607 0
0.35 0.5143191653 60.453503 0.35 0.214945144 73.55285 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.4 0.5673055993 62.636727 0.4 0.253166169 71.36962 X1,Y1

0.45 0.6167227233 64.819951 0.45 0.293799375 69.1864

0.5 0.662919443 67.003175 0.5 0.337080557 67.00317
0.55 0.7062006249 69.186399 0.55 0.383277277 64.81995 100
0.6 0.7468338309 71.369623 0.6 0.432694401 62.63673 90
0.65 0.785054856 73.552847 0.65 0.485680835 60.4535 80
70
0.7 0.821072306 75.736071 0.7 0.542637775 58.27028
60
0.75 0.8550714072 77.919295 0.75 0.604028885 56.08705 50 X2
P/kPa

0.8 0.8872171919 80.102519 0.8 0.670392945 53.90383 40 Y2

0.85 0.9176571782 82.285743 0.85 0.742359709 51.72061 30
0.9 0.9465236326 84.468967 0.9 0.820669948 49.53738 20
10
0.95 0.9739354916 86.65219 0.95 0.906201043 47.35416 0
1 1 88.835414 1 1 45.17093 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X2,Y2
 P 72 T℃ TK ln P1 sat P1 sat Ln P2 P2 sat X1 X2 Y1 Y2
TK 273.15 363.58 4.904776 134.9327 4.276666 72 0.0 1.0 0.0 1.0
Ln P 4.276666 360.15 4.801435 121.685 4.161597 64.17395 0.1 0.9 0.2 0.8
t1 sat K 343.8227 355.15 4.646681 104.2384 3.989042 54.00314 0.4 0.6 0.5 0.5
t2 363.5809 77 350.15 4.486785 88.83541 3.810454 45.17093 0.6 0.4 0.8 0.2
344.15 4.287756 72.80291 3.587729 36.15187 1.0 0.0 1.0 0.0

Grafik Pxy asetonitril dan nitrometana pada tekanan 72 kPa

Grafik X1,Y1 vs Temperatur pada tekanan 72 kPa Grafik X2,Y2 vs Temperatur pada tekanan 72 kPa
365.00 365.00

360.00 360.00
Temperatur (K)

Temperatur (K)
355.00 355.00

350.00 X1 350.00 X2
Y1 Y2
345.00 345.00

340.00 340.00

335.00 335.00
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
X1,Y1 X2,Y2