Lembar Kerja Peserta Didik

Titrasi Asam Basa

Kelas XI Semester 2

Nama Anggota :
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Kelompok :

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 Titrasi
Titrasi
asam
asambasa
basa

KOMPETENSI DASAR DARI KI 3 KOMPETENSI DASAR DARI KI 4

3.13. Menganalisis data hasil berbagai 4.13. Menyimpulkan hasil analisis data
jenis titrasi asam- basa. percobaan titrasi asam-basa.

IPK dari KD3 IPK dari KD4

3.13.1 Menjelaskan istilah-istilah dalam
titrasi
3.13.2 Menentukan titik akhir titrasi dan
titik ekivalen titrasi asam basa
3.13.3 Menghitung konsentrasi/kadar asam
atau basa berdasarkan data hasil
titrasi asam basa.
4.13.1 Merancang percobaan titrasi asam basa.
4.13.2 Melakukan percobaan titrasi asam-basa.
4.13.3 Menyimpulkan hasil percobaan titrasi
asam- basa.
4.13.4 Menyajikan hasil percobaan titrasi
asam-basa.

3.13.4 Membuat kurva titrasi asam basa.

3.13.5 Mendiskripsikan makna QS Al-

Qamar ayat 49.

3.13.6 Mendeskripsikan makna pepatah

Asam di gunuang garam dilawik
dalam balango batamunyo

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PETUNJUK
BELAJAR
Untuk membantu anda dalam memahami materi dalam modul ini, ikuti petunjuk belajar dibawah
ini :

Hendaklah mengingat kembali mengenai reaksi asam basa.

Cobalah untuk melengkapi isian pada setiap kegiatan secara mandiri dengan memperhatikan
keterangan yang diberikan pada LKPD ini.

Apabila Anda mengalami kesulitan dalam memahami konsep dan mengerjakan tugas
mintalah petunjuk kepada Guru.

INFORMASI

Titrasi adalah prosedur menetapkan kadar suatu larutan dengan mereaksikan sejumlah
larutan tersebut yang volumenya terukur dengan suatu larutan lain yang telah diketahui kadarnya
(larutan standar) secara bertahap.

Rumus : V1 N1 = V2 N2

N = normalitas, N = x . M , x = Valensi asam atau basa

Prinsip Titrasi Asam basa

Titrasi asam basa melibatkan asam maupun basa sebagai titer ataupun titrant. Kadar larutan
asam ditentukan dengan menggunakan larutan basa atau sebaliknya. Titrant ditambahkan titer
tetes demi tetes sampai mencapai keadaan ekuivalen ( artinya secara stoikiometri titrant dan titer
tepat habis bereaksi) yang biasanya ditandai dengan berubahnya warna indikator. Keadaan ini
disebut sebagai “titik ekuivalen”, yaitu titik dimana konsentrasi asam sama dengan konsentrasi
basa atau titik dimana jumlah basa yang ditambahkan sama dengan jumlah asam yang
dinetralkan : [H+] = [OH–]. Sedangkan keadaan dimana titrasi dihentikan dengan cara melihat

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perubahan warna indikator disebut sebagai “titik akhir titrasi”. Titik akhir titrasi ini mendekati
titik ekuivalen, tapi biasanya titik akhir titrasi melewati titik ekuivalen. Oleh karena itu, titik
akhir titrasi sering disebut juga sebagai titik ekuivalen.

Titrasi asam basa terdiri atas :

 titrasi asam kuat dengan basa kuat

 titarsi asam kuat dengan basa lemah
 titrasi asam lemah dengan basa kuat
 titrasi asam lemah dengan basa lemah atau sebaliknya tidak dianjurkan karena berjalan
lambat dan tidak tuntas

KEGIATAN 1 Menjelaskan istilah-istilah dalam titrasi

1) Jelaskan pengertian dari istilah berikut :

a. Titrasi
b. Larutan standar
c. Kurva titrasi
d. Titik ekuivalen
e. Titik akhir titrasi
f. Buret
g. Asidimetri
h. Alkalimetri
i. Standarisasi
j. Volume titrasi

