Diyah Indriya Lestari

2B / D3 TK
1831410112 / 03

3.24
Diket :
Ca 1 2 4 6 7 9 12
-ra 0.06 0.1 0.25 1 2 1 0.5
Cao = 10 mol / liter
Ca = 2 mol / liter
Ditanya : t
Dijawab :
Interpolasi untuk menemukan nilai –ra pada Ca 8 dan 10
Nilai –ra pada Ca 8
x Y
1 7 2
2 8 ?
3 9 1
x 2−x 1 y 2− y 1
=
x 3−x 1 y 3− y 1
8−7 y 2−2
=
9−7 1−2
Y2 = 1.5
Nilai –ra pada Ca 10
x Y
1 9 1
2 10 ?
3 12 0.5
x 2−x 1 y 2− y 1
=
x 3−x 1 y 3− y 1
10−9 y 2−1
=
12−9 0.5−1
Y2 = 0.833
Ca 2 4 6 8 10
-ra 0.1 0.25 1 1.5 0.833
1/-ra 10 4 1 0.66 1.2
 Batch time
12
10
8
1/-ra

6
4
2
0
1 2 3 4 5 6 7 8 9 10 11
Ca
`

Cao 10
dCa dCa
t= ∫ =¿ ∫ =tinggi rata rata x luas area grafik ¿
Caf −ra 2 −ra

1 ( 10 ) + 4 ( 4 ) +2 (1 )+ 4 ( 0.66 )+1(1.2)
t= (10-2)
12
t = 21,24 jam

5.21
Diket :
Cao = 1.3 mol/liter
Caf = 0.3 mol/liter
Ca mol / liter -ra mol / lit.min
0.1 0.1
0.2 0.3
0.3 0.5
0.4 0.6
0.5 0.5
0.6 0.25
0.7 0.1
0.8 0.06
1 0.05
1.3 0.045
Ditanya 2 Ca -ra 0.042 1/-ra :t
Dijawab : 0.1 0.1 10
Grafik0.2 0.3 3.333333
–ra vs Ca untuk melengkapi data antara Ca= 0.8 hingga Ca=1.3
Interpolasi
0.3 untuk0.5 menemukan 2nilai –ra pada Ca 0.9 ; 1.1 ; 1,2
0.4 0.6 1.666667
0.5 0.5 2
0.6 0.25 4
0.7 0.1 10
0.8 0.06 16.66667
0.9 0.055 18.18182
1 0.05 20
1.1 0.048 20.83333
1.2 0.0465 21.50538
1.3 0.045 22.22222
 Batch Time
25

20

15
1/-ra

10

0
0 0.2 0.4 0.6 0.8 1 1.2 1.4
Ca

Karena berupa cairan, maka system kerapatanya konstan

Cao C 1.3
dCa dCa deltaCa 1 1
t=∫ =¿ ∫ = { + + … }¿
Caf −ra 0.3 −ra 2 −rao −raf
0.1 x 10 1 1 1 1 1 1 1 1 1 1 1
t= { + { + + + + + + + + }
2 5 0.45 6 5 2.5 1 0.6 0.55 0.5 0.48 0.465
t = 12.8 min

1.
Diket :
Na
=10
No
K = 0.046
Persamaan kecepatan : -ra = kCa (orde 1)
Ditanya : t
Dijawab :
Na Ca
= =10
No Coo
-ra = kCa
K (dt) = ln Ca/Cao
K t = ln Ca /Cao
ln Ca/Cao
t=
k
t = ln 10/0.046
 t = 50.056

2.
Diket :
Reaksi Penyabunan:
NaOH (aq) + C2H5(CH3CO) ---- Na(CH3CO) (aq) + C2H5OH (aq)
 Kondisi 1
M [NaOH] = 0.1 M
M [C2H5(CH3CO)] = 0.1 M
t = 15 mnt
x = 18% = 18/100 x 0.1 M =0.018M
 Kondisi 2
M [NaOH] = 0.2
M [C2H5(CH3CO)] = 0.2 M
X = 30 % = 30/100 x 0.2M = 0.06 M
m = 50 kg N (CH3COO)
Ditanya:
a) t
b) v
Dijawab :
 Kondisi 1
NaOH (aq) + C2H5(CH3CO) ---- Na(CH3CO) (aq) + C2H5OH (aq)
m : 0.1 0.1 - -
r : 0.018 0.018 0.018 0.018
s : 0.082 0.082 0.018 0.018

Sodium asetat Na(CH3CO)

Xa
=¿ k.Cao.t
1−Xa
0.18
=¿ k x 0.1 x 15
1−0.18
K = 0.1463 / menit
 Kondisi 2
Xa
=¿ k.Cao.t
1−Xa
0.3
=¿ 0.1463 x 0.1 x t
1−0.3
t = 14.627 menit
Volume yang diperlukan untuk menghasilkan 50 kg Na(CH3CO)
mol Na(CH3CO) = m/mr
= 50 kg / 72
= 0.69444 kgmol
M Na(CH3CO = n / V
0.2 = 0.694 / V
V = 3.472 liter

3.
Diket :
Kecepatan produksi asam asetat : 10 ton/hari
Reaksi : CH3COOH + C2H5OH --- CH3COOC2H5 + H2O
p etanol : 500 kg/m3
p asetat : 250 kg/m3
p campuran : 1045 kg/m3
persamaan kecepatan reaksi : -ra = kCaCb (orde 2)
T = 100 C
k = 8 x 10-6 m3/kgmoldetik
x = 30% = 0.3
A = asetat
B = etanol
Ditanya : V
Dijawab :
 Asumsi v = konstan, p = m, n = C (konsentrasi)
p B = m B = 500 kg n B = m B / mr = 500/46.06 = 10.8554 kgmol = Cbo
p A = m A = 250 kg n A = m A / mr = 250/60.05 = 4.1631 kgmol = Cao
M = Cbo/Cao = 10.8554/4.1631 = 2.6075

 Mencari nilai t
M −xa
ln =¿ (Cbo-Cao)kt
1− Xa
2.6075−0.3
ln =¿ (10.8554-4.1631). 8 x10-6 . t
1−0.3
t = 22279.5024 detik

 rxn = 0.3 x 4.1631 = 1.2489

CH3COOH + C2H5OH --- CH3COOC2H5 + H2O
t=0 4.1631 10.8554 - -
rxn 1.2489 1.2489 1,2489 1.2489
t=t 2.9142 9.6065 .2489 1.2489
Ca = 2.9142
Cb = 9.6065
 nilai –ra
-ra = k.Ca.Cb
-ra = 8x10-6. 2.9142 . 9.6065
-ra = 2.2396 x 10-4 kgmol/m3detik
 Volume Reaktor
x
dx
t=∫
0 −ra . v
0.3
dx
22279.5024 = ∫ −4
0 2.2396 x 10 . v
0.3
1
22279.5024 = ∫ dx
2.2396 x 10− 4 . v 0
0.3
22279.5024 = 4465.083/v [0.3]0
V = 0.060123 m3
V = 60.123 liter