BAB III

NERACA MASSA DAN ENERGI

3.1 Neraca Massa

A. Akumulator (AC-01)
Komponen: Laju Alir (Kg/jam):
Acetaldehyde 0,7446
VAM 0,8130
Air 1,8152
Asam Asetat 1423,4536 +
TOTAL 1426,8264

Komponen: Laju Alir (Kg/jam):

Komponen: Laju Alir (Kg/jam):
Acetaldehyde 4,9828
Acetaldehyde 5,7273
Air 11,7684 6
VAM 6,2538
Asam Asetat 7844,2429 +
1 2 Air 13,9630
TOTAL 7860,9941 AC-01
Asam Asetat 10949,6431 +
TOTAL 10975,5872
43

Komponen: Laju Alir (Kg/jam):

VAM 5,4408
Air 0,3794
Asam Asetat 1681,9466 +
TOTAL 1687,7668
B. Separator (S-01)

Komponen: Laju Alir (Kg/jam): Komponen: Laju Alir (Kg/jam):

Acetaldehyde 5,7273 Acetaldehyde 4,9828
VAM 6,2538
4 5 VAM 5,4408
Air 13,9630 S-01
S-01
Air 12,1478
Asam Asetat 10949,6431 + Asam Asetat 9526,1895 +
TOTAL 10975,5872 6 TOTAL 9548,7609

Komponen: Laju Alir (Kg/jam):

Acetaldehyde 0,7446
VAM 0,8130
Air 1,8152
Asam Asetat 1423,4536 +
TOTAL 1426,8264

C. Akumulator (AC-02)

Komponen: Laju Alir (Kg/jam): Komponen: Laju Alir (Kg/jam):

Metana 0,9064 Nitrogen 15,8291
Etilena 2047,3926 Argon 11,2883
Etana 3,3986 + Oksigen 389,4782
TOTAL 2051,6976 9 10
AC-02
S-01 Metana 3,6996
Etilena 8356,2228
Etana 13,8712 +
35
TOTAL 8790,3892
Komponen: Laju Alir (Kg/jam):
Nitrogen 15,8291
Argon 11,2883
Oksigen 389,4782
Metana 2,7931
Etilena 6308,8302
Etana 10,4726 +
TOTAL 6738,6915
 D. Akumulator (AC-03)
Komponen: Laju Alir (Kg/jam):
Nitrogen 48,7756
Argon 34,7838
Oksigen 711,1017 +
TOTAL 794,6611 Komponen: Laju Alir (Kg/jam):
Nitrogen 64,6047
Komponen: Argon 46,0721
Laju Alir (Kg/jam):
Nitrogen Oksigen 1100,5799
15,8291
16 Metana
Argon 11,2883 3,6996
Oksigen Etilena 8356,2228
389,4782
12 17
Metana 3,6996 AC-03
S-01 Etana 13,8712
Etilena Acetaldehyde 4,9828
8356,2228
Etana VAM 5,4408
13,8712 + 7
TOTAL Air 12,1478
8790,3892
Asam Asetat 9526,1895 +
Komponen: Laju Alir (Kg/jam): TOTAL 19133,8114
Acetaldehyde 4,9828
VAM 5,4408
Air 12,1478
Asam Asetat 9526,1895 +
TOTAL 9548,7609

E. Reaktor (R-01)
Komponen: Komponen: Laju Alir (Kg/jam):
Laju Alir (Kg/jam):
Nitrogen Nitrogen 64,6047
64,6047
Argon Argon 46,0721
46,0721
Oksigen Oksigen 553,8068
1100,5799
Metana Metana 3,6996
3,6996
Etilena Etilena 6308,8302
8356,2228 18 19
R-01 Etana 13,8712
Etana 13,8712
Acetaldehyde CO2 19,0355
4,9828
VAM Acetaldehyde 4,9828
5,4408
Air VAM 6957,7646
12,1478
Asam Asetat Air 485,1874
9526,1895 +
TOTAL Asam Asetat 4675,9565 +
19133,8114
TOTAL 19133,8114
F. KO-Drum (KO-01)
Komponen: Laju Alir (Kg/jam):
Nitrogen 64,6047
Komponen: Laju Alir (Kg/jam): Argon 46,0721
Nitrogen 64,6047 Oksigen 553,8068
Argon 46,0721 Metana 3,6996
22
Oksigen 553,8068 Etilena 6308,8302
Metana 3,6996 20 Etana 13,8712
KO-01
S-01
Etilena 6308,8302 CO2 19,0355 +
Etana 13,8712 TOTAL 7009,9201
CO2 19,0355 21
Acetaldehyde 4,9828
VAM 6957,7646
Air 485,1874 Komponen: Laju Alir (Kg/jam):
Asam Asetat 4675,9565 + Acetaldehyde 4,9828
TOTAL 19133,8114 VAM 6957,7646
Air 485,1874
Asam Asetat 4675,9565 +
TOTAL 12123,8913