Jawab :
a. ......................................................................................................................................................
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b. ......................................................................................................................................................
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c. ......................................................................................................................................................
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d. ......................................................................................................................................................
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 e. ......................................................................................................................................................
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f. ......................................................................................................................................................
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g. ......................................................................................................................................................
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h. ......................................................................................................................................................
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i. ......................................................................................................................................................
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j. ......................................................................................................................................................
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KEGIATAN 2 Praktikum menentukan titik ekuivalen dan titik akhir titrasi

penetralan asam kuat oleh basa kuat

LEMBAR KEGIATAN PRAKTIKUM

A. Judul : Titik ekuivalen titrasi asam kuat oleh basa kuat

B. Tujuan : Menentukan titik ekuivalen dan titik akhir titrasi penetralan asam kuat oleh
basa kuat

C. Alat dan bahan :

1. Buret
2. Statif
3. Erlenmeyer
4. NaOH 0,1 M
5. HCl 0,05 M
6. Indikator PP

D. Cara kerja :

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 A. Masukkan sebanyak 10 mL larutan HCl 0,05 M dalam erlenmeyer dan tambahkan
3 tetes indikator PP.
B. Isilah buret dengan larutan NaOH 0,1 M hingga tanda 0 mL
C. Lakukan titrasi NaOH 0,1 M ke dalam larutan HCl sedikit demi sedikit sambil
dikocok / digoyang
D. Hentikan titrasi saat larutan tepat berubah warna, catat volume NaOH yang
terpakai.
E. Ulangi langkah di atas sebanyak 2 kali.

E. Tabel pengamatan :

NO Volume HCl Volume NaOH Warna yang diamati

1. 10 mL .................................. ...........................................
2. 10 mL .................................. ..........................................
3. 10 mL .................................. ...........................................

A. Pertanyaan :

a. Mengapa indikator PP dapat digunakan sebagai indikator titik ekuivalen reaksi basa kuat
oleh asam kuat ?

Jawab :
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b. Tentukan titik ekuivalen titrasi ?

Jawab :
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c. Apakah pada saat titik ekuivalen jumlah mmol NaOH dan HCl sama pada ketiga
percoabaan ? Mengapa demikian ?

Jawab :
..................................................................................................................................................
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...................................................................................................................................
d. Buatlah kurva titrasi 10 mL HCl 0,05 M dengan NaOH 0, 1 M !

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 Jawab :
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Kesimpulan :

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KEGIATAN 3 Menghitung konsentrasi/kadar asam atau

basa berdasarkan data hasil titrasi asam basa.

A. Perhatikan reaksi berikut :

H3PO4 → 2H+ + HPO4-2
Apabila 10 mL larutan H3PO4 0,05 M dititrasi dengan larutan NaOH 0,1 M hingga tepat
berubah menjadi HPO4-2. Berapakah volume NaOH yang diperlukan ?
Jawab:
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 ...........................................................................................................................................................
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.

B. Untuk menentukan kadar cuka makanan (asam asetat) diambil 10 mL cuka makan,
kemudian diencerkan dengan akuades sampai volumenya 200 mL. Dari larutan encer
tersebut, diambil 10 mL, kemudian ditirasi dengan larutan NaOH 0,1 M dengan
indikator PP. Titik akhir titrasi tercapai pada saat volume NaOH 25,4 mL. Berapa kadar
cuka tersebut dalam persen jika kadar cuka murni 17,4 M?

Jawab :

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C. Larutan H2SO4 sebanyak 15,1 mL dititrasi dengan larutan NaOH 0,1 M menggunakan
indikator Fenolftalein. Pada saat volume NaOH yang ditambahkan tepat 30,2 mL warna
indikator mulai berubah. Berapakah konsentrasi H2SO4 tersebut ?
Jawab :
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KEGIATAN 4 Membuat kurva titrasi asam basa.

Buatlah kurva titrasi pada proses titrasi antara 30 mL NaOH 0,05 M dengan larutan HCl
0,1 M.

Jawab:
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Good Luck

Daftar Pustaka
Johari, J.M.C & Rachmawati, M. 2009. Kimia SMA dan MA untuk Kelas XI Jilid 2. Jakarta :
Esis.
McMurry, John E., Fay, Robert C., & Robinson, Jill K. 2016. Chemistry (7th edition). New
Jesey: Pearson Education, Inc.
Purba, Michael. 2006. Kimia 2B untuk SMA kelas XI. Jakarta : Erlangga.
Sudarmo unggul, 2016. Kimia untuk SMA/MA kelas XI Kurikulum 2013. Surakarta. Erlangga