Massa Spektroskopi Amina

dan Sulfida

KELOMPOK VI

ALI MUHAKIM
RAHMI MARATUS SOLEHA
MUTIA NUR RAHMI
MERLIN MALIMONGAN
SUHAELA
NUR HASNI
 AMINA
Ciri :
Terjadi fragmentasi pada posisi-(sebagai
base peak)
m/z ganjil: jumlah N ganjil.
m/z genap : mungkin terdapat N genap
ISOMER AMINA

NH2

NH2

NH2
 NH2 H2C NH2+ m/z = 30

m/z = 72

NH2 NH2

m/z = 44
NH2 NH2

NH2 NH2

m/z = 58
 86

CH3CH2 CH2 N CH2 CH2CH2CH3

H

72
 H

H3C N CH3
C C
H2 H2
 H H

H H2 -H
CH3 C N C CH3 CH3 C N CH2
H
m/z= 73
H H CH2

- CH3 m/z = 72

CH3 C NH2
H2C N CH2 H
m/z = 44
H CH2
m/z = 58

H2C NH2
m/z = 30
 58

100

115 (M)

menggunakan the rule of thirteen diperol

7H17N !
 CH3 CH3

H3C N CH3
H3C N CH3
CH CH
C CH
H
CH3 CH3
CH3
m/e =
m/e =
115
100
CH3
CH3
H3C N CH3
C CH H3C NH
H
C
CH2 H
H
m/e =
m/e = 58
100
Sulfida
 sulfida
C2H5HC OH C2H5HC SH
h, m/z 73 h, m/z 89

H H
C2H5 C (CH2)4 C C2H5

SCH3 OCH3

- C2H5 - CH3OH - SCH3

m/z 189 m/z 186 m/z 171

- CH3OH - CH3SH - CH3SH - CH3OH

m/z 157 m/z 141 m/z 138 m/z 139