G. Absorber (AB-01)
Komponen: Laju Alir (Kg/jam):
Komponen: Laju Alir (Kg/jam):
Nitrogen 64,6047
Air 10,6781
Argon 46,0721
CO2 26,0935
33 Oksigen 515,8748
MEA 77,5981 +
32 Metana 3,6996
TOTAL 114,3697
Etilena 6308,8302
Etana 13,8712 +
Komponen: Laju Alir (Kg/jam): AB-01 TOTAL 6952,9525
Nitrogen 64,6047
Argon 46,0721
22 Komponen: Laju Alir (Kg/jam):
Oksigen 553,8068
Oksigen 37,9320
Metana 3,6996
CO2 10,6781
Etilena 6308,8302
Air 45,1290
Etana 13,8712 23
MEA 77,5981 +
CO2 19,0355 +
TOTAL 171,3372
TOTAL 7009,9201
H. Valve Purging (VLV-05)
Komponen: Laju Alir (Kg/jam):
Nitrogen 48,7756
Argon 34,7838
Oksigen 126,3966
Metana 0,9064
Etana 3,3986 +
TOTAL 214,2610

Komponen: Laju Alir (Kg/jam): Komponen: Laju Alir (Kg/jam):

Nitrogen 64,6047 Nitrogen 15,8291
Argon 46,0721 34 Argon 11,2883
Oksigen 515,8748 Oksigen 389,4782
33 35
Metana 3,6996 EV-03
S-01
Metana 2,7931
Etilena 6308,8302 Etilena 6308,8302
Etana 13,8712 + Etana 10,4726 +
TOTAL 6952,9525 TOTAL 6738,6916

I. Stripper (ST-01)
26
Komponen: Laju Alir (Kg/jam):
Oksigen 37,9320
CO2 45,1290
Air 3,2034 +
Komponen: Laju Alir (Kg/jam):
TOTAL 86,2644
Oksigen 37,9320
CO2 45,1290
ST-01
Air 10,6781 25
MEA 77,5981 +
TOTAL 171,3372

Komponen: Laju Alir (Kg/jam):

Air 7,4747
27 MEA 77,5981 +
TOTAL 85,0728
 J. Destilasi (MD-01)

39 Komponen: Laju Alir (Kg/jam):

Acetaldehyde 4,9828
Komponen: Laju Alir (Kg/jam): VAM 6942,6511
Acetaldehyde 4,9828 Air 484,1334
VAM 6957,7646 Asam Asetat 3,8826 +
Air 485,1874 TOTAL 7435,6499
Asam Asetat 4675,9565 +
MD-01
TOTAL 12123,8913 38

Komponen: Laju Alir (Kg/jam):

VAM 15,1135
Air 1,0539
40 Asam Asetat 4672,0739 +
TOTAL 4688,2413

K. Reboiler (E-05)

Komponen: Laju Alir (Kg/jam):

VAM 9,6726
Air 0,6745
Asam Asetat 2990,1273 +
TOTAL 3000,4744

41

40 42
EV-03
S-01
Komponen: Laju Alir (Kg/jam): Komponen: Laju Alir (Kg/jam):
VAM 15,1135 VAM 5,4408
Air 1,0539 Air 0,3794
Asam Asetat 4672,0739 + Asam Asetat 1681,9466 +
TOTAL 4688,2413 TOTAL 1687,7668
 L. Dekanter (D-01)

Komponen: Laju Alir (Kg/jam):

Acetaldehyde 4,9828 Komponen: Laju Alir (Kg/jam):
VAM 6942,6511 Acetaldehyde 4,9828
Air 484,1334 VAM 6942,6511
Asam Asetat 3,8826 + Air 0,7268 +
TOTAL 7435,6499 45 47 TOTAL
AC-02
S-01 6948,3607

46

Komponen: Laju Alir (Kg/jam):

Air 483,4067
Asam Asetat 3,8826 +
TOTAL 487,2893

M. Flash Drum (S-02)

Komponen: Laju Alir (Kg/jam):
49 Acetaldehyde 3,9162 +
TOTAL 3,9162
Komponen: Laju Alir (Kg/jam):
Acetaldehyde 4,9828
48
VAM 6942,6511 S-02
S-01
Air 0,7268 +
TOTAL 6948,3607 50

Komponen: Laju Alir (Kg/jam):

