Neraca Panas

Kode : R-01 Q loss

Mereaksikan umpan Reaktor-01 berupa CO 2 dan A

H2 dengan konversi CO2 sebesar 48.80% dan ratio
B
mol CO2 dan H2 =4. Bahan CO2 dan H2 sisa akan Reaktor
keluar dari bagian atas reaktor dan produk CH3OH A
dan H2O keluar dari bagian bawah reaktor. B
Kapasitas reaktor 7000 kg/jam 1
Jenis : Reaktor Fixed bed

Fase : Gas Keterangan

Kondisi Operasi A CO2
T= 220 0C B H2
P= 50 bar = 49.35 atm C CH3OH 3
Sifat Reaksi Eksotermis (Adiabatis, Isotermal) D H2O C
𝐶𝑂2 + 3𝐻2 ↔ 𝐶𝐻3𝑂𝐻 + 𝐻2𝑂 D
∆H1 Inlet

T
referen
Componen MASS (kg/hr) MW Cp T(C) s ( C ) ∆T ( C ) ∆H1 (KJ/hr)
CO2 19723.36066 44 -64.4996878 220 25 195 (248,069,367.96)
H2 3586.065574 2 18.81158485 220 25 195 13,154,617.48
TOTAL (234,914,750.48)

∆H2 Outlet

T
referen
Componen MASS (kg/hr) MW Cp T(C) s ( C ) ∆T ( C ) ∆H2 (KJ/hr)
CO2 10098.36066 44 -64.4996878 220 25 195 (127,011,516.42)
H2 2273.565574 2 18.81158485 220 25 195 8,340,027.48
TOTAL (118,671,488.94)

∆H3 Outlet

T
referen
Componen MASS (kg/hr) MW Cp T(C) s ( C ) ∆T ( C ) ∆H3 (KJ/hr)
CH3OH 7000 32 49.18183295 220 25 195 67,133,201.98
H2O 3937.5 18 13.26735042 220 25 195 10,186,837.49
TOTAL 77,320,039.47
 Neraca Panas

∆HR Heat of Reaction ∆HR

CO2 + 3H2 CH3OH + H2O

A B C D
∆Hf, 298 (C. ∆Hfc+ D. ∆Hfd)-(A.∆Hfa+ B.∆Hfb)

From Coulson and Richardson, Appendix D, ∆Hf, 298

∆Hf, 298
Componen(kJ/mol)
CO2 -394
H2 0
CH3OH -238660
H2O -285.5
∆Hf, 298 -238551.5 ∆HR =
∆HR =

Total heat inlet from the streams

Total heat inlet from the streams (234,914,750.48) KJ/hr Q steam
Q steam
Total heat outlet from the streams
Total heat outlet from the streams (41,351,449.47) KJ/hr Kesimpulan
Panas Masuk (KJ/hr)

Q loss ∆H1
Q loss = 10% x Total heat inet from the streams = (23,491,475.05) KJ/hr ∆HR
Q Steam
TOTAL
 Neraca Panas

220 0C

220 0C
∆HR produk
∆HR reaktan

25 0C ∆Hf 25 0C

193,324,749.51 KJ/hr
(∆Hproduk+∆Hf)-(∆Hreaktan)

(23,252,923.55) KJ/hr

Panas Masuk (KJ/hr) Panas Keluar (KJ/hr)

(234,914,750.48) ∆H2 (118,671,488.94)

193,324,749.51 ∆H3 77,320,039.47
(23,252,923.55) Q loss (23,491,475.05)
(64,842,924.52) TOTAL (64,842,924.52)
 Neraca Panas

Separator Q loss

Metanol yang dihasilkan dipisahkan 2 H2

dari gas-gas impuritisnya, dan CO2
dipisahkan. Dalam hal ini tidak
terjadi reaksi. CH4
Kondisi Operasi 7000kg/jam Sepa N2
rator
T= 50 0C CH3OH 1
P= 50 bar = H2
49.35 atm CO2
CH4
N2
3 CH3OH
H2O

