Energy Balances 54 that Accouy oe! Wop Chomicat f ; tion 445 ype standard heat of formation (he for the formation of Emote of yn, "formation AML, is the special for example MpOUNE fre iar ¢ nn it at py ott eel constituent ele set C(s) HO) the standard state The initial in ‘wm. iat constant emperature, but can be “eel from the elements. By defini e for each e > CO(p) AMS and f 7 . and final 4 ‘The reaction does not Necessarily represent Products must be at 25°C and SCM a real te; a i 4 fictitious proc compound 7 “cutning the heat of to, dard tor ¢ ement, it is possible peat of formation for all compounds at 25°C tions discussed above, then the thermochemical calculations will all be consistent and you should we experience any confusion as to signs, Appendix I re ae table of the standard heats of ‘formation, In the computer disk in the back of this pook you will find heats of formation for 700 compounds provided throu zh the courtesy of Professor Yaws.5 Remember that the values for the standard heats of formation are negative for exothermic reactions, : ‘action that would pro- Ss for the formation of a rmation as zero in the to design 4 system to express the and 1 atm, tf you use the conven- EXAMPLE 5.18 Retrieval of Heats of Formation from Referer What is the standard heat of formation of HCI(g)? nce Data Solution Look in Appendix F. The column heading is Af®, and in the colurin opposite HCI(g) reads -92.311 kJ/g mol. In the reaction to form HCI(g) at 25°C and 1 atm. 4HQ(g) +4Cla(g) > HCI(g) both Hy(g) and Cl,(g) would be assigned Aff? values of 0, and the value shown in Ap- pendix F for HCI(g) of -92.311 J/g mol is the standard heat of formation for this com- Pound as well as the standard heat of reaction for the reaction as written above: AH pn = 1(-92.311) — [4 (O) + $ (O)] = 92.311 kI/g mol HCl(g) The value tabulated in Appendix F might actually be determined by carrying out the action shown for HC\(g) and measuring the heat transfer from a calorimeter, or by ‘ome other more convenient method. Scanned with CamScanner