Acetaldehyde 1,0666
VAM 6942,6511
Air 0,7268 +
TOTAL 6944,4445
3.2 Neraca Energi

A. Pompa Asam Asetat (P-01)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

B. Pompa Absorber (P-02)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

C. Pompa Stipper (P-03)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

D. Pompa Destilasi (P-04)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar
E. Pompa Recycle Asam Asetat (P-05)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

F. Pompa Dekanter (P-06)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

G. Pompa Flash Drum (P-07)

Q = 190727,2767 J/s

T = 96,75oC
3 4 T = 199,7oC
VP-01
P = 8 bar
P = 8 bar

H. Kompresor (K-01)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar
I. Cooler 1 (C-01)

T = 123,8oC 20 21 T = 95,24oC
E-01
P = 10 bar P = 8,9 bar

Qh = -699444,4444 J/s

J. Cooler 2 (C-02)

T = 123,8oC 20 21 T = 95,24oC
E-01
P = 10 bar P = 8,9 bar

Qh = -699444,4444 J/s

K. Heater Gas Etilena (E-01)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

L. Heater Gas Oksigen (E-02)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar
M. Heater Umpan Reaktor (E-03)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

N. Heater Umpan Destilasi (E-04)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

O. Heat Exchanger (HE-01)

Qc = 956861,9439 J/s

Tc,in = 106,1oC Tc,out = 150oC

Pc,in = 10 bar 17 18
Pc,out = 10 bar
20 HE-01 19
Th,out = 123,8oC Th,in = 150oC
Ph,out = 8,9 bar Ph,in = 10 bar

Qh = -956861,9439 J/s
 P. Vaporizer (VP-01)

W =739,7492 J/s

T = 199,711oC 5 7 T =210,8oC
P-01
P = 8 bar P = 10 bar

Q. Menara Destilasi (MD-01)

Q=

T = 95,07oC
P = 1,5 bar
T = 119 oC
Q = -2,75x104 J/s
P = 1,5 bar MD-01
Q = -6575x105 J/s T = 98oC
P = 1,5 bar
Q = -6319x105 J/s

Q=

R. Absorber (AB-01)

Q=

T = 64,56oC
T = 60 oC
P = 8,8 bar
P = 8,8 bar
Q = -2564x104 J/s
Q = -5278x105 J/s AB-01

o
T = 27,2oC
T = 120 C
P = 8,8 bar
P = 8,8 bar
Q = -6167x105 J/s
Q = -6327x104 J/s
Q=
 S. Stripper MEA (ST-01)

T = 95,07oC
P = 1,5 bar
T = 119 oC
Q = -2,75x104 J/s
P = 1,5 bar MD-01
5
Q = -6575x10 J/s T = 98oC
P = 1,5 bar
Q = -6319x105 J/s

Q=

T. Separator (S-01)

Q=

T = 64,56oC
T = 60 oC
P = 8,8 bar
P = 8,8 bar
5
Q = -2564x104 J/s
Q = -5278x10 J/s AB-01
T = 27,2oC
T = 120 oC
P = 8,8 bar
P = 8,8 bar
4
Q = -6167x105 J/s
Q = -6327x10 J/s
Q=

U. Knock Out Drum (KO-01)

T = 64,56oC
T = 60 oC
P = 8,8 bar
P = 8,8 bar
Q = -2564x104 J/s
Q = -5278x105 J/s AB-01
T = 27,2oC
T = 120 oC
P = 8,8 bar
P = 8,8 bar
Q = -6167x105 J/s
Q = -6327x104 J/s
 V. Dekanter (D-01)

T = 64,56oC
T = 60 oC
P = 8,8 bar
P = 8,8 bar
5
Q = -2564x104 J/s
Q = -5278x10 J/s AB-01
T = 27,2oC
T = 120 oC
P = 8,8 bar
P = 8,8 bar
4
Q = -6167x105 J/s
Q = -6327x10 J/s

W. Flash Drum (FD-01)

T = 64,56oC
T = 60 oC
P = 8,8 bar
P = 8,8 bar
5
Q = -2564x104 J/s
Q = -5278x10 J/s AB-01
T = 27,2oC
T = 120 oC
P = 8,8 bar
P = 8,8 bar
4
Q = -6167x105 J/s
Q = -6327x10 J/s

X. Reaktor Fixbed Multi Tulbular (R-01)

Q=

T = 64,56oC
T = 60 oC
P = 8,8 bar
P = 8,8 bar
5
Q = -2564x104 J/s
Q = -5278x10 J/s AB-01
T = 27,2oC
T = 120 oC
P = 8,8 bar
P = 8,8 bar
4
Q = -6167x105 J/s
Q = -6327x10 J/s
Q=