Menghitung Neraca Massa Primary

Laju aliran gas umpan masuk = 54312 kg/hr

laju alir masa gas umpanmasuk

mol total gas umpanmasuk=
Bm rata−rata

54312
mol total gas umpan masuk= = 2900,78619 kmol/hr
18,7232

mol komponen senyawa inlet primary reformer

Mol CH4 = mol total gas umpan x fraksi mol CH4

Mol CH4 = 2900,78619 x 0,8835

= 2562,844599 kmol

Tabel 2.komposisi gas umpan masuk PR (101-B)

Komponen fraksi mol mol total(kmol) mol(kmol)
CH4 0,8835 2900,7862 2562,8446
C2H6 0,0431 2900,7862 125,0239
C3H8 0,0097 2900,7862 28,1376
I-C4H10 0,0021 2900,7862 6,0917
N-C4H10 0,0021 2900,7862 6,0917
I-C5H12 0,0010 2900,7862 2,9008
N-C5H12 0,0006 2900,7862 1,7405
CO2 0,0522 2900,7862 151,4210
N2 0,0048 2900,7862 13,9238
C6H14 0,0009 2900,7862 2,6107
Ar 0,0000 2900,7862 0,0000
H2 0,0000 2900,7862 0,0000
H2O 0,0000 2900,7862 0,0000

mol satuan ( kmol )=mol total x fraksi mol

CH4 = 2900,7862 x 0,8835

= 2562,8446

C2H6 = 2900,7862 x 0,0431

= 125,0239

C3H8 = 2900,7862 x 0,0097

= 28,1376

I-C4H10 = 2900,7862 x 0,0021

= 6,0917

N-C4H10 = 2900,7862 x 0,0021

= 6,0917
I-C5H12 = 2900,7862 x 0,0010

= 2,9008

N-C5H12 = 2900,7862 x 0,0006

= 1,7405

CO2 = 2900,7862 x 0,0522

= 151,4210

N2 = 2900,7862 x 0,0048

= 13,9238

C6H14 = 2900,7862 x 0,0009

= 2,6107

Ar = 2900,7862 x 0,0000

= 0,0000

H2 = 2900,7862 x 0,0000

= 0,0000

H2O = 2900,7862 x 0,0000

= 0,0000

*Steam

Laju alir massa steam masuk = 153441 kg/hr

BM steam = 18 kg/kmol

laju alir masa steam masuk

mol steam masuk=
BM steam ¿
¿
153441 kg/hr
mol steam masuk=
18 kg /kmol

kmol
mol steam masuk=8524,5
hr

laju alir massa masuk ke PR=Laju alir gas alam masuk+ laju alir massa steam masuk

kg kg
laju alir massa masuk ke PR=54312 +153441
hr hr

kg
laju alir massa masuk ke PR=207753
hr
Neraca mol komponen masuk Primary Reformer (101-B)

Atom C dalam CH4 = 1x 2562,8446 kmol

= 2562,8446 kmol

Atom C dalam C2H6 = 2 x 125,0239 kmol

= 250,0478 kmol

Atom C dalam C3H8 = 3 x 28,1376 kmol

= 84,4129 kmol

Tabel 5. komposisi gas keluaran PR

Komponen %mol fraksi mol
CH4 26,2600 0,2626
CO2 12,1800 0,1218
CO 4,8800 0,0488
Ar 0,0600 0,0006
N2 0,4600 0,0046
H2 56,1600 0,5616
  100,0000 1,0000
Neraca Atom C

Mol C masuk = mol C keluar

3136,3300 kmol

total % atom C=mol CH 4+ mol CO 2+mol CO

¿ 26,2600 %+12,1800 % +4,8800 %

¿ 43,3200 %

Mol CH4 keluar = (%mol CH4 / total % atom C ) x total atom C

= (26,2600 / 43,3200) x 3136,3300 kmol

= 1901,2010 kmol

Mol CO2 keluar = (%mol CO2 / total % atom C ) x total atom C

= (12,1800/43,3200) x 3136,3300 kmol

= 881,8213 kmol

Mol CO keluar = (%mol CO / total % atom C ) x total atom C

= (4,8800/43,3200) x 3136,3300 kmol

= 353,3077 kmol
 tabel 6.neraca mol komponen C keluar PR
Komponen %Mol Mol Flow
CH4 26,2600 1901,2010
CO2 12,1800 881,8213
CO 4,8800 353,3077
Total 43,3200 3136,3300

Neraca atom O

Atom O dalam CO2 = 2 x mol CO2 keluar

= 2 x 881,8213 kmol

= 1763,6426 kmol/hr

Atom O dalam CO = 1x mol CO keluar

= 1x 353,3077 kmol

= 353,3077 kmol/hr

Atom O dalam H2O = total atom O inlet- (atom O dalam CO2+atom O dalam CO)

= 8827,3421 – ( 1763,6426+353,3077)

=
Neraca Massa Secondary Reformer

Aliran Udara = 117967 Nm3/hr