tergantung pada posisi karbon-20 hidroksil di ginsenosides.

20 (S) -OH secara geometris

dekat dengan karbon12 hidroksil dari ginsenosides. 20 (R) -OH jauh dari karbon-12 hidroksil.
Stereokimia yang berbeda dari 20 (R) - dan 20 (S) -ginsenosides menghasilkan efek
farmakologis yang berbeda. Meskipun 20 (S) dan 20 (R) -Rg3 menunjukkan hal serupa aktivitas,
untuk pasangan ginsenosides PPD, 20 (S) -Rg3 memiliki lebih banyak efek antiproliferatif kuat
yang potensial dari 20 (R) -Rg3, menunjukkan bahwa 20 (S) -ginsenosides memiliki antikanker
yang lebih kuat potensial daripada 20 (R) -stereoisomer mereka.
Selain itu, posisi ikatan rangkap juga mempengaruhi aktivitas antikanker. Dalam ginseng
merah, jarang terjadi ginsenosides dengan struktur terdehidroksilasi diidentifikasi selama proses
mengukus. Ginsenosides Rk3 / Rh4, Rk1 / Rg5 dan Rk2 / Rh3 adalah produk dehidroksilasi dari
Rh1, Rg3, dan Rh2 masing-masing pada karbon-20. Laporan terbaru telah menunjukkan bahwa
ginsenosides Rk1 dan Rk3 dengan ganda ikatan pada C20-21 menunjukkan efek antikanker
yang lebih tinggi daripada Rg5 dan Rh4 dengan ikatan rangkap pada C20-22. Jadi, ginsenosides
dengan ikatan rangkap pada pameran C20-21 lebih efektif aktivitas antikanker dari pada C20-22.
Kesimpulan :
Ginseng, termasuk ginseng Asia, ginseng Amerika dan notoginseng, adalah beberapa herbal yang
paling umum digunakan obat. Investigasi efek ginseng pada kemoprevensi dan terapi kanker telah
menarik perhatian. Dibandingkan dengan ginseng putih yang tidak laku, aktivitas antikanker merah
ginseng meningkat secara signifikan karena ginsenosida besar dengan aktivitas antikanker yang
rendah seperti Rb1, Rg1 dan Re being dikonversi menjadi ginsenosides antikanker aktif seperti Rg3,
Rk1, Rh1, dan Rh2. Ginseng adalah tumbuhan kaya dan saponin pemrosesan uap dapat
menghasilkan jumlah aktif yang sangat tinggi ginsenosides. Selain itu, ada baiknya mengeksplorasi
lebih lanjut sistemik perbedaan komposisi kimia di antara tiga merah ginseng dan hubungan antara
turunan ginsenoside dan potensi antitumor mereka. Karena ginseng juga mengandung senyawa lain
selain saponin, bagaimana perubahan struktural dari pengaruh senyawa ginseng lainnya efek
antikanker mereka perlu dikarakterisasi lebih lanjut. Namun demikian, terungkap hubungan struktur-
aktivitas menyediakan informasi penting untuk semi-sintesis lebih lanjut turunan ginsenoside untuk
penemuan antikanker baru narkoba.
 Part 01
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