∆H1 Inlet

T referens
Componen MASS (kg/hr) MW Cp T(C) (C) ∆T ( C ) ∆H1 (KJ/hr)
CH3OH 4900 32 -49.181833 50 25 25 (6,024,774.54)
H2 560 2 18.8115849 50 25 25 263,362.19
CO2 1050 44 -64.499688 50 25 25 (1,693,116.80)
CH4 350 16 33.8214313 50 25 25 295,937.52
N2 140 28 31.7136509 50 25 25 110,997.78
TOTAL 406,935.30

∆H2 Outlet

T referens
Componen MASS (kg/hr) MW Cp T(C) (C) ∆T ( C ) ∆H2 (KJ/hr)
H2 560 2 18.8115849 50 25 25 263,362.19
CO2 1050 44 -64.499688 50 25 25 (1,693,116.80)
CH4 350 16 33.8214313 50 25 25 295,937.52
N2 140 28 31.7136509 50 25 25 110,997.78
TOTAL (1,022,819.31)

∆H3 Outlet

T referens
Componen MASS (kg/hr) MW Cp T(C) (C) ∆T ( C ) ∆H3 (KJ/hr)
CH3OH 4900 32 -49.181833 50 25 25 (6,024,774.54)
H2O 257.8947368 18 13.2673504 50 25 25 85,539.50
TOTAL (5,939,235.04)
 Neraca Panas

Total heat inlet from the streams

Total heat inlet from the streams 406,935.30 KJ/hr

Total heat outlet from the streams

Total heat outlet from the streams (6,962,054.36) KJ/hr

Q loss
Q loss = 10% x Total heat inet from the streams = 40,693.53 KJ/hr

∆HR
50 0C

50 0C
∆HR produk

∆HR reaktan

25 0C 25 0C

∆HR = (7,368,989.66) KJ/hr

∆HR = (∆Hproduk)-(∆Hreaktan)

Q steam
Q steam 40,693.53 KJ/hr

Kesimpulan
Panas Masuk (KJ/hr) Panas Keluar (KJ/hr)
∆H1 406,935.30 ∆H2 (1,022,819.31)
∆HR (7,368,989.66) ∆H3 (5,939,235.04)

Q Steam 40,693.53 Q loss 40,693.53

TOTAL (6,921,360.82) TOTAL (6,921,360.82)
 T(C) T ( C) ∆T ( C )
220 25 195
48400 625 47775
10648000 15625 10632375
2342560000 390625 2342169375
0.001 1E-06 1E-05
KomponenA B C D CpA CpB CpC
CO2 5.457 0.001045 0 -1.157E-05 1064.115 24.96244 0
H2 3.249 0.000422 0 8.3E-07 633.555 10.08053 0
CH3OH -51.28 0.13113 0.00013113 0 -9999.6 3132.368 464.7411113
H2O 1.25 -0.00018 -1.8E-07 0 243.75 -4.29975 -0.6379425
CH4 1.702 0.009081 -2.164E-06 0 331.89 216.9224 -7.6694865
N2 3.28 0.000593 0 4E-07 639.6 14.16529 0

KomponenA B C D
CO2 5.457 1.045 -1.157
H2 3.249 0.422 0.083
CH3OH -51.28 131.13 131.13
H2O 1.25 -0.18 -0.18
CH4 1.702 9.081 -2.164
N2 3.28 0.593 0.04
CpD cp Total
-6774.7249172 -5685.6474797 KJ/KgMol
486.00014531 1129.6356703 KJ/KgMol
0 -6402.4910138 KJ/KgMol
0 238.8123075 KJ/KgMol
0 541.142901 KJ/KgMol
234.2169375 887.982225 KJ/KgMol
Mr KJ/KG
88.15 -64.499687801
60.05 18.811584851
130.18 -49.181832952
18 13.267350417
16 33.821431313
28 31.713650893