Konsentrasi (ppm) Konsentrasi (mg/ml) Absorbansi

10 0.01 0.203
15 0.015 0.302
20 0.02 0.405
25 0.025 0.505
30 0.03 0.604
35 0.035 0.703
40 0.04 0.8

STABILITAS OBAT 1 (SUHU 60 ˚ C)

t-ke Absorbansi Konsentrasi AS (mg/ml)
0 0.302 0.0149
15 0.424 0.0211
30 0.547 0.0272
45 0.295 0.0146
60 0.344 0.0171

STABILITAS OBAT 2 (SUHU 70˚C)

t-ke Absorbansi Konsentrasi AS (mg/ml)
0 0.71 0.0354
15 0.393 0.0195
30 0.474 0.0236
45 0.556 0.0277
60 0.194 0.0095

STABILITAS OBAT 3 (SUHU 80˚C)

t-ke Absorbansi Konsentrasi AS (mg/ml)
0 0.484 0.0241
15 0.566 0.0282
30 0.648 0.0323
45 0.729 0.0364
60 0.206 0.0101

Menetukan Orde Reaksi

Suhu (˚C ) Orde Reaksi Persamaan
60 (˚C ) 1 y = -0.006x + 4.464
R² = 0.987
 70 (˚C ) 1 y = -0.033x + 4.456
R² = 0.776
80 (˚C ) 1 y = -0.057x + 4.229
R² = 0.797

Konstanta Kecepatan Reaksi (Kapp)

Suhu 60 (˚C )
t ke- ASA utuh (mg) Ln ASA Utuh
0 85.384 4.4472
15 79.4002 4.3745
30 73.3674 4.2955
45 64.3182 4.1638
60 58.3099 4.0658

Konstanta Kecepatan Reaksi (Kapp)

Suhu 70 (˚C )
t ke- ASA utuh (mg) Ln ASA utuh
0 65.3727 4.1801
15 52.3017 3.9570
30 42.3696 3.7464
45 32.3149 3.4755
60 6.8104 1.9185

Konstanta Kecepatan Reaksi (Kapp)

Suhu 80 (˚C )
t ke- ASA Utuh (mg) Ln ASA Utuh
0 41.1434 3.7171
15 31.0888 3.4368
30 21.0341 3.0461
45 11.1021 2.4071
60 0.9248 -0.0782

Persamaan Arrhenius
Suhu (˚C ) Suhu T (˚K) 1/T
60 333 0.0030
70 343 0.0029
80 353 0.0028

Nilai Kapp Suhu Ruang (25˚C )

T = 25˚C + 273
 T = 298 ˚K

Intercept = Ln α
Slope = - Ea/R
ln Kapp = - (-b).1/T + a
= -9.6310738255
Kapp = 0.00006568
T90 = 1604.7503045067 menit
= 26.7458 jam
 Persamaan Kurva Baku
y = 19.94x + 0.004 Ab
a = 0.004
0.9
b = 19.94
0.8
R²= 0.999 f(x) = 19.9428571429x + 0.0045714286
0.7 R² = 0.9999404802
0.6

Absorbansi
0.5 0.505
0.4 0.405
0.3 0.302
0.2 0.203
0.1
0
0.005 0.01 0.015 0.02 0.025
Konsentrasi (m

FP Volume sampel total (ml) Jumlah Asam Salisilat (mg)

15 50 11.2086
15 50 15.7974
15 50 20.4238
37.5 50 27.3633
37.5 50 31.9709

FP Volume sampel total (ml) Jumlah Asam Salisilat (mg)

15 50 26.5547
37.5 50 36.5785
37.5 50 44.1951
37.5 50 51.9057
150 50 71.4644

FP Volume sampel total (ml) Jumlah Asam Salisilat (mg)

37.5 50 45.1354
37.5 50 52.8460
37.5 50 60.5567
37.5 50 68.1733
150 50 75.9779
 4.5000
4.4472
4.4000 f(x) = - 0.0064895462x
4.3745 + 4.4640371536
4.3000 R² = 0.98775901964.2955
Persamaan Regresi
4.2000 4.1638
y = -0.006x + 4.464 Column C
4.1000 4.0658
R² = 0.987 Linear (Column C)
4.0000
Slope = -0.006 3.9000
Kapp = 0.006 3.8000
0 10 20 30 40 50 60 70

5.0000
4.0000 4.1801
f(x) = - 0.0333653881x + 4.4564704479
3.9570 3.7464
Persamaan Regresi R² = 0.7768913135 3.4755
3.0000
y = -0.033x + 4.456 Column C
R² = 0.776 2.0000 1.9185 Linear (Column C)
Slope = -0.033 1.0000
Kapp = 0.033 0.0000
0 10 20 30 40 50 60 70

4.0000
3.7171
f(x) = -3.4368
0.0574679731x + 4.2298417078
3.0000 R² = 0.7979223586
3.0461
Persamaan Regresi 2.4071
2.0000 Column C
y = -0.057x + 4.229
R² = 0.797 1.0000 Linear (Column C)
Slope = -0.057
0.0000 -0.0782
Kapp = 0.057 0 10 20 30 40 50 60 70
-1.0000

Persamaan Arrhenius
Kapp ln Kapp Persamaan Regresi
0.006 -5.1160 y = -13294x + 34.98
0.033 -3.4112 R² = 0.927
0.057 -2.8647 Intercept (a) = 34.98
Slope (b) = -13294
 Absorbansi

0.8
1429x + 0.0045714286
02 0.703
0.604
0.505 Absorbans
0.405 Linear (Abs
2

0.015 0.02 0.025 0.03 0.035 0.04 0.045

Konsentrasi (mg/ml)

Faktor Kesetaraan R Aspirin terdegradasi (mg) Aspirin awal (mg)

1.304 14.6160 100
1.304 20.5998 100
1.304 26.6326 100
1.304 35.6818 100
1.304 41.6901 100

Faktor Kesetaraan R Aspirin terdegradasi (mg) Aspirin awal (mg)

1.304 34.6273 100
1.304 47.6983 100
1.304 57.6304 100
1.304 67.6851 100
1.304 93.1896 100

Faktor Kesetaraan R Aspirin terdegradasi (mg) Aspirin awal (mg)

1.304 58.8566 100
1.304 68.9112 100
1.304 78.9659 100
1.304 88.8979 100
1.304 99.0752 100
 Column C
58 Linear (Column C)

70

Column C
85 Linear (Column C)

Column C
Linear (Column C)

782
0

0.0000
0.0028 0.0029 0.0029 0.0030 0.0030 0.0031
-1.0000

-2.0000

-2.8647 Column E
-3.0000 f(x) = - 13294.2427476635x + 34.983390965
R² = 0.927877342-3.4112 Linear (Column E)
-4.0000

-5.0000 -5.1160

-6.0000
-3.0000 f(x) = - 13294.2427476635x + 34.983390965
R² = 0.927877342-3.4112 Linear (Column E)
-4.0000

-5.0000 -5.1160

-6.0000
0.8

Absorbansi
Linear (Absorbansi)

0.04 0.045

Aspirin utuh (mg)

85.3840
79.4002
73.3674
64.3182
58.3099

Aspirin utuh (mg)

65.3727
52.3017
42.3696
32.3149
6.8104

Aspirin utuh (mg)

41.1434
31.0888
21.0341
11.1021
0